CN104168980A - 选择性酸性气体分离的胺处理方法 - Google Patents

选择性酸性气体分离的胺处理方法 Download PDF

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Publication number
CN104168980A
CN104168980A CN201380013802.XA CN201380013802A CN104168980A CN 104168980 A CN104168980 A CN 104168980A CN 201380013802 A CN201380013802 A CN 201380013802A CN 104168980 A CN104168980 A CN 104168980A
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China
Prior art keywords
amine
gas
acid gas
reaction
contact
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CN201380013802.XA
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English (en)
Chinese (zh)
Inventor
R·B·费迪施
P·科图诺夫
M·西什金
H·托曼
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ExxonMobil Technology and Engineering Co
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ExxonMobil Research and Engineering Co
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Publication of CN104168980A publication Critical patent/CN104168980A/zh
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493—Selection of liquid materials for use as absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1462—Removing mixtures of hydrogen sulfide and carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1468—Removing hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20405—Monoamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/2041—Diamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20426—Secondary amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20478—Alkanolamines
    • B01D2252/20484—Alkanolamines with one hydroxyl group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/40—Absorbents explicitly excluding the presence of water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/304—Hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/50—Sulfur oxides
    • B01D53/508—Sulfur oxides by treating the gases with solids

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Gas Separation By Absorption (AREA)
  • Treating Waste Gases (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN201380013802.XA 2012-03-14 2013-03-13 选择性酸性气体分离的胺处理方法 Pending CN104168980A (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201261610727P 2012-03-14 2012-03-14
US61/610,727 2012-03-14
US13/793,410 US20130243677A1 (en) 2012-03-14 2013-03-11 Amine treating process for selective acid gas separation
US13/793,410 2013-03-11
PCT/US2013/030780 WO2013138437A2 (en) 2012-03-14 2013-03-13 Amine treating process for selective acid gas separations

Publications (1)

Publication Number Publication Date
CN104168980A true CN104168980A (zh) 2014-11-26

Family

ID=49157833

Family Applications (1)

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CN201380013802.XA Pending CN104168980A (zh) 2012-03-14 2013-03-13 选择性酸性气体分离的胺处理方法

Country Status (10)

Country Link
US (1) US20130243677A1 (enExample)
EP (1) EP2825289A2 (enExample)
JP (1) JP2015517897A (enExample)
KR (1) KR20140134321A (enExample)
CN (1) CN104168980A (enExample)
CA (1) CA2867284A1 (enExample)
IN (1) IN2014DN07127A (enExample)
PE (1) PE20142110A1 (enExample)
RU (1) RU2618829C2 (enExample)
WO (1) WO2013138437A2 (enExample)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108136317A (zh) * 2015-09-29 2018-06-08 巴斯夫欧洲公司 用于选择性移除硫化氢的方法
CN109715267A (zh) * 2016-09-14 2019-05-03 埃克森美孚上游研究公司 与增强的选择性污染物除去方法相关的设备和系统
CN109868167A (zh) * 2019-03-27 2019-06-11 长沙而道新能源科技有限公司 一种沼气发电的方法
CN110382084A (zh) * 2017-02-10 2019-10-25 巴斯夫欧洲公司 从流体料流中除去酸性气体的方法

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US10722863B2 (en) 2011-10-18 2020-07-28 The Regents Of The University Of California Cooperative chemical adsorption of acid gases in functionalized metal-organic frameworks
EP2768608A4 (en) 2011-10-18 2015-06-03 Univ California ALKYLAMINE-FUNCTIONALIZED METAL-ORGANIC FRAMING MATERIALS FOR COMPOSITE GAS SEPARATION
EP3027293A1 (en) * 2013-07-29 2016-06-08 ExxonMobil Research and Engineering Company Separation of hydrogen sulfide from natural gas
AU2015227041B2 (en) 2014-03-05 2018-02-15 Bechtel Energy Technologies & Solutions, Inc. Systems and methods for enhanced separation of hydrogen sulfide and ammonia in a hydrogen sulfide stripper
JP2017518169A (ja) * 2014-04-22 2017-07-06 ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア 官能化された金属−有機フレームワーク内における酸性ガスの協同化学吸着
FR3021049B1 (fr) * 2014-05-16 2016-05-27 Ifp Energies Now Nouvelles diamines tertiaires beta-hydroxylees, leur procede de synthese et leur utilisation pour l'elimination de composes acides d'un effluent gazeux
US9453174B2 (en) 2014-06-26 2016-09-27 Uop Llc Apparatuses and methods for removing impurities from a hydrocarbon stream
KR101658448B1 (ko) 2014-06-27 2016-09-30 한국에너지기술연구원 천연가스에 포함된 산성가스 및 수분 제거를 위한 다단계 혼성 장치 및 방법
US9962644B2 (en) * 2015-12-28 2018-05-08 Exxonmobil Research And Engineering Company Process for increased selectivity and capacity for hydrogen sulfide capture from acid gases
KR102170273B1 (ko) * 2019-02-27 2020-10-28 한국에너지기술연구원 이산화탄소 흡수제 및 이를 이용한 이산화탄소 포집방법
KR20230023723A (ko) 2020-06-09 2023-02-17 글로벌 써모스탯 오퍼레이션스, 엘엘씨 연속-동작 직접 공기 포집 시스템
EP4178711A4 (en) 2020-07-07 2024-08-07 ExxonMobil Technology and Engineering Company PROCESS FOR ACID GAS WASHING WITH AMINE PHASE SEPARATION FOR HYDROGEN SULPHIDE SEPARATION
CN119255856A (zh) 2022-05-27 2025-01-03 零碳系统公司 高吞吐量移动面板直接空气捕获系统
CN117000306B (zh) * 2023-08-04 2025-01-24 天津大学 一种硫化氢氧化制硫催化剂及其制备方法

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CN1356157A (zh) * 2001-09-26 2002-07-03 南化集团研究院 从含二氧化碳的气体混合物中选择性脱除硫化物的溶剂
CN1421264A (zh) * 2002-12-11 2003-06-04 南化集团研究院 从气体混合物中脱除硫化物的吸收液

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108136317A (zh) * 2015-09-29 2018-06-08 巴斯夫欧洲公司 用于选择性移除硫化氢的方法
CN109715267A (zh) * 2016-09-14 2019-05-03 埃克森美孚上游研究公司 与增强的选择性污染物除去方法相关的设备和系统
CN110382084A (zh) * 2017-02-10 2019-10-25 巴斯夫欧洲公司 从流体料流中除去酸性气体的方法
CN110382084B (zh) * 2017-02-10 2023-01-17 巴斯夫欧洲公司 从流体料流中除去酸性气体的方法
CN109868167A (zh) * 2019-03-27 2019-06-11 长沙而道新能源科技有限公司 一种沼气发电的方法

Also Published As

Publication number Publication date
IN2014DN07127A (enExample) 2015-04-24
CA2867284A1 (en) 2013-09-19
PE20142110A1 (es) 2015-01-04
JP2015517897A (ja) 2015-06-25
KR20140134321A (ko) 2014-11-21
US20130243677A1 (en) 2013-09-19
RU2014139221A (ru) 2016-05-10
WO2013138437A2 (en) 2013-09-19
RU2618829C2 (ru) 2017-05-11
EP2825289A2 (en) 2015-01-21
WO2013138437A3 (en) 2013-11-07

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Application publication date: 20141126