CN103781817A - 制备二羧酸锌的方法 - Google Patents
制备二羧酸锌的方法 Download PDFInfo
- Publication number
- CN103781817A CN103781817A CN201280043741.7A CN201280043741A CN103781817A CN 103781817 A CN103781817 A CN 103781817A CN 201280043741 A CN201280043741 A CN 201280043741A CN 103781817 A CN103781817 A CN 103781817A
- Authority
- CN
- China
- Prior art keywords
- zinc
- dicarboxylic acid
- acid
- oxide
- cationic emulsifier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011701 zinc Substances 0.000 title claims abstract description 41
- 229910052725 zinc Inorganic materials 0.000 title claims abstract description 40
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims abstract description 34
- 238000000034 method Methods 0.000 claims abstract description 33
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 15
- 125000002091 cationic group Chemical group 0.000 claims abstract description 12
- 239000002904 solvent Substances 0.000 claims abstract description 11
- JFCQEDHGNNZCLN-UHFFFAOYSA-N glutaric acid Chemical compound OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims description 18
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 229920000379 polypropylene carbonate Polymers 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 11
- 150000003751 zinc Chemical class 0.000 claims description 8
- -1 n-hexadecane amine Chemical class 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 150000002924 oxiranes Chemical class 0.000 claims description 6
- 238000006116 polymerization reaction Methods 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 6
- 239000011949 solid catalyst Substances 0.000 claims description 6
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 5
- 235000011089 carbon dioxide Nutrition 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- GJEZBVHHZQAEDB-UHFFFAOYSA-N 6-oxabicyclo[3.1.0]hexane Chemical compound C1CCC2OC21 GJEZBVHHZQAEDB-UHFFFAOYSA-N 0.000 claims description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical group C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 3
- ZWAJLVLEBYIOTI-UHFFFAOYSA-N cyclohexene oxide Chemical compound C1CCCC2OC21 ZWAJLVLEBYIOTI-UHFFFAOYSA-N 0.000 claims description 3
- FWFSEYBSWVRWGL-UHFFFAOYSA-N cyclohexene oxide Natural products O=C1CCCC=C1 FWFSEYBSWVRWGL-UHFFFAOYSA-N 0.000 claims description 3
- DCAYPVUWAIABOU-UHFFFAOYSA-N alpha-n-hexadecene Natural products CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 claims description 2
- 125000003158 alcohol group Chemical group 0.000 claims 1
- 150000003752 zinc compounds Chemical class 0.000 abstract 1
- SCRKTTJILRGIEY-UHFFFAOYSA-N pentanedioic acid;zinc Chemical compound [Zn].OC(=O)CCCC(O)=O SCRKTTJILRGIEY-UHFFFAOYSA-N 0.000 description 25
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 20
- 230000000694 effects Effects 0.000 description 17
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 14
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 239000003054 catalyst Substances 0.000 description 12
- FJLUATLTXUNBOT-UHFFFAOYSA-N 1-Hexadecylamine Chemical compound CCCCCCCCCCCCCCCCN FJLUATLTXUNBOT-UHFFFAOYSA-N 0.000 description 8
- 150000001412 amines Chemical class 0.000 description 8
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 8
- 239000011787 zinc oxide Substances 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- XIOUDVJTOYVRTB-UHFFFAOYSA-N 1-(1-adamantyl)-3-aminothiourea Chemical compound C1C(C2)CC3CC2CC1(NC(=S)NN)C3 XIOUDVJTOYVRTB-UHFFFAOYSA-N 0.000 description 4
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 4
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 230000009466 transformation Effects 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000013019 agitation Methods 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 150000005676 cyclic carbonates Chemical class 0.000 description 3
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000002798 polar solvent Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000011345 viscous material Substances 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000002638 heterogeneous catalyst Substances 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- RZJRJXONCZWCBN-UHFFFAOYSA-N octadecane Chemical compound CCCCCCCCCCCCCCCCCC RZJRJXONCZWCBN-UHFFFAOYSA-N 0.000 description 2
- 239000003880 polar aprotic solvent Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000012874 anionic emulsifier Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000011951 cationic catalyst Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000002815 homogeneous catalyst Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000012875 nonionic emulsifier Substances 0.000 description 1
- 229940038384 octadecane Drugs 0.000 description 1
- 150000001282 organosilanes Chemical class 0.000 description 1
- 238000004375 physisorption Methods 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N propylene glycol Substances CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 150000003509 tertiary alcohols Chemical class 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/06—Zinc compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/20—General preparatory processes
- C08G64/32—General preparatory processes using carbon dioxide
- C08G64/34—General preparatory processes using carbon dioxide and cyclic ethers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/41—Preparation of salts of carboxylic acids
- C07C51/412—Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Polyesters Or Polycarbonates (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11180727 | 2011-09-09 | ||
| EP11180727.7 | 2011-09-09 | ||
| PCT/EP2012/066930 WO2013034489A1 (fr) | 2011-09-09 | 2012-08-31 | Procédé de préparation de dicarboxylate de zinc |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103781817A true CN103781817A (zh) | 2014-05-07 |
Family
ID=46755016
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280043741.7A Pending CN103781817A (zh) | 2011-09-09 | 2012-08-31 | 制备二羧酸锌的方法 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20140200328A1 (fr) |
| EP (1) | EP2753653A1 (fr) |
| KR (1) | KR20140062130A (fr) |
| CN (1) | CN103781817A (fr) |
| WO (1) | WO2013034489A1 (fr) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106457212A (zh) * | 2014-06-13 | 2017-02-22 | 株式会社Lg化学 | 有机锌催化剂及其制备方法，以及使用该有机锌催化剂制备聚(碳酸亚烃酯)的方法 |
| WO2023217161A1 (fr) * | 2022-05-11 | 2023-11-16 | 烟台大学 | Catalyseur polymère de coordination de zinc, procédé de préparation associé et utilisation correspondante |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101747399B1 (ko) | 2014-06-13 | 2017-06-14 | 주식회사 엘지화학 | 유기 아연 촉매의 제조 방법 및 폴리알킬렌 카보네이트 수지의 제조 방법 |
| WO2015190874A1 (fr) * | 2014-06-13 | 2015-12-17 | 주식회사 엘지화학 | Catalyseur de zinc organique, procédé de fabrication de ce dernier et procédé de préparation d'une résine de carbonate de polyalkylène à l'aide d'un catalyseur de zinc organique |
| US10047032B2 (en) | 2014-06-13 | 2018-08-14 | Lg Chem, Ltd. | Preparation method of organic zinc catalyst and poly(alkylene carbonate) resin |
| KR101767310B1 (ko) | 2015-07-10 | 2017-08-10 | 국민대학교산학협력단 | 전자끄는기를 포함하는 에폭사이드, 이산화탄소 및 전자끄는기를 포함하지 않는 에폭사이드의 삼원중합체 제조방법 |
| KR102088505B1 (ko) * | 2015-07-13 | 2020-03-12 | 주식회사 엘지화학 | 아연계 촉매의 제조방법 및 이를 이용한 폴리알킬렌카보네이트의 제조방법 |
| WO2017155307A2 (fr) | 2016-03-09 | 2017-09-14 | 주식회사 엘지화학 | Catalyseur organozincique, son procédé de préparation et procédé de préparation d'une résine de carbonate de polyalkylène au moyen de ce catalyseur |
| KR102000129B1 (ko) * | 2016-03-24 | 2019-07-15 | 주식회사 엘지화학 | 유기 아연 담지 촉매, 이의 제조 방법, 및 상기 촉매를 이용한 폴리알킬렌 카보네이트 수지의 제조 방법 |
| EP3527286A4 (fr) | 2017-08-28 | 2020-09-02 | LG Chem, Ltd. | Procédé de production d'un catalyseur de zinc organique et catalyseur de zinc organique produit par ce procédé, et procédé de préparation de résine de carbonate de polyalkylène utilisant ce catalyseur |
| WO2019045418A1 (fr) * | 2017-08-28 | 2019-03-07 | 주식회사 엘지화학 | Procédé de production d'un catalyseur de zinc organique et catalyseur de zinc organique produit par ce procédé, et procédé de préparation de résine de carbonate de polyalkylène utilisant ce catalyseur |
| EP3778022A4 (fr) | 2018-12-20 | 2021-11-17 | Lg Chem, Ltd. | Procédé de préparation d'un catalyseur au zinc organique et procédé de préparation d'une résine au carbonate-polyalkylène à l'aide du catalyseur au zinc organique ainsi préparé |
| JPWO2021140869A1 (fr) * | 2020-01-08 | 2021-07-15 | ||
| IT202000029237A1 (it) * | 2020-12-01 | 2022-06-01 | Epox Co2 S R L | Processo per la preparazione di zinco dicarbossilato e il suo uso come catalizzatore nella sintesi di polialchilene carbonato a partire da co2 tramite catalisi eterogenea |
| KR102576776B1 (ko) * | 2022-10-28 | 2023-09-07 | 아주대학교산학협력단 | 이산화탄소-에폭사이드 반응 촉매, 이의 제조 방법 및 이를 이용한 폴리머 합성 방법 |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3706713A (en) * | 1970-08-11 | 1972-12-19 | Shell Oil Co | Aliphatic polycarbonates |
| US4783445A (en) * | 1987-12-14 | 1988-11-08 | Arco Chemical Company | Soluble epoxide/carbon dioxide copolymerization catalysts |
| CN1040375A (zh) * | 1988-08-09 | 1990-03-14 | 三井石油化学工业株式会社 | 含锌固体催化剂及其制备方法和制备聚亚烷基碳酸酯的方法 |
| US5026676A (en) * | 1989-06-07 | 1991-06-25 | Air Products And Chemicals, Inc. | Catalyst for the copolymerization of epoxides with CO2 |
| CN1302694A (zh) * | 2000-11-22 | 2001-07-11 | 中国科学院广州化学研究所 | 二元羧酸锌催化剂的制备方法 |
| WO2003029325A1 (fr) * | 2001-09-27 | 2003-04-10 | Basf Aktiengesellschaft | Procede de fabrication de polycarbonates aliphatiques |
| CN1668671A (zh) * | 2002-06-20 | 2005-09-14 | Posco公司 | 脂肪族聚碳酸酯聚合用催化剂的制备方法及聚合脂肪族聚碳酸酯的方法 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102005010320B4 (de) | 2005-03-03 | 2007-02-15 | Grillo-Werke Ag | Oberflächenmodifizierte Zinkoxidpartikel |
-
2012
- 2012-08-31 EP EP12751534.4A patent/EP2753653A1/fr not_active Withdrawn
- 2012-08-31 US US14/343,604 patent/US20140200328A1/en not_active Abandoned
- 2012-08-31 CN CN201280043741.7A patent/CN103781817A/zh active Pending
- 2012-08-31 WO PCT/EP2012/066930 patent/WO2013034489A1/fr active Application Filing
- 2012-08-31 KR KR1020147009329A patent/KR20140062130A/ko not_active Application Discontinuation
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3706713A (en) * | 1970-08-11 | 1972-12-19 | Shell Oil Co | Aliphatic polycarbonates |
| US4783445A (en) * | 1987-12-14 | 1988-11-08 | Arco Chemical Company | Soluble epoxide/carbon dioxide copolymerization catalysts |
| CN1040375A (zh) * | 1988-08-09 | 1990-03-14 | 三井石油化学工业株式会社 | 含锌固体催化剂及其制备方法和制备聚亚烷基碳酸酯的方法 |
| US5026676A (en) * | 1989-06-07 | 1991-06-25 | Air Products And Chemicals, Inc. | Catalyst for the copolymerization of epoxides with CO2 |
| CN1302694A (zh) * | 2000-11-22 | 2001-07-11 | 中国科学院广州化学研究所 | 二元羧酸锌催化剂的制备方法 |
| WO2003029325A1 (fr) * | 2001-09-27 | 2003-04-10 | Basf Aktiengesellschaft | Procede de fabrication de polycarbonates aliphatiques |
| CN1668671A (zh) * | 2002-06-20 | 2005-09-14 | Posco公司 | 脂肪族聚碳酸酯聚合用催化剂的制备方法及聚合脂肪族聚碳酸酯的方法 |
Non-Patent Citations (2)
| Title |
|---|
| JONG-SEONG KIM ET AL: "Synthesis of Zinc Glutarates with Various Morphologies Using an Amphiphilic Template and Their Catalytic Activities in the Copolymerization of Carbon Dioxide and Propylene Oxide", 《JOURNAL OF POLYMER SCIENCE PART A：POLYMER CHEMISTRY》 * |
| M.REE ET AL: "A New Copolymerization Process Leading to Poly(propylene carbonate) with a Highly Enhanced Yield from Carbon Dioxide and Propylene Oxide", 《JOURNAL OF POLYMER SCIENCE PART A：POLYMER CHEMISTRY》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106457212A (zh) * | 2014-06-13 | 2017-02-22 | 株式会社Lg化学 | 有机锌催化剂及其制备方法，以及使用该有机锌催化剂制备聚(碳酸亚烃酯)的方法 |
| CN106457212B (zh) * | 2014-06-13 | 2019-04-23 | 株式会社Lg化学 | 有机锌催化剂及其制备方法，以及使用该有机锌催化剂制备聚(碳酸亚烃酯)的方法 |
| WO2023217161A1 (fr) * | 2022-05-11 | 2023-11-16 | 烟台大学 | Catalyseur polymère de coordination de zinc, procédé de préparation associé et utilisation correspondante |
Also Published As
| Publication number | Publication date |
|---|---|
| US20140200328A1 (en) | 2014-07-17 |
| EP2753653A1 (fr) | 2014-07-16 |
| WO2013034489A1 (fr) | 2013-03-14 |
| KR20140062130A (ko) | 2014-05-22 |
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