CN103773277B - A kind of based on etherificate class-pasted starch and the amyloid starchiness cigarette glue of non-gelatinization - Google Patents
A kind of based on etherificate class-pasted starch and the amyloid starchiness cigarette glue of non-gelatinization Download PDFInfo
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- CN103773277B CN103773277B CN201210400079.8A CN201210400079A CN103773277B CN 103773277 B CN103773277 B CN 103773277B CN 201210400079 A CN201210400079 A CN 201210400079A CN 103773277 B CN103773277 B CN 103773277B
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Abstract
A kind of based on etherificate class-pasted starch and non-gelatinization amyloid novel starch matter cigarette glue, it is characterized in that: be grouped into by the one-tenth of following weight ratio: water 35%-85%, etherificate class-pasted starch 5%-45%, non-gelatinization kind of starch 5%-45%, sanitas 0.05%-1%, defoamer 0.05%-1%, functional agent 0-5%; Described etherificate class-pasted starch refers to by any one in etherification starch, degraded class-etherification starch or multiplely to obtain through gelatinization; Described non-gelatinization kind of starch refers to the treated starch without gelatinization reaction.Cigarette glue of the present invention has good viscosity, mobility and stability, can stablize at normal temperatures and deposit more than three months time, can use as any one sizing agent in production of cigarettes, as overlapping glue, connect mouth glue, filter stick centre-line glue, packaging glue and aluminum foil composite glue etc., and go for the cigarette machine of any type.
Description
Technical field
The present invention relates to starchiness sizing agent, be particularly applicable to the one of production of cigarettes based on etherificate class-pasted starch and the amyloid starchiness cigarette glue of non-gelatinization.
Background technology
Sizing agent is one of raw and auxiliary material important in production of cigarettes manufacturing processed, all relates to sizing agent, mainly comprise in a lot of production of cigarettes operation: overlapping glue, connect mouth glue, filter stick centre-line glue, packaging glue and aluminum foil composite glue etc.At present, the domestic main flow cigarette machine list rifle speed of a motor vehicle is substantially about 7000/minute (speed of a motor vehicle of some new cigarette machine reaches 14000-16000 props up/minute), calculate with this cigarette speed, the speed that rolls out of plume is about about 500 ms/min, such as, concerning overlapping glue, from its be coated in cigarette tissue to plume out time be less than 0.1 second, time of drying is only less than 0.1 second, otherwise cigarette machine just there will be " race bar " phenomenon and quits work; Therefore, this just requires that cigarette glue has excellent adhesive property, rheological property etc.
Because polyvinyl acetate emulsion class sizing agent possesses above-mentioned performance characteristics, can adapt to high-speed cigarette machine requirement, thus at home and abroad cigarette industry is generally used.But the sizing agent based on polyvinyl acetate emulsion is non-natural sizing agent, at present, the sizing agent of people to natural class is interested, as starchiness sizing agent etc. because the raw material sources of natural class tackiness agent more extensively, more environmental protection.
Starch High Speed Cigarette Adhesives is developed abroad from the 80s and 90s in last century, such as United States Patent (USP) 5085228 proposes the mixture that one comprises cross-linking starch and modified starch (referring in particular to denaturated starch by acid), starch cigarette glue is obtained after gelatinization is carried out to mixture, the amylopection content wherein specially requiring ative starch is at least 70%(weight), and this mixture can be selected to carry out etherificate, esterification and oxidation modification before gelatinization, this starch cigarette glue is applicable to the production of the speed of a motor vehicle 6000/minute and above cigarette machine.United States Patent (USP) 5155140 proposes a kind of tackiness agent, mainly contains and is made up of the mixture of 100 parts of water, 4-120 part gum arabic, 3-80 part water soluble starch degraded product, carboxymethyl starch, gelling starch.United States Patent (USP) 5329004 proposes a kind of with amylopection content at least 90%(weight) ative starch for raw material, obtain a kind of starch cigarette glue by Acid denaturation (or enzymolysis, oxidation), Phosphation, gelatinization, this starch cigarette glue is applicable to the production of the speed of a motor vehicle 6000/minute and above cigarette machine.United States Patent (USP) 5490875 proposes a kind of with amylopection content at least 70%(weight) ative starch for raw material, prepared white dextrin and hydrolyzed starch (by enzyme and/or acid) respectively, then carried out gelatinization, obtain starch adhesive.Chinese patent CN1095864C proposes a kind of starch cigarette glue of unmodified starch, 5-60% treated starch, 0-5% rheology modifier, about 0-1% sanitas and the 0-1% defoamer composition comprising 2-25% dispersiveness, and this amylan is applicable to production rate and is greater than per minute 7000 cigarette and the cigarette machine being sometimes greater than per minute 10000 cigarette.Chinese patent CN100556973C proposes a kind of with one or more treated starch (acetylated starch, acetylize two cross-linking starch, etherification starch, Crosslinked and hydroxypropyl starch) the modified starch-based adhesive obtained of process second time again; the second time modification of treated starch carries out in the process of gelatinization plastic; be acylation modification or etherification modifiedly synchronously carry out with degraded, this amylan is applicable to the cigarette machine being more than or equal to 7000/minute.But, the problems such as the speed of a motor vehicle low even not mentioned start speed of a motor vehicle when a lot of starch cigarette glues related in existing patent still also exist production, viscosity are poor, glue poor stability, and domesticly at present not yet there is the commercial starchiness sizing agent product meeting cigarette industry practical application request.Therefore, still need numerous requirements such as the high speed of a motor vehicle that can meet existing cigarette machine and there is the starchiness cigarette sizing agent of good viscosity, mobility, stability.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, there is provided one can meet the normal Production requirement of existing cigarette machine (single rifle speed of a motor vehicle 7000/minute and with first-class), and the one with good viscosity, mobility and stability is based on etherificate class-pasted starch and non-gelatinization amyloid novel starch matter cigarette glue.
The object of the invention is to be achieved through the following technical solutions:
A kind of based on etherificate class-pasted starch and the amyloid starchiness cigarette glue of non-gelatinization, be grouped into by the one-tenth of following weight ratio:
Water 35%-85%
Etherificate class-pasted starch 5%-45%
Non-gelatinization kind of starch 5%-45%
Sanitas 0.05%-1%
Defoamer 0.05%-1%
Functional agent 0-5%
Described etherificate class-pasted starch refers to by any one in etherification starch, degraded class-etherification starch or multiplely to obtain through gelatinization; Described non-gelatinization kind of starch refers to the treated starch without gelatinization reaction.
Described etherification starch refers to hydroxyethylamyle, hydroxypropylated starch, carboxymethyl starch, preferred hydroxyethylamyle, carboxymethyl starch.Described degraded class-etherification starch refers to pyrolysis-hydroxyethylamyle, pyrolysis-hydroxypropylated starch, pyrolysis-carboxymethyl starch, enzymolysis-hydroxyethylamyle, enzymolysis-hydroxypropylated starch, enzymolysis-carboxymethyl starch, Acid denaturation-hydroxyethylamyle, Acid denaturation-hydroxypropylated starch, Acid denaturation-carboxymethyl starch, oxidation-hydroxyethylamyle, oxidation-hydroxypropylated starch, oxidation-carboxymethyl starch, wherein preferred pyrolysis hydroxyethylamyle, pyrolysis-carboxymethyl starch, Acid denaturation-hydroxyethylamyle, Acid denaturation-carboxymethyl starch.
Described non-gelatinization kind of starch comprises ative starch, cross-linking starch, Acetylated potato starch, organic phosphate starch, hydroxyethyl starch, hydroxypropyl starch, carboxymethylated starch, wherein preferred cross-linking starch, hydroxyethylamyle.
Treated starch in the present invention all by obtaining ative starch modification, wherein ative starch select in following kind any one or multiple: W-Gum, Starch rice, wheat starch, barley starch, sorghum starch, yam starch, tapioca (flour), sweet potato starch, green starch, pea starch, bajiao banana starch, sago starch and waxy starch are as waxy corn starch, Waxy Rice Starch, wax sorghum starch etc.
The composite modified starch such as the pyrolysis-hydroxyethylamyle in the present invention, enzymolysis-hydroxypropylated starch refer to and adopt multiple method of modifying to carry out composite modified product to ative starch, adopt method for pyrolysis and hydroxyethylated etherification method to carry out composite modified product to ative starch as pyrolysis-hydroxyethylamyle refers to.
" gelatinization " in the present invention, also known as " αization ", its essence is that water molecules enters in starch small grain, and the hydrogen bond rupture between the starch molecule of crystallization phases and unformed phase, destroys the associated state between starch molecule, is dispersed in water and becomes hydrophilic colloidal solution.According to the difference of equipment used, have multiple production method, the present invention can select cooking process, heat rolls method, in the method such as spray method, extruding puffing method, microwave method, pulse jet method any one or multiple.
Sanitas in the present invention select in following kind any one or multiple: phenylformic acid and its esters, potassium sorbate, Sodium dehydroacetate, calcium propionate, sodium Diacetate, Sodium.alpha.-hydroxypropionate, nisin, tennecetin etc.
Defoamer in the present invention select in following kind any one or multiple: ester class, mineral oil and the composite anti-foaming agent etc. such as polyethers, Tweens, Tripolyglycerol monostearates such as the alcohols such as propylene glycol, dimethyl-silicon wet goods are polysiloxane-based, polypropylene glycerol aether.
Functional agent in the present invention select in following kind any one or multiple: glyceryl monostearate, CSL sodium; The polyalcohols such as glycerine, sorbyl alcohol; The carbohydrates such as sucrose; Some mineral substance classes such as wilkinite, silicon-dioxide; Some vegetable jelly such as bean gum, gelatine, gelatin class.By selecting the functional agent be suitable for, thickening can be played, improve liquidity and the effect such as stability.
The solid content of the starchiness cigarette glue in the present invention is about 15%-65%(weight), pH value is about 3-9 and preferred 5-8, viscosity is about 100cps-20000cps(25 DEG C), and it has good viscosity, mobility and stability, can stablize at normal temperatures and deposit more than three months time.
Starchiness cigarette glue in the present invention can use as any one sizing agent in production of cigarettes, as overlapping glue, connect mouth glue, filter stick centre-line glue, packaging glue and aluminum foil composite glue etc., and go for the cigarette machine of any type, particularly the cigarette machine of single rifle speed of a motor vehicle more than 7000/minute and the speed of a motor vehicle are greater than the cigarette machines faster such as 10000/minute.
Starchiness cigarette glue in the present invention be also applicable to other occasion as binding papers, bottle label, packing box etc. relate to paper bonding occasion.
Embodiment
Below in conjunction with embodiment, further detailed description is done to the present invention, but the scope of the invention is not limited to these embodiments.
Embodiment 1
Adopt 15% hydroxyethylation-pasted starch, 10% cross-linking starch, 1% Sodium Benzoate, the propylene glycol of 1%, the glyceryl monostearate of 3% and 70% water prepare starchiness cigarette glue, wherein all treated starches prepare by sweet potato starch.The preparation flow of starchiness cigarette glue is: first hydroxyethylation-pasted starch, cross-linking starch are added to the water, and then adds Sodium Benzoate, propylene glycol and glyceryl monostearate successively, is uniformly mixed.
After testing: the product made has the solid content of 27%, 25 DEG C time, brookfield viscosity is 890cps, and the viscosity of this product was stable in three months, and had good viscosity and mobility etc.
Embodiment 2
Adopt the gelatinization thing of the mixture of the hydroxypropyl starch of 5% and the carboxymethylated starch of 5%, 10% ative starch, 1% potassium sorbate, the silicone emulsion of 1%, the glycerine of 5% and 73% water prepare starchiness cigarette glue, wherein all treated starches prepare by Waxy Rice Starch.The preparation flow of starchiness cigarette glue is: first the gelatinization thing of the mixture of hydroxypropylated starch and carboxymethyl starch and ative starch are added to the water, then add potassium sorbate, silicone emulsion and glycerine successively, be uniformly mixed.
After testing: the product made has the solid content of 24%, 25 DEG C time, brookfield viscosity is 9270cps, and the viscosity of this product was stable in three months, and had good viscosity and mobility etc.
Embodiment 3
Adopt the gelatinization thing of the mixture of the hydroxypropylated starch of 5% and the pyrolysis-hydroxyethyl starch of 10%, 10% hydroxyethylamyle, 1% Sodium dehydroacetate, the dimethyl silicone oil of 1%, the sorbyl alcohol of 5% and 68% water prepare starchiness cigarette glue, wherein all treated starches prepare by yam starch.The preparation flow of starchiness cigarette glue is: first the gelatinization thing of the mixture of hydroxypropylated starch and pyrolysis-hydroxyethyl starch and hydroxypropylated starch are added to the water, then add Sodium dehydroacetate, dimethyl silicone oil and sorbyl alcohol successively, be uniformly mixed.
After testing: the product made has the solid content of 30%, 25 DEG C time, brookfield viscosity is 3920cps, and the viscosity of this product was stable in three months, and had good viscosity and mobility etc.
Embodiment 4
Adopt the carboxymethyl starch of 5%, the Acid denaturation-hydroxypropyl starch of 5% and 5% oxidation-carboxymethylated starch mixture gelatinization thing, 15% cross-linking starch, the calcium propionate of 1%, the dimethyl silicone oil of 1% and 68% water prepare starchiness cigarette glue, wherein all treated starches prepare by sorghum starch.The preparation flow of starchiness cigarette glue is: first the gelatinization thing of the mixture of carboxymethyl starch, Acid denaturation-hydroxypropyl starch and oxidation-carboxymethylated starch and cross-linking starch are added to the water, then add calcium propionate and dimethyl silicone oil successively, be uniformly mixed.
After testing: the product made has the solid content of 29%, 25 DEG C time, brookfield viscosity is 2640cps, and the viscosity of this product was stable in three months, and had good viscosity and mobility etc.
Embodiment 5
Adopt 3% hydroxyethylamyle, the hydroxypropylated starch of 3%, the pyrolysis-hydroxypropyl starch of 5% and 5% enzymolysis-carboxymethylated starch mixture gelatinization thing, 15% acetate starch, 1% sodium Diacetate, the mineral oil of 1%, the attapulgite of 3% and 64% water prepare starchiness cigarette glue, wherein all treated starches prepare by green starch.The preparation flow of starchiness cigarette glue is: first the gelatinization thing of the mixture of hydroxyethylamyle, hydroxypropylated starch, pyrolysis-hydroxypropyl starch and enzymolysis-carboxymethylated starch and acetate starch are added to the water, then add sodium Diacetate, mineral oil and attapulgite successively, be uniformly mixed.
After testing: the product made has the solid content of 35%, 25 DEG C time, brookfield viscosity is 6340cps, and the viscosity of this product was stable in three months, and had good viscosity and mobility etc.
Embodiment 6
Adopt the gelatinization thing of the mixture of the oxidation-hydroxyethyl starch of 15% and the oxidation-carboxymethylated starch of 20%, 15% acetate starch, 0.5% Sodium Benzoate, the mineral oil of 0.5%, the glucose of 3% and 46% water prepare starchiness cigarette glue, wherein all treated starches prepare by tapioca (flour).The preparation flow of starchiness cigarette glue is: first the gelatinization thing of the mixture of oxidation-hydroxyethyl starch and oxidation-carboxymethylated starch and ative starch are added to the water, then add Sodium Benzoate, mineral oil and glucose successively, be uniformly mixed.
After testing: the product made has the solid content of 52%, 25 DEG C time, brookfield viscosity is 13530cps, and the viscosity of this product was stable in three months, and had good viscosity and mobility etc.
Claims (6)
1. based on etherificate class-pasted starch and the amyloid starchiness cigarette glue of non-gelatinization, its feature
Be: be grouped into by the one-tenth of following weight ratio:
Water 35%-85%
Etherificate class-pasted starch 5%-45%
Non-gelatinization kind of starch 5%-45%
Sanitas 0.05%-1%
Defoamer 0.05%-1%
Functional agent 0-5%
Described etherificate class-pasted starch refers to by any one in etherification starch, degraded class-etherification starch or multiplely to obtain through gelatinization; Described etherification starch refers to hydroxyethylamyle, hydroxypropylated starch, carboxymethyl starch; Described degraded class-etherification starch refers to pyrolysis-hydroxyethylamyle, pyrolysis-hydroxypropylated starch, pyrolysis-carboxymethyl starch, enzymolysis-hydroxyethylamyle, enzymolysis-hydroxypropylated starch, enzymolysis-carboxymethyl starch, Acid denaturation-hydroxyethylamyle, Acid denaturation-hydroxypropylated starch, Acid denaturation-carboxymethyl starch, oxidation-hydroxyethylamyle, oxidation-hydroxypropylated starch, oxidation-carboxymethyl starch; Wherein: pyrolysis-hydroxyethylamyle, enzymolysis-hydroxypropylated starch refer to and adopt multiple method of modifying to carry out composite modified product to ative starch, pyrolysis-hydroxyethylamyle refers to and adopts method for pyrolysis and hydroxyethylated etherification method to carry out composite modified product to ative starch;
Described non-gelatinization kind of starch refers to the treated starch without gelatinization reaction;
Described functional agent select in following kind any one or multiple: glyceryl monostearate, CSL sodium, glycerine, sorbyl alcohol, sucrose, wilkinite, silicon-dioxide, vegetable jelly, gelatin.
2. one according to claim 1 is based on etherificate class-pasted starch and the amyloid starchiness cigarette glue of non-gelatinization, it is characterized in that: described non-gelatinization kind of starch comprises cross-linking starch, Acetylated potato starch, organic phosphate starch, hydroxyethyl starch, hydroxypropyl starch, carboxymethylated starch.
3. one according to claim 1 is based on etherificate class-pasted starch and the amyloid starchiness cigarette glue of non-gelatinization, it is characterized in that: described treated starch all by obtaining ative starch modification, wherein ative starch select in following kind any one or multiple: W-Gum, Starch rice, wheat starch, barley starch, sorghum starch, yam starch, tapioca (flour), sweet potato starch, green starch, pea starch, bajiao banana starch, sago starch.
4. one according to claim 1 is based on etherificate class-pasted starch and the amyloid starchiness cigarette glue of non-gelatinization, it is characterized in that: sanitas select in following kind any one or multiple: phenylformic acid and its esters, potassium sorbate, Sodium dehydroacetate, calcium propionate, sodium Diacetate, Sodium.alpha.-hydroxypropionate, nisin, tennecetin.
5. one according to claim 1 is based on etherificate class-pasted starch and the amyloid starchiness cigarette glue of non-gelatinization, it is characterized in that: described defoamer select in following kind any one or multiple: propylene glycol, dimethyl silicone oil, polypropylene glycerol aether, tween, Tripolyglycerol monostearates, mineral oil and composite anti-foaming agent.
6. one according to claim 1 is based on etherificate class-pasted starch and the amyloid starchiness cigarette glue of non-gelatinization, it is characterized in that: the solid content of described starchiness cigarette glue is 15%-65%, and pH value is 3-9, and viscosity is 100cps-20000cps.
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| CN106753033B (en) * | 2016-12-02 | 2019-01-04 | 中山华方包装有限公司 | Phosphate tapioca solid adhesive and preparation method thereof |
| CN107974216A (en) * | 2017-12-07 | 2018-05-01 | 明光市永德包装有限公司 | A kind of water-fast adhesive of corrugated case |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1135231A (en) * | 1993-11-18 | 1996-11-06 | 赖克霍德化学公司 | Starch-based adhesive |
| CN1769361A (en) * | 2004-11-03 | 2006-05-10 | 胡正水 | Starchiness adhesives and preparation method |
| CN101962518A (en) * | 2010-02-03 | 2011-02-02 | 内蒙古奈伦农业科技股份有限公司 | Starch bonding agent, and preparation method and use thereof |
| CN102391797A (en) * | 2011-07-09 | 2012-03-28 | 山西大学 | Corn starch adhesive for building and preparation method thereof |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1135231A (en) * | 1993-11-18 | 1996-11-06 | 赖克霍德化学公司 | Starch-based adhesive |
| CN1769361A (en) * | 2004-11-03 | 2006-05-10 | 胡正水 | Starchiness adhesives and preparation method |
| CN101962518A (en) * | 2010-02-03 | 2011-02-02 | 内蒙古奈伦农业科技股份有限公司 | Starch bonding agent, and preparation method and use thereof |
| CN102391797A (en) * | 2011-07-09 | 2012-03-28 | 山西大学 | Corn starch adhesive for building and preparation method thereof |
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