KR101688709B1 - 촉매 성분 - Google Patents

촉매 성분 Download PDF

Info

Publication number
KR101688709B1
KR101688709B1 KR1020147021049A KR20147021049A KR101688709B1 KR 101688709 B1 KR101688709 B1 KR 101688709B1 KR 1020147021049 A KR1020147021049 A KR 1020147021049A KR 20147021049 A KR20147021049 A KR 20147021049A KR 101688709 B1 KR101688709 B1 KR 101688709B1
Authority
KR
South Korea
Prior art keywords
group
compound
catalyst component
alkyl
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR1020147021049A
Other languages
English (en)
Korean (ko)
Other versions
KR20140107637A (ko
Inventor
게오르기 키피아니
띠모 레이노넨
페터 데니플
레이요 무랄리
또미 끄로게루스
Original Assignee
보레알리스 아게
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 보레알리스 아게 filed Critical 보레알리스 아게
Publication of KR20140107637A publication Critical patent/KR20140107637A/ko
Application granted granted Critical
Publication of KR101688709B1 publication Critical patent/KR101688709B1/ko
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/06Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/16Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of silicon, germanium, tin, lead, titanium, zirconium or hafnium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
KR1020147021049A 2011-12-30 2012-12-19 촉매 성분 Expired - Fee Related KR101688709B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11196166.0 2011-12-30
EP11196166.0A EP2610273B1 (en) 2011-12-30 2011-12-30 Catalyst component
PCT/EP2012/076053 WO2013098139A1 (en) 2011-12-30 2012-12-19 Catalyst component

Publications (2)

Publication Number Publication Date
KR20140107637A KR20140107637A (ko) 2014-09-04
KR101688709B1 true KR101688709B1 (ko) 2016-12-21

Family

ID=47522535

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020147021049A Expired - Fee Related KR101688709B1 (ko) 2011-12-30 2012-12-19 촉매 성분

Country Status (8)

Country Link
US (2) US20140378298A1 (enExample)
EP (1) EP2610273B1 (enExample)
JP (1) JP5992534B2 (enExample)
KR (1) KR101688709B1 (enExample)
CN (1) CN104039841B (enExample)
ES (1) ES2665889T3 (enExample)
IN (1) IN2014DN05988A (enExample)
WO (1) WO2013098139A1 (enExample)

Families Citing this family (59)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2610274A1 (en) * 2011-12-30 2013-07-03 Borealis AG Propylene random copolymer
US8575283B1 (en) 2012-06-28 2013-11-05 Formosa Plastics Corporation, U.S.A. Heterocyclic organic compounds as electron donors for polyolefin catalysts
ES2653868T3 (es) * 2012-12-21 2018-02-09 Borealis Ag Procatalizador de Ziegler Natta soportado para la polimerización de etileno
EP2746300B1 (en) * 2012-12-21 2016-12-07 Borealis AG Process for producing a ziegler natta procatalyst for ethylene polymerisation
JP6171225B2 (ja) * 2013-06-03 2017-08-02 ルムス ノヴォレン テクノロジー ゲーエムベーハー 高性能チーグラー・ナッタ触媒系、該触媒系を製造するための方法、及びその使用
KR101820613B1 (ko) 2013-08-14 2018-01-19 보레알리스 아게 저온에서 개선된 충격 저항성을 갖는 프로필렌 조성물
JP2016528368A (ja) 2013-08-21 2016-09-15 ボレアリス・アクチェンゲゼルシャフトBorealis Ag 高い剛性および靭性を有する高流動ポリオレフィン組成物
MX2016001930A (es) 2013-08-21 2016-05-26 Borealis Ag Composicion de poliolefina de alto flujo con alta rigidez y tenacidad.
ES2587781T3 (es) 2013-09-27 2016-10-26 Borealis Ag Películas adecuadas para procesamiento BOPP de polímeros con altos XS y alta Tm
EP2860031B1 (en) 2013-10-11 2016-03-30 Borealis AG Machine direction oriented film for labels
ES2661108T3 (es) 2013-10-24 2018-03-27 Borealis Ag Homopolímero de polipropileno de bajo punto de fusión con alto contenido de regioerrores y alto peso molecular
PL2865713T3 (pl) 2013-10-24 2016-10-31 Wyrób formowany z rozdmuchiwaniem na bazie dwumodalnego bezładnego kopolimeru
WO2015062936A1 (en) 2013-10-29 2015-05-07 Borealis Ag Solid single site catalysts with high polymerisation activity
WO2015075088A1 (en) 2013-11-22 2015-05-28 Borealis Ag Low emission propylene homopolymer with high melt flow
CN105793298B (zh) 2013-12-04 2019-06-28 博里利斯股份公司 用于熔喷纤维的不含邻苯二甲酸酯的pp均聚物
WO2015091839A1 (en) 2013-12-18 2015-06-25 Borealis Ag Bopp film with improved stiffness/toughness balance
CN105829364B (zh) 2014-01-17 2017-11-10 博里利斯股份公司 用于制备丙烯/1‑丁烯共聚物的方法
WO2015117958A1 (en) 2014-02-06 2015-08-13 Borealis Ag Soft copolymers with high impact strength
ES2767498T3 (es) 2014-02-06 2020-06-17 Borealis Ag Copolímeros de impacto transparentes y suaves
EP2907841A1 (en) 2014-02-14 2015-08-19 Borealis AG Polypropylene composite
EP2947118B1 (en) 2014-05-20 2017-11-29 Borealis AG Polypropylene composition for automotive interior applications
EP3015503A1 (en) 2014-10-27 2016-05-04 Borealis AG Heterophasic polypropylene with improved stiffness/impact balance
BR112017003454B1 (pt) 2014-10-27 2021-10-26 Borealis Ag Composição de polipropileno heterofásico, processos para polimerização de propileno e para preparação de uma composição de polipropileno heterofásico, uso de uma composição de polímero de propileno, e, película, artigo extrudado, moldado por sopro ou moldado por injeção
US9593184B2 (en) * 2014-10-28 2017-03-14 Formosa Plastics Corporation, Usa Oxalic acid diamides as modifiers for polyolefin catalysts
US10118977B2 (en) 2014-12-18 2018-11-06 Borealis Ag Ziegler-natta catalyst and preparation thereof
EP3237466B1 (en) 2014-12-22 2023-05-03 Borealis AG Process for producing polypropylene
EP3253807B1 (en) * 2015-02-05 2023-04-26 Borealis AG Process for producing polyethylene
KR101867254B1 (ko) * 2015-06-12 2018-06-12 보레알리스 아게 프로필렌 중합체 조성물의 제조 방법
EP3170864B1 (en) 2015-11-17 2018-10-17 Borealis AG High flow tpo composition with excellent balance in mechanical properties for automotive interior
EP3397657B1 (en) * 2015-12-31 2024-06-12 Braskem America, Inc. Non-phthalate catalyst system and its use in the polymerization of olefins
BR112018014299B1 (pt) 2016-01-29 2022-07-26 Borealis Ag Artigo automotivo
WO2017148970A1 (en) 2016-03-04 2017-09-08 Borealis Ag High flow heterophasic polyolefin composition having improved stiffness/impact balance
EP3255071B1 (en) 2016-06-06 2024-02-14 Borealis AG Polypropylene composition with improved heat resistance
DK3257988T3 (da) 2016-06-13 2019-11-04 Borealis Ag Smelteblæste baner af høj kvalitet med forbedrede barriereegenskaber
EP3260489B1 (en) 2016-06-24 2019-12-25 Borealis AG Novel polypropylene compositions with low fogging
EP3263640B1 (en) 2016-06-28 2025-08-13 Borealis GmbH Soft and transparent polypropylene composition
CN111205559B (zh) 2016-08-03 2022-10-21 博里利斯股份公司 纤维增强的聚丙烯复合材料
US11427660B2 (en) 2016-08-17 2022-08-30 Formosa Plastics Corporation, Usa Organosilicon compounds as electron donors for olefin polymerization catalysts and methods of making and using same
EP3309211B1 (en) 2016-10-17 2018-12-12 Borealis AG Fiber reinforced polypropylene composite
EP3336109B1 (en) 2016-12-15 2023-06-07 Borealis AG Polypropylene composition with excellent paint adhesion
ES2887577T3 (es) 2017-04-04 2021-12-23 Borealis Ag Composición de polipropileno blando con propiedades mejoradas
ES2959196T3 (es) 2017-06-29 2024-02-21 Borealis Ag Composición de polipropileno con excelente rendimiento al impacto
EP3421538B1 (en) 2017-06-30 2021-03-17 Borealis AG Polyolefin composition with improved surface appearance
CN110741039B (zh) 2017-07-14 2022-02-18 博里利斯股份公司 聚丙烯组合物
EP3489296B1 (en) 2017-11-28 2021-09-01 Borealis AG Polymer composition with improved paint adhesion
EP3489297B1 (en) 2017-11-28 2021-08-04 Borealis AG Polymer composition with improved paint adhesion
PL3495423T3 (pl) 2017-12-05 2021-08-09 Borealis Ag Wyrób zawierający kompozycję polipropylenową wzmocnioną włóknami
EP3495422B1 (en) 2017-12-05 2020-11-11 Borealis AG Fiber reinforced polypropylene composition
WO2020016370A1 (en) 2018-07-19 2020-01-23 Borealis Ag Process for the preparation of an uhmwpe homopolymer
US12359005B2 (en) 2019-10-04 2025-07-15 Borealis Ag Ziegler-Natta catalysts for olefin polymerization
EP4038116A1 (en) 2019-10-04 2022-08-10 Borealis AG Ziegler-natta catalysts for olefin polymerization
JP7365503B2 (ja) * 2019-10-04 2023-10-19 ボレアリス エージー オレフィン重合用チーグラー・ナッタ触媒
WO2021064081A1 (en) 2019-10-04 2021-04-08 Borealis Ag Ziegler-natta catalysts for olefin polymerization
EP3892653A1 (en) * 2020-04-09 2021-10-13 Borealis AG (co)polymerization of ethylene
CN119301191A (zh) 2022-03-23 2025-01-10 博里利斯股份公司 用于汽车应用的聚丙烯组合物
EP4375328A1 (en) 2022-11-23 2024-05-29 Borealis AG Polypropylene composition for automotive applications
US20250109218A1 (en) 2023-09-29 2025-04-03 Formosa Plastics Corporation, U.S.A. Method for preparing catalyst component for polymerization of polyolefin without the use of internal electron donors
EP4527884A1 (en) 2023-09-20 2025-03-26 Borealis AG Polypropylene composition for automotive applications
WO2025202314A1 (en) 2024-03-27 2025-10-02 Borealis Gmbh Polyolefin composition comprising polypropylene polymers and a blend of a plastic material comprising polypropylene and polyethylene

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3471099B2 (ja) 1994-11-25 2003-11-25 昭和電工株式会社 オレフィン重合用触媒担体の製造方法
US5955396A (en) 1995-10-17 1999-09-21 Bp Amoco Corporation Morphology-controlled olefin polymerization catalyst formed from an emulsion
JP3824738B2 (ja) * 1996-06-10 2006-09-20 三井化学株式会社 オレフィン重合用固体状チタン触媒成分の製造方法
MY125673A (en) * 1996-06-10 2006-08-30 Mitsui Chemicals Inc Solid titanium catalyst component for olefin polymerization,process for preparing the same, olefin plymerization catalyst containing the catalyst component and olefin polymerization process using thecatalyst
DE69812172T2 (de) 1997-12-23 2003-08-28 Borealis Technology Oy, Porvoo Magnesium-,halogen- und alkoxy-enthaldendes produkt
FI981717A7 (fi) 1998-08-07 2000-02-08 Borealis As Katalysaattorikomponentti, joka käsittää magnesiumia, titaania, halogeenia ja elektronidonorin, sen valmistus ja käyttö
FI981718L (fi) 1998-08-07 2000-02-08 Borealis As Katalysaattorikomponentti, joka käsittää magnesiumia, titaania, halogeenia ja elektrodonorin, sen valmistus ja käyttö
CN1137155C (zh) * 1999-12-06 2004-02-04 中国石油化工集团公司 用于烯烃聚合或共聚合的催化剂体系
GB0001914D0 (en) 2000-01-27 2000-03-22 Borealis Polymers Oy Catalyst
ES2266053T3 (es) * 2001-06-20 2007-03-01 Borealis Technology Oy Preparacion de un componente de catalizador para la polimerizacion de olefina.
CN1169845C (zh) * 2002-02-07 2004-10-06 中国石油化工股份有限公司 用于烯烃聚合的固体催化剂组分和含该催化剂组分的催化剂及其应用
BR0303381B1 (pt) * 2002-03-08 2012-08-21 processo para preparar um componente catalìtico com base em diéter e processo para a homo- ou copolimerização de alfa-olefinas.
EP1505084A4 (en) * 2002-05-10 2005-11-16 Idemitsu Kosan Co SOLID CATALYST COMPONENT FOR OLEFIN POLYMERIZATION, CATALYST FOR OLEFIN POLYMERIZATION AND METHOD FOR PRODUCING OLEFINE POLYMER
EP1403292B1 (en) 2002-09-30 2016-04-13 Borealis Polymers Oy Process for preparing an olefin polymerisation catalyst component with improved high temperature activity
JP5069414B2 (ja) * 2002-12-18 2012-11-07 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ 二塩化マグネシウムベースの付加物およびそれから得られる触媒成分
AU2003292199A1 (en) * 2002-12-18 2004-07-09 Basell Poliolefine Italia S.P.A. Catalyst components for the polymerization of olefins
ES2377948T3 (es) 2003-06-20 2012-04-03 Borealis Polymers Oy Procedimiento para la preparación de una composición de un catalizador para la polimerización de olefinas
EP1668045B1 (en) * 2003-09-23 2012-10-03 Dow Global Technologies LLC Catalyst composition with monocarboxylic acid ester internal donor and propylene polymerization process
US7135531B2 (en) 2004-01-28 2006-11-14 Basf Catalysts Llc Spherical catalyst for olefin polymerization
US7351778B2 (en) * 2004-04-30 2008-04-01 China Petroleum & Chemical Corporation Catalyst component for olefin polymerization and catalyst comprising the same
US7067451B1 (en) * 2004-12-17 2006-06-27 Fina Technology, Inc. Soluble magnesium complexes useful for the production of polyolefin catalysts and catalysts prepared therewith
CN1670043A (zh) * 2005-03-07 2005-09-21 营口市向阳催化剂有限责任公司 烯烃聚合用催化剂及其制备和聚合方法
EP2845868A1 (en) 2006-05-31 2015-03-11 Borealis Technology Oy Oxidation state of Ti as means for increasing catalyst activity
EP1862481B1 (en) 2006-05-31 2016-08-31 Borealis Technology Oy Catalyst with al-alkoxy component
WO2007147714A1 (en) * 2006-06-23 2007-12-27 Basell Poliolefine Italia S.R.L. Magnesium chloroalkolate-based catalyst precursors
JP5689232B2 (ja) * 2009-03-24 2015-03-25 三井化学株式会社 固体状チタン触媒成分、オレフィン重合用触媒およびオレフィンの重合方法
KR101719981B1 (ko) * 2010-07-13 2017-03-27 엘지전자 주식회사 3차원 컨텐츠를 출력하는 디스플레이 기기의 사용자 인터페이스 출력 방법 및 그 방법을 채용한 디스플레이 기기
ES2541701T3 (es) * 2010-07-13 2015-07-23 Borealis Ag Componente de catalizador
EP2610274A1 (en) * 2011-12-30 2013-07-03 Borealis AG Propylene random copolymer
US8575283B1 (en) * 2012-06-28 2013-11-05 Formosa Plastics Corporation, U.S.A. Heterocyclic organic compounds as electron donors for polyolefin catalysts

Also Published As

Publication number Publication date
JP5992534B2 (ja) 2016-09-14
IN2014DN05988A (enExample) 2015-06-26
WO2013098139A1 (en) 2013-07-04
CN104039841A (zh) 2014-09-10
US20140378298A1 (en) 2014-12-25
JP2015503646A (ja) 2015-02-02
CN104039841B (zh) 2017-02-22
US20170066852A1 (en) 2017-03-09
EP2610273A1 (en) 2013-07-03
EP2610273B1 (en) 2018-02-07
KR20140107637A (ko) 2014-09-04
ES2665889T3 (es) 2018-04-30

Similar Documents

Publication Publication Date Title
KR101688709B1 (ko) 촉매 성분
KR101623292B1 (ko) 프탈레이트 무함유 zn pp 촉매의 제조
KR101639497B1 (ko) 프로필렌 랜덤 공중합체
EP2610270B1 (en) Catalyst component
EP2610272B1 (en) Catalyst component
EP2746300B1 (en) Process for producing a ziegler natta procatalyst for ethylene polymerisation
US9676876B2 (en) Catalyst for polymerization of olefins and process thereof

Legal Events

Date Code Title Description
A201 Request for examination
AMND Amendment
E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

AMND Amendment
P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

D13-X000 Search requested

St.27 status event code: A-1-2-D10-D13-srh-X000

D14-X000 Search report completed

St.27 status event code: A-1-2-D10-D14-srh-X000

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

T11-X000 Administrative time limit extension requested

St.27 status event code: U-3-3-T10-T11-oth-X000

AMND Amendment
E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PE0601 Decision on rejection of patent

St.27 status event code: N-2-6-B10-B15-exm-PE0601

T11-X000 Administrative time limit extension requested

St.27 status event code: U-3-3-T10-T11-oth-X000

AMND Amendment
E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PX0901 Re-examination

St.27 status event code: A-2-3-E10-E12-rex-PX0901

PX0701 Decision of registration after re-examination

St.27 status event code: A-3-4-F10-F13-rex-PX0701

X701 Decision to grant (after re-examination)
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 5

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 6

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 7

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 8

PC1903 Unpaid annual fee

St.27 status event code: A-4-4-U10-U13-oth-PC1903

Not in force date: 20241216

Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

PN2301 Change of applicant

St.27 status event code: A-5-5-R10-R13-asn-PN2301

St.27 status event code: A-5-5-R10-R11-asn-PN2301

R11 Change to the name of applicant or owner or transfer of ownership requested

Free format text: ST27 STATUS EVENT CODE: A-5-5-R10-R11-ASN-PN2301 (AS PROVIDED BY THE NATIONAL OFFICE)

R13 Change to the name of applicant or owner recorded

Free format text: ST27 STATUS EVENT CODE: A-5-5-R10-R13-ASN-PN2301 (AS PROVIDED BY THE NATIONAL OFFICE)

H13 Ip right lapsed

Free format text: ST27 STATUS EVENT CODE: N-4-6-H10-H13-OTH-PC1903 (AS PROVIDED BY THE NATIONAL OFFICE); TERMINATION CATEGORY : DEFAULT_OF_REGISTRATION_FEE

Effective date: 20241216

PC1903 Unpaid annual fee

St.27 status event code: N-4-6-H10-H13-oth-PC1903

Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

Not in force date: 20241216