CN103910554B - Be applicable to the organic calcium fertilizer of acidified soil - Google Patents
Be applicable to the organic calcium fertilizer of acidified soil Download PDFInfo
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- CN103910554B CN103910554B CN201410149489.9A CN201410149489A CN103910554B CN 103910554 B CN103910554 B CN 103910554B CN 201410149489 A CN201410149489 A CN 201410149489A CN 103910554 B CN103910554 B CN 103910554B
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- soil
- fertilizer
- trace element
- attapulgite
- oyster shell
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- 239000002689 soil Substances 0.000 title claims abstract description 49
- 239000003337 fertilizer Substances 0.000 title claims abstract description 31
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 229910052791 calcium Inorganic materials 0.000 title claims abstract description 23
- 239000011575 calcium Substances 0.000 title claims abstract description 23
- 229960000892 attapulgite Drugs 0.000 claims abstract description 13
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract description 13
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 9
- 241000276489 Merlangius merlangus Species 0.000 claims abstract description 9
- 239000011573 trace mineral Substances 0.000 claims abstract description 9
- 235000013619 trace mineral Nutrition 0.000 claims abstract description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims description 4
- 239000011733 molybdenum Substances 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims description 3
- ZVCNBVJYXBEKTC-UHFFFAOYSA-L azanium;zinc;phosphate Chemical compound [NH4+].[Zn+2].[O-]P([O-])([O-])=O ZVCNBVJYXBEKTC-UHFFFAOYSA-L 0.000 claims description 3
- 229910021538 borax Inorganic materials 0.000 claims description 3
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 3
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 3
- 239000011790 ferrous sulphate Substances 0.000 claims description 3
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 3
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 3
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 3
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 3
- 239000011669 selenium Substances 0.000 claims description 3
- 229910052711 selenium Inorganic materials 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 239000004328 sodium tetraborate Substances 0.000 claims description 3
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 238000010521 absorption reaction Methods 0.000 abstract description 3
- 230000003139 buffering effect Effects 0.000 abstract description 2
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 abstract description 2
- 239000000292 calcium oxide Substances 0.000 abstract description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 abstract description 2
- 230000000050 nutritive effect Effects 0.000 abstract description 2
- 239000004615 ingredient Substances 0.000 abstract 1
- 241000209140 Triticum Species 0.000 description 7
- 235000021307 Triticum Nutrition 0.000 description 7
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 4
- 229910001424 calcium ion Inorganic materials 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 230000020477 pH reduction Effects 0.000 description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 210000004027 cell Anatomy 0.000 description 2
- 238000005056 compaction Methods 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 231100000572 poisoning Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 206010006956 Calcium deficiency Diseases 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 238000003782 apoptosis assay Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000032677 cell aging Effects 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000004720 fertilization Effects 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000618 nitrogen fertilizer Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000005522 programmed cell death Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000001850 reproductive effect Effects 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 230000019491 signal transduction Effects 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 238000005527 soil sampling Methods 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
- 230000005945 translocation Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 230000003612 virological effect Effects 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Abstract
The invention discloses a kind of organic calcium fertilizer being applicable to acidified soil, be prepared from according to a certain weight ratio by attapulgite breeze, oyster shell whiting, trace element.The present invention utilizes the excellent absorption property of attapulgite oyster shell whiting and trace element to be adsorbed, effectively control the calcium oxide component in oyster shell whiting and the rate of release of the nutritive ingredient in trace element in soil, enhance the function timeliness of fertilizer, each composition safety nuisance free, to environment and farm crop pollution-free, fertilizer efficiency utilization ratio can be significantly improved, and improve buffering power of soil, thus improve the function of crop yield and quality.
Description
Technical field
The present invention relates to fertilizer and manufacture field, be specifically related to a kind of organic calcium fertilizer being applicable to acidified soil.
Background technology
In recent decades, soil acidification has become a serious global ecological environment problem.In China, research finds the acidification phenomenon all occurring in various degree up to the agricultural land soil of 90%, soil pH value on average declines about 0.5 unit, be equivalent to soil acid amount and add 2.2 times on the original basis, become one of main Environmental Problems of the intensive agrosystem of China, recent statistical figure show that the soil acidification problem that the excessive use of a large amount of nitrogenous fertilizer causes is more serious, the amount of the unit surface acidic substance that Term Fertilization produces is much larger than the Utilization ability of farm crop etc., cause a large amount of fertilizer residue in soil, form the acidifying of soil, and cause wheat, corn, the underproduction such as peanut, disease and pest increases the weight of.Another obvious feature of the soil of acidifying is that the wherein cationic loss of trophicity is serious, and wherein especially serious with the loss of calcium ion, and multinomial research shows under acidification, and in soil, the number of dropouts of calcium ion is generally greater than 50%, causes soil calcium deficiency.
Calcium, as the necessary nutritive element of growth and development of plants, plays extremely important effect in plant materials.It is the necessary element that cell walls glue-line is formed, play an important role in the integrity maintaining cytolemma, calcium ion can also reduce respiration, prevents cell aging, promotes photosynthate translocation, prevents the murder by poisoning of metal ion and eliminate oxalic acid to the murder by poisoning of plant materials simultaneously.On a cellular level, calcium ion, as the second messenger of cell, is the key signal molecule in vegetable cell S-R signal transduction mechanism, participates in reconciling reproductive growth and various coercive defensive ractions etc.In addition, the vital role of calcium in programmed cell death has been familiar with and has been come into one's own.Obviously, in acidified soil, the shortage of calcium must cause a series of harm reaction of crop.
In current agriculture production, the general lime material that uses improves acidified soil, but long-term application lime not only causes, and soil permeability is deteriorated, soil compaction is serious, also affects the absorption of plant phosphorus.Acidified soil is used these fertilizer, is unfavorable for the improvement of acidified soil, therefore, it is very necessary for inventing calcareous fertilisers special on acidified soil.
Summary of the invention
The object of the invention is to: propose a kind of organic calcium fertilizer being applicable to acidified soil, be manured into soil middle slow releasing, while improvement soil function, can also improve air permeability and the surge capability of soil, avoids the further acidifying harm of soil.
Technical solution of the present invention is: this organic calcium fertilizer is made up of the raw material of following weight percent: attapulgite breeze 25%, oyster shell whiting 60%, trace element 15%.
Wherein, described trace element is made up of the raw material of following weight percent: borax 35%, manganous sulfate 10%, silica 1 5%, zinc ammonium phosphate 15%, ferrous sulfate 15%, copper sulfate 5%, molybdenum 2.5%, selenium 2.5%.
Wherein, the preparation method of described organic calcium fertilizer is: attapulgite and grinding shells are crossed 50 mesh sieves and obtain powder particle, attapulgite breeze, oyster shell whiting, trace element are mixed according to the above ratio, stir, obtain organic calcium fertilizer.
Wherein, the using method of described organic calcium fertilizer is: apply by the rate of fertilizer application of every square metre of farmland area 200g fertilizer.
Beneficial effect of the present invention is: the adsorption function 1, utilizing attapulgite, is released slowly in soil, is conducive to effective release of fertilizer efficiency and the abundant absorption of crop by organic calcareous in fertilizer, long-term shortage of supplementing calcium in acidified soil; 2, attapulgite can also pass through its good granulation performance, reduces the antagonism between soil intermediate ion, improves the crumb structure of soil, chessom, improves the ventilation property of soil, reduces and eliminates soil compaction and viral disorder; 3, increase adsorption by soil structure, improve the fertilizer conservation function of soil further, reach improvement recovery soil object, thus improve the function of crop yield and quality; 4, improve buffering power of soil, increase its dispersiveness, keep soil from packing together.
Accompanying drawing explanation
fig. 1for applying the regulating and controlling effect of fertilizer to acidified soil pH value in application examples 2, HZGJ: Xun He village, Gao Jian town, Hongze County, XYGT: Heshan village, county magistrate beach town, Xuyi.
fig. 2for applying the change of fertilizer to the commutative calcium contents of soil in application examples 2, HZGJ: Xun He village, Gao Jian town, Hongze County, XYGT: Heshan village, county magistrate beach town, Xuyi.
fig. 3 isthe impact of fertilizer on wheat yield is applied, HZGJ: Xun He village, Gao Jian town, Hongze County, XYGT: Heshan village, county magistrate beach town, Xuyi in application examples 2.
Embodiment
According to following embodiment, the technical solution that the present invention may be better understood.But those skilled in the art will readily understand, concrete material proportion, processing condition and result thereof described by embodiment only for illustration of the present invention, and should can not limit the present invention described in detail in claims yet.
Embodiment 1: prepare organic calcium fertilizer according to following steps
(1) by attapulgite and shell ground 50 mesh sieves respectively, attapulgite breeze and oyster shell whiting is obtained;
(2) get borax 3.5 kg, manganous sulfate 1.0kg, silica 1 .5kg, zinc ammonium phosphate 1.5 kg, ferrous sulfate 1.5 kg, copper sulfate 0.5kg, molybdenum 0.25 kg, selenium 0.25 kg, stir, obtain micro-;
(3) get attapulgite breeze 12.5 kg, oyster shell whiting 30.0 kg, micro-7.5 kg, stir, pack on request, obtain finished product organic calcium fertilizer.
Analyzing and testing is carried out to the organic calcium fertilizer of the present embodiment: calcium oxide content is 42.2%, magnesium oxide 7.3%, boron 25.4%, silicon oxide 22.3%, other iron, aluminium, zinc, molybdenum 2.8%.
application examples 2:in order to verify practical function of the present invention further, we have selected Xun He village, Gao Jian town, Hongze County (HZGJ), acidifying in recent years obvious winter wheat field soil in two pieces, Heshan village, county magistrate beach town, Xuyi (XYGT) compares test.The area of each community is 100m
2.Before winter wheat sowing, use organic calcium fertilizer, rate of fertilizer is: 200g/m
2, check plot does not apply.Before winter wheat harvesting time, soil sampling measured the pH value of the soil (soil depth 0-10cm) of each community and commutative calcium contents and investigated the output of winter wheat every month.Acquired results as Figure 1-3.Use fertilizer provided by the invention after 6 months, soil (soil depth 0-10cm) pH value average specific foundation soil pH value improves 0.6 unit, with between SAS statistical software analyzing and processing in significant difference (
p< 0.05), in soil interchangeability calcium contents than plantation before improve nearly 1 times, winter wheat yields is 485kg/ mu, comparatively contrast output increased 12%, with between SAS statistical software analyzing and processing in significant difference (
p< 0.05).
Claims (1)
1. be applicable to the organic calcium fertilizer of acidified soil, it is characterized in that: this organic calcium fertilizer is made up of the raw material of following weight percent: attapulgite breeze 25%, oyster shell whiting 60%, trace element 15%; Wherein said trace element is made up of the raw material of following weight percent: borax 35%, manganous sulfate 10%, silica 1 5%, zinc ammonium phosphate 15%, ferrous sulfate 15%, copper sulfate 5%, molybdenum 2.5%, selenium 2.5%; Attapulgite and grinding shells are crossed 50 mesh sieves and obtain powder particle, attapulgite breeze, oyster shell whiting, trace element are mixed according to the above ratio, stirs, the organic calcium fertilizer prepared.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410149489.9A CN103910554B (en) | 2014-04-15 | 2014-04-15 | Be applicable to the organic calcium fertilizer of acidified soil |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410149489.9A CN103910554B (en) | 2014-04-15 | 2014-04-15 | Be applicable to the organic calcium fertilizer of acidified soil |
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| Publication Number | Publication Date |
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| CN103910554A CN103910554A (en) | 2014-07-09 |
| CN103910554B true CN103910554B (en) | 2015-10-28 |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106588456A (en) * | 2016-12-04 | 2017-04-26 | 钦州市星火计划办公室 | Fertilizer for acidified soil and preparation method thereof |
| CN107267150A (en) * | 2017-06-20 | 2017-10-20 | 兰州坤仑环保科技有限公司 | A kind of concave convex rod base inorganic mineral soil conditioner and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1807366A (en) * | 2005-01-20 | 2006-07-26 | 蒋文兰 | Granular moisture-keeping formula fertilizer and it production method |
| CN101085920A (en) * | 2007-07-16 | 2007-12-12 | 广东省农业科学院土壤肥料研究所 | Method for preparing southern dry land acidic soil conditioner |
| CN102701885A (en) * | 2012-06-29 | 2012-10-03 | 陕西盛丰农业科技有限公司 | Soil conditioner |
-
2014
- 2014-04-15 CN CN201410149489.9A patent/CN103910554B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1807366A (en) * | 2005-01-20 | 2006-07-26 | 蒋文兰 | Granular moisture-keeping formula fertilizer and it production method |
| CN101085920A (en) * | 2007-07-16 | 2007-12-12 | 广东省农业科学院土壤肥料研究所 | Method for preparing southern dry land acidic soil conditioner |
| CN102701885A (en) * | 2012-06-29 | 2012-10-03 | 陕西盛丰农业科技有限公司 | Soil conditioner |
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Effective date of registration: 20210527 Address after: 102600 316, 3rd floor, building 10, yard 50, Chunhe Road, Daxing District, Beijing Patentee after: Beijing liaoyi Biotechnology Co.,Ltd. Address before: No. 111, Changjiang West Road, Huaian, Jiangsu, Jiangsu Patentee before: HUAIYIN NORMAL University |
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Effective date of registration: 20231207 Address after: No. 3-1 Weijiu Road, Nansun Community, Gaoli Street, Hanting District, Weifang City, Shandong Province, 261000 Patentee after: Shandong Luming Biotechnology Co.,Ltd. Address before: 102600 316, 3rd floor, building 10, yard 50, Chunhe Road, Daxing District, Beijing Patentee before: Beijing liaoyi Biotechnology Co.,Ltd. |