CN103773269B - A kind of starchiness cigarette glue that contains synthetic polymer - Google Patents
A kind of starchiness cigarette glue that contains synthetic polymer Download PDFInfo
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- CN103773269B CN103773269B CN201210400084.9A CN201210400084A CN103773269B CN 103773269 B CN103773269 B CN 103773269B CN 201210400084 A CN201210400084 A CN 201210400084A CN 103773269 B CN103773269 B CN 103773269B
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Abstract
A starchiness cigarette glue that contains synthetic polymer, is characterized in that: the one-tenth by following weight ratio is grouped into: water: 35%-85%, pyrolysis dextrin 5%-50%, sucrose<i>:</i>5%-50%, synthetic polymer 0.1%-20%, anticorrisive agent 0.05%-1%, defoamer 0.05%-1%, auxiliary agent 0-5%. Starchiness cigarette glue of the present invention has good viscosity, mobility and stability, can stablize more than three months time of depositing at normal temperatures. Any one adhesive can be used as in production of cigarettes uses, as overlapping glue, connect mouth glue, filter stick centre-line glue, packaging glue and aluminum foil composite glue etc., and go for the cigarette machine of any type, particularly the above cigarette machines of 7000/minute of single rifle speed of a motor vehicle and the speed of a motor vehicle are greater than the cigarette machines faster such as 10000/minute. Also relate to the occasion of paper bonding applicable to other occasion as binding papers, bottle label, packing box etc.
Description
Technical field
The present invention relates to starchiness adhesive, be particularly a kind ofly applicable to the shallow lake of containing synthetic polymer that production of cigarettes is usedOpaque cigarette glue.
Background technology
Adhesive is one of raw and auxiliary material important in production of cigarettes manufacture process, in a lot of production of cigarettes operations, all relates toAnd to adhesive, mainly comprise: overlapping glue, connect mouth glue, filter stick centre-line glue, packaging glue and aluminum foil composite glue etc. At present, domestic masterThe stream cigarette machine list rifle speed of a motor vehicle substantially about 7000/minute (speed of a motor vehicle of some new cigarette machine reaches 14000-16000 props up/Minute), to calculate with this cigarette speed, the speed that rolls out of plume is about 500 ms/min of left and right, for example, concerning overlapping glue, fromIt is coated on cigarette paper the time of plume between out and is less than 0.1 second, and drying time is only less than 0.1 second, otherwise cigarette machineJust there will be " race bar " phenomenon and quit work; Therefore, this just requires cigarette glue to have excellent adhesive property, rheological propertyDeng.
Because polyvinyl acetate emulsion class adhesive possesses above-mentioned performance characteristics, can adapt to high-speed cigarette machine requirement, because ofAnd at home and abroad cigarette industry is generally used. But be non-natural glue taking polyvinyl acetate emulsion as basic adhesiveGlutinous agent, at present, people are interested in the adhesive of natural class, as starchiness adhesive etc., because natural class adhesive is formerMaterial is originated more extensively, more environmental protection.
Abroad, since the 80s and 90s in last century developing starch High Speed Cigarette Adhesives, for example United States Patent (USP) 5085228 proposesOne comprise and the mixture of crosslinked starch and converted starch (referring in particular to denaturated starch by acid) mixture carried out obtaining after gelatinizationStarch cigarette glue, wherein the amylopectin content of special requirement ative starch is at least 70%(weight), and this mixture is before gelatinizationCan select to carry out etherificate, esterification and oxidation modification, this starch cigarette glue is applicable to 6000/minute of the speed of a motor vehicle and above volumeThe production of cigarette machine. United States Patent (USP) 5155140 has proposed a kind of adhesive, mainly contains by 100 parts of water, 4-120 part Arabic gum, 3-The mixture of 80 parts of water soluble starch catabolites, CMS, gelling starch forms. United States Patent (USP) 5329004 has proposedA kind of taking at least 90%(weight of amylopectin content) ative starch as raw material, by sour sex change (or enzymolysis, oxidation), phosphoric acidEsterification, gelatinization have obtained a kind of starch cigarette glue, and this starch cigarette glue is applicable to 6000/minute of the speed of a motor vehicle and above cigaretteThe production of machine. United States Patent (USP) 5490875 has proposed a kind of taking at least 70%(weight of amylopectin content) ative starch as raw material,Prepare respectively white dextrin and hydrolyzed starch (by enzyme and/or acid), then carried out gelatinization, obtained starch adhesive.Chinese patent CN1095864C has proposed a kind of unmodified starch, 5-60% modified starch, 0-5% stream of the 2-25% of comprising dispersivenessThe starch cigarette glue that becomes modifier, about 0-1% anticorrisive agent and 0-1% defoamer composition, this amylan is large applicable to speed of productionIn 7000 cigarette per minute and be sometimes greater than the cigarette machine of 10000 cigarette per minute. Chinese patent CN100556973C carriesA kind of modified starch with one or more (acetylated starch, acetylation two crosslinked starch, etherification starch, etherificate are gone outCrosslinked starch) starch-based adhesive that obtains after modification for the second time again, the modification for the second time of modified starch is to be pasted intoIn the process of glue, carry out, be acylation modification or etherification modifiedly synchronize and carry out with degraded, this amylan is applicable to being greater than etc.In the cigarette machine of 7000/minute. But a lot of starch cigarette glues that relate in existing patent still exist car while productionThe problems such as the speed low even not mentioned start speed of a motor vehicle, viscosity is poor, glue poor stability, and at present domesticly not yet there is meeting cigaretteThe commercial starchiness cigarette glue product of industry practical application request. Therefore, still need to meet existing cigarette machineNumerous requirements such as the high speed of a motor vehicle also have the starchiness cigarette glue of good viscosity, mobility, stability.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, provide one can meet existing cigarette machine and normally produceDemand (7000/minute of single rifle speed of a motor vehicle and with first-class), and the one with good viscosity, mobility and stability contains and closesBecome the starchiness cigarette glue of polymer.
The object of the invention is to be achieved through the following technical solutions:
A starchiness cigarette glue that contains synthetic polymer, is grouped into by the one-tenth of following weight ratio:
Water 35%-85%
Pyrolysis dextrin 5%-50%
Sucrose 5%-50%
Synthetic polymer 0.1%-20%
Anticorrisive agent 0.05%-1%
Defoamer 0.05%-1%
Auxiliary agent 0-5%
Pyrolysis dextrin in the present invention comprises yellow starch gum, Britain glue.
Sucrose in the present invention can use malt syrup, glucose, maltitol, maltodextrin, fruit glucose syrup, ring to stick with pasteAny one in essence or multiple replacement.
Synthetic polymer in the present invention comprises polyethylene glycol oxide, polyvinyl alcohol, polyvinylpyrrolidone, polyacrylamideAmine, Sodium Polyacrylate etc., have the effect that strengthens cohesive force, regulation and control cigarette glue viscosity.
Pyrolysis dextrin in the present invention is all by ative starch, modification obtains, and wherein ative starch is selected in following kindAny one or multiple: cornstarch, rice starch, wheaten starch, barley starch, sorghum starch, farina, cassavaStarch, starch from sweet potato, green starch, pea starch, bajiao banana starch, sago starch and waxy starch as waxy corn starch,Waxy Rice Starch, wax sorghum starch etc.
Anticorrisive agent in the present invention select in following kind any one or multiple: benzoic acid and its esters, sorbic acidPotassium, dehydro sodium acetate, calcium propionate, sodium Diacetate, sodium lactate, nisin, natamycin etc.
Defoamer in the present invention select in following kind any one or multiple: the alcohols such as propane diols, dimethyl-siliconEster class, the mineral oil such as polyethers, Tweens, Tripolyglycerol monostearates such as wet goods is polysiloxane-based, polypropylene glycerol aetherAnd compound defoamer etc.
Function additive in the present invention select in following kind any one or multiple: glycerin monostearate, tristearinAcyl calcium lactate sodium; The polyalcohols such as glycerine, sorbierite; Some mineral matter classes such as bentonite, silica. Suitable by selectingFunction additive, can play tackify, improve liquidity and the effect such as stability.
The solid content of the starchiness cigarette glue in the present invention is about 15%-65%(weight), pH value is about 3-9 and preferred 5-8,Viscosity is about 100cps-20000cps(25 DEG C), and it has good viscosity, mobility and stability, at normal temperatures canEnough stable depositing more than three months time.
Any one adhesive that starchiness cigarette glue in the present invention can be used as in production of cigarettes uses, as takes mouthGlue, connect mouth glue, filter stick centre-line glue, packaging glue and aluminum foil composite glue etc., and go for the cigarette machine of any type, specialThat the above cigarette machines of 7000/minute of single rifle speed of a motor vehicle and the speed of a motor vehicle are greater than the cigarette machines faster such as 10000/minute.
Starchiness cigarette glue in the present invention also applicable to other occasion as binding papers, bottle label, packing box etc.Relate to the occasion of paper bonding.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is done to further detailed description, but the scope of the invention is not limited to these enforcementExample.
Embodiment 1
Adopt 8% Britain glue, 8% sucrose, 4% polyethylene glycol oxide, 1% potassium sorbate, 1% dimethicone withAnd 78% water prepares starchiness cigarette glue, wherein Britain glue is prepared by tapioca. The preparation flow of starchiness cigarette glueFor: first polyethylene glycol oxide is dissolved in water, then adds successively Britain glue, sucrose, potassium sorbate and dimethicone, stirMix and mix.
After testing: products obtained therefrom has 20% solid content, in the time of 25 DEG C, brookfield viscosity is 895cps, this productThe viscosity of product was stable in three months, and had good viscosity and mobility etc.
Embodiment 2
Adopt 10% yellow starch gum, 15% glucose, 5% polyvinyl alcohol, 3% silica, 1% epoxidized soybean oil,1% glycerine, 1% potassium sorbate, 1% the fatty acid ester compounded thing of higher alcohols and 63% water are prepared starchiness cigarette glue, itsMiddle yellow starch gum is prepared by farina. The preparation flow of starchiness cigarette glue is: first polyvinyl alcohol is dissolvedIn water, then add successively yellow starch gum, glucose, silica, epoxidized soybean oil, glycerine, potassium sorbate and high-carbon alcohol esterFat acid esters compound, is uniformly mixed.
After testing: products obtained therefrom has 35% solid content, in the time of 25 DEG C, brookfield viscosity is 8100cps, this productThe viscosity of product was stable in three months, and had good viscosity and mobility etc.
Embodiment 3
Adopt 10% Britain glue, 18% maltitol, 10% polyvinylpyrrolidone, 2% bentonite, 1% silicon ashStone flour, 1% benzoic acid, 1% polyoxyethylene polyoxypropylene amidogen ether and 57% water are prepared starchiness cigarette glue, wherein BritainGlue is prepared by waxy corn starch. The preparation flow of starchiness cigarette glue is: first polyvinylpyrrolidone is dissolved inIn water, then add successively Britain glue, maltitol, bentonite, wollastonite in powder, benzoic acid and polyoxyethylene polyoxypropylene amineEther, is uniformly mixed.
After testing: products obtained therefrom has 41% solid content, in the time of 25 DEG C, brookfield viscosity is 12620cps, shouldThe viscosity of product was stable in three months, and had good viscosity and mobility etc.
Embodiment 4
Adopt 15% Britain glue, 8% cyclodextrin, 7% polyacrylamide, 2% bentonite, 0.5% potassium sorbate,0.5% natamycin, 1% dimethicone and 66% water are prepared starchiness cigarette glue, and wherein Britain glue is by wheaten starchPrepare. The preparation flow of starchiness cigarette glue is: first polyacrylamide is dissolved in water, then adds successively BritainGlue, cyclodextrin, bentonite, potassium sorbate, natamycin and dimethicone, be uniformly mixed.
After testing: products obtained therefrom has 32% solid content, in the time of 25 DEG C, brookfield viscosity is 7690cps, this productThe viscosity of product was stable in three months, and had good viscosity and mobility etc.
Embodiment 5
Adopt 13% yellow starch gum, 20% sucrose, 15% maltodextrin, 6% Sodium Polyacrylate, 1% streptococcus lactisElement, 1% silicone emulsion and 44% water are prepared starchiness cigarette glue, and its Sino-British yellow starch gum is to be prepared into by waxy corn starchArrive. The preparation flow of starchiness cigarette glue is: first Sodium Polyacrylate is dissolved in water, then add successively yellow starch gum,Sucrose, maltodextrin, nisin and silicone emulsion, be uniformly mixed.
After testing: products obtained therefrom has 53% solid content, in the time of 25 DEG C, brookfield viscosity is 14900cps, shouldThe viscosity of product was stable in three months, and had good viscosity and mobility etc.
Embodiment 6
Adopt 5% Britain glue, 12% glucose, 5% cyclodextrin, 3% polyethylene glycol oxide, 0.5% potassium sorbate,0.5% dimethicone and 74% water are prepared starchiness cigarette glue, and wherein Britain glue is prepared by cornstarch.The preparation flow of starchiness cigarette glue is: first polyethylene glycol oxide is dissolved in water, then adds successively Britain glue, grapeSugar, cyclodextrin, potassium sorbate and dimethicone, be uniformly mixed.
After testing: products obtained therefrom has 24% solid content, in the time of 25 DEG C, brookfield viscosity is 885ps, this productViscosity in three months, be stable, and there is good viscosity and mobility etc.
Claims (7)
1. a starchiness cigarette glue that contains synthetic polymer, is characterized in that: the one-tenth by following weight ratio is grouped into:
Water 35%-85%
Pyrolysis dextrin 5%-50%
Sucrose 5%-50%
Synthetic polymer 0.1%-20%
Anticorrisive agent 0.05%-1%
Defoamer 0.05%-1%
Auxiliary agent 0-5%
Described synthetic polymer comprises polyethylene glycol oxide, polyvinyl alcohol, polyvinylpyrrolidone, polyacrylamide, polyacrylic acidSodium.
2. a kind of starchiness cigarette glue that contains synthetic polymer according to claim 1, is characterized in that: described pyrolysisDextrin comprises yellow starch gum, Britain glue.
3. a kind of starchiness cigarette glue that contains synthetic polymer according to claim 1, is characterized in that: described sucroseCan use any one or multiple generation in malt syrup, glucose, maltitol, maltodextrin, fruit glucose syrup, cyclodextrinReplace.
4. a kind of starchiness cigarette glue that contains synthetic polymer according to claim 1, is characterized in that: anticorrisive agent choosingSelect in following kind any one or multiple: benzoic acid and its esters, potassium sorbate, dehydro sodium acetate, calcium propionate, diacetic acidSodium, sodium lactate, nisin, natamycin.
5. a kind of starchiness cigarette glue that contains synthetic polymer according to claim 1, is characterized in that: defoamer choosingSelect in following kind any one or multiple: propane diols, dimethicone, polypropylene glycerol aether, Tweens, three polyglycereolMonostearate, mineral oil and compound defoamer.
6. a kind of starchiness cigarette glue that contains synthetic polymer according to claim 1, is characterized in that: auxiliary agent is selectedAny one in following kind or multiple: glycerin monostearate, CSL sodium; Glycerine, sorbierite; Bentonite,Silica.
7. a kind of starchiness cigarette glue that contains synthetic polymer according to claim 1, is characterized in that: described starchThe solid content of matter cigarette glue is weight ratio 15%-65%, and pH value is 3-9, and viscosity is 100cps-20000cps at 25 DEG C.
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| CN201210400084.9A CN103773269B (en) | 2012-10-20 | 2012-10-20 | A kind of starchiness cigarette glue that contains synthetic polymer |
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| CN201210400084.9A CN103773269B (en) | 2012-10-20 | 2012-10-20 | A kind of starchiness cigarette glue that contains synthetic polymer |
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| CN103773269A CN103773269A (en) | 2014-05-07 |
| CN103773269B true CN103773269B (en) | 2016-05-25 |
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| CN105860872A (en) * | 2016-04-06 | 2016-08-17 | 江苏理工学院 | Preparation method of special back gum for glass fiber wall cloth |
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| CN109294451A (en) * | 2018-07-27 | 2019-02-01 | 江苏斯瑞达新材料科技有限公司 | Anti-static adhesive and its preparation process |
| CN113150724A (en) * | 2021-03-31 | 2021-07-23 | 江苏唐彩新材料科技股份有限公司 | Water-based PET composite adhesive for cigarette paperboard and preparation method thereof |
| CN114032051A (en) * | 2021-12-28 | 2022-02-11 | 贵阳银镒新材料科技有限公司 | Adhesive for packaging fine cigarettes and preparation method |
| CN115522404B (en) * | 2022-11-01 | 2023-12-19 | 江西广源化工有限责任公司 | Needle-like wollastonite, preparation method thereof and application thereof in preparation of cigarette paper |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1135231A (en) * | 1993-11-18 | 1996-11-06 | 赖克霍德化学公司 | Starch-based adhesive |
| CN102105544A (en) * | 2007-07-02 | 2011-06-22 | 格林百奥生态材料科技（上海）有限公司 | Polymeric composition for cellulosic materials binding and modification |
-
2012
- 2012-10-20 CN CN201210400084.9A patent/CN103773269B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1135231A (en) * | 1993-11-18 | 1996-11-06 | 赖克霍德化学公司 | Starch-based adhesive |
| CN102105544A (en) * | 2007-07-02 | 2011-06-22 | 格林百奥生态材料科技（上海）有限公司 | Polymeric composition for cellulosic materials binding and modification |
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| CN103773269A (en) | 2014-05-07 |
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