CN104136467B - 具有改善的熔体强度的基于乙烯的聚合物及其方法 - Google Patents
具有改善的熔体强度的基于乙烯的聚合物及其方法 Download PDFInfo
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- CN104136467B CN104136467B CN201280070142.4A CN201280070142A CN104136467B CN 104136467 B CN104136467 B CN 104136467B CN 201280070142 A CN201280070142 A CN 201280070142A CN 104136467 B CN104136467 B CN 104136467B
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- Prior art keywords
- stable hydrocarbon
- ethene
- polymkeric substance
- hydrogen
- replacement
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- Expired - Fee Related
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- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims abstract description 95
- 239000000126 substance Substances 0.000 title claims abstract description 87
- 238000000034 method Methods 0.000 title claims description 29
- 239000000155 melt Substances 0.000 title description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 137
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 137
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 137
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 68
- 239000001257 hydrogen Substances 0.000 claims abstract description 68
- 239000000178 monomer Substances 0.000 claims abstract description 56
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims abstract description 32
- 239000012986 chain transfer agent Substances 0.000 claims abstract description 24
- 239000000203 mixture Substances 0.000 claims description 46
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 30
- 125000000217 alkyl group Chemical group 0.000 claims description 28
- 125000001118 alkylidene group Chemical group 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 150000002431 hydrogen Chemical group 0.000 abstract description 33
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 28
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 26
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 25
- 238000006243 chemical reaction Methods 0.000 description 20
- 239000003999 initiator Substances 0.000 description 19
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 14
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 14
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 14
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 14
- 229920000642 polymer Polymers 0.000 description 14
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 12
- 239000005977 Ethylene Substances 0.000 description 12
- -1 density Chemical compound 0.000 description 10
- 238000006116 polymerization reaction Methods 0.000 description 10
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 10
- 238000000576 coating method Methods 0.000 description 9
- 229920001038 ethylene copolymer Polymers 0.000 description 9
- 150000003254 radicals Chemical class 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 8
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 7
- 239000004711 α-olefin Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 229920001684 low density polyethylene Polymers 0.000 description 6
- 239000004702 low-density polyethylene Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000011541 reaction mixture Substances 0.000 description 6
- 238000012546 transfer Methods 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 150000002978 peroxides Chemical class 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 4
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 4
- 230000009466 transformation Effects 0.000 description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 238000010526 radical polymerization reaction Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 description 2
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N 1-nonene Chemical compound CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- XYFRHHAYSXIKGH-UHFFFAOYSA-N 3-(5-methoxy-2-methoxycarbonyl-1h-indol-3-yl)prop-2-enoic acid Chemical compound C1=C(OC)C=C2C(C=CC(O)=O)=C(C(=O)OC)NC2=C1 XYFRHHAYSXIKGH-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 2
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 2
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 150000003053 piperidines Chemical class 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000005086 pumping Methods 0.000 description 2
- 229920006300 shrink film Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 0 *C(*)=C(C(N)=O)C(OIOC(C(I)=C)=O)=O Chemical compound *C(*)=C(C(N)=O)C(OIOC(C(I)=C)=O)=O 0.000 description 1
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical class CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 101000643895 Homo sapiens Ubiquitin carboxyl-terminal hydrolase 6 Proteins 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 1
- 102100021015 Ubiquitin carboxyl-terminal hydrolase 6 Human genes 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 238000000333 X-ray scattering Methods 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- NLDGJRWPPOSWLC-UHFFFAOYSA-N deca-1,9-diene Chemical group C=CCCCCCCC=C NLDGJRWPPOSWLC-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000001739 density measurement Methods 0.000 description 1
- 239000012933 diacyl peroxide Substances 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical group CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 150000002976 peresters Chemical class 0.000 description 1
- 150000004978 peroxycarbonates Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000010094 polymer processing Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000001175 rotational moulding Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N sec-butylidene Natural products CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 229960000834 vinyl ether Drugs 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161579067P | 2011-12-22 | 2011-12-22 | |
| US61/579,067 | 2011-12-22 | ||
| PCT/US2012/068727 WO2013095969A1 (en) | 2011-12-22 | 2012-12-10 | Ethylene-based polymers with improved melt strength and processes for the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104136467A CN104136467A (zh) | 2014-11-05 |
| CN104136467B true CN104136467B (zh) | 2016-01-20 |
Family
ID=47470201
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280070142.4A Expired - Fee Related CN104136467B (zh) | 2011-12-22 | 2012-12-10 | 具有改善的熔体强度的基于乙烯的聚合物及其方法 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US9388260B2 (enExample) |
| EP (1) | EP2794675B1 (enExample) |
| JP (1) | JP6042906B2 (enExample) |
| KR (1) | KR101989335B1 (enExample) |
| CN (1) | CN104136467B (enExample) |
| AR (1) | AR089419A1 (enExample) |
| BR (1) | BR112014015135A2 (enExample) |
| ES (1) | ES2564545T3 (enExample) |
| IN (1) | IN2014CN04648A (enExample) |
| MX (1) | MX360854B (enExample) |
| WO (1) | WO2013095969A1 (enExample) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104507982B (zh) | 2012-06-27 | 2017-06-20 | 陶氏环球技术有限责任公司 | 基于乙烯的聚合物以及用于其的方法 |
| US9394389B2 (en) | 2012-11-20 | 2016-07-19 | Dow Global Technologies Llc | Low density ethylene-based polymers with high melt strength |
| ES2637970T3 (es) | 2013-05-22 | 2017-10-18 | Dow Global Technologies Llc | Composiciones poliméricas basadas en etileno de baja densidad con alta resistencia en estado fundido y control de densidad medio-alto |
| KR102284307B1 (ko) * | 2013-12-26 | 2021-08-04 | 다우 글로벌 테크놀로지스 엘엘씨 | 비대칭 폴리엔을 이용하여 에틸렌계 중합체의 제조를 위한 반응기 안정성을 개선하는 방법 |
| CN106170472B (zh) | 2013-12-26 | 2020-04-14 | 陶氏环球技术有限责任公司 | 用于锂盐催化的酯基转移过程的抑制剂组合和用于移除锂盐的方法 |
| WO2015100318A1 (en) * | 2013-12-26 | 2015-07-02 | Dow Global Technologies Llc | Processes to form ethylene-based polymers using asymmetrical polyenes |
| WO2015200426A1 (en) * | 2014-06-27 | 2015-12-30 | Dow Global Technologies Llc | Ethylene-based polymers comprising units derived from carbon monoxide and a rheology modifying agent |
| US9856338B2 (en) | 2014-06-27 | 2018-01-02 | Dow Global Technologies Llc | Processes to prepare ethylene-based polymers using a distribution of carbon monoxide |
| WO2016209381A1 (en) | 2015-06-24 | 2016-12-29 | Dow Global Technologies Llc | Processes to prepare ethylene-based polymers with improved melt-strength |
| ES2786677T3 (es) | 2015-06-25 | 2020-10-13 | Dow Global Technologies Llc | Proceso para formar polímeros basados en etileno |
| EP3313902B1 (en) | 2015-06-25 | 2023-07-19 | Dow Global Technologies LLC | A process for producing an ethylene-based polymer |
| EP3313894B1 (en) | 2015-06-25 | 2019-12-18 | Dow Global Technologies LLC | Improved process to make tubular ethylene based polymers with high g' and broad mwd |
| US10400046B2 (en) | 2015-06-25 | 2019-09-03 | Joseph J. Matsko | Portable powered paint system |
| CN107810208B (zh) | 2015-06-25 | 2020-07-24 | 陶氏环球技术有限责任公司 | 具有低己烷可萃取率的乙烯基聚合物 |
| EP3238938A1 (en) | 2016-04-29 | 2017-11-01 | Borealis AG | Machine direction oriented films comprising multimodal copolymer of ethylene and at least two alpha-olefin comonomers |
| US20200087492A1 (en) | 2016-12-22 | 2020-03-19 | Dow Global Technologies Llc | Process to Make High Density Ethylene-Based Polymer Compositions with High Melt Strength |
| US11084893B2 (en) | 2017-06-02 | 2021-08-10 | Dow Global Technologies Llc | Ethylene-based polymers and processes for the same |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3167583A (en) * | 1962-08-24 | 1965-01-26 | Nat Starch Chem Corp | Ethylenically unsaturated derivatives of ortho-hydroxy aromatic acids |
| CN1163621A (zh) * | 1994-10-11 | 1997-10-29 | 博雷尔斯股份公司 | 宽分子量分布的新聚丙烯组合物 |
| EP1650232A1 (en) * | 2004-10-25 | 2006-04-26 | Total Petrochemicals Research Feluy | LDPE-Like polymers with bisindenyl-based ligands having different rings |
| CN101918463A (zh) * | 2007-11-19 | 2010-12-15 | 陶氏环球技术公司 | 长链支化丙烯-α-烯烃共聚物 |
| CN102050904A (zh) * | 2001-11-16 | 2011-05-11 | 纳幕尔杜邦公司 | 烯烃与乙烯基-和烯丙基-硅烷的共聚物 |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3615562A1 (de) * | 1986-05-09 | 1987-11-12 | Basf Ag | Verfahren zur herstellung von copolymerisaten des ethylens mit acrylsaeureestern in einem roehrenreaktor bei druecken oberhalb 500 bar |
| US5408023A (en) * | 1989-10-23 | 1995-04-18 | The Dow Chemical Company | Preparation of modified vinyl polymers |
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- 2012-12-10 WO PCT/US2012/068727 patent/WO2013095969A1/en not_active Ceased
- 2012-12-10 JP JP2014549098A patent/JP6042906B2/ja not_active Expired - Fee Related
- 2012-12-10 BR BR112014015135A patent/BR112014015135A2/pt not_active Application Discontinuation
- 2012-12-10 EP EP12809026.3A patent/EP2794675B1/en not_active Not-in-force
- 2012-12-10 IN IN4648CHN2014 patent/IN2014CN04648A/en unknown
- 2012-12-10 CN CN201280070142.4A patent/CN104136467B/zh not_active Expired - Fee Related
- 2012-12-10 ES ES12809026.3T patent/ES2564545T3/es active Active
- 2012-12-10 MX MX2014007666A patent/MX360854B/es active IP Right Grant
- 2012-12-10 US US14/367,849 patent/US9388260B2/en not_active Expired - Fee Related
- 2012-12-10 KR KR1020147019437A patent/KR101989335B1/ko not_active Expired - Fee Related
- 2012-12-21 AR ARP120104924A patent/AR089419A1/es not_active Application Discontinuation
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Also Published As
| Publication number | Publication date |
|---|---|
| US20150344599A1 (en) | 2015-12-03 |
| JP2015503636A (ja) | 2015-02-02 |
| WO2013095969A1 (en) | 2013-06-27 |
| AR089419A1 (es) | 2014-08-20 |
| IN2014CN04648A (enExample) | 2015-09-18 |
| CN104136467A (zh) | 2014-11-05 |
| EP2794675B1 (en) | 2016-02-24 |
| ES2564545T3 (es) | 2016-03-23 |
| JP6042906B2 (ja) | 2016-12-14 |
| KR20140116101A (ko) | 2014-10-01 |
| MX360854B (es) | 2018-11-20 |
| MX2014007666A (es) | 2014-07-30 |
| BR112014015135A2 (pt) | 2017-06-13 |
| US9388260B2 (en) | 2016-07-12 |
| KR101989335B1 (ko) | 2019-06-17 |
| EP2794675A1 (en) | 2014-10-29 |
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