CN104212242B - 一种喷墨用石墨烯与碳纳米管导电油墨的制备方法 - Google Patents
一种喷墨用石墨烯与碳纳米管导电油墨的制备方法 Download PDFInfo
- Publication number
- CN104212242B CN104212242B CN201410441770.XA CN201410441770A CN104212242B CN 104212242 B CN104212242 B CN 104212242B CN 201410441770 A CN201410441770 A CN 201410441770A CN 104212242 B CN104212242 B CN 104212242B
- Authority
- CN
- China
- Prior art keywords
- ink
- graphene
- preparation
- solvent
- dispersion liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 98
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 45
- 238000002360 preparation method Methods 0.000 title claims abstract description 35
- 239000002041 carbon nanotube Substances 0.000 title claims abstract description 29
- 229910021393 carbon nanotube Inorganic materials 0.000 title claims abstract description 29
- 239000006185 dispersion Substances 0.000 claims abstract description 54
- 239000007788 liquid Substances 0.000 claims abstract description 42
- 238000000498 ball milling Methods 0.000 claims abstract description 27
- 238000000034 method Methods 0.000 claims abstract description 19
- 238000001914 filtration Methods 0.000 claims abstract description 9
- 238000005406 washing Methods 0.000 claims abstract description 9
- 230000008569 process Effects 0.000 claims abstract description 7
- 239000002904 solvent Substances 0.000 claims description 43
- 239000000203 mixture Substances 0.000 claims description 22
- 229910002804 graphite Inorganic materials 0.000 claims description 18
- 239000010439 graphite Substances 0.000 claims description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- 229920000178 Acrylic resin Polymers 0.000 claims description 9
- 239000004925 Acrylic resin Substances 0.000 claims description 9
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 9
- 239000003223 protective agent Substances 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 9
- 229920005989 resin Polymers 0.000 claims description 9
- 239000011347 resin Substances 0.000 claims description 9
- 239000004593 Epoxy Substances 0.000 claims description 8
- 238000013019 agitation Methods 0.000 claims description 8
- 238000012216 screening Methods 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 7
- 150000001298 alcohols Chemical class 0.000 claims description 6
- 229920000180 alkyd Polymers 0.000 claims description 6
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- 239000001913 cellulose Substances 0.000 claims description 6
- 229920002678 cellulose Polymers 0.000 claims description 6
- 239000003822 epoxy resin Substances 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- 239000003999 initiator Substances 0.000 claims description 6
- 150000002576 ketones Chemical class 0.000 claims description 6
- 229920000647 polyepoxide Polymers 0.000 claims description 6
- 239000007962 solid dispersion Substances 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 239000013530 defoamer Substances 0.000 claims description 5
- 238000004821 distillation Methods 0.000 claims description 5
- 229920001225 polyester resin Polymers 0.000 claims description 5
- 239000004645 polyester resin Substances 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 229920001213 Polysorbate 20 Polymers 0.000 claims description 4
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 4
- 235000002906 tartaric acid Nutrition 0.000 claims description 4
- 239000011975 tartaric acid Substances 0.000 claims description 4
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical group [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 3
- 229920002907 Guar gum Polymers 0.000 claims description 3
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 3
- 239000002033 PVDF binder Substances 0.000 claims description 3
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 3
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 claims description 3
- 150000001299 aldehydes Chemical class 0.000 claims description 3
- 239000010775 animal oil Substances 0.000 claims description 3
- 230000000844 anti-bacterial effect Effects 0.000 claims description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 3
- 229910021383 artificial graphite Inorganic materials 0.000 claims description 3
- JBANFLSTOJPTFW-UHFFFAOYSA-N azane;boron Chemical compound [B].N JBANFLSTOJPTFW-UHFFFAOYSA-N 0.000 claims description 3
- 235000011089 carbon dioxide Nutrition 0.000 claims description 3
- 238000005119 centrifugation Methods 0.000 claims description 3
- HGAZMNJKRQFZKS-UHFFFAOYSA-N chloroethene;ethenyl acetate Chemical compound ClC=C.CC(=O)OC=C HGAZMNJKRQFZKS-UHFFFAOYSA-N 0.000 claims description 3
- 239000007822 coupling agent Substances 0.000 claims description 3
- 239000003431 cross linking reagent Substances 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 239000002270 dispersing agent Substances 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- 239000010408 film Substances 0.000 claims description 3
- 239000000665 guar gum Substances 0.000 claims description 3
- 235000010417 guar gum Nutrition 0.000 claims description 3
- 229960002154 guar gum Drugs 0.000 claims description 3
- 229930195733 hydrocarbon Natural products 0.000 claims description 3
- 150000002430 hydrocarbons Chemical class 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 239000002480 mineral oil Substances 0.000 claims description 3
- 235000010446 mineral oil Nutrition 0.000 claims description 3
- 239000000178 monomer Substances 0.000 claims description 3
- 239000002048 multi walled nanotube Substances 0.000 claims description 3
- 150000007524 organic acids Chemical class 0.000 claims description 3
- 235000006408 oxalic acid Nutrition 0.000 claims description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 3
- 229920001568 phenolic resin Polymers 0.000 claims description 3
- 239000005011 phenolic resin Substances 0.000 claims description 3
- 239000004014 plasticizer Substances 0.000 claims description 3
- 229920002401 polyacrylamide Polymers 0.000 claims description 3
- 229940113115 polyethylene glycol 200 Drugs 0.000 claims description 3
- 229940068918 polyethylene glycol 400 Drugs 0.000 claims description 3
- 229920001721 polyimide Polymers 0.000 claims description 3
- 239000009719 polyimide resin Substances 0.000 claims description 3
- 229920000053 polysorbate 80 Polymers 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 229920005749 polyurethane resin Polymers 0.000 claims description 3
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 3
- 239000002109 single walled nanotube Substances 0.000 claims description 3
- 239000003381 stabilizer Substances 0.000 claims description 3
- 239000013008 thixotropic agent Substances 0.000 claims description 3
- 239000000080 wetting agent Substances 0.000 claims description 3
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 229920000128 polypyrrole Polymers 0.000 claims description 2
- 229920003051 synthetic elastomer Polymers 0.000 claims description 2
- 239000005061 synthetic rubber Substances 0.000 claims description 2
- 239000002562 thickening agent Substances 0.000 claims description 2
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 2
- 239000001993 wax Substances 0.000 claims description 2
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 claims 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 2
- OSNIIMCBVLBNGS-UHFFFAOYSA-N 1-(1,3-benzodioxol-5-yl)-2-(dimethylamino)propan-1-one Chemical compound CN(C)C(C)C(=O)C1=CC=C2OCOC2=C1 OSNIIMCBVLBNGS-UHFFFAOYSA-N 0.000 claims 1
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 claims 1
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 claims 1
- 125000002252 acyl group Chemical group 0.000 claims 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 claims 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 229920006122 polyamide resin Polymers 0.000 claims 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims 1
- 239000002245 particle Substances 0.000 abstract description 9
- 238000005516 engineering process Methods 0.000 abstract description 7
- 239000008187 granular material Substances 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 3
- 238000005229 chemical vapour deposition Methods 0.000 abstract description 2
- 238000000227 grinding Methods 0.000 abstract description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 4
- -1 graphite alkene Chemical class 0.000 description 4
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 4
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 4
- 229910052709 silver Inorganic materials 0.000 description 4
- 239000004332 silver Substances 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- 230000000903 blocking effect Effects 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 2
- 229920006387 Vinylite Polymers 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000002322 conducting polymer Substances 0.000 description 2
- 229920001940 conductive polymer Polymers 0.000 description 2
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- PHNWGDTYCJFUGZ-UHFFFAOYSA-N hexyl dihydrogen phosphate Chemical compound CCCCCCOP(O)(O)=O PHNWGDTYCJFUGZ-UHFFFAOYSA-N 0.000 description 2
- 238000007641 inkjet printing Methods 0.000 description 2
- WFKAJVHLWXSISD-UHFFFAOYSA-N isobutyramide Chemical compound CC(C)C(N)=O WFKAJVHLWXSISD-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002071 nanotube Substances 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 229940116411 terpineol Drugs 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- HBGPNLPABVUVKZ-POTXQNELSA-N (1r,3as,4s,5ar,5br,7r,7ar,11ar,11br,13as,13br)-4,7-dihydroxy-3a,5a,5b,8,8,11a-hexamethyl-1-prop-1-en-2-yl-2,3,4,5,6,7,7a,10,11,11b,12,13,13a,13b-tetradecahydro-1h-cyclopenta[a]chrysen-9-one Chemical compound C([C@@]12C)CC(=O)C(C)(C)[C@@H]1[C@H](O)C[C@]([C@]1(C)C[C@@H]3O)(C)[C@@H]2CC[C@H]1[C@@H]1[C@]3(C)CC[C@H]1C(=C)C HBGPNLPABVUVKZ-POTXQNELSA-N 0.000 description 1
- PFRGGOIBYLYVKM-UHFFFAOYSA-N 15alpha-hydroxylup-20(29)-en-3-one Natural products CC(=C)C1CCC2(C)CC(O)C3(C)C(CCC4C5(C)CCC(=O)C(C)(C)C5CCC34C)C12 PFRGGOIBYLYVKM-UHFFFAOYSA-N 0.000 description 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 1
- SOKRNBGSNZXYIO-UHFFFAOYSA-N Resinone Natural products CC(=C)C1CCC2(C)C(O)CC3(C)C(CCC4C5(C)CCC(=O)C(C)(C)C5CCC34C)C12 SOKRNBGSNZXYIO-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- PRPAGESBURMWTI-UHFFFAOYSA-N [C].[F] Chemical compound [C].[F] PRPAGESBURMWTI-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 1
- 229910001863 barium hydroxide Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000002079 cooperative effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 229910021392 nanocarbon Inorganic materials 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410441770.XA CN104212242B (zh) | 2014-09-02 | 2014-09-02 | 一种喷墨用石墨烯与碳纳米管导电油墨的制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410441770.XA CN104212242B (zh) | 2014-09-02 | 2014-09-02 | 一种喷墨用石墨烯与碳纳米管导电油墨的制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104212242A CN104212242A (zh) | 2014-12-17 |
CN104212242B true CN104212242B (zh) | 2016-08-24 |
Family
ID=52094164
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201410441770.XA Expired - Fee Related CN104212242B (zh) | 2014-09-02 | 2014-09-02 | 一种喷墨用石墨烯与碳纳米管导电油墨的制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN104212242B (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102665173B1 (ko) * | 2021-10-20 | 2024-05-21 | 주식회사 지브이엘 | 전도성 잉크 및 이의 제조방법 |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105622832B (zh) * | 2016-02-19 | 2017-07-04 | 成都新柯力化工科技有限公司 | 一种涂料用石墨烯微球的制备方法 |
CN106085201A (zh) * | 2016-08-05 | 2016-11-09 | 代长华 | 一种氧化石墨烯导电涂料及其制备方法 |
CN107298901A (zh) * | 2017-08-28 | 2017-10-27 | 厦门大学 | 一种碳系导电油墨 |
CN108323023B (zh) * | 2018-01-16 | 2020-07-17 | 湖南国盛石墨科技有限公司 | 一种基于热固化石墨烯导电油墨印刷方法 |
CN108373660A (zh) * | 2018-05-11 | 2018-08-07 | 山东省圣泉生物质石墨烯研究院 | 一种导电墨水及其制备方法 |
CN111326274B (zh) * | 2018-12-13 | 2022-01-28 | 山东欧铂新材料有限公司 | 一种高分散稳定性的改性石墨烯复合浆料及其制备方法 |
CN110117440B (zh) * | 2019-05-10 | 2021-11-05 | 齐鲁工业大学 | 一种导电墨水及其制备方法 |
CN114174219A (zh) * | 2019-06-25 | 2022-03-11 | 堪萨斯州立大学研究基金会 | 用于打印和涂覆的碳纳米材料的纳米油墨 |
CN110895998A (zh) * | 2019-11-22 | 2020-03-20 | 西安交通大学 | 一种电极材料墨汁、制备方法及利用其制备微型超级电容器的方法 |
CN112254850B (zh) * | 2020-08-28 | 2022-01-11 | 苏州烯时代材料科技有限公司 | 柔性压力传感器用导电碳浆及其制备方法和压力传感器 |
CN113683920B (zh) * | 2021-08-11 | 2022-12-27 | 哈工大机器人(中山)无人装备与人工智能研究院 | 一种高温石墨烯导电油墨、微晶板及其制备方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20120062451A (ko) * | 2010-12-06 | 2012-06-14 | 도레이첨단소재 주식회사 | 전도성 잉크 및 이를 이용한 투명전극 |
CN102942906A (zh) * | 2012-11-28 | 2013-02-27 | 上海第二工业大学 | 一种高导热、低粘度水基含复合导热填料纳米流体及其制备方法 |
CN103436074A (zh) * | 2013-08-05 | 2013-12-11 | 南昌大学 | 一种水性导电墨的制备方法 |
CN103456520A (zh) * | 2012-05-31 | 2013-12-18 | 海洋王照明科技股份有限公司 | 一种石墨烯/碳纳米管复合薄膜的制备方法及其应用 |
CN103733271A (zh) * | 2011-08-22 | 2014-04-16 | 拜耳知识产权有限责任公司 | 包含碳纳米管和石墨烯片材的分散体 |
WO2014070500A1 (en) * | 2012-10-29 | 2014-05-08 | 3M Innovative Properties Company | Conductive inks and conductive polymeric coatings |
-
2014
- 2014-09-02 CN CN201410441770.XA patent/CN104212242B/zh not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20120062451A (ko) * | 2010-12-06 | 2012-06-14 | 도레이첨단소재 주식회사 | 전도성 잉크 및 이를 이용한 투명전극 |
CN103733271A (zh) * | 2011-08-22 | 2014-04-16 | 拜耳知识产权有限责任公司 | 包含碳纳米管和石墨烯片材的分散体 |
CN103456520A (zh) * | 2012-05-31 | 2013-12-18 | 海洋王照明科技股份有限公司 | 一种石墨烯/碳纳米管复合薄膜的制备方法及其应用 |
WO2014070500A1 (en) * | 2012-10-29 | 2014-05-08 | 3M Innovative Properties Company | Conductive inks and conductive polymeric coatings |
CN102942906A (zh) * | 2012-11-28 | 2013-02-27 | 上海第二工业大学 | 一种高导热、低粘度水基含复合导热填料纳米流体及其制备方法 |
CN103436074A (zh) * | 2013-08-05 | 2013-12-11 | 南昌大学 | 一种水性导电墨的制备方法 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102665173B1 (ko) * | 2021-10-20 | 2024-05-21 | 주식회사 지브이엘 | 전도성 잉크 및 이의 제조방법 |
Also Published As
Publication number | Publication date |
---|---|
CN104212242A (zh) | 2014-12-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN104212242B (zh) | 一种喷墨用石墨烯与碳纳米管导电油墨的制备方法 | |
CN104517664A (zh) | 基于石墨烯团簇的碳系电热浆料、其制备方法及应用 | |
CN107384026B (zh) | 一种水性石墨烯/碳纳米管复合电热转化油墨及制备方法 | |
CN108047822B (zh) | 利用剪切增稠体系剥离石墨制备石墨烯导热散热复合材料的方法 | |
CN108133768A (zh) | 一种高电导率低温固化型导电浆料及其制备方法 | |
CN102925100B (zh) | 一种高导热性能导电银胶及其制备方法 | |
CN105131607A (zh) | 点、线、面三维立体碳材料复合导热硅胶及其制备方法 | |
CN104058393B (zh) | 一种剥离层状三维材料得到片层二维材料的方法 | |
CN103374207B (zh) | 一种环氧复合材料及其制备方法 | |
CN105819435A (zh) | 原位修饰的还原氧化石墨烯及其制备方法 | |
CN105504999A (zh) | 一种双组份导电油墨及其制备方法 | |
Wang et al. | Functional inks for printable energy storage applications based on 2 D materials | |
CN108597676B (zh) | 一种含有有机膨润土低温固化银浆的制备方法和应用 | |
CN107236165B (zh) | 一种具有隔离结构的橡胶/石墨烯复合材料的制备方法 | |
CN1205730A (zh) | 制造油墨的方法 | |
CN106047242A (zh) | 一种环氧树脂基导电胶及其制备方法 | |
CN109206853A (zh) | 一种高导热环氧树脂基复合材料、及其制备方法和应用 | |
CN106433316B (zh) | 一种纳米银线喷墨导电墨水的制备方法 | |
CN110467782A (zh) | 一种碳纳米管塑料导电复合材料及其湿法制备工艺 | |
CN107069008A (zh) | 硅碳负极材料及其制备方法 | |
CN103949649B (zh) | 一种水性体系下制备片状铜粉的方法 | |
CN103897345A (zh) | TiO2/PU-EP复合材料的制备方法 | |
CN105754330A (zh) | 一种pa66纳米导电复合材料 | |
CN109979681A (zh) | 一种复合碳纳米管纳米银浆的制备方法 | |
CN103467925B (zh) | 环氧树脂/纳米铜/碳纳米管热界面复合材料及其制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20170714 Address after: 226000 Jiangsu province Nantong Luyuan Chongchuan District No. 7 South Building Room 101 Co-patentee after: Nanjing University of Aeronautics and Astronautics Patentee after: Li Juan Address before: 226000, Zhenxing Road, Nantong economic and Technological Development Zone, Jiangsu 19, China Co-patentee before: Nanjing University of Aeronautics and Astronautics Patentee before: Jiangsu Gemei High-Tech Development Co., Ltd. |
|
TR01 | Transfer of patent right | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160824 Termination date: 20170902 |
|
CF01 | Termination of patent right due to non-payment of annual fee |