CN103814052B - 含具有硫醚连接基的(甲基)丙烯酸酯单体的能聚合的组合物 - Google Patents

含具有硫醚连接基的(甲基)丙烯酸酯单体的能聚合的组合物 Download PDF

Info

Publication number
CN103814052B
CN103814052B CN201280043489.XA CN201280043489A CN103814052B CN 103814052 B CN103814052 B CN 103814052B CN 201280043489 A CN201280043489 A CN 201280043489A CN 103814052 B CN103814052 B CN 103814052B
Authority
CN
China
Prior art keywords
optionally substituted
polymerizable composition
formula
independently
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201280043489.XA
Other languages
English (en)
Chinese (zh)
Other versions
CN103814052A (zh
Inventor
R·D·赫罗德
N·伯杰克瓦
M·J·格雷厄姆
C·R·希肯伯斯
G·J·麦克拉姆
W·H·雷特施
周宏英
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PPG Industries Ohio Inc
Original Assignee
PPG Industries Ohio Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by PPG Industries Ohio Inc filed Critical PPG Industries Ohio Inc
Publication of CN103814052A publication Critical patent/CN103814052A/zh
Application granted granted Critical
Publication of CN103814052B publication Critical patent/CN103814052B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/38—Esters containing sulfur
    • C08F220/382—Esters containing sulfur and containing oxygen, e.g. 2-sulfoethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/38—Esters containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/10—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C323/11—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C323/12—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F128/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur
    • C08F128/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur by a bond to sulfur
    • C08F128/04—Thioethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/20—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds unconjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F228/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Eyeglasses (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)
  • Optical Filters (AREA)
  • Polarising Elements (AREA)
CN201280043489.XA 2011-09-08 2012-09-07 含具有硫醚连接基的(甲基)丙烯酸酯单体的能聚合的组合物 Active CN103814052B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201161532275P 2011-09-08 2011-09-08
US61/532,275 2011-09-08
US13/605,100 2012-09-06
US13/605,100 US9334345B2 (en) 2011-09-08 2012-09-06 Polymerizable compositions containing (meth)acrylate monomers having sulfide linkages
PCT/US2012/054175 WO2013036774A1 (en) 2011-09-08 2012-09-07 Polymerizable compositions containing (meth)acrylate monomers having sulfide linkages

Publications (2)

Publication Number Publication Date
CN103814052A CN103814052A (zh) 2014-05-21
CN103814052B true CN103814052B (zh) 2016-01-27

Family

ID=46889478

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201280043489.XA Active CN103814052B (zh) 2011-09-08 2012-09-07 含具有硫醚连接基的(甲基)丙烯酸酯单体的能聚合的组合物

Country Status (8)

Country Link
US (1) US9334345B2 (enExample)
EP (3) EP2753649B8 (enExample)
JP (3) JP5848453B2 (enExample)
KR (1) KR101657380B1 (enExample)
CN (1) CN103814052B (enExample)
PH (1) PH12014500441A1 (enExample)
TW (2) TWI547506B (enExample)
WO (1) WO2013036774A1 (enExample)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX2011009084A (es) 2009-03-06 2012-01-25 Biopolymer Technologies Ltd Espumas que contienen proteinas, su produccion y sus usos.
EP2403888B1 (en) 2009-03-06 2021-05-12 Evertree Protein-containing emulsions and adhesives, and manufacture and use thereof
CA2801262C (en) 2010-06-07 2021-02-09 Biopolymer Technologies, Ltd. Protein-containing adhesives, and manufacture and use thereof
WO2013036744A1 (en) 2011-09-09 2013-03-14 Biopolymer Technologies, Ltd. Protein-containing adhesives, and manufacture and use thereof
BR112014005502A2 (pt) 2011-09-09 2017-04-04 Biopolymer Tech Ltd adesivos contendo proteínas, e fabricação e uso dos mesmos
US9873823B2 (en) 2012-07-30 2018-01-23 Evertree Protein adhesives containing an anhydride, carboxylic acid, and/or carboxylate salt compound and their use
KR101944168B1 (ko) * 2014-03-14 2019-01-30 피피지 인더스트리즈 오하이오 인코포레이티드 전기활성 광학 디바이스
JP2018521845A (ja) * 2015-07-13 2018-08-09 東京エレクトロン株式会社 多孔質材料をコーティングまたは充填する方法
CN106831510B (zh) * 2017-01-16 2018-10-19 黄河三角洲京博化工研究院有限公司 1,11-二羟基-3,6,9-三硫代十一烷及其制备方法
EP3702348A4 (en) 2017-10-26 2021-07-21 Shikoku Chemicals Corporation THIOLS COMPOUNDS, PROCESS FOR SYNTHESIS THEREOF, AND USE OF SAID THIOLS COMPOUNDS
CN109516934B (zh) * 2018-10-30 2021-06-18 辽宁石油化工大学 一种有机叔胺催化正辛硫醇与碳酸乙烯酯反应的方法
JP6814317B1 (ja) * 2019-12-13 2021-01-13 東洋インキＳｃホールディングス株式会社 ブロック共重合体、樹脂組成物、伸縮性導体、電子デバイスおよび粘着フィルム
EP4136070B1 (en) * 2020-04-14 2024-05-29 Solventum Intellectual Properties Company Monomers, polymers, and articles for biomaterial capture
JP7620700B2 (ja) 2020-06-01 2025-01-23 アイケアーズ メディカス インコーポレイテッド 両面非球面回折多焦点レンズ、その製造、および使用
WO2023111723A1 (en) * 2021-12-15 2023-06-22 3M Innovative Properties Company Degradable crosslinkers for (meth)acrylic resins and methods thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0810210A2 (en) * 1996-05-29 1997-12-03 Mitsui Toatsu Chemicals, Inc. Thiol and sulfur-containing o-(meth)acrylate compounds and use thereof

Family Cites Families (55)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3361706A (en) 1964-03-06 1968-01-02 American Cyanamid Co Control of the photochromic return rate of (arylazo) thioformic arylhydrazidates
US3567605A (en) 1966-03-30 1971-03-02 Ralph S Becker Photochemical process
GB1186987A (en) 1967-08-30 1970-04-08 Fuji Photo Film Co Ltd Photochromic Compounds
JPS4948631B1 (enExample) 1968-10-28 1974-12-23
US4215010A (en) 1978-09-08 1980-07-29 American Optical Corporation Photochromic compounds
US4342668A (en) 1978-09-08 1982-08-03 American Optical Corporation Photochromic compounds
US4429092A (en) * 1982-12-06 1984-01-31 U.S. Peroxygen Company Room temperature polymerization of acrylate monomers with peroxyesters
US4637698A (en) 1983-11-04 1987-01-20 Ppg Industries, Inc. Photochromic compound and articles containing the same
US4880667A (en) 1985-09-24 1989-11-14 Ppg Industries, Inc. Photochromic plastic article and method for preparing same
JPS62195383A (ja) 1986-02-21 1987-08-28 Toray Ind Inc 新規スピロナフトピラン化合物
GB8611837D0 (en) 1986-05-15 1986-06-25 Plessey Co Plc Photochromic spiropyran compounds
GB8614680D0 (en) 1986-06-17 1986-07-23 Plessey Co Plc Photoreactive lenses
US4816584A (en) 1986-11-12 1989-03-28 Ppg Industries, Inc. Photochromic spiro(indoline)benzoxazines
US4931219A (en) 1987-07-27 1990-06-05 Ppg Industries, Inc. Photochromic compound and articles containing the same
JP2570776B2 (ja) * 1987-11-13 1997-01-16 三菱瓦斯化学株式会社 イオウ含有脂肪族系アクリル化合物
US4931220A (en) 1987-11-24 1990-06-05 Ppg Industries, Inc. Organic photochromic pigment particulates
US5066818A (en) 1990-03-07 1991-11-19 Ppg Industries, Inc. Photochromic naphthopyran compounds
JPH0710897B2 (ja) 1990-04-27 1995-02-08 日本油脂株式会社 プラスチックレンズ
JP2867638B2 (ja) 1990-07-03 1999-03-08 日本油脂株式会社 光学用樹脂
JP2811353B2 (ja) 1990-07-06 1998-10-15 ゼリア新薬工業株式会社 炎症性腸疾患予防・治療剤
JPH05303003A (ja) * 1992-04-28 1993-11-16 Nippon Oil & Fats Co Ltd 光学材料用組成物及び光学材料
US5274132A (en) 1992-09-30 1993-12-28 Transitions Optical, Inc. Photochromic naphthopyran compounds
US5405958A (en) 1992-12-21 1995-04-11 Transitions Optical, Inc. Photochromic spiro(indoline)naphthoxazine compounds
WO1994020869A1 (en) 1993-03-12 1994-09-15 Ppg Industries, Inc. Novel benzopyrans
US5466398A (en) 1993-06-21 1995-11-14 Transitions Optical, Inc. Photochromic substituted naphthopyran compounds
US5384077A (en) 1993-06-21 1995-01-24 Transitions Optical, Inc. Photochromic naphthopyran compounds
US6096375A (en) 1993-12-21 2000-08-01 3M Innovative Properties Company Optical polarizer
US5882774A (en) 1993-12-21 1999-03-16 Minnesota Mining And Manufacturing Company Optical film
JP3203142B2 (ja) * 1994-04-21 2001-08-27 セイコーエプソン株式会社 被膜形成用塗布液および合成樹脂製レンズ
US5789476A (en) 1995-03-03 1998-08-04 Seiko Epson Corporation Film-forming coating solution and synthetic resin lens
JP3429393B2 (ja) * 1995-06-14 2003-07-22 Ｈｏｙａ株式会社 軟性眼内レンズ
US5867316A (en) 1996-02-29 1999-02-02 Minnesota Mining And Manufacturing Company Multilayer film having a continuous and disperse phase
JP3966577B2 (ja) * 1996-05-29 2007-08-29 三井化学株式会社 含硫ｏ−（メタ）アクリレート化合物、その製造方法および用途
JP4617331B2 (ja) * 1996-05-29 2011-01-26 三井化学株式会社 チオール化合物、含硫ｏ−（メタ）アクリレート化合物およびその用途
US5811503A (en) * 1996-11-27 1998-09-22 Ppg Industries, Inc. Polymerizable composition
JP3465528B2 (ja) * 1997-04-22 2003-11-10 三菱瓦斯化学株式会社 新規な光学材料用樹脂
FR2765879B1 (fr) 1997-07-11 2002-06-07 Essilor Int Nouvelles compositions polymerisables et lentilles optiques a haut indice de refraction obtenues a partir de ces compositions
JPH11125701A (ja) 1997-10-23 1999-05-11 Kureha Chem Ind Co Ltd プラスチックレンズ
JPH11174201A (ja) * 1997-12-16 1999-07-02 Mitsubishi Rayon Co Ltd プラスチックレンズ用組成物およびプラスチックレンズ
JP3560461B2 (ja) 1998-03-02 2004-09-02 株式会社トクヤマ フォトクロミック硬化性組成物
AU735154B2 (en) 1998-03-02 2001-07-05 Tokuyama Corporation Photochromic curable composition
JP2000186120A (ja) 1998-12-22 2000-07-04 Tokuyama Corp 硬化性組成物
CN100494239C (zh) 1999-11-18 2009-06-03 Ppg工业俄亥俄公司 光学树脂组合物
AU777978B2 (en) * 1999-12-02 2004-11-11 Tokuyama Corporation Method of preparing a sulfur-containing compound
ES2245366T3 (es) * 2000-05-31 2006-01-01 Tokuyama Corporation Composicion endurecible y producto endurecido fotocromico.
JP2002082201A (ja) 2000-09-07 2002-03-22 Seed Co Ltd 合成樹脂製レンズ及びその製造方法
US6541591B2 (en) * 2000-12-21 2003-04-01 3M Innovative Properties Company High refractive index microreplication resin from naphthyloxyalkylmethacrylates or naphthyloxyacrylates polymers
JP2004536934A (ja) 2001-07-25 2004-12-09 ピーピージー インダストリーズ オハイオ， インコーポレイテッド 高屈折率光学樹脂組成物
US6808657B2 (en) 2002-02-12 2004-10-26 3M Innovative Properties Company Process for preparing a K-type polarizer
WO2004009659A1 (ja) 2002-07-22 2004-01-29 Mitsui Chemicals, Inc. 無機超微粒子を含有する樹脂組成物
US7256921B2 (en) 2003-07-01 2007-08-14 Transitions Optical, Inc. Polarizing, photochromic devices and methods of making the same
EP1830205B1 (en) 2004-12-20 2014-08-20 Nikon Corporation Close-bonded diffractive optical element
WO2007131149A1 (en) 2006-05-05 2007-11-15 Ppg Industries Ohio, Inc. Thioether functional oligomeric polythiols and articles prepared therefrom
JP2009102550A (ja) 2007-10-24 2009-05-14 Mitsubishi Chemicals Corp 重合性組成物およびその硬化物
EP2221325B1 (en) * 2007-12-13 2014-04-16 Tokuyama Corporation Photochromic curable composition

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0810210A2 (en) * 1996-05-29 1997-12-03 Mitsui Toatsu Chemicals, Inc. Thiol and sulfur-containing o-(meth)acrylate compounds and use thereof

Also Published As

Publication number Publication date
JP2014526575A (ja) 2014-10-06
EP3838935A2 (en) 2021-06-23
EP3957661A1 (en) 2022-02-23
JP2015187276A (ja) 2015-10-29
US9334345B2 (en) 2016-05-10
JP6022642B2 (ja) 2016-11-09
TWI547506B (zh) 2016-09-01
WO2013036774A1 (en) 2013-03-14
JP5848453B2 (ja) 2016-01-27
TW201317263A (zh) 2013-05-01
KR101657380B1 (ko) 2016-09-19
EP3838935A3 (en) 2021-10-13
HK1196387A1 (zh) 2014-12-12
EP3957661A8 (en) 2022-04-27
JP2016135876A (ja) 2016-07-28
CN103814052A (zh) 2014-05-21
TWI582120B (zh) 2017-05-11
EP2753649B1 (en) 2022-03-09
TW201619218A (zh) 2016-06-01
US20130082220A1 (en) 2013-04-04
PH12014500441A1 (en) 2014-04-28
KR20140058687A (ko) 2014-05-14
EP2753649A1 (en) 2014-07-16
EP2753649B8 (en) 2022-04-27

Similar Documents

Publication Publication Date Title
CN103814052B (zh) 含具有硫醚连接基的(甲基)丙烯酸酯单体的能聚合的组合物
US6342571B1 (en) High refractive index optical resin composition
EP1409562B1 (en) High refractive index optical resin composition
CN101300507B (zh) 光致变色多焦点光学制品
AU746457B2 (en) Optical resin composition
DE60020963T2 (de) Optische harzzusammensetzung mit thiol-ene prepolymer
WO2012141306A1 (ja) 眼鏡用フォトクロミックレンズ
JP2004536934A (ja) 高屈折率光学樹脂組成物
KR102622246B1 (ko) 고굴절률 조성물 및 이의 용도
US9752025B2 (en) Polymerizable compositions and optical articles prepared therefrom
AU764146B2 (en) Polymerizable sulfur-containing (meth)acrylate, polymerizable composition and optical lens
HK1196387B (en) Polymerizable compositions containing (meth)acrylate monomers having sulfide linkages
JP3981602B2 (ja) ラジカル重合性含硫黄アダマンタン化合物および硬化体
JP7287819B2 (ja) 眼鏡レンズおよび眼鏡
MXPA01010711A (en) Optical resin composition comprising thiol-ene prepolymer

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
REG Reference to a national code

Ref country code: HK

Ref legal event code: DE

Ref document number: 1196387

Country of ref document: HK

C14 Grant of patent or utility model
GR01 Patent grant
REG Reference to a national code

Ref country code: HK

Ref legal event code: GR

Ref document number: 1196387

Country of ref document: HK