CN1081703A - A kind of preparation method of cigarette glue - Google Patents
A kind of preparation method of cigarette glue Download PDFInfo
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- CN1081703A CN1081703A CN 92109062 CN92109062A CN1081703A CN 1081703 A CN1081703 A CN 1081703A CN 92109062 CN92109062 CN 92109062 CN 92109062 A CN92109062 A CN 92109062A CN 1081703 A CN1081703 A CN 1081703A
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Abstract
The present invention is a kind of preparation method of cigarette glue, mainly be in the polymerization process of Vinyl Acetate Copolymer homopolymerization emulsion, after the viscosity of emulsion is brought up to a certain degree (〉=10000CPS), the glue stiff that becomes, be difficult for flowing, according to these characteristics, adopt and add the ethene-vinyl acetate copolymer emulsion, improve the flowability of emulsion, this additive has self-plasticizing action, solid content height (〉=54.5%) and viscosity is low by (500～1000CPS), both have complementary action, the performance of glue are obviously improved, not only the viscosity height, and good flowability is arranged, be best suited for bonding cigarette and prop up.Cigarette glue of the present invention has viscosity height, good fluidity, reaches 6000/minute in the cigarette machine speed of a motor vehicle and uses when above, do not occur leaking sticking phenomenon, and advantage such as adhesive effect is good.
Description
The present invention relates to the production technology of glue, specifically a kind of preparation method of cigarette glue.
Using the bonding filter-tip of Vinyl Acetate Copolymer homopolymerization emulsion (hereinafter to be referred as PVAC) is of long duration; its performance all has detailed description (Yang Yukun with method for making in relevant document; Liao Zengkun etc. write " synthetic adhesive " 529-532 page or leaf; Science Press in 1985; clear and the 51-2341 of special permission communique etc.); by vinyl acetate between to for plastic (hereinafter to be referred as AVC) monomer; with polyvinyl alcohol (hereinafter to be referred as PVA) is protective colloid; ammonium persulphate (hereinafter to be referred as APS) is an initiator; with water is medium, through the product of emulsion polymerization gained, is the oyster white thick liquid; nontoxic; have good tack, can regulate viscosity arbitrarily, easily mix with various additives; can be mixed with the various kind of performance; and become broad-spectrum tackiness agent, be used for the kind of bonding cigarette, so be referred to as cigarette glue.
At present, the manufacturer of domestic cigarette glue more (" Chemicals handbook tackiness agent " the 9th page, Chemical Industry Press in 1985 are compiled in the Ministry of Chemical Industry tackiness agent Scientific And Technical Intelligence Center station), 4000/minute of the cigarette glue car scooters of being produced are for domestic cigarette station-service.And about the quality good or not of cigarette glue, except that checking performance index, also will be used in and try glue on the cigarette machine, looking its speed of a motor vehicle that can reach comes evaluation quality, because the speed of a motor vehicle of cigarette machine is higher, to the more strictness of requirement of glue.Now the speed of a motor vehicle of new cigarette machine is generally all more than 6000/minute, and is very high to the performance requriements of glue, goes up machine with the glue (as 4000/minute of the speed of a motor vehicle) of general property, and it is serious often to leak sticking phenomenon, and waste is many, the fraction defective height, thus increased the cost of cigarette glue.
The object of the present invention is to provide a kind of preparation method of new cigarette glue, Zhi Bei glue in this way, car scooter is more than 6000/minute, and do not leak sticking phenomenon, and adhesive effect is good, can carry out suitability for industrialized production.
The present invention is achieved in that and has comprised vinyl acetate between to for plastic (hereinafter to be referred as the VAC monomer), polyvinyl alcohol (hereinafter to be referred as PVA), deionized water, ammonium persulphate (hereinafter to be referred as APS), defoamer (octanol), emulsifying agent (OP-10), PH conditioning agent (yellow soda ash), softening agent (dibutyl phthalate is called for short DBP) in the prescription of polyreaction (PVAC emulsion polymerization); The present invention is in this polymerization process, after bringing up to a certain degree according to the viscosity of PVAC emulsion (〉=10000CPS), the glue stiff that becomes then, not runny characteristics, adopt and add ethene-vinyl acetate copolymer emulsion (hereinafter to be referred as the VAE emulsion), improve its flowability, VAE has self-plasticizing action, and is opposite with the PVAC emulsion, solid content height (〉=54.5%) and viscosity is low by (500～1000CPS), both have complementary action, thereby add behind the VAE performance of glue and obviously improve, viscosity height not only, and good flowability is arranged, be best suited for bonding cigarette and prop up, the consumption of VAE is: VAC monomer: VAE=100: (20～70) (weight percent).The preparation were established of cigarette glue is as follows: polyreaction is carried out in the polymeric kettle that has whipping appts and condenser, deionized water is added in the still, add PVA then, be warming up to 90 ± 2 ℃, being retained to PVA dissolves fully, be cooled to 75 ℃ and add emulsifying agent and VAE emulsion, be warming up to 75 ± 2 ℃ and add 1/6 of defoamer and APS(total amount) with 8 times of water dissolution, slowly add the VAC monomer, temperature of reaction keeps 75 ± 2 ℃, adds in 3～5 hours, add then the APS(total amount 1/6), being warming up to 82 ℃ kept 0.5 hour, be cooled to 70 ℃, add PH conditioning agent and softening agent, under agitation be cooled to 40 ℃ of plastic emittings.
Cigarette glue of the present invention has viscosity height, good fluidity, reaches 6000/minute in the cigarette machine speed of a motor vehicle and uses when above, do not occur leaking sticking phenomenon, and adhesive effect is good.
Below in conjunction with the detailed description of embodiment to one step of cigarette glue preparation method time spent of the present invention:
Example 1,2 liters of three mouthfuls of round bottoms burn and on, assemble motor-driven agitator, prolong and dropping funnel, insert thermometer.Get the APS0.46 gram and put into 50 ml beakers, standby with 24 milliliters of deionized water dissolvings, get yellow soda ash 0.14 gram and put into 50 with ml beaker, standby with 10 milliliters of deionized water dissolvings.Xiang Bingzhong adds PVA(17-99) 11 gram and PVA(17-88) 12 grams, add 245 milliliters of deionized waters then, be warming up to 90 ℃, be retained to whole dissolvings, add VAE emulsion (BJ-707) 50 grams and emulsifying agent (OP-10) 1 gram, temperature remains on 75 ℃, add octanol 1 gram and APS4 milliliter (total amount 1/6), beginning slowly drips 230 gram VAC monomers, transfer the knot feed rate according to return velocity and foaming situation, add APS solution 3-4 milliliter every half an hour, the VAC monomer added in 3 hours, added remaining APS solution, be warming up to 82 ℃, keep half an hour, be cooled to 70 ℃ and add 10 milliliters of sodium carbonate solutions (containing yellow soda ash 0.14 gram) and DBP23 gram, under agitation be cooled to 40 ℃ of plastic emittings.Gained sample solid content 50%, viscosity 12000CPS has good flowability.
Example 2, get VAC monomer 230 grams, VEA emulsion (BJ-707) 115 grams, 310 milliliters of deionized waters, PVA(17-99) 7.7 grams, PVA(17-88) 15.3 grams, remaining material usage, processing condition and working method are with example 1, gained sample solid content is 51%, viscosity 10000CPS, good fluidity.
Example 3, get VAC monomer 230 grams, VAE emulsion (BJ-707) 138 grams, PVA(17-99) 15.3 grams, PVA(17-88) 7.7 grams, 230 milliliters of deionized waters, remaining material usage, processing condition and working method are with example 1, gained sample solid content is 53%, viscosity 8200CPS, glue stiff, good fluidity.
Claims (2)
1, a kind of preparation method of cigarette glue, comprise vinyl acetate between to for plastic (hereinafter to be referred as the VAC monomer) in the prescription of polyreaction (PVAC emulsion polymerization), polyvinyl alcohol (hereinafter to be referred as PVA), deionized water, ammonium persulphate (hereinafter to be referred as APS), defoamer (octanol), emulsifying agent (OP-10), PH conditioning agent (yellow soda ash), softening agent (dibutyl phthalate, be called for short DBP), it is characterized in that in polymerization process, add ethene-vinyl acetate copolymer emulsion (hereinafter to be referred as the VAE emulsion), its consumption is: VAC monomer: VAE=100: (20～70) (weight percent).
2, method according to claim 1 is characterized in that polyreaction carries out in the polymeric kettle that has whipping appts and condenser, deionized water is added in the still, add PVA then, be warming up to 90 ± 2 ℃, be retained to PVA and dissolve fully, add the VAE emulsion when being cooled to 75 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 92109062 CN1033332C (en) | 1992-07-29 | 1992-07-29 | Preparation method for cigarette glue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 92109062 CN1033332C (en) | 1992-07-29 | 1992-07-29 | Preparation method for cigarette glue |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1081703A true CN1081703A (en) | 1994-02-09 |
| CN1033332C CN1033332C (en) | 1996-11-20 |
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ID=4943946
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 92109062 Expired - Fee Related CN1033332C (en) | 1992-07-29 | 1992-07-29 | Preparation method for cigarette glue |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1033332C (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1807471B (en) * | 2005-01-20 | 2010-05-05 | 常德市金芙蓉精细化工有限责任公司 | Vinyl acetate based high viscosity latex preparation method |
| CN101215449B (en) * | 2008-01-07 | 2010-06-09 | 红云红河烟草(集团)有限责任公司 | Function cigarette overlapping glue and preparation method thereof |
| CN102229788A (en) * | 2011-05-13 | 2011-11-02 | 山西三维集团股份有限公司 | Preparation method for green and environment-friendly cigarette adhesive |
| CN102031075B (en) * | 2009-09-27 | 2013-02-27 | 曲靖宏程工贸有限公司 | Environmentally-friendly energy-saving cigarette adhesive and production method thereof |
| CN103045125A (en) * | 2012-12-26 | 2013-04-17 | 海南必凯水性涂料有限公司 | Environment-friendly mouth-stick molding plastic and preparation method thereof |
| CN103045136A (en) * | 2012-12-26 | 2013-04-17 | 海南必凯水性涂料有限公司 | Environment-friendly high-speed cigarette holder glue for cigarettes and preparation method thereof |
| CN103102845A (en) * | 2013-02-27 | 2013-05-15 | 海南必凯水性涂料有限公司 | Copolymerization prepared environment-friendly high-speed packaging adhesive for cigarette and preparation method thereof |
| CN103113837A (en) * | 2012-12-26 | 2013-05-22 | 海南必凯水性涂料有限公司 | Environment-friendly high-speed package adhesive for cigarette and copolymerization preparation method of environment-friendly high-speed package adhesive |
| CN103319637A (en) * | 2013-05-23 | 2013-09-25 | 淮阴师范学院 | Preparation method of artificial zigzag high-speed compound cigarette adhesive emulsion |
| CN103773267A (en) * | 2012-10-20 | 2014-05-07 | 中国烟草总公司郑州烟草研究院 | Amyloid cigarette adhesive based on degradable gelatinized starch and etherified gelatinized starch |
| CN106520020A (en) * | 2016-11-17 | 2017-03-22 | 大理新天制胶回收有限公司 | Environmentally friendly high speed cigarette adhesive for filter tipping and preparation method thereof |
-
1992
- 1992-07-29 CN CN 92109062 patent/CN1033332C/en not_active Expired - Fee Related
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1807471B (en) * | 2005-01-20 | 2010-05-05 | 常德市金芙蓉精细化工有限责任公司 | Vinyl acetate based high viscosity latex preparation method |
| CN101215449B (en) * | 2008-01-07 | 2010-06-09 | 红云红河烟草(集团)有限责任公司 | Function cigarette overlapping glue and preparation method thereof |
| CN102031075B (en) * | 2009-09-27 | 2013-02-27 | 曲靖宏程工贸有限公司 | Environmentally-friendly energy-saving cigarette adhesive and production method thereof |
| CN102229788A (en) * | 2011-05-13 | 2011-11-02 | 山西三维集团股份有限公司 | Preparation method for green and environment-friendly cigarette adhesive |
| CN102229788B (en) * | 2011-05-13 | 2012-11-14 | 山西三维集团股份有限公司 | Preparation method for green and environment-friendly cigarette adhesive |
| CN103773267A (en) * | 2012-10-20 | 2014-05-07 | 中国烟草总公司郑州烟草研究院 | Amyloid cigarette adhesive based on degradable gelatinized starch and etherified gelatinized starch |
| CN103773267B (en) * | 2012-10-20 | 2016-05-04 | 中国烟草总公司郑州烟草研究院 | A kind of starchiness cigarette glue based on degraded class-gelatinized starch and etherificate class-gelatinized starch |
| CN103045136A (en) * | 2012-12-26 | 2013-04-17 | 海南必凯水性涂料有限公司 | Environment-friendly high-speed cigarette holder glue for cigarettes and preparation method thereof |
| CN103113837A (en) * | 2012-12-26 | 2013-05-22 | 海南必凯水性涂料有限公司 | Environment-friendly high-speed package adhesive for cigarette and copolymerization preparation method of environment-friendly high-speed package adhesive |
| CN103045125A (en) * | 2012-12-26 | 2013-04-17 | 海南必凯水性涂料有限公司 | Environment-friendly mouth-stick molding plastic and preparation method thereof |
| CN103102845A (en) * | 2013-02-27 | 2013-05-15 | 海南必凯水性涂料有限公司 | Copolymerization prepared environment-friendly high-speed packaging adhesive for cigarette and preparation method thereof |
| CN103319637A (en) * | 2013-05-23 | 2013-09-25 | 淮阴师范学院 | Preparation method of artificial zigzag high-speed compound cigarette adhesive emulsion |
| CN103319637B (en) * | 2013-05-23 | 2016-01-27 | 淮阴师范学院 | The preparation method of imitative prionodont high speed compound cigarette glue emulsion |
| CN106520020A (en) * | 2016-11-17 | 2017-03-22 | 大理新天制胶回收有限公司 | Environmentally friendly high speed cigarette adhesive for filter tipping and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1033332C (en) | 1996-11-20 |
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