CN103773274B - One kind is based on the non-amyloid novel starch matter cigarette glue of gelatinization - Google Patents
One kind is based on the non-amyloid novel starch matter cigarette glue of gelatinization Download PDFInfo
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- CN103773274B CN103773274B CN201210400085.3A CN201210400085A CN103773274B CN 103773274 B CN103773274 B CN 103773274B CN 201210400085 A CN201210400085 A CN 201210400085A CN 103773274 B CN103773274 B CN 103773274B
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Abstract
One kind is based on the non-amyloid novel starch matter cigarette glue of gelatinization, it is characterised in that：It is made of the component of following weight ratio：Water 35% 85%, non-gelatinization kind of starch 10% 60%, preservative 0.05% 1%, defoamer 0.05% 1%, function additive 0 5%；The non-gelatinization kind of starch refers to the modified starch without gelatinization reaction, including degraded class esterification starch and degraded class etherification starch.The cigarette glue of the present invention has good viscosity, mobility and stability, more than the three months time of storage can be stablized at normal temperatures, it can be used as the adhesive of any one in production of cigarettes, such as overlapping glue, connect mouth glue, filter stick centre-line glue, packaging glue and aluminum foil composite glue, and it can be adapted for the cigarette machine of any type, cigarette machine and speed more than particularly single 7000/minute of rifle speed is more than the faster cigarette machine such as 10000/minute.
Description
Technical field
It is particularly a kind of based on the non-amyloid novel starch matter cigarette glue of gelatinization the present invention relates to starchiness adhesive.
Background technology
Adhesive is one of raw and auxiliary material important in production of cigarettes manufacturing process, is related in many production of cigarettes processes
And to adhesive, mainly include：Overlapping glue, connect mouth glue, filter stick centre-line glue, packaging glue and aluminum foil composite glue etc..At present, it is domestic main
Cigarette machine list rifle speed is flowed substantially in 7000/minute or so（The speed of some new cigarette machines reach 14000-16000 branch/
Minute）, being calculated with this cigarette speed, the speed that rolls out of plume is about 500 ms/min or so, for example, for overlapping glue, from
It is coated on cigarette paper is less than 0.1 second to time between plume comes out, drying time only less than 0.1 second, otherwise cigarette machine
" race bar " phenomenon just occurs and is stopped；Therefore, this requires cigarette glue has excellent adhesive property, rheological property
Deng.
Since polyvinyl acetate emulsion class adhesive possesses above-mentioned performance characteristics, high-speed cigarette machine requirement is can adapt to, because
And at home and abroad cigarette industry is generally used.But the adhesive based on polyvinyl acetate emulsion is non-natural glue
Glutinous agent, at present, people are interested in the adhesive of natural class, such as starchiness adhesive, because the original of natural class adhesive
Expect that source is more extensive, more environmentally friendly.
Foreign countries develop starch High Speed Cigarette Adhesives since the 80s and 90s in last century, such as United States Patent (USP) 5085228 proposes
It is a kind of to include crosslinked starch and converted starch（Refer in particular to denaturated starch by acid）Mixture, obtained after being gelatinized to mixture
Starch cigarette glue, wherein the amylopectin content of special requirement ative starch is at least 70%（Weight）, and this mixture is before gelatinization
It can select to be etherified, be esterified and oxidation modification, the starch cigarette glue are applicable to the volume of 6000/minute of speed and the above
The production of smoke machine.United States Patent (USP) 5155140 proposes a kind of adhesive, mainly has by 100 parts of water, 4-120 parts of Arabic gums, 3-
80 parts of water soluble starch catabolites, carboxymethyl starch, the mixture of gelling starch are formed.United States Patent (USP) 5329004 proposes
One kind is with amylopectin content at least 90%（Weight）Ative starch be raw material, pass through Acid denaturation（Or enzymolysis, oxidation）, phosphoric acid
Esterification, gelatinization have obtained a kind of starch cigarette glue, which is applicable to the cigarette of 6000/minute of speed and the above
The production of machine.United States Patent (USP) 5490875 proposes one kind with amylopectin content at least 70%（Weight）Ative starch be raw material,
White dextrin and hydrolysis starch are prepared for respectively（Pass through enzyme and/or acid）, then it is gelatinized, has obtained starch adhesive.
Chinese patent CN 1095864C propose a kind of unmodified starch including 2-25% dispersivenesses, 5-60% modified starches, 0-5% streams
Become the starch cigarette glue of modifying agent, about 0-1% preservatives and 0-1% defoamers composition, it is big which is applicable to speed of production
In 7000 cigarette per minute and the cigarette machine of 10000 cigarette sometimes more than per minute.Chinese patent CN 100556973C are carried
Go out a kind of with one or more kinds of modified starches（Acetylated starch, two crosslinked starch of acetylation, etherification starch, etherificate
Crosslinked starch）Again by second of modified obtained starch-based adhesive, second of modification of modified starch is to be gelatinized into
Carried out during glue, be acylation modification or it is etherification modified with degraded synchronously carry out, the amylan be applicable to be more than etc.
In the cigarette machine of 7000/minute.However, still there is car during production for many starch cigarette glues arrived involved in existing patent
Speed it is low in addition do not refer to start speed, viscosity it is poor, glue stability is poor the problems such as, and at present the country not yet occur meeting cigarette
The starchiness adhesive product of the commercialization of industrial practical application request.Therefore, there is still a need for it can meet existing cigarette machine
High speed etc. is numerous to be required and with good viscosity, mobility, the starchiness cigarette adhesive of stability.
The content of the invention
It disclosure satisfy that existing cigarette machine normally produces it is an object of the invention to overcome the deficiencies of the prior art and provide one kind
Demand（Single 7000/minute of rifle speed and with first-class）, and one kind with good viscosity, mobility and stability is based on non-
It is gelatinized amyloid novel starch matter cigarette glue.
The purpose of the present invention is what is be achieved through the following technical solutions：
One kind is made of based on the non-amyloid novel starch matter cigarette glue of gelatinization the component of following weight ratio：
Water 35%-85%
Non- gelatinization kind of starch 10%-60%
Preservative 0.05%-1%
Defoamer 0.05%-1%
Function additive 0-5%
The non-gelatinization kind of starch refers to the modified starch without gelatinization reaction, including degraded class -ester starch and drop
Solve class-etherification starch.
The degraded class -ester starch refers to pyrolysis-Acetylated potato starch, pyrolysis-organic phosphate starch, enzymolysis-acetic acid
Esterification starch, enzymolysis-organic phosphate starch, Acid denaturation-Acetylated potato starch, Acid denaturation-organic phosphate starch, oxidation-acetic acid
Esterification starch, oxidation-organic phosphate starch, preferably Acid denaturation-organic phosphate starch, oxidation-organic phosphate starch.
Degraded class-the etherification starch refers to pyrolysis-hydroxyethyl starch, pyrolysis-hydroxypropyl starch, pyrolysis-carboxylic first
Base starch, enzymolysis-hydroxyethyl starch, enzymolysis-hydroxypropyl starch, enzymolysis-carboxymethylated starch, Acid denaturation-ethoxy
Change starch, Acid denaturation-hydroxypropyl starch, Acid denaturation-carboxymethylated starch, oxidation-hydroxyethyl starch, oxidation-hydroxypropyl
Change starch, preferably oxidation-carboxymethylated starch, Acid denaturation-hydroxypropyl starch, Acid denaturation-carboxymethylated starch, oxidation-hydroxyl
Propylated starches, oxidation-carboxymethylated starch.
In addition, it is above-mentioned it is non-gelatinization kind of starch can use ative starch, crosslinked starch, Acetylated potato starch, organic phosphate starch,
In hydroxyethyl starch, hydroxypropul starch, carboxymethyl starch any one or more and preferably ative starch and acetate starch into
The equivalent substitution of row part, it is about 5 with the non-amyloid proportion of gelatinization:1-0:1.
Modified starch in the present invention to ative starch by being modified to obtain, and wherein ative starch is selected in following species
Any one or more：Cornstarch, rice starch, wheaten starch, barley starch, sorghum starch, farina, cassava
Starch, starch from sweet potato, green starch, pea starch, bajiao banana starch, sago starch and waxy starch such as waxy corn starch,
Waxy Rice Starch, wax sorghum starch etc..
Non- gelatinization kind of starch in the present invention refers to the product to ative starch modification for composite using a variety of method of modifying,
As pyrolysis-Acetylated potato starch refers to the production that is modified using the esterification process of method for pyrolysis and acetic acid esterified to ative starch
Thing, oxidation-hydroxyethyl starch refer to using method for oxidation and hydroxyethylated etherification method to ative starch modification for composite
Product.
Preservative in the present invention selects any one or more in following species：Benzoic acid and its esters, sorbic acid
Potassium, dehydroactic acid sodium, calcium propionate, sodium Diacetate, sodium lactate, nisin, natamycin etc..
Defoamer in the present invention selects any one or more in following species：The alcohols such as propane diols, dimethyl-silicon
Esters, the mineral oil such as polyethers, Tweens, the Tripolyglycerol monostearates such as oil etc. is polysiloxane-based, polypropylene glycerol aether
And composite anti-foaming agent etc..
Function additive in the present invention selects any one or more in following species：Glycerin monostearate, tristearin
Acyl calcium lactate sodium；The polyalcohols such as glycerine, sorbierite；The carbohydrates such as sucrose；Some mineral matter classes such as bentonite, silica；Beans
Some natural plant gum such as glue, gelatine, animal glue class.By selecting suitable function additive, can play thickening, improve mobility and
Stability etc. acts on.
The solid content of starchiness cigarette glue in the present invention is about 15%-65%（Weight）, pH value is about 3-9 and preferred 5-8,
Viscosity is about 100cps-20000cps（25℃）, and it at normal temperatures can with good viscosity, mobility and stability
It is enough to stablize more than the three months time of storage.
Starchiness cigarette glue in the present invention can be used as the adhesive of any one in production of cigarettes, such as take mouth
Glue, connect mouth glue, filter stick centre-line glue, packaging glue and aluminum foil composite glue etc., and can be adapted for the cigarette machine of any type, especially
It is that more than single 7000/minute of rifle speed cigarette machine and speed are more than the faster cigarette machine such as 10000/minute.
Starchiness cigarette glue in the present invention is equally applicable to other occasions such as binding papers, bottle label, packing box etc.
It is related to the occasion of paper bonding.
Embodiment
Further detailed description is done to the present invention below in conjunction with embodiment, but the scope of the invention is not limited to these.
Embodiment 1
Using 10% Acid denaturation-organic phosphate starch, 20% Acid denaturation-hydroxypropyl starch, 10% ative starch, 1%
Sodium benzoate, 1% dimethicone, 1% gelatin and 57% water prepare starchiness cigarette glue, all modified starches
It is prepared by cornstarch.The preparation flow of starchiness cigarette glue is：Acid denaturation-organic phosphate starch, acid are become first
Property-hydroxypropyl starch and ative starch be added to the water, sodium benzoate, dimethicone and gelatin are then sequentially added, is stirred
It is uniformly mixed.
After testing：Manufactured product has 40% solid content, and at 25 DEG C, brookfield viscosity is 1250cps, should
The viscosity of product was stable in three months, and with good viscosity and mobility etc..
Embodiment 2
Using 20% oxidation-hydroxypropyl starch, 25% oxidation-carboxymethylated starch, 10% Acetylated potato starch,
0.25% potassium sorbate, 0.75% dimethicone, 1% pectin and 43% water prepare starchiness cigarette glue, all
Modified starch is prepared by rice starch.The preparation flow of starchiness cigarette glue is：Oxidation-hydroxypropylation is formed sediment first
Powder, oxidation-carboxymethylated starch and acetate starch are added to the water, then sequentially add potassium sorbate, dimethicone and
Pectin, is uniformly mixed.
After testing：Manufactured product has 56% solid content, and at 25 DEG C, brookfield viscosity is 14620cps,
The viscosity of the product was stable in three months, and with good viscosity and mobility etc..
Embodiment 3
Formed sediment using 5% pyrolysis-Acetylated potato starch, 5% pyrolysis-organic phosphate starch, 10% pyrolysis-hydroxyethylation
Powder, 5% crosslinked starch, 1% dehydroactic acid sodium, 1% propane diols, 5% sorbierite and 68% water prepare starchiness volume
Smoked sheet, all modified starches are prepared by farina.The preparation flow of starchiness cigarette glue is：First by heat
Solution-Acetylated potato starch, pyrolysis-organic phosphate starch, pyrolysis-hydroxyethyl starch and crosslinked starch are added to the water, then
Dehydroactic acid sodium, propane diols and sorbierite are sequentially added, is uniformly mixed.
After testing：Manufactured product has 30% solid content, and at 25 DEG C, brookfield viscosity is 350cps, should
The viscosity of product was stable in three months, and with good viscosity and mobility etc..
Embodiment 4
Using 10% oxidation-organic phosphate starch, 10% oxidation-hydroxyethyl starch, 10% enzymolysis-Phosphation
Starch, 10% ative starch, 1% sodium Diacetate, 1% mineral oil, 5% glucose and 53% water prepare starchiness cigarette
Glue, all modified starches are prepared by tapioca.The preparation flow of starchiness cigarette glue is：First by oxidation-phosphoric acid
Esterification starch, oxidation-hydroxyethyl starch, enzymolysis-organic phosphate starch and ative starch are added to the water, and then sequentially add double
Sodium acetate, mineral oil and glucose, are uniformly mixed.
After testing：Products obtained therefrom has 45% solid content, and at 25 DEG C, brookfield viscosity is 7290cps, the production
The viscosity of product was stable in three months, and with good viscosity and mobility etc..
Embodiment 5
Using 5% Acid denaturation-carboxymethylated starch, 5% enzymolysis-organic phosphate starch, 3% pyrolysis-hydroxyethylation
, 2% oxidation-hydroxypropyl starch, 1% sodium lactate, 1% polyoxyethylene polyoxypropylene amidogen ether and 78% water prepares and forms sediment
Silty cigarette glue, all modified starches are prepared by wheaten starch.The preparation flow of starchiness cigarette glue is：First by acid
Denaturation-carboxymethylated starch, enzymolysis-organic phosphate starch, pyrolysis-hydroxyethylated and oxidation-hydroxypropyl starch are added to
In water, then sequentially add sodium lactate and polyoxyethylene polyoxypropylene amidogen ether, be stirred by.
After testing：Products obtained therefrom has 20% solid content, and at 25 DEG C, brookfield viscosity is 250cps, the production
The viscosity of product was stable in three months, and with good viscosity and mobility etc..
Embodiment 6
Using 15% pyrolysis-Acetylated potato starch, 20% Acid denaturation-hydroxypropyl starch, 10% hydroxyethyl starch,
1% potassium sorbate, 1% polyoxypropylene ethylene oxide glycerin ether, 2% bentonite and 51% water prepare starchiness cigarette
Glue, all modified starches are prepared by Waxy Rice Starch.The preparation flow of starchiness cigarette glue is：First by heat
Solution-Acetylated potato starch, Acid denaturation-hydroxypropyl starch and hydroxyethyl starch are added to the water, and then sequentially add sorbic acid
Potassium, polyoxypropylene ethylene oxide glycerin ether and bentonite, are uniformly mixed.
Products obtained therefrom has 47% solid content after testing, and at 25 DEG C, brookfield viscosity is 9350cps, the production
The viscosity of product was stable in three months, and with good viscosity and mobility etc..
Claims (6)
1. one kind is based on the non-amyloid novel starch matter cigarette glue of gelatinization, it is characterised in that：By following weight
The component composition of ratio：
Water 35%-85%
Non- gelatinization kind of starch 10%-60%
Preservative 0.05%-1%
Defoamer 0.05%-1%
Function additive 1-5%
It is described it is non-gelatinization kind of starch refer to without gelatinization reaction modified starch, including degraded class -ester starch and degraded class-
Etherification starch；
The degraded class -ester starch refers to pyrolysis-Acetylated potato starch, pyrolysis-organic phosphate starch, enzymolysis-acetic acid esterified
Starch, enzymolysis-organic phosphate starch, Acid denaturation-Acetylated potato starch, Acid denaturation-organic phosphate starch, oxidation-acetic acid esterified
Starch, oxidation-organic phosphate starch；
Degraded class-the etherification starch refers to pyrolysis-hydroxyethyl starch, pyrolysis-hydroxypropyl starch, pyrolysis-carboxy methylation
Starch, enzymolysis-hydroxyethyl starch, enzymolysis-hydroxypropyl starch, enzymolysis-carboxymethylated starch, Acid denaturation-hydroxyethylation form sediment
Powder, Acid denaturation-hydroxypropyl starch, Acid denaturation-carboxymethylated starch, oxidation-hydroxyethyl starch, oxidation-hydroxypropylation form sediment
Powder, oxidation-carboxymethylated starch；
Above-mentioned non-gelatinization kind of starch can use ative starch, crosslinked starch, Acetylated potato starch, organic phosphate starch, ethoxy to form sediment
The equivalent substitution of any one or more progress part in powder, hydroxypropul starch, carboxymethyl starch；
The novel starch matter cigarette glue is made by following preparation flow：The non-gelatinized starch is included into degraded
Class -ester starch and degraded class-etherification starch, are added to the water, then sequentially add preservative, defoamer and function additive,
It is uniformly mixed.
It is 2. according to claim 1 a kind of based on the non-amyloid novel starch matter cigarette glue of gelatinization, it is characterised in that：Institute
Modified starch is stated by being modified to obtain to ative starch, wherein any one in the following species of ative starch selection or more
Kind：Cornstarch, rice starch, wheaten starch, barley starch, sorghum starch, farina, tapioca, starch from sweet potato,
Green starch, pea starch, bajiao banana starch, sago starch and waxy corn starch, Waxy Rice Starch, wax sorghum are formed sediment
Powder.
It is 3. according to claim 1 a kind of based on the non-amyloid novel starch matter cigarette glue of gelatinization, it is characterised in that：It is anti-
Rotten agent selects any one or more in following species：Benzoic acid and its esters, potassium sorbate, dehydroactic acid sodium, calcium propionate,
Sodium Diacetate, sodium lactate, nisin, natamycin.
It is 4. according to claim 1 a kind of based on the non-amyloid novel starch matter cigarette glue of gelatinization, it is characterised in that：Institute
State any one or more in the following species of defoamer selection：Propane diols, dimethicone are polysiloxane-based, polyoxypropylene is sweet
Oily ether polyethers, Tweens, Tripolyglycerol monostearates esters, mineral oil and composite anti-foaming agent.
It is 5. according to claim 1 a kind of based on the non-amyloid novel starch matter cigarette glue of gelatinization, it is characterised in that：Institute
State any one or more in the following species of function additive selection：Glycerin monostearate, stearyl lactate sodium；Glycerine,
Sorbitol polyol class；Sucrose；Bentonite, silicon dioxide mine material class；Natural plant gum, animal glue class.
It is 6. according to claim 1 a kind of based on the non-amyloid novel starch matter cigarette glue of gelatinization, it is characterised in that：Institute
The solid content for stating starchiness cigarette glue is 15%-65%, pH value 3-9, viscosity 100cps-20000cps.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210400085.3A CN103773274B (en) | 2012-10-20 | 2012-10-20 | One kind is based on the non-amyloid novel starch matter cigarette glue of gelatinization |
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|---|---|---|---|
| CN201210400085.3A CN103773274B (en) | 2012-10-20 | 2012-10-20 | One kind is based on the non-amyloid novel starch matter cigarette glue of gelatinization |
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| CN103773274A CN103773274A (en) | 2014-05-07 |
| CN103773274B true CN103773274B (en) | 2018-04-17 |
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| CN110003817A (en) * | 2019-02-25 | 2019-07-12 | 朱东洋 | A kind of starch type cigarette glue and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1135231A (en) * | 1993-11-18 | 1996-11-06 | 赖克霍德化学公司 | Starch-based adhesive |
| CN1769361A (en) * | 2004-11-03 | 2006-05-10 | 胡正水 | Starchiness adhesives and preparation method |
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2012
- 2012-10-20 CN CN201210400085.3A patent/CN103773274B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1135231A (en) * | 1993-11-18 | 1996-11-06 | 赖克霍德化学公司 | Starch-based adhesive |
| CN1769361A (en) * | 2004-11-03 | 2006-05-10 | 胡正水 | Starchiness adhesives and preparation method |
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| CN103773274A (en) | 2014-05-07 |
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