CN103974943A - 使用单相混合的水-有机溶剂系统从果糖生产5-羟甲基糠醛 - Google Patents
使用单相混合的水-有机溶剂系统从果糖生产5-羟甲基糠醛 Download PDFInfo
- Publication number
- CN103974943A CN103974943A CN201280061061.8A CN201280061061A CN103974943A CN 103974943 A CN103974943 A CN 103974943A CN 201280061061 A CN201280061061 A CN 201280061061A CN 103974943 A CN103974943 A CN 103974943A
- Authority
- CN
- China
- Prior art keywords
- fructose
- glucose
- scope
- seminose
- organic solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
- C07D307/48—Furfural
- C07D307/50—Preparation from natural products
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P17/00—Preparation of heterocyclic carbon compounds with only O, N, S, Se or Te as ring hetero atoms
- C12P17/02—Oxygen as only ring hetero atoms
- C12P17/04—Oxygen as only ring hetero atoms containing a five-membered hetero ring, e.g. griseofulvin, vitamin C
Landscapes
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Biotechnology (AREA)
- Microbiology (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Furan Compounds (AREA)
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11184895 | 2011-10-12 | ||
| EP11184895.8 | 2011-10-12 | ||
| US201161548831P | 2011-10-19 | 2011-10-19 | |
| US61/548,831 | 2011-10-19 | ||
| US201261640958P | 2012-05-01 | 2012-05-01 | |
| US61/640,958 | 2012-05-01 | ||
| PCT/EP2012/070151 WO2013053816A1 (en) | 2011-10-12 | 2012-10-11 | Production of 5-hydroxymethylfurfural from fructose using a single-phase mixed aqueous-organic solvent system |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103974943A true CN103974943A (zh) | 2014-08-06 |
Family
ID=48081398
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280061061.8A Pending CN103974943A (zh) | 2011-10-12 | 2012-10-11 | 使用单相混合的水-有机溶剂系统从果糖生产5-羟甲基糠醛 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20140349351A1 (enExample) |
| EP (1) | EP2766351A1 (enExample) |
| CN (1) | CN103974943A (enExample) |
| BR (1) | BR112014008911A2 (enExample) |
| IN (1) | IN2014CN03466A (enExample) |
| WO (1) | WO2013053816A1 (enExample) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106810518A (zh) * | 2015-12-02 | 2017-06-09 | 长春工业大学 | 一种由葡萄糖制备5-羟甲基糠醛的方法 |
| CN108473455A (zh) * | 2015-11-04 | 2018-08-31 | 巴斯夫欧洲公司 | 用于制备包含5-(羟基甲基)糠醛和特定的hmf酯的混合物的方法 |
| CN112236419A (zh) * | 2018-05-29 | 2021-01-15 | 祖德楚克尔股份公司 | 盐和酸混合物催化的hmf生产 |
| CN112313365A (zh) * | 2018-05-29 | 2021-02-02 | 祖德楚克尔股份公司 | 阳极电解液部分催化的hmf生产 |
| CN112778244A (zh) * | 2020-12-18 | 2021-05-11 | 中国科学院宁波材料技术与工程研究所 | 一种果糖脱水制备5-羟甲基糠醛的方法 |
| CN115626902A (zh) * | 2022-09-30 | 2023-01-20 | 清华大学 | 葡萄糖连续制备5-羟甲基糠醛的方法 |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101217137B1 (ko) * | 2012-03-05 | 2012-12-31 | 한국생산기술연구원 | 프록토오스를 포함하는 옥수수시럽으로부터 5-히드록시메틸-2-푸르푸랄을 제조하는 방법 |
| US10138217B2 (en) | 2013-09-03 | 2018-11-27 | Virdia, Inc. | Methods for extracting and converting hemicellulose sugars |
| US9611241B2 (en) * | 2014-01-27 | 2017-04-04 | Rennovia Inc. | Conversion of fructose-containing feedstocks to HMF-containing product |
| KR101629699B1 (ko) | 2014-09-02 | 2016-06-14 | 한국화학연구원 | 5-히드록시메틸푸푸랄의 제조방법 |
| US10112916B2 (en) | 2014-12-23 | 2018-10-30 | The Regents Of The University Of California | HMF production from glucose in ionic liquid media |
| US20190062293A1 (en) * | 2014-12-23 | 2019-02-28 | Noppadon Sathitsuksanoh | Metal-organic frameworks for the conversion of lignocellulosic derivatives to renewable platform chemicals |
| EP3402787A4 (en) | 2016-01-13 | 2019-11-27 | Stora Enso Oyj | PROCESS FOR THE PREPARATION OF 2,5-FURANDIC ACETIC ACID AND INTERMEDIATES AND DERIVATIVES THEREOF |
| WO2017184545A1 (en) * | 2016-04-18 | 2017-10-26 | Rennovia, Inc. | Conversion of fructose-containing feedstocks to hmf-containing product |
| SG11201913469PA (en) | 2017-07-12 | 2020-01-30 | Stora Enso Oyj | Purified 2,5-furandicarboxylic acid pathway products |
| CN111187236A (zh) * | 2018-11-14 | 2020-05-22 | 远东新世纪股份有限公司 | 自含有葡萄糖的原料制备5-羟甲基糠醛的方法 |
| CN113825745B (zh) | 2019-04-15 | 2025-04-04 | 斯道拉恩索公司 | 用于回收溶剂和分离腐殖质材料及其组合物的方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2858618A1 (fr) * | 2003-08-07 | 2005-02-11 | Sucreries Et Raffineries D Ers | Procede et reacteur de fabrication d'hydroxymethylfurfural |
| CN101434589A (zh) * | 2007-11-14 | 2009-05-20 | 中国科学院大连化学物理研究所 | 一种由果糖源生物质制备5-羟甲基糠醛的方法 |
| CN101724664A (zh) * | 2009-12-02 | 2010-06-09 | 天津大学 | 异构酶/稀盐酸耦合催化由葡萄糖制备5-羟甲基糠醛的方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2929823A (en) * | 1956-11-26 | 1960-03-22 | Merck & Co Inc | Production of 5-hydroxymethylfurfural |
| DE3601281A1 (de) * | 1986-01-17 | 1987-07-23 | Sueddeutsche Zucker Ag | Verfahren zur herstellung von 5-hydroxymethylfurfural einschliesslich eines kristallinen produktes unter ausschliesslicher verwendung von wasser als loesungsmittel |
| DE3826073A1 (de) | 1988-07-30 | 1990-02-01 | Hoechst Ag | Verfahren zur oxidation von 5-hydroxymethylfurfural |
| US6022419A (en) * | 1996-09-30 | 2000-02-08 | Midwest Research Institute | Hydrolysis and fractionation of lignocellulosic biomass |
| US7317116B2 (en) | 2004-12-10 | 2008-01-08 | Archer-Daniels-Midland-Company | Processes for the preparation and purification of hydroxymethylfuraldehyde and derivatives |
| EP1834951A1 (en) * | 2006-03-10 | 2007-09-19 | Avantium International B.V. | Method for the synthesis of organic acid esters of 5-hydroxymethylfurfural and their use |
| JP4804187B2 (ja) | 2006-03-28 | 2011-11-02 | キヤノン株式会社 | フラン−2,5−ジカルボン酸の製造方法 |
| EP2032550B1 (en) | 2006-06-06 | 2013-11-20 | Wisconsin Alumni Research Foundation | Catalytic process for producing furan derivatives from carbohydrates in a biphasic reactor |
| US7700788B2 (en) | 2006-10-31 | 2010-04-20 | Battelle Memorial Institute | Hydroxymethyl furfural oxidation methods |
| US20090030215A1 (en) | 2007-07-18 | 2009-01-29 | Dignan Christine | Method for production of 5-hydroxymethyl-2-furfural from fructose |
| DE602008005035D1 (de) * | 2007-09-07 | 2011-03-31 | Furanix Technologies Bv | In ionischen flüssigkeiten erzeugte hydroxymethylfurfuralether und -ester |
-
2012
- 2012-10-11 EP EP12770491.4A patent/EP2766351A1/en not_active Withdrawn
- 2012-10-11 US US14/351,108 patent/US20140349351A1/en not_active Abandoned
- 2012-10-11 BR BR112014008911A patent/BR112014008911A2/pt not_active IP Right Cessation
- 2012-10-11 IN IN3466CHN2014 patent/IN2014CN03466A/en unknown
- 2012-10-11 CN CN201280061061.8A patent/CN103974943A/zh active Pending
- 2012-10-11 WO PCT/EP2012/070151 patent/WO2013053816A1/en not_active Ceased
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2858618A1 (fr) * | 2003-08-07 | 2005-02-11 | Sucreries Et Raffineries D Ers | Procede et reacteur de fabrication d'hydroxymethylfurfural |
| CN101434589A (zh) * | 2007-11-14 | 2009-05-20 | 中国科学院大连化学物理研究所 | 一种由果糖源生物质制备5-羟甲基糠醛的方法 |
| CN101724664A (zh) * | 2009-12-02 | 2010-06-09 | 天津大学 | 异构酶/稀盐酸耦合催化由葡萄糖制备5-羟甲基糠醛的方法 |
Non-Patent Citations (15)
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108473455A (zh) * | 2015-11-04 | 2018-08-31 | 巴斯夫欧洲公司 | 用于制备包含5-(羟基甲基)糠醛和特定的hmf酯的混合物的方法 |
| CN106810518A (zh) * | 2015-12-02 | 2017-06-09 | 长春工业大学 | 一种由葡萄糖制备5-羟甲基糠醛的方法 |
| CN112236419A (zh) * | 2018-05-29 | 2021-01-15 | 祖德楚克尔股份公司 | 盐和酸混合物催化的hmf生产 |
| CN112313365A (zh) * | 2018-05-29 | 2021-02-02 | 祖德楚克尔股份公司 | 阳极电解液部分催化的hmf生产 |
| US11697642B2 (en) | 2018-05-29 | 2023-07-11 | Südzucker AG | HMF preparation catalysed by anolyte fraction |
| CN112313365B (zh) * | 2018-05-29 | 2023-09-01 | 祖德楚克尔股份公司 | 阳极电解液部分催化的hmf生产 |
| CN112236419B (zh) * | 2018-05-29 | 2025-03-18 | 祖德楚克尔股份公司 | 盐和酸混合物催化的hmf生产 |
| CN112778244A (zh) * | 2020-12-18 | 2021-05-11 | 中国科学院宁波材料技术与工程研究所 | 一种果糖脱水制备5-羟甲基糠醛的方法 |
| CN115626902A (zh) * | 2022-09-30 | 2023-01-20 | 清华大学 | 葡萄糖连续制备5-羟甲基糠醛的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2013053816A1 (en) | 2013-04-18 |
| EP2766351A1 (en) | 2014-08-20 |
| BR112014008911A2 (pt) | 2017-05-09 |
| IN2014CN03466A (enExample) | 2015-07-03 |
| US20140349351A1 (en) | 2014-11-27 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20140806 |
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| WD01 | Invention patent application deemed withdrawn after publication |