CN103773267B - A kind of starchiness cigarette glue based on degraded class-gelatinized starch and etherificate class-gelatinized starch - Google Patents
A kind of starchiness cigarette glue based on degraded class-gelatinized starch and etherificate class-gelatinized starch Download PDFInfo
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Abstract
A kind of novel starch matter cigarette glue based on degraded class-gelatinized starch and etherificate class-gelatinized starch, it is characterized in that: the one-tenth by following weight ratio is grouped into: water: 35%-90%, degraded class-gelatinized starch: 10%-45%, etherificate class-gelatinized starch: 1%-25%, anticorrisive agent: 0.05%-1%, defoamer: 0.05%-1%, function additive: 0-5%. After testing, starchiness cigarette glue of the present invention has good viscosity, mobility and stability, can stablize more than three months time of depositing at normal temperatures, any one adhesive can be used as in production of cigarettes uses, as overlapping glue, connect mouth glue, filter stick centre-line glue, packaging glue and aluminum foil composite glue etc., and go for the cigarette machine of any type, particularly the above cigarette machines of 7000/minute of single rifle speed of a motor vehicle and the speed of a motor vehicle are greater than the cigarette machines faster such as 10000/minute. This starchiness cigarette glue also relates to the occasion of paper bonding applicable to other occasion as binding papers, bottle label, packing box etc.
Description
Technical field
The present invention relates to starchiness adhesive, be particularly applicable to the one that production of cigarettes uses and form sediment based on degraded class-gelatinizationThe novel starch matter cigarette glue of powder and etherificate class-gelatinized starch.
Background technology
Adhesive is one of raw and auxiliary material important in production of cigarettes manufacture process, in a lot of production of cigarettes operations, all relates toAnd to adhesive, mainly comprise: overlapping glue, connect mouth glue, filter stick centre-line glue, packaging glue and aluminum foil composite glue etc. At present, domestic masterThe stream cigarette machine list rifle speed of a motor vehicle substantially about 7000/minute (speed of a motor vehicle of some new cigarette machine reaches 14000-16000 props up/Minute), to calculate with this cigarette speed, the speed that rolls out of plume is about 500 ms/min of left and right, for example, concerning overlapping glue, fromIt is coated on cigarette paper the time of plume between out and is less than 0.1 second, and drying time is only less than 0.1 second, otherwise cigarette machineJust there will be " race bar " phenomenon and quit work; Therefore, this just requires cigarette glue to have excellent adhesive property, rheological propertyDeng.
Because polyvinyl acetate emulsion class adhesive possesses above-mentioned performance characteristics, can adapt to high-speed cigarette machine requirement, because ofAnd at home and abroad cigarette industry is generally used. But be non-natural glue taking polyvinyl acetate emulsion as basic adhesiveGlutinous agent, at present, people are interested in the adhesive of natural class, as starchiness adhesive etc., because natural class adhesive is formerMaterial is originated more extensively, more environmental protection.
Abroad, since the 80s and 90s in last century developing starch High Speed Cigarette Adhesives, for example United States Patent (USP) 5085228 proposesOne comprise and the mixture of crosslinked starch and converted starch (referring in particular to denaturated starch by acid) mixture carried out obtaining after gelatinizationStarch cigarette glue, wherein the amylopectin content of special requirement ative starch is at least 70%(weight), and this mixture is before gelatinizationCan select to carry out etherificate, esterification and oxidation modification, this starch cigarette glue is applicable to 6000/minute of the speed of a motor vehicle and above volumeThe production of cigarette machine. United States Patent (USP) 5155140 has proposed a kind of adhesive, mainly contains by 100 parts of water, 4-120 part Arabic gum, 3-The mixture of 80 parts of water soluble starch catabolites, CMS, gelling starch forms. United States Patent (USP) 5329004 has proposedA kind of taking at least 90%(weight of amylopectin content) ative starch as raw material, by sour sex change (or enzymolysis, oxidation), phosphoric acidEsterification, gelatinization have obtained a kind of starch cigarette glue, and this starch cigarette glue is applicable to 6000/minute of the speed of a motor vehicle and above cigaretteThe production of machine. United States Patent (USP) 5490875 has proposed a kind of taking at least 70%(weight of amylopectin content) ative starch as raw material,Prepare respectively white dextrin and hydrolyzed starch (by enzyme and/or acid), then carried out gelatinization, obtained starch adhesive.Chinese patent CN1095864C has proposed a kind of unmodified starch, 5-60% modified starch, 0-5% stream of the 2-25% of comprising dispersivenessThe starch cigarette glue that becomes modifier, about 0-1% anticorrisive agent and 0-1% defoamer composition, this amylan is large applicable to speed of productionIn 7000 cigarette per minute and be sometimes greater than the cigarette machine of 10000 cigarette per minute. Chinese patent CN100556973C carriesA kind of modified starch with one or more (acetylated starch, acetylation two crosslinked starch, etherification starch, etherificate are gone outCrosslinked starch) starch-based adhesive that obtains after modification for the second time again, the modification for the second time of modified starch is to be pasted intoIn the process of glue, carry out, be acylation modification or etherification modifiedly synchronize and carry out with degraded, this amylan is applicable to being greater than etc.In the cigarette machine of 7000/minute. But a lot of starch cigarette glues that relate in existing patent still exist car while productionThe problems such as the speed low even not mentioned start speed of a motor vehicle, viscosity is poor, glue poor stability, and at present domesticly not yet there is meeting cigaretteThe commercial starchiness cigarette glue product of industry practical application request. Therefore, still need to meet existing cigarette machineNumerous requirements such as the high speed of a motor vehicle also have the starchiness cigarette glue of good viscosity, mobility, stability.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, provide one can meet existing cigarette machine and normally produceDemand (7000/minute of single rifle speed of a motor vehicle and with first-class), and the one with good viscosity, mobility and stability is based on fallingSeparate the novel starch matter cigarette glue of class-gelatinized starch and etherificate class-gelatinized starch.
The object of the invention is to be achieved through the following technical solutions:
Novel starch matter cigarette glue of the present invention, is grouped into by the one-tenth of following weight ratio:
Water 35%-85%
Degraded class-gelatinized starch 10%-45%
Etherificate class-gelatinized starch 1%-25%
Anticorrisive agent 0.05%-1%
Defoamer 0.05%-1%
Function additive 0-5%
In the present invention, described degraded class-gelatinized starch is to be formed sediment by pyrolysis dextrin, enzymolysis starch, denaturated starch by acid, oxidationAny one in the DAMs such as powder or the gelatinization of multiple process obtain, preferential oxidation starch.
Described etherificate class-gelatinized starch is to be formed sediment by HES, hydroxypropul starch, CMS, oxidation-ethoxyAny one in the etherificate kind of starch such as powder, oxidation-hydroxypropul starch, oxidation-CMS or the gelatinization of multiple process obtain, preferably hydroxypropul starch, CMS, oxidation-hydroxypropul starch and oxidation-CMS.
Described oxidation-HES, oxidation-hydroxypropul starch, oxidation-CMS refer to adopt method for oxidation andEtherification method, method for oxidation and the carboxymethylated etherification method of hydroxyethylated etherification method, method for oxidation and hydroxypropylationRespectively ative starch is carried out to composite modified product.
" gelatinization " in the present invention claims again " αization ", and its essence is that hydrone enters in amylum body, crystalline phase and unformed phaseStarch molecule between hydrogen bond rupture, destroyed the association state between starch molecule, be dispersed in water and become hydrophilic glueLiquid solution. According to the difference of device therefor, have multiple production method, the present invention can select cooking process, heat roll method, spray-on process,Any one in the methods such as extrusion method, microwave method, pulse jet method or multiple.
Modified starch in the present invention is all by ative starch, modification obtains, and wherein ative starch is selected in following kindAny one or multiple: cornstarch, rice starch, wheaten starch, barley starch, sorghum starch, farina, cassavaStarch, starch from sweet potato, green starch, pea starch, bajiao banana starch, sago starch and waxy starch as waxy corn starch,Waxy Rice Starch, wax sorghum starch etc.
Anticorrisive agent select in following kind any one or multiple: benzoic acid and its esters, potassium sorbate, dehydroactic acidSodium, calcium propionate, sodium Diacetate, sodium lactate, nisin, natamycin etc.
Defoamer select in following kind any one or multiple: the poly-silica of the alcohols such as propane diols, dimethyl-silicon wet goodsEster class, mineral oil and compound the disappearing such as the polyethers such as alkanes, polypropylene glycerol aether, Tweens, Tripolyglycerol monostearatesInfusion etc.
Function additive select in following kind any one or multiple: glycerin monostearate, CSL sodium;The polyalcohols such as glycerine, sorbierite; The carbohydrates such as sucrose; Some mineral matter classes such as bentonite, silica; Bean gum, gelatine etc. oneA little natural plant gum, animal glue class. By selecting suitable function additive, can play tackify, improve liquidity and the work such as stabilityWith.
The solid content of the starchiness cigarette glue in the present invention is about 15%-65%(weight), pH value is about 3-9 and preferred 5-8,Viscosity is about 100cps-20000cps(25 DEG C), and it has good viscosity, mobility and stability, at normal temperatures canEnough stable depositing more than three months time.
Any one adhesive that starchiness cigarette glue in the present invention can be used as in production of cigarettes uses, as takes mouthGlue, connect mouth glue, filter stick centre-line glue, packaging glue and aluminum foil composite glue etc., and go for the cigarette machine of any type, specialThat the above cigarette machines of 7000/minute of single rifle speed of a motor vehicle and the speed of a motor vehicle are greater than the cigarette machines faster such as 10000/minute.
Starchiness cigarette glue in the present invention also applicable to other occasion as binding papers, bottle label, packing box etc.Relate to the occasion of paper bonding.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is done to further detailed description, but the scope of the invention is not limited to these enforcementExample.
Embodiment 1
Adopt oxidation-gelatinized starch of 15%, hydroxypropylation-gelatinized starch of 1%, 0.5% Sodium Benzoate, 0.5% twoMethyl-silicone oil, 3% glycerine and 80% water are prepared starchiness cigarette glue, and oxidation-gelatinized starch used is by waxy cornStarch prepares, and hydroxypropylation-gelatinized starch is prepared by wheaten starch. The preparation flow of starchiness cigarette glueFor: first oxidation-gelatinized starch and hydroxypropylation-gelatinized starch are added to the water, then add successively Sodium Benzoate, diformazanBase silicone oil and glycerine, be uniformly mixed.
After testing: the product of making has 18% solid content, in the time of 25 DEG C, brookfield viscosity is 600cps, shouldThe viscosity of product was stable in three months, and had good viscosity and mobility etc.
Embodiment 2,
Adopt the gelatinization of the mixture of the carboxymethylated starch of oxidation-gelatinized starch of 10%, 5% hydroxypropul starch and 5%Thing, 0.5% potassium sorbate, 0.25% dimethicone, 0.25% propane diols, 5% sucrose and 74% water are prepared starchMatter cigarette glue, the gelatinization thing of the mixture of oxidation-gelatinized starch, hydroxypropul starch and CMS used is high by waxFine strain of millet starch prepares. The preparation flow of starchiness cigarette glue is: first will be oxidized-gelatinized starch, hydroxypropul starch and carboxylic firstThe gelatinization thing of both mixtures of base starch is added to the water, then add successively potassium sorbate, dimethicone, propane diols andSucrose, is uniformly mixed all and has.
After testing: products obtained therefrom has 24% solid content, in the time of 25 DEG C, brookfield viscosity is 16000cps, shouldThe viscosity of product was stable in three months, and had good viscosity and mobility etc.
Embodiment 3
Adopt oxidation-CMS mixed of oxidation-gelatinized starch of 10%, oxidation-hydroxypropul starch of 20% and 20%The gelatinization thing of compound, 0.5% dehydro sodium acetate, 0.5% natamycin, 1% polypropylene glycerol aether and 48% water systemStandby starchiness cigarette glue, oxidation-gelatinized starch used is prepared by Waxy Rice Starch, oxidation-hydroxypropul starchAnd the gelatinization thing of the mixture of oxidation-CMS is prepared by farina. The preparation of starchiness cigarette glueFlow process is: first by the gelatinization of the mixture of oxidation-gelatinized starch, oxidation-hydroxypropul starch and oxidation-CMSThing is added to the water, and then adds successively dehydro sodium acetate, natamycin and polypropylene glycerol aether, is uniformly mixedCan.
After testing: products obtained therefrom has 50% solid content, in the time of 25 DEG C, brookfield viscosity is 8900cps, this productThe viscosity of product was stable in three months, and had good viscosity and mobility etc.
Embodiment 4
Adopt the gelatinization thing, 5% hydroxypropul starch and 10% of the mixture of 10% pyrolysis dextrin and 10% oxidized starchThe gelatinization thing of the mixture of oxidation-hydroxypropul starch, 1% calcium propionate, 1% Tween-40,1% glycerin monostearate, 1%Bentonite and 61% water prepare starchiness cigarette glue, modified starch used prepares by waxy corn starch. Form sedimentThe preparation flow of opaque cigarette glue is: first by the gelatinization thing of the mixture of pyrolysis dextrin and oxidized starch, hydroxypropul starch andThe gelatinization thing of the mixture of oxidation-hydroxypropul starch is added to the water, and then adds successively calcium propionate, Tween-40, monostearateGlyceride and bentonite, be uniformly mixed.
After testing: products obtained therefrom has 35% solid content, in the time of 25 DEG C, brookfield viscosity is 2400cps, this productThe viscosity of product was stable in three months, and had good viscosity and mobility etc.
Embodiment 5
The gelatinization thing of the mixture of the denaturated starch by acid of employing 5% and 5% enzymolysis starch, 6% hydroxypropul starch and 10%The gelatinization thing, 1% sodium Diacetate, 1% mineral oil, 3% CSL sodium of mixture of oxidation-CMSAnd 69% water prepares starchiness cigarette glue, the gelatinization thing of the mixture of denaturated starch by acid used and enzymolysis starch is by waxCornstarch prepares, and the gelatinization thing of the mixture of hydroxypropul starch and oxidation-CMS is to be prepared by tapiocaObtain. The preparation flow of starchiness cigarette glue is: first by gelatinization thing, the hydroxypropyl of the mixture of denaturated starch by acid and enzymolysisThe gelatinization thing of the mixture of starch and oxidation-CMS is added to the water, then add successively sodium Diacetate, mineral oil andCSL sodium, is uniformly mixed.
After testing: products obtained therefrom has 29% solid content, in the time of 25 DEG C, brookfield viscosity is 5700cps, this productThe viscosity of product was stable in three months, and had good viscosity and mobility etc.
Embodiment 6
Adopt the gelatinization thing of the mixture of the denaturated starch by acid of 3% pyrolysis dextrin, 5% oxidized starch and 3%, 8% carboxylicMethylate-gelatinized starch, 0.5% sodium lactate, 0.5% nisin, 1% Tripolyglycerol monostearates, 3% twoSilica and 76% water are prepared starchiness cigarette glue, the mixture of pyrolysis dextrin, oxidized starch and denaturated starch by acid usedGelatinization thing prepared by Waxy Rice Starch, carboxy methylation-gelatinized starch is prepared by starch from sweet potato. StarchinessThe preparation flow of cigarette glue is: first by gelatinization thing, the carboxymethyl of the mixture of pyrolysis dextrin, oxidized starch and denaturated starch by acidChange-gelatinized starch is added to the water, and then adds successively sodium lactate, nisin, Tripolyglycerol monostearates and twoSilica, is uniformly mixed.
After testing: products obtained therefrom has 21% solid content, in the time of 25 DEG C, brookfield viscosity is 5100cps, this productThe viscosity of product was stable in three months, and had good viscosity and mobility etc.
Claims (6)
1. the novel starch matter cigarette glue based on degraded class-gelatinized starch and etherificate class-gelatinized starch, is characterized in that:One-tenth by following weight ratio is grouped into:
Water 35%-85%
Degraded class-gelatinized starch 10%-45%
Etherificate class-gelatinized starch 1%-25%
Anticorrisive agent 0.05%-1%
Defoamer 0.05%-1%
Function additive 0-5%
Described degraded class-gelatinized starch is by any one in pyrolysis dextrin, enzymolysis starch, denaturated starch by acid, oxidized starchOr multiplely obtain through gelatinization;
Described etherificate class-gelatinized starch be by HES, hydroxypropul starch, CMS, oxidation-HES,Any one in oxidation-hydroxypropul starch, oxidation-CMS or the gelatinization of multiple process obtain.
2. a kind of novel starch matter based on degraded class-gelatinized starch and etherificate class-gelatinized starch according to claim 1Cigarette glue, is characterized in that: described oxidation-HES, oxidation-hydroxypropul starch, oxidation-CMS refer to employingEtherification method, method for oxidation and the carboxy methylation of method for oxidation and hydroxyethylated etherification method, method for oxidation and hydroxypropylationEtherification method respectively ative starch is carried out to composite modified product.
3. a kind of novel starch matter based on degraded class-gelatinized starch and etherificate class-gelatinized starch according to claim 1Cigarette glue, is characterized in that: anticorrisive agent select in following kind any one or multiple: benzoic acid and its esters, sorbic acidPotassium, dehydro sodium acetate, calcium propionate, sodium Diacetate, sodium lactate, nisin, natamycin.
4. a kind of novel starch matter based on degraded class-gelatinized starch and etherificate class-gelatinized starch according to claim 1Cigarette glue, is characterized in that: defoamer select in following kind any one or multiple: the poly-silicon of propane diols, dimethiconeOxygen alkanes, polypropylene glycerol aether polyethers, Tweens, Tripolyglycerol monostearates class, mineral oil and compound defoamer.
5. a kind of novel starch matter based on degraded class-gelatinized starch and etherificate class-gelatinized starch according to claim 1Cigarette glue, is characterized in that: function additive select in following kind any one or multiple: glycerin monostearate, tristearinAcyl calcium lactate sodium; Glycerine, sorbierite; Sucrose; Bentonite, silicon dioxide mine material type; Natural plant gum, animal glue class.
6. a kind of novel starch matter based on degraded class-gelatinized starch and etherificate class-gelatinized starch according to claim 1Cigarette glue, is characterized in that: the solid content of starchiness cigarette glue is weight ratio 15%-65%, and pH value is 3-9, and viscosity is at 25 DEG C100cps-20000cps。
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| CN106700966A (en) * | 2016-12-14 | 2017-05-24 | 龚亚龙 | Adhesive and preparation method thereof |
| CN108822762A (en) * | 2018-06-20 | 2018-11-16 | 滁州市光威化工有限公司 | A kind of flame-proof starch connects mouth glue and preparation method thereof |
| CN113088218B (en) * | 2021-05-25 | 2021-11-30 | 佛山市南海华昊华丰淀粉有限公司 | Preparation method and application of starch adhesive for environment-friendly paper bags |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5085228A (en) * | 1990-05-21 | 1992-02-04 | National Starch And Chemical Investment Holding Corporation | Starch based natural adhesives used in cigarette manufacture |
| CN1081703A (en) * | 1992-07-29 | 1994-02-09 | 李有才 | A kind of preparation method of cigarette glue |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5085228A (en) * | 1990-05-21 | 1992-02-04 | National Starch And Chemical Investment Holding Corporation | Starch based natural adhesives used in cigarette manufacture |
| CN1081703A (en) * | 1992-07-29 | 1994-02-09 | 李有才 | A kind of preparation method of cigarette glue |
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