CN103773273B - A kind of based on esterification class-pasted starch and the amyloid starchiness cigarette glue of non-gelatinization - Google Patents
A kind of based on esterification class-pasted starch and the amyloid starchiness cigarette glue of non-gelatinization Download PDFInfo
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- CN103773273B CN103773273B CN201210400078.3A CN201210400078A CN103773273B CN 103773273 B CN103773273 B CN 103773273B CN 201210400078 A CN201210400078 A CN 201210400078A CN 103773273 B CN103773273 B CN 103773273B
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Abstract
A kind of based on esterification class-pasted starch and non-gelatinization amyloid novel starch matter cigarette glue, it is characterized in that: be grouped into by the one-tenth of following weight ratio: water 35%-85%, esterification class-pasted starch 5%-45%, non-gelatinization kind of starch 5%-45%, sanitas 0.05%-1%, defoamer 0.05%-1%, functional agent 0-5%; Described gelatinization kind of starch refers to by any one in esterification starch, degraded class-ester starch or multiplely to obtain through gelatinization; Described non-gelatinization kind of starch refers to the treated starch without gelatinization reaction.Cigarette glue of the present invention has good viscosity, mobility and stability, can stablize at normal temperatures and deposit more than three months time, can use as any one sizing agent in production of cigarettes, as overlapping glue, connect mouth glue, filter stick centre-line glue, packaging glue and aluminum foil composite glue etc., and go for the cigarette machine of any type, particularly the cigarette machine of single rifle speed of a motor vehicle more than 7000/minute.
Description
Technical field
The present invention relates to starchiness sizing agent, be particularly applicable to the one of production of cigarettes based on esterification class-pasted starch and the amyloid starchiness cigarette glue of non-gelatinization.
Background technology
Sizing agent is one of raw and auxiliary material important in production of cigarettes manufacturing processed, all relates to sizing agent, mainly comprise in a lot of production of cigarettes operation: overlapping glue, connect mouth glue, filter stick centre-line glue, packaging glue and aluminum foil composite glue etc.At present, the domestic main flow cigarette machine list rifle speed of a motor vehicle is substantially about 7000/minute (speed of a motor vehicle of some new cigarette machine reaches 14000-16000 props up/minute), calculate with this cigarette speed, the speed that rolls out of plume is about about 500 ms/min, such as, concerning overlapping glue, from its be coated in cigarette tissue to plume out time be less than 0.1 second, time of drying is only less than 0.1 second, otherwise cigarette machine just there will be " race bar " phenomenon and quits work; Therefore, this just requires that cigarette glue has excellent adhesive property, rheological property etc.
Because polyvinyl acetate emulsion class sizing agent possesses above-mentioned performance characteristics, can adapt to high-speed cigarette machine requirement, thus at home and abroad cigarette industry is generally used.But the sizing agent based on polyvinyl acetate emulsion is non-natural sizing agent, at present, the sizing agent of people to natural class is interested, as starchiness sizing agent etc. because the raw material sources of natural class tackiness agent more extensively, more environmental protection.
Starch High Speed Cigarette Adhesives is developed abroad from the 80s and 90s in last century, such as United States Patent (USP) 5085228 proposes the mixture that one comprises cross-linking starch and modified starch (referring in particular to denaturated starch by acid), starch cigarette glue is obtained after gelatinization is carried out to mixture, the amylopection content wherein specially requiring ative starch is at least 70%(weight), and this mixture can be selected to carry out etherificate, esterification and oxidation modification before gelatinization, this starch cigarette glue is applicable to the production of the speed of a motor vehicle 6000/minute and above cigarette machine.United States Patent (USP) 5155140 proposes a kind of tackiness agent, mainly contains and is made up of the mixture of 100 parts of water, 4-120 part gum arabic, 3-80 part water soluble starch degraded product, carboxymethyl starch, gelling starch.United States Patent (USP) 5329004 proposes a kind of with amylopection content at least 90%(weight) ative starch for raw material, obtain a kind of starch cigarette glue by Acid denaturation (or enzymolysis, oxidation), Phosphation, gelatinization, this starch cigarette glue is applicable to the production of the speed of a motor vehicle 6000/minute and above cigarette machine.United States Patent (USP) 5490875 proposes a kind of with amylopection content at least 70%(weight) ative starch for raw material, prepared white dextrin and hydrolyzed starch (by enzyme and/or acid) respectively, then carried out gelatinization, obtain starch adhesive.Chinese patent CN1095864C proposes a kind of starch cigarette glue of unmodified starch, 5-60% treated starch, 0-5% rheology modifier, about 0-1% sanitas and the 0-1% defoamer composition comprising 2-25% dispersiveness, and this amylan is applicable to production rate and is greater than per minute 7000 cigarette and the cigarette machine being sometimes greater than per minute 10000 cigarette.Chinese patent CN100556973C proposes a kind of with one or more treated starch (acetylated starch, acetylize two cross-linking starch, etherification starch, Crosslinked and hydroxypropyl starch) the modified starch-based adhesive obtained of process second time again; the second time modification of treated starch carries out in the process of gelatinization plastic; be acylation modification or etherification modifiedly synchronously carry out with degraded, this amylan is applicable to the cigarette machine being more than or equal to 7000/minute.But, the problems such as the speed of a motor vehicle low even not mentioned start speed of a motor vehicle when a lot of starch cigarette glues related in existing patent still also exist production, viscosity are poor, glue poor stability, and domesticly at present not yet there is the commercial starchiness sizing agent product meeting cigarette industry practical application request.Therefore, still need numerous requirements such as the high speed of a motor vehicle that can meet existing cigarette machine and there is the starchiness cigarette sizing agent of good viscosity, mobility, stability.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, there is provided one can meet the normal Production requirement of existing cigarette machine (single rifle speed of a motor vehicle 7000/minute and with first-class), and the one with good viscosity, mobility and stability is based on esterification class-pasted starch and non-gelatinization amyloid novel starch matter cigarette glue.
The object of the invention is to be achieved through the following technical solutions:
A kind of based on esterification class-pasted starch and the amyloid starchiness cigarette glue of non-gelatinization, be grouped into by the one-tenth of following weight ratio:
Water 35%-85%
Esterification class-pasted starch 5%-45%
Non-gelatinization kind of starch 5%-45%
Sanitas 0.05%-1%
Defoamer 0.05%-1%
Functional agent 0-5%
Described esterification class-pasted starch refers to by any one in esterification starch, degraded class-ester starch or multiplely to obtain through gelatinization.Described esterification starch comprises Acetylated potato starch, organic phosphate starch, preferably phosphoric acid esterification starch.Described degraded class-ester starch comprises in pyrolysis-Acetylated potato starch, pyrolysis-organic phosphate starch, enzymolysis-Acetylated potato starch, enzymolysis-organic phosphate starch, Acid denaturation-Acetylated potato starch, Acid denaturation-organic phosphate starch, oxidation-Acetylated potato starch, oxidation-organic phosphate starch, wherein preferred pyrolysis-phosphate ester starch, enzymolysis-phosphate ester starch.
Described non-gelatinization kind of starch refers to the treated starch without gelatinization reaction, comprise ative starch, cross-linking starch, Acetylated potato starch, organic phosphate starch, hydroxyethyl starch, hydroxypropyl starch, carboxymethylated starch, wherein preferred acetate starch, hydroxypropylated starch.
Treated starch in the present invention all by obtaining ative starch modification, wherein ative starch select in following kind any one or multiple: W-Gum, Starch rice, wheat starch, barley starch, sorghum starch, yam starch, tapioca (flour), sweet potato starch, green starch, pea starch, bajiao banana starch, sago starch and waxy starch are as waxy corn starch, Waxy Rice Starch, wax sorghum starch etc.
The composite modified starch such as the pyrolysis-Acetylated potato starch in the present invention, pyrolysis-organic phosphate starch refer to and adopt the multipair ative starch of multiple method of modifying to carry out composite modified product, adopt the esterification process of method for pyrolysis and acetic acid esterified to carry out composite modified product to ative starch as pyrolysis-Acetylated potato starch refers to.
" gelatinization " in the present invention, also known as " αization ", its essence is that water molecules enters in starch small grain, and the hydrogen bond rupture between the starch molecule of crystallization phases and unformed phase, destroys the associated state between starch molecule, is dispersed in water and becomes hydrophilic colloidal solution.According to the difference of equipment used, have multiple production method, the present invention can select cooking process, heat rolls method, in the method such as spray method, extruding puffing method, microwave method, pulse jet method any one or multiple.
Sanitas in the present invention select in following kind any one or multiple: phenylformic acid and its esters, potassium sorbate, Sodium dehydroacetate, calcium propionate, sodium Diacetate, Sodium.alpha.-hydroxypropionate, nisin, tennecetin etc.
Defoamer in the present invention select in following kind any one or multiple: ester class, mineral oil and the composite anti-foaming agent etc. such as polyethers, Tweens, Tripolyglycerol monostearates such as the alcohols such as propylene glycol, dimethyl-silicon wet goods are polysiloxane-based, polypropylene glycerol aether.
Functional agent in the present invention select in following kind any one or multiple: glyceryl monostearate, CSL sodium; The polyalcohols such as glycerine, sorbyl alcohol; The carbohydrates such as sucrose; Some mineral substance classes such as wilkinite, silicon-dioxide; Some vegetable jelly such as bean gum, gelatine, gelatin class.By selecting the functional agent be suitable for, thickening can be played, improve liquidity and the effect such as stability.
The solid content of the starchiness cigarette glue in the present invention is about 15%-65%(weight), pH value is about 3-9 and preferred 5-8, viscosity is about 100cps-20000cps(25 DEG C), and it has good viscosity, mobility and stability, can stablize at normal temperatures and deposit more than three months time.
Starchiness cigarette glue in the present invention can use as any one sizing agent in production of cigarettes, as overlapping glue, connect mouth glue, filter stick centre-line glue, packaging glue and aluminum foil composite glue etc., and go for the cigarette machine of any type, particularly the cigarette machine of single rifle speed of a motor vehicle more than 7000/minute and the speed of a motor vehicle are greater than the cigarette machines faster such as 10000/minute.
Starchiness cigarette glue in the present invention be also applicable to other occasion as binding papers, bottle label, packing box etc. relate to paper bonding occasion.
Embodiment
Below in conjunction with embodiment, further detailed description is done to the present invention, but the scope of the invention is not limited to these embodiments.
Embodiment 1
Adopt the gelatinization thing of the mixture of the phosphate ester starch of 10% and the pyrolysis-organic phosphate starch of 15%, 15% Acetylated potato starch, 0.75% Sodium Benzoate, the dimethyl silicone oil of 0.75%, the glyceryl monostearate of 3% and 54.5% water prepare starchiness cigarette glue, wherein phosphate ester starch and pyrolysis-organic phosphate starch are prepared by W-Gum, and acetate starch is prepared by green starch.The preparation flow of starchiness cigarette glue is: first the gelatinization thing of the mixture of phosphate ester starch and pyrolysis-organic phosphate starch and acetate starch are added to the water, then add Sodium Benzoate, dimethyl silicone oil and glyceryl monostearate successively, be uniformly mixed.
After testing: the product made has the solid content of 42%, 25 DEG C time, brookfield viscosity is 5320cps, and the viscosity of this product was stable in three months, and had good viscosity and mobility etc.
Embodiment 2
Adopt the Acetylated potato starch of 1%, the organic phosphate starch of 8% and 15% enzymolysis-organic phosphate starch mixture gelatinization thing, 10% Acetylated potato starch, 1% potassium sorbate, the dimethyl silicone oil of 1%, the sorbyl alcohol of 5% and 59% water prepare starchiness cigarette glue, wherein all treated starches prepare by tapioca (flour).The preparation flow of starchiness cigarette glue is: first the gelatinization thing of the mixture of Acetylated potato starch, organic phosphate starch and enzymolysis-organic phosphate starch and Acetylated potato starch are added to the water, then add potassium sorbate, dimethyl silicone oil and sorbyl alcohol successively, be uniformly mixed.
After testing: the product made has the solid content of 39%, 25 DEG C time, brookfield viscosity is 3260cps, and the viscosity of this product was stable in three months, and had good viscosity and mobility etc.
Embodiment 3
Adopt 15% pyrolysis-Phosphation-pasted starch, 10% ative starch, 1% Sodium dehydroacetate, the mineral oil of 1%, the CSL sodium of 2% and 71% water prepare starchiness cigarette glue, pyrolysis-Phosphation-pasted starch is prepared by wheat starch, and ative starch is pea starch.The preparation flow of starchiness cigarette glue is: first pyrolysis-Phosphation-pasted starch and ative starch are added to the water, and then adds Sodium dehydroacetate, mineral oil and CSL sodium successively, is uniformly mixed.
After testing: the product made has the solid content of 26%, 25 DEG C time, brookfield viscosity is 1420cps, and the viscosity of this product was stable in three months, and had good viscosity and mobility etc.
Embodiment 4
Adopt the gelatinization thing of the mixture of the Acid denaturation-Acetylated potato starch of 5% and the oxidation-organic phosphate starch of 5%, 10% hydroxypropylated starch, 1% Sodium dehydroacetate, the mineral oil of 1%, the wilkinite of 1% and 77% water prepare starchiness cigarette glue, wherein all treated starches prepare by Starch rice.The preparation flow of starchiness cigarette glue is: first the gelatinization thing of the mixture of Acid denaturation-Acetylated potato starch and oxidation-organic phosphate starch and hydroxypropylated starch are added to the water, then add Sodium dehydroacetate, mineral oil and wilkinite successively, be uniformly mixed.
After testing: the product made has the solid content of 20%, 25 DEG C time, brookfield viscosity is 480cps, and the viscosity of this product was stable in three months, and had good viscosity and mobility etc.
Embodiment 5
Adopt the pyrolysis-organic phosphate starch of 14%, the Acid denaturation-organic phosphate starch of 15% and 10% oxidation-organic phosphate starch mixture gelatinization thing, 15% hydroxypropylated starch, the sodium Diacetate of 1%, the propylene glycol of 1% and 44% water prepare starchiness cigarette glue, all treated starches prepare by Waxy Rice Starch.The preparation flow of starchiness cigarette glue is: first the gelatinization thing of the mixture of pyrolysis-organic phosphate starch, Acid denaturation-organic phosphate starch and oxidation-organic phosphate starch and hydroxypropylated starch are added to the water, then add sodium Diacetate and propylene glycol successively, be uniformly mixed.
After testing: the product made has the solid content of 54%, 25 DEG C time, brookfield viscosity is 16340cps, and the viscosity of this product was stable in three months, and had good viscosity and mobility etc.
Embodiment 6
Adopt 20% enzymolysis-Phosphation-pasted starch, 20% cross-linking starch, 0.5% Sodium.alpha.-hydroxypropionate, 0.5% nisin, the Tween-60 of 1%, the glucose of 5% and 53% water prepare starchiness cigarette glue, all treated starches prepare by sweet potato starch.The preparation flow of starchiness cigarette glue is: first enzymolysis-Phosphation-pasted starch and cross-linking starch are added to the water, then add Sodium.alpha.-hydroxypropionate, nisin, Tween-60 and glucose successively, be uniformly mixed.
After testing: the product made has the solid content of 45%, 25 DEG C time, brookfield viscosity is 8320cps, and the viscosity of this product was stable in three months, and had good viscosity and mobility etc.
Claims (6)
1., based on esterification class-pasted starch and the amyloid starchiness cigarette glue of non-gelatinization, it is characterized in that: be grouped into by the one-tenth of following weight ratio:
Water 35%-85%
Esterification class-pasted starch 5%-45%
Non-gelatinization kind of starch 5%-45%
Sanitas 0.05%-1%
Defoamer 0.05%-1%
Functional agent 0-5%
Described esterification class-pasted starch refers to by any one in esterification starch, degraded class-ester starch or multiplely to obtain through gelatinization;
Described non-gelatinization kind of starch refers to the treated starch without gelatinization reaction;
Described esterification starch comprises Acetylated potato starch, organic phosphate starch; Described degraded class-ester starch comprises pyrolysis-Acetylated potato starch, pyrolysis-organic phosphate starch, enzymolysis-Acetylated potato starch, enzymolysis-organic phosphate starch, Acid denaturation-Acetylated potato starch, Acid denaturation-organic phosphate starch, oxidation-Acetylated potato starch, oxidation-organic phosphate starch;
Wherein: pyrolysis-Acetylated potato starch, pyrolysis-organic phosphate starch refer to and adopt multiple method of modifying to carry out composite modified product to ative starch, pyrolysis-Acetylated potato starch refers to and adopts the esterification process of method for pyrolysis and acetic acid esterified to carry out composite modified product to ative starch;
Described functional agent select in following kind any one or multiple: glyceryl monostearate, CSL sodium, glycerine, sorbyl alcohol, sucrose, wilkinite, silicon-dioxide, vegetable jelly, gelatin.
2. according to claim 1 based on esterification class-pasted starch and the amyloid starchiness cigarette glue of non-gelatinization, it is characterized in that: described non-gelatinization kind of starch comprises cross-linking starch, Acetylated potato starch, organic phosphate starch, hydroxyethyl starch, hydroxypropyl starch, carboxymethylated starch.
3. according to claim 1 based on esterification class-pasted starch and the amyloid starchiness cigarette glue of non-gelatinization, it is characterized in that: described treated starch all by obtaining ative starch modification, wherein ative starch select in following kind any one or multiple: W-Gum, Starch rice, wheat starch, barley starch, sorghum starch, yam starch, tapioca (flour), sweet potato starch, green starch, pea starch, bajiao banana starch, sago starch and waxy corn starch, Waxy Rice Starch, wax sorghum starch.
4. according to claim 1 based on esterification class-pasted starch and the amyloid starchiness cigarette glue of non-gelatinization, it is characterized in that: sanitas select in following kind any one or multiple: phenylformic acid and its esters, potassium sorbate, Sodium dehydroacetate, calcium propionate, sodium Diacetate, Sodium.alpha.-hydroxypropionate, nisin, tennecetin.
5. according to claim 1 based on esterification class-pasted starch and the amyloid starchiness cigarette glue of non-gelatinization, it is characterized in that: described defoamer select in following kind any one or multiple: propylene glycol, dimethyl silicone oil, polypropylene glycerol aether, tween, Tripolyglycerol monostearates, mineral oil and composite anti-foaming agent.
6. according to claim 1 based on esterification class-pasted starch and the amyloid starchiness cigarette glue of non-gelatinization, it is characterized in that: the solid content of described starchiness cigarette glue is 15%-65%, and pH value is 3-9, and viscosity is 100cps-20000cps.
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| CN114108384B (en) * | 2021-11-19 | 2023-03-24 | 青岛嘉泽包装有限公司 | Processing and production method for composite laser aluminum foil lining paper |
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| CN101962518A (en) * | 2010-02-03 | 2011-02-02 | 内蒙古奈伦农业科技股份有限公司 | Starch bonding agent, and preparation method and use thereof |
| CN102031075A (en) * | 2009-09-27 | 2011-04-27 | 曲靖宏程工贸有限公司 | Environmentally-friendly energy-saving cigarette adhesive and production method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102031075A (en) * | 2009-09-27 | 2011-04-27 | 曲靖宏程工贸有限公司 | Environmentally-friendly energy-saving cigarette adhesive and production method thereof |
| CN101962518A (en) * | 2010-02-03 | 2011-02-02 | 内蒙古奈伦农业科技股份有限公司 | Starch bonding agent, and preparation method and use thereof |
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