CN104039841B - 催化剂组分 - Google Patents

催化剂组分 Download PDF

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Publication number
CN104039841B
CN104039841B CN201280064680.2A CN201280064680A CN104039841B CN 104039841 B CN104039841 B CN 104039841B CN 201280064680 A CN201280064680 A CN 201280064680A CN 104039841 B CN104039841 B CN 104039841B
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group
formula
compound
alkyl
catalyst
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CN104039841A (zh
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乔基·基皮阿尼
蒂莫·莱诺宁
彼得·德尼弗
雷约·姆拉瑞
托米·克罗格罗斯
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Borealis AS
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/16—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of silicon, germanium, tin, lead, titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CN201280064680.2A 2011-12-30 2012-12-19 催化剂组分 Active CN104039841B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11196166.0 2011-12-30
EP11196166.0A EP2610273B1 (en) 2011-12-30 2011-12-30 Catalyst component
PCT/EP2012/076053 WO2013098139A1 (en) 2011-12-30 2012-12-19 Catalyst component

Publications (2)

Publication Number Publication Date
CN104039841A CN104039841A (zh) 2014-09-10
CN104039841B true CN104039841B (zh) 2017-02-22

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CN201280064680.2A Active CN104039841B (zh) 2011-12-30 2012-12-19 催化剂组分

Country Status (8)

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US (2) US20140378298A1 (enExample)
EP (1) EP2610273B1 (enExample)
JP (1) JP5992534B2 (enExample)
KR (1) KR101688709B1 (enExample)
CN (1) CN104039841B (enExample)
ES (1) ES2665889T3 (enExample)
IN (1) IN2014DN05988A (enExample)
WO (1) WO2013098139A1 (enExample)

Families Citing this family (59)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2610274A1 (en) * 2011-12-30 2013-07-03 Borealis AG Propylene random copolymer
US8575283B1 (en) 2012-06-28 2013-11-05 Formosa Plastics Corporation, U.S.A. Heterocyclic organic compounds as electron donors for polyolefin catalysts
ES2653868T3 (es) * 2012-12-21 2018-02-09 Borealis Ag Procatalizador de Ziegler Natta soportado para la polimerización de etileno
EP2746300B1 (en) * 2012-12-21 2016-12-07 Borealis AG Process for producing a ziegler natta procatalyst for ethylene polymerisation
JP6171225B2 (ja) * 2013-06-03 2017-08-02 ルムス ノヴォレン テクノロジー ゲーエムベーハー 高性能チーグラー・ナッタ触媒系、該触媒系を製造するための方法、及びその使用
KR101820613B1 (ko) 2013-08-14 2018-01-19 보레알리스 아게 저온에서 개선된 충격 저항성을 갖는 프로필렌 조성물
JP2016528368A (ja) 2013-08-21 2016-09-15 ボレアリス・アクチェンゲゼルシャフトＢｏｒｅａｌｉｓ Ａｇ 高い剛性および靭性を有する高流動ポリオレフィン組成物
MX2016001930A (es) 2013-08-21 2016-05-26 Borealis Ag Composicion de poliolefina de alto flujo con alta rigidez y tenacidad.
ES2587781T3 (es) 2013-09-27 2016-10-26 Borealis Ag Películas adecuadas para procesamiento BOPP de polímeros con altos XS y alta Tm
EP2860031B1 (en) 2013-10-11 2016-03-30 Borealis AG Machine direction oriented film for labels
ES2661108T3 (es) 2013-10-24 2018-03-27 Borealis Ag Homopolímero de polipropileno de bajo punto de fusión con alto contenido de regioerrores y alto peso molecular
PL2865713T3 (pl) 2013-10-24 2016-10-31 Wyrób formowany z rozdmuchiwaniem na bazie dwumodalnego bezładnego kopolimeru
WO2015062936A1 (en) 2013-10-29 2015-05-07 Borealis Ag Solid single site catalysts with high polymerisation activity
WO2015075088A1 (en) 2013-11-22 2015-05-28 Borealis Ag Low emission propylene homopolymer with high melt flow
CN105793298B (zh) 2013-12-04 2019-06-28 博里利斯股份公司 用于熔喷纤维的不含邻苯二甲酸酯的pp均聚物
WO2015091839A1 (en) 2013-12-18 2015-06-25 Borealis Ag Bopp film with improved stiffness/toughness balance
CN105829364B (zh) 2014-01-17 2017-11-10 博里利斯股份公司 用于制备丙烯/1‑丁烯共聚物的方法
WO2015117958A1 (en) 2014-02-06 2015-08-13 Borealis Ag Soft copolymers with high impact strength
ES2767498T3 (es) 2014-02-06 2020-06-17 Borealis Ag Copolímeros de impacto transparentes y suaves
EP2907841A1 (en) 2014-02-14 2015-08-19 Borealis AG Polypropylene composite
EP2947118B1 (en) 2014-05-20 2017-11-29 Borealis AG Polypropylene composition for automotive interior applications
EP3015503A1 (en) 2014-10-27 2016-05-04 Borealis AG Heterophasic polypropylene with improved stiffness/impact balance
BR112017003454B1 (pt) 2014-10-27 2021-10-26 Borealis Ag Composição de polipropileno heterofásico, processos para polimerização de propileno e para preparação de uma composição de polipropileno heterofásico, uso de uma composição de polímero de propileno, e, película, artigo extrudado, moldado por sopro ou moldado por injeção
US9593184B2 (en) * 2014-10-28 2017-03-14 Formosa Plastics Corporation, Usa Oxalic acid diamides as modifiers for polyolefin catalysts
US10118977B2 (en) 2014-12-18 2018-11-06 Borealis Ag Ziegler-natta catalyst and preparation thereof
EP3237466B1 (en) 2014-12-22 2023-05-03 Borealis AG Process for producing polypropylene
EP3253807B1 (en) * 2015-02-05 2023-04-26 Borealis AG Process for producing polyethylene
KR101867254B1 (ko) * 2015-06-12 2018-06-12 보레알리스 아게 프로필렌 중합체 조성물의 제조 방법
EP3170864B1 (en) 2015-11-17 2018-10-17 Borealis AG High flow tpo composition with excellent balance in mechanical properties for automotive interior
EP3397657B1 (en) * 2015-12-31 2024-06-12 Braskem America, Inc. Non-phthalate catalyst system and its use in the polymerization of olefins
BR112018014299B1 (pt) 2016-01-29 2022-07-26 Borealis Ag Artigo automotivo
WO2017148970A1 (en) 2016-03-04 2017-09-08 Borealis Ag High flow heterophasic polyolefin composition having improved stiffness/impact balance
EP3255071B1 (en) 2016-06-06 2024-02-14 Borealis AG Polypropylene composition with improved heat resistance
DK3257988T3 (da) 2016-06-13 2019-11-04 Borealis Ag Smelteblæste baner af høj kvalitet med forbedrede barriereegenskaber
EP3260489B1 (en) 2016-06-24 2019-12-25 Borealis AG Novel polypropylene compositions with low fogging
EP3263640B1 (en) 2016-06-28 2025-08-13 Borealis GmbH Soft and transparent polypropylene composition
CN111205559B (zh) 2016-08-03 2022-10-21 博里利斯股份公司 纤维增强的聚丙烯复合材料
US11427660B2 (en) 2016-08-17 2022-08-30 Formosa Plastics Corporation, Usa Organosilicon compounds as electron donors for olefin polymerization catalysts and methods of making and using same
EP3309211B1 (en) 2016-10-17 2018-12-12 Borealis AG Fiber reinforced polypropylene composite
EP3336109B1 (en) 2016-12-15 2023-06-07 Borealis AG Polypropylene composition with excellent paint adhesion
ES2887577T3 (es) 2017-04-04 2021-12-23 Borealis Ag Composición de polipropileno blando con propiedades mejoradas
ES2959196T3 (es) 2017-06-29 2024-02-21 Borealis Ag Composición de polipropileno con excelente rendimiento al impacto
EP3421538B1 (en) 2017-06-30 2021-03-17 Borealis AG Polyolefin composition with improved surface appearance
CN110741039B (zh) 2017-07-14 2022-02-18 博里利斯股份公司 聚丙烯组合物
EP3489296B1 (en) 2017-11-28 2021-09-01 Borealis AG Polymer composition with improved paint adhesion
EP3489297B1 (en) 2017-11-28 2021-08-04 Borealis AG Polymer composition with improved paint adhesion
PL3495423T3 (pl) 2017-12-05 2021-08-09 Borealis Ag Wyrób zawierający kompozycję polipropylenową wzmocnioną włóknami
EP3495422B1 (en) 2017-12-05 2020-11-11 Borealis AG Fiber reinforced polypropylene composition
WO2020016370A1 (en) 2018-07-19 2020-01-23 Borealis Ag Process for the preparation of an uhmwpe homopolymer
US12359005B2 (en) 2019-10-04 2025-07-15 Borealis Ag Ziegler-Natta catalysts for olefin polymerization
EP4038116A1 (en) 2019-10-04 2022-08-10 Borealis AG Ziegler-natta catalysts for olefin polymerization
JP7365503B2 (ja) * 2019-10-04 2023-10-19 ボレアリス エージー オレフィン重合用チーグラー・ナッタ触媒
WO2021064081A1 (en) 2019-10-04 2021-04-08 Borealis Ag Ziegler-natta catalysts for olefin polymerization
EP3892653A1 (en) * 2020-04-09 2021-10-13 Borealis AG (co)polymerization of ethylene
CN119301191A (zh) 2022-03-23 2025-01-10 博里利斯股份公司 用于汽车应用的聚丙烯组合物
EP4375328A1 (en) 2022-11-23 2024-05-29 Borealis AG Polypropylene composition for automotive applications
US20250109218A1 (en) 2023-09-29 2025-04-03 Formosa Plastics Corporation, U.S.A. Method for preparing catalyst component for polymerization of polyolefin without the use of internal electron donors
EP4527884A1 (en) 2023-09-20 2025-03-26 Borealis AG Polypropylene composition for automotive applications
WO2025202314A1 (en) 2024-03-27 2025-10-02 Borealis Gmbh Polyolefin composition comprising polypropylene polymers and a blend of a plastic material comprising polypropylene and polyethylene

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1170003A (zh) * 1996-06-10 1998-01-14 三井石油化学工业株式会社 固体钛催化剂组分及制备,含该催化剂组分的催化剂及应用
CN1247625C (zh) * 2001-06-20 2006-03-29 玻利阿黎斯聚合物有限公司 烯烃聚合催化剂组分的制备方法
CN101080271A (zh) * 2004-12-17 2007-11-28 弗纳技术股份有限公司 可用于生产聚烯烃催化剂的可溶性镁络合物和由此生产的催化剂

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3471099B2 (ja) 1994-11-25 2003-11-25 昭和電工株式会社 オレフィン重合用触媒担体の製造方法
US5955396A (en) 1995-10-17 1999-09-21 Bp Amoco Corporation Morphology-controlled olefin polymerization catalyst formed from an emulsion
JP3824738B2 (ja) * 1996-06-10 2006-09-20 三井化学株式会社 オレフィン重合用固体状チタン触媒成分の製造方法
DE69812172T2 (de) 1997-12-23 2003-08-28 Borealis Technology Oy, Porvoo Magnesium-,halogen- und alkoxy-enthaldendes produkt
FI981717A7 (fi) 1998-08-07 2000-02-08 Borealis As Katalysaattorikomponentti, joka käsittää magnesiumia, titaania, halogeenia ja elektronidonorin, sen valmistus ja käyttö
FI981718L (fi) 1998-08-07 2000-02-08 Borealis As Katalysaattorikomponentti, joka käsittää magnesiumia, titaania, halogeenia ja elektrodonorin, sen valmistus ja käyttö
CN1137155C (zh) * 1999-12-06 2004-02-04 中国石油化工集团公司 用于烯烃聚合或共聚合的催化剂体系
GB0001914D0 (en) 2000-01-27 2000-03-22 Borealis Polymers Oy Catalyst
CN1169845C (zh) * 2002-02-07 2004-10-06 中国石油化工股份有限公司 用于烯烃聚合的固体催化剂组分和含该催化剂组分的催化剂及其应用
BR0303381B1 (pt) * 2002-03-08 2012-08-21 processo para preparar um componente catalìtico com base em diéter e processo para a homo- ou copolimerização de alfa-olefinas.
EP1505084A4 (en) * 2002-05-10 2005-11-16 Idemitsu Kosan Co SOLID CATALYST COMPONENT FOR OLEFIN POLYMERIZATION, CATALYST FOR OLEFIN POLYMERIZATION AND METHOD FOR PRODUCING OLEFINE POLYMER
EP1403292B1 (en) 2002-09-30 2016-04-13 Borealis Polymers Oy Process for preparing an olefin polymerisation catalyst component with improved high temperature activity
JP5069414B2 (ja) * 2002-12-18 2012-11-07 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ 二塩化マグネシウムベースの付加物およびそれから得られる触媒成分
AU2003292199A1 (en) * 2002-12-18 2004-07-09 Basell Poliolefine Italia S.P.A. Catalyst components for the polymerization of olefins
ES2377948T3 (es) 2003-06-20 2012-04-03 Borealis Polymers Oy Procedimiento para la preparación de una composición de un catalizador para la polimerización de olefinas
EP1668045B1 (en) * 2003-09-23 2012-10-03 Dow Global Technologies LLC Catalyst composition with monocarboxylic acid ester internal donor and propylene polymerization process
US7135531B2 (en) 2004-01-28 2006-11-14 Basf Catalysts Llc Spherical catalyst for olefin polymerization
US7351778B2 (en) * 2004-04-30 2008-04-01 China Petroleum & Chemical Corporation Catalyst component for olefin polymerization and catalyst comprising the same
CN1670043A (zh) * 2005-03-07 2005-09-21 营口市向阳催化剂有限责任公司 烯烃聚合用催化剂及其制备和聚合方法
EP2845868A1 (en) 2006-05-31 2015-03-11 Borealis Technology Oy Oxidation state of Ti as means for increasing catalyst activity
EP1862481B1 (en) 2006-05-31 2016-08-31 Borealis Technology Oy Catalyst with al-alkoxy component
WO2007147714A1 (en) * 2006-06-23 2007-12-27 Basell Poliolefine Italia S.R.L. Magnesium chloroalkolate-based catalyst precursors
JP5689232B2 (ja) * 2009-03-24 2015-03-25 三井化学株式会社 固体状チタン触媒成分、オレフィン重合用触媒およびオレフィンの重合方法
KR101719981B1 (ko) * 2010-07-13 2017-03-27 엘지전자 주식회사 3차원 컨텐츠를 출력하는 디스플레이 기기의 사용자 인터페이스 출력 방법 및 그 방법을 채용한 디스플레이 기기
ES2541701T3 (es) * 2010-07-13 2015-07-23 Borealis Ag Componente de catalizador
EP2610274A1 (en) * 2011-12-30 2013-07-03 Borealis AG Propylene random copolymer
US8575283B1 (en) * 2012-06-28 2013-11-05 Formosa Plastics Corporation, U.S.A. Heterocyclic organic compounds as electron donors for polyolefin catalysts

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1170003A (zh) * 1996-06-10 1998-01-14 三井石油化学工业株式会社 固体钛催化剂组分及制备,含该催化剂组分的催化剂及应用
CN1247625C (zh) * 2001-06-20 2006-03-29 玻利阿黎斯聚合物有限公司 烯烃聚合催化剂组分的制备方法
CN101080271A (zh) * 2004-12-17 2007-11-28 弗纳技术股份有限公司 可用于生产聚烯烃催化剂的可溶性镁络合物和由此生产的催化剂

Also Published As

Publication number Publication date
JP5992534B2 (ja) 2016-09-14
IN2014DN05988A (enExample) 2015-06-26
WO2013098139A1 (en) 2013-07-04
KR101688709B1 (ko) 2016-12-21
CN104039841A (zh) 2014-09-10
US20140378298A1 (en) 2014-12-25
JP2015503646A (ja) 2015-02-02
US20170066852A1 (en) 2017-03-09
EP2610273A1 (en) 2013-07-03
EP2610273B1 (en) 2018-02-07
KR20140107637A (ko) 2014-09-04
ES2665889T3 (es) 2018-04-30

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