RU2618829C2 - Способ обработки аминами для селективного отделения кислых газов - Google Patents

Способ обработки аминами для селективного отделения кислых газов Download PDF

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RU2618829C2
RU2618829C2 RU2014139221A RU2014139221A RU2618829C2 RU 2618829 C2 RU2618829 C2 RU 2618829C2 RU 2014139221 A RU2014139221 A RU 2014139221A RU 2014139221 A RU2014139221 A RU 2014139221A RU 2618829 C2 RU2618829 C2 RU 2618829C2
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compound
amine
gas
reaction
amines
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RU2014139221A
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Russian (ru)
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RU2014139221A (ru
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Роберт Б. ФЕДИЧ
Павел КОРТУНОВ
Майкл СИСКИН
Ханс ТОМАНН
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ЭкссонМобил Рисерч энд Энджиниринг Компани
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493Selection of liquid materials for use as absorbents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456Removing acid components
    • B01D53/1462Removing mixtures of hydrogen sulfide and carbon dioxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456Removing acid components
    • B01D53/1468Removing hydrogen sulfide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20Organic absorbents
    • B01D2252/204Amines
    • B01D2252/20405Monoamines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20Organic absorbents
    • B01D2252/204Amines
    • B01D2252/2041Diamines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20Organic absorbents
    • B01D2252/204Amines
    • B01D2252/20426Secondary amines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20Organic absorbents
    • B01D2252/204Amines
    • B01D2252/20478Alkanolamines
    • B01D2252/20484Alkanolamines with one hydroxyl group
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/40Absorbents explicitly excluding the presence of water
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/304Hydrogen sulfide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • B01D53/508Sulfur oxides by treating the gases with solids

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Gas Separation By Absorption (AREA)
  • Treating Waste Gases (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
RU2014139221A 2012-03-14 2013-03-13 Способ обработки аминами для селективного отделения кислых газов RU2618829C2 (ru)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201261610727P 2012-03-14 2012-03-14
US61/610,727 2012-03-14
US13/793,410 US20130243677A1 (en) 2012-03-14 2013-03-11 Amine treating process for selective acid gas separation
US13/793,410 2013-03-11
PCT/US2013/030780 WO2013138437A2 (en) 2012-03-14 2013-03-13 Amine treating process for selective acid gas separations

Publications (2)

Publication Number Publication Date
RU2014139221A RU2014139221A (ru) 2016-05-10
RU2618829C2 true RU2618829C2 (ru) 2017-05-11

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RU2014139221A RU2618829C2 (ru) 2012-03-14 2013-03-13 Способ обработки аминами для селективного отделения кислых газов

Country Status (10)

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US (1) US20130243677A1 (enExample)
EP (1) EP2825289A2 (enExample)
JP (1) JP2015517897A (enExample)
KR (1) KR20140134321A (enExample)
CN (1) CN104168980A (enExample)
CA (1) CA2867284A1 (enExample)
IN (1) IN2014DN07127A (enExample)
PE (1) PE20142110A1 (enExample)
RU (1) RU2618829C2 (enExample)
WO (1) WO2013138437A2 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2786848C1 (ru) * 2021-12-17 2022-12-26 Борис Семенович Ксенофонтов Способ очистки газовых выбросов от углекислого газа

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013059527A1 (en) 2011-10-18 2013-04-25 The Regents Of The University Of California Alkylamine functionalized metal-organic frameworks for composite gas separations
US10722863B2 (en) 2011-10-18 2020-07-28 The Regents Of The University Of California Cooperative chemical adsorption of acid gases in functionalized metal-organic frameworks
US20150027055A1 (en) * 2013-07-29 2015-01-29 Exxonmobil Research And Engineering Company Separation of hydrogen sulfide from natural gas
EA201691564A1 (ru) * 2014-03-05 2017-02-28 Бектел Гидрокарбон Текнолоджи Солушенз, Инк. Системы и способы для усовершенствованного разделения сероводорода и аммиака в отпарной колонне сероводорода
CA2945783C (en) * 2014-04-22 2023-10-03 The Regents Of The University Of California Cooperative chemical adsorption of acid gases in functionalized metal-organic frameworks
FR3021049B1 (fr) 2014-05-16 2016-05-27 Ifp Energies Now Nouvelles diamines tertiaires beta-hydroxylees, leur procede de synthese et leur utilisation pour l'elimination de composes acides d'un effluent gazeux
US9453174B2 (en) 2014-06-26 2016-09-27 Uop Llc Apparatuses and methods for removing impurities from a hydrocarbon stream
KR101658448B1 (ko) 2014-06-27 2016-09-30 한국에너지기술연구원 천연가스에 포함된 산성가스 및 수분 제거를 위한 다단계 혼성 장치 및 방법
CN108136317A (zh) * 2015-09-29 2018-06-08 巴斯夫欧洲公司 用于选择性移除硫化氢的方法
US9962644B2 (en) 2015-12-28 2018-05-08 Exxonmobil Research And Engineering Company Process for increased selectivity and capacity for hydrogen sulfide capture from acid gases
CA3035598A1 (en) * 2016-09-14 2018-03-22 Exxonmobil Upstream Research Company Apparatus and system for enhanced selective contaminant removal processes related thereto
CN110382084B (zh) * 2017-02-10 2023-01-17 巴斯夫欧洲公司 从流体料流中除去酸性气体的方法
KR102170273B1 (ko) * 2019-02-27 2020-10-28 한국에너지기술연구원 이산화탄소 흡수제 및 이를 이용한 이산화탄소 포집방법
CN109868167B (zh) * 2019-03-27 2021-03-16 长沙而道新能源科技有限公司 一种沼气发电的方法
CN116348412A (zh) 2020-06-09 2023-06-27 全球温控营运有限责任公司 连续运动直接空气捕集系统
US12325004B2 (en) 2020-07-07 2025-06-10 Exxonmobil Technology & Engineering Company Acid gas scrubbing methods featuring amine phase separation for hydrogen sulfide capture
AU2023276583A1 (en) 2022-05-27 2024-11-28 Zero Carbon Systems, Inc. High throughput moving panel direct air capture system
CN117000306B (zh) * 2023-08-04 2025-01-24 天津大学 一种硫化氢氧化制硫催化剂及其制备方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1543748A (en) * 1975-06-10 1979-04-04 Basf Ag Removal of co2 and/or h2s from cracked gases
US4405583A (en) * 1982-01-18 1983-09-20 Exxon Research And Engineering Co. Process for selective removal of H2 S from mixtures containing H22 using di-severely sterically hindered secondary aminoethers
EP0672446A2 (en) * 1994-03-18 1995-09-20 The Kansai Electric Power Co., Inc. Method for the removal of hydrogen sulfide present in gases
RU2227060C2 (ru) * 1998-06-29 2004-04-20 Басф Акциенгезельшафт Способ удаления газовых компонентов кислотного характера из газов
WO2010086334A1 (de) * 2009-01-29 2010-08-05 Basf Se Aminosäure und sauren Promotor enthaltendes Absorptionsmittel zum Entfernen saurer Gase
RU2010101220A (ru) * 2007-06-18 2011-07-27 Мицубиси Хеви Индастриз, Лтд. (Jp) Абсорбент, установка для снижения содержания co2 или h2s и способ снижения содержания co2 или h2s с использованием абсорбента

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4405581A (en) 1982-01-18 1983-09-20 Exxon Research And Engineering Co. Process for the selective removal of hydrogen sulfide from gaseous mixtures with severely sterically hindered secondary amino compounds
US4471138A (en) 1982-01-18 1984-09-11 Exxon Research And Engineering Co. Severely sterically hindered secondary aminoether alcohols
US4405585A (en) 1982-01-18 1983-09-20 Exxon Research And Engineering Co. Process for the selective removal of hydrogen sulfide from gaseous mixtures with severely sterically hindered secondary aminoether alcohols
US4816121A (en) 1983-10-03 1989-03-28 Keefer Bowie Gas phase chemical reactor
US4801308A (en) 1983-10-03 1989-01-31 Keefer Bowie Apparatus and process for pressure swing adsorption separation
US4894178A (en) 1987-10-13 1990-01-16 Exxon Research And Engineering Company Absorbent composition containing severely-hindered amine mixture for the absorption of H2 S
US4968329A (en) 1987-10-26 1990-11-06 Keefer Bowie Pressure swing adsorption for concentration of a gas component
US5102643A (en) 1990-01-25 1992-04-07 Mobil Oil Corp. Composition of synthetic porous crystalline material, its synthesis
US5057296A (en) 1990-12-10 1991-10-15 Mobil Oil Corp. Method for synthesizing mesoporous crystalline material
US5108725A (en) 1990-01-25 1992-04-28 Mobil Oil Corp. Synthesis of mesoporous crystalline material
US5082473A (en) 1990-07-23 1992-01-21 Keefer Bowie Extraction and concentration of a gas component
US5256172A (en) 1992-04-17 1993-10-26 Keefer Bowie Thermally coupled pressure swing adsorption
US5618506A (en) * 1994-10-06 1997-04-08 The Kansai Electric Power Co., Inc. Process for removing carbon dioxide from gases
US6063161A (en) 1996-04-24 2000-05-16 Sofinoy Societte Financiere D'innovation Inc. Flow regulated pressure swing adsorption system
JPH10139419A (ja) 1996-11-11 1998-05-26 Yukong Ltd 非結晶性中間細孔モレキュラーシーブの製造方法及びそのモレキュラーシーブ
US6051050A (en) 1997-12-22 2000-04-18 Questor Industries Inc. Modular pressure swing adsorption with energy recovery
AU5381200A (en) 1999-06-09 2001-01-02 Questair Technologies, Inc. Rotary pressure swing adsorption apparatus
US6691702B2 (en) 2000-08-03 2004-02-17 Sequal Technologies, Inc. Portable oxygen concentration system and method of using the same
US6651658B1 (en) 2000-08-03 2003-11-25 Sequal Technologies, Inc. Portable oxygen concentration system and method of using the same
CN1171659C (zh) * 2001-09-26 2004-10-20 南化集团研究院 从含二氧化碳的气体混合物中选择性脱除硫化物的溶剂
CN1219579C (zh) * 2002-12-11 2005-09-21 南化集团研究院 从气体混合物中脱除硫化物的吸收液
CA2540240A1 (en) 2003-09-29 2005-04-14 Questair Technologies Inc. High density adsorbent structures
US7166149B2 (en) 2004-01-12 2007-01-23 Uop Llc Adsorption process for continuous purification of high value gas feeds
US20060048648A1 (en) 2004-08-20 2006-03-09 Questair Technologies Inc. Parallel passage contactor structure
US7645324B2 (en) 2005-01-07 2010-01-12 Xebec Adsorption Inc. Engineered adsorbent structures for kinetic separation
KR101384413B1 (ko) 2005-08-09 2014-04-10 엑손모빌 리서치 앤드 엔지니어링 컴퍼니 산 가스 세정 공정을 위한 알킬아미노 알킬옥시 (알코올)모노알킬 에터
US8529662B2 (en) 2007-05-18 2013-09-10 Exxonmobil Research And Engineering Company Removal of heavy hydrocarbons from gas mixtures containing heavy hydrocarbons and methane
US8221712B2 (en) * 2009-05-12 2012-07-17 Basf Se Absorption medium for the selective removal of hydrogen sulfide from fluid streams

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1543748A (en) * 1975-06-10 1979-04-04 Basf Ag Removal of co2 and/or h2s from cracked gases
US4405583A (en) * 1982-01-18 1983-09-20 Exxon Research And Engineering Co. Process for selective removal of H2 S from mixtures containing H22 using di-severely sterically hindered secondary aminoethers
EP0672446A2 (en) * 1994-03-18 1995-09-20 The Kansai Electric Power Co., Inc. Method for the removal of hydrogen sulfide present in gases
RU2227060C2 (ru) * 1998-06-29 2004-04-20 Басф Акциенгезельшафт Способ удаления газовых компонентов кислотного характера из газов
RU2010101220A (ru) * 2007-06-18 2011-07-27 Мицубиси Хеви Индастриз, Лтд. (Jp) Абсорбент, установка для снижения содержания co2 или h2s и способ снижения содержания co2 или h2s с использованием абсорбента
WO2010086334A1 (de) * 2009-01-29 2010-08-05 Basf Se Aminosäure und sauren Promotor enthaltendes Absorptionsmittel zum Entfernen saurer Gase

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2786848C1 (ru) * 2021-12-17 2022-12-26 Борис Семенович Ксенофонтов Способ очистки газовых выбросов от углекислого газа

Also Published As

Publication number Publication date
JP2015517897A (ja) 2015-06-25
EP2825289A2 (en) 2015-01-21
KR20140134321A (ko) 2014-11-21
WO2013138437A2 (en) 2013-09-19
RU2014139221A (ru) 2016-05-10
WO2013138437A3 (en) 2013-11-07
PE20142110A1 (es) 2015-01-04
CA2867284A1 (en) 2013-09-19
IN2014DN07127A (enExample) 2015-04-24
US20130243677A1 (en) 2013-09-19
CN104168980A (zh) 2014-11-26

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