CN104169263B - 在蒸汽存在下由己糖溶液制备5-羟甲基糠醛(hmf) - Google Patents

在蒸汽存在下由己糖溶液制备5-羟甲基糠醛(hmf) Download PDF

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Publication number
CN104169263B
CN104169263B CN201280059056.3A CN201280059056A CN104169263B CN 104169263 B CN104169263 B CN 104169263B CN 201280059056 A CN201280059056 A CN 201280059056A CN 104169263 B CN104169263 B CN 104169263B
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China
Prior art keywords
hmf
starting solution
solution
steam
fructose
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Expired - Fee Related
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CN201280059056.3A
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English (en)
Chinese (zh)
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CN104169263A (zh
Inventor
R·贝克斯
B·布兰科
A·金德勒
C·菲尔内尔
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BASF SE
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BASF SE
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Furan Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201280059056.3A 2011-12-13 2012-12-11 在蒸汽存在下由己糖溶液制备5-羟甲基糠醛(hmf) Expired - Fee Related CN104169263B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11193157.2 2011-12-13
EP11193157 2011-12-13
PCT/EP2012/075055 WO2013087613A1 (de) 2011-12-13 2012-12-11 Herstellung von 5-hydroxymethylfurfural (hmf) aus hexoselösungen in gegenwart von wasserdampf

Publications (2)

Publication Number Publication Date
CN104169263A CN104169263A (zh) 2014-11-26
CN104169263B true CN104169263B (zh) 2016-06-15

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Family Applications (1)

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CN201280059056.3A Expired - Fee Related CN104169263B (zh) 2011-12-13 2012-12-11 在蒸汽存在下由己糖溶液制备5-羟甲基糠醛(hmf)

Country Status (10)

Country Link
EP (1) EP2791126B1 (cg-RX-API-DMAC7.html)
JP (1) JP6073363B2 (cg-RX-API-DMAC7.html)
KR (1) KR101970853B1 (cg-RX-API-DMAC7.html)
CN (1) CN104169263B (cg-RX-API-DMAC7.html)
BR (1) BR112014014054B1 (cg-RX-API-DMAC7.html)
CA (1) CA2856864C (cg-RX-API-DMAC7.html)
ES (1) ES2626835T3 (cg-RX-API-DMAC7.html)
HU (1) HUE033363T2 (cg-RX-API-DMAC7.html)
RU (1) RU2014128460A (cg-RX-API-DMAC7.html)
WO (1) WO2013087613A1 (cg-RX-API-DMAC7.html)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9156802B2 (en) 2011-12-13 2015-10-13 Basf Se Separating off 5-hydroxymethylfurfural (HMF) from reaction solutions by steam distillation
DE102016224073A1 (de) * 2016-12-02 2018-06-07 Südzucker AG Verbessertes HMF-Herstellungsverfahren
JP2022529935A (ja) * 2019-04-15 2022-06-27 ストラ エンソ オーユーイー 溶媒の回収方法、腐植質の単離方法、および溶媒または腐植質からなる組成物

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2929823A (en) * 1956-11-26 1960-03-22 Merck & Co Inc Production of 5-hydroxymethylfurfural
US3201331A (en) * 1962-10-17 1965-08-17 Atlas Chem Ind Purification of hydroxymethyl furfural
FR2663933A1 (fr) * 1990-06-27 1992-01-03 Beghin Say Sa Nouveau procede de preparation du 5-hydroxymethylfurfural a partir de saccharides.
CN101456850A (zh) * 2007-12-12 2009-06-17 中国科学院大连化学物理研究所 一种制备5-羟甲基糠醛的方法
CN101812039A (zh) * 2010-05-14 2010-08-25 天津大学 一种利用离子液体催化生成5-羟甲基糠醛的方法
CN102399203A (zh) * 2011-12-19 2012-04-04 浙江大学 一种离子液体降解碳水化合物制备5-羟甲基糠醛的方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3601281A1 (de) 1986-01-17 1987-07-23 Sueddeutsche Zucker Ag Verfahren zur herstellung von 5-hydroxymethylfurfural einschliesslich eines kristallinen produktes unter ausschliesslicher verwendung von wasser als loesungsmittel
EP1834950A1 (en) 2006-03-10 2007-09-19 Avantium International B.V. Method for the synthesis of 5-alkoxymethylfurfural ethers and their use
ATE473218T1 (de) 2006-03-10 2010-07-15 Furanix Technologies Bv Verwendung organischer säureester von 5- hydroxymethylfurfural
EP2033958A1 (en) * 2007-09-07 2009-03-11 Furanix Technologies B.V Hydroxymethylfurfural ethers from sugars and di- and triols

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2929823A (en) * 1956-11-26 1960-03-22 Merck & Co Inc Production of 5-hydroxymethylfurfural
US3201331A (en) * 1962-10-17 1965-08-17 Atlas Chem Ind Purification of hydroxymethyl furfural
FR2663933A1 (fr) * 1990-06-27 1992-01-03 Beghin Say Sa Nouveau procede de preparation du 5-hydroxymethylfurfural a partir de saccharides.
CN101456850A (zh) * 2007-12-12 2009-06-17 中国科学院大连化学物理研究所 一种制备5-羟甲基糠醛的方法
CN101812039A (zh) * 2010-05-14 2010-08-25 天津大学 一种利用离子液体催化生成5-羟甲基糠醛的方法
CN102399203A (zh) * 2011-12-19 2012-04-04 浙江大学 一种离子液体降解碳水化合物制备5-羟甲基糠醛的方法

Non-Patent Citations (7)

* Cited by examiner, † Cited by third party
Title
5-Hydroxymethylfurfural (HMF) as a building block platform: Biological properties, synthesis and synthetic applications;Andreia A. Rosatella et al.;《Green Chemistry》;20110228;第13卷;第754-793页 *
5-Hydroxymethylfurfural (HMF). A Review Focussing on its Manufacture;B. F. M. Kuster et al.;《Starch/starke》;19901231;第42卷;第314-321页 *
Catalytic pyrolysis of cellulose in sulfolane with some acidic catalysts;Haruo Kawamoto et al.;《J. Wood Sci.》;20061202;第53卷;第127-133页 *
Production of 5-hydroxymethylfurfural and furfural by dehydration of biomass-derived mono- and poly-saccharides;Juben N. Chheda et al.;《Green Chemistry》;20070117;第9卷;第342-350页 *
The Conversion of Fructose and Glucose in Acidic Media: Formation of Hydroxymethylfurfural;H. E. van Dam et al.;《Starch/starke》;19861231;第38卷;第95-101页 *
水蒸气蒸馏技术在精细化学品生产中的应用;张珍明;《化工时刊》;20040625;第18卷(第6期);第48-49页 *
薄膜蒸发器的应用;尹侠等;《化工设备与防腐蚀》;20020620;第5卷(第3期);第188-189页 *

Also Published As

Publication number Publication date
JP6073363B2 (ja) 2017-02-01
WO2013087613A1 (de) 2013-06-20
ES2626835T3 (es) 2017-07-26
BR112014014054B1 (pt) 2019-03-19
HUE033363T2 (en) 2017-11-28
EP2791126B1 (de) 2017-03-01
JP2015500313A (ja) 2015-01-05
CA2856864C (en) 2021-05-25
KR101970853B1 (ko) 2019-04-19
CN104169263A (zh) 2014-11-26
RU2014128460A (ru) 2016-02-10
EP2791126A1 (de) 2014-10-22
CA2856864A1 (en) 2013-06-20
BR112014014054A2 (pt) 2017-06-13
KR20140101849A (ko) 2014-08-20

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