CN103773272B - Based on the non-amyloid novel starch matter cigarette glue of gelatinization - Google Patents
Based on the non-amyloid novel starch matter cigarette glue of gelatinization Download PDFInfo
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- CN103773272B CN103773272B CN201210400095.7A CN201210400095A CN103773272B CN 103773272 B CN103773272 B CN 103773272B CN 201210400095 A CN201210400095 A CN 201210400095A CN 103773272 B CN103773272 B CN 103773272B
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Abstract
Based on the non-amyloid novel starch matter cigarette glue of gelatinization, it is characterised in that：It is made of the component of following weight ratio：Water 35% 85%, non-gelatinization kind of starch 10% 60%, preservative 0.05% 1%, defoamer 0.05% 1%, function additive 0 5%；The non-gelatinization kind of starch refers to the modified starch without gelatinization reaction, including degraded class esterified and cross-linked starch and degraded class crosslinking etherified starch.The cigarette glue of the present invention has good viscosity, mobility and stability, more than the three months time of storage can be stablized at normal temperatures, it can be used as the adhesive of any one in production of cigarettes, such as overlapping glue, connect mouth glue, filter stick centre-line glue, packaging glue and aluminum foil composite glue, and it can be adapted for the cigarette machine of any type, cigarette machine and speed more than particularly single 7000/minute of rifle speed is more than the faster cigarette machine such as 10000/minute.
Description
Technical field
The present invention relates to starchiness adhesive, the one kind for being particularly suitable for production of cigarettes is amyloid based on non-gelatinization
Novel starch matter cigarette glue.
Background technology
Adhesive is one of raw and auxiliary material important in production of cigarettes manufacturing process, is related in many production of cigarettes processes
And to adhesive, mainly include：Overlapping glue, connect mouth glue, filter stick centre-line glue, packaging glue and aluminum foil composite glue etc..At present, it is domestic main
Cigarette machine list rifle speed is flowed substantially in 7000/minute or so（The speed of some new cigarette machines reach 14000-16000 branch/
Minute）, being calculated with this cigarette speed, the speed that rolls out of plume is about 500 ms/min or so, for example, for overlapping glue, from
It is coated on cigarette paper is less than 0.1 second to time between plume comes out, drying time only less than 0.1 second, otherwise cigarette machine
" race bar " phenomenon just occurs and is stopped；Therefore, this requires cigarette glue has excellent adhesive property, rheological property
Deng.
Since polyvinyl acetate emulsion class adhesive possesses above-mentioned performance characteristics, high-speed cigarette machine requirement is can adapt to, because
And at home and abroad cigarette industry is generally used.But the adhesive based on polyvinyl acetate emulsion is non-natural glue
Glutinous agent, at present, people are interested in the adhesive of natural class, such as starchiness adhesive, because the original of natural class adhesive
Expect that source is more extensive, more environmentally friendly.
Foreign countries develop starch High Speed Cigarette Adhesives since the 80s and 90s in last century, such as United States Patent (USP) 5085228 proposes
It is a kind of to include crosslinked starch and converted starch（Refer in particular to denaturated starch by acid）Mixture, obtained after being gelatinized to mixture
Starch cigarette glue, wherein the amylopectin content of special requirement ative starch is at least 70%（Weight）, and this mixture is before gelatinization
It can select to be etherified, be esterified and oxidation modification, the starch cigarette glue are applicable to the volume of 6000/minute of speed and the above
The production of smoke machine.United States Patent (USP) 5155140 proposes a kind of adhesive, mainly has by 100 parts of water, 4-120 parts of Arabic gums, 3-
80 parts of water soluble starch catabolites, carboxymethyl starch, the mixture of gelling starch are formed.United States Patent (USP) 5329004 proposes
One kind is with amylopectin content at least 90%（Weight）Ative starch be raw material, pass through Acid denaturation（Or enzymolysis, oxidation）, phosphoric acid
Esterification, gelatinization have obtained a kind of starch cigarette glue, which is applicable to the cigarette of 6000/minute of speed and the above
The production of machine.United States Patent (USP) 5490875 proposes one kind with amylopectin content at least 70%（Weight）Ative starch be raw material,
White dextrin and hydrolysis starch are prepared for respectively（Pass through enzyme and/or acid）, then it is gelatinized, has obtained starch adhesive.
Chinese patent CN 1095864C propose a kind of unmodified starch including 2-25% dispersivenesses, 5-60% modified starches, 0-5% streams
Become the starch cigarette glue of modifying agent, about 0-1% preservatives and 0-1% defoamers composition, it is big which is applicable to speed of production
In 7000 cigarette per minute and the cigarette machine of 10000 cigarette sometimes more than per minute.Chinese patent CN 100556973C are carried
Go out a kind of with one or more kinds of modified starches（Acetylated starch, two crosslinked starch of acetylation, etherification starch, etherificate
Crosslinked starch）Again by second of modified obtained starch-based adhesive, second of modification of modified starch is to be gelatinized into
Carried out during glue, be acylation modification or it is etherification modified with degraded synchronously carry out, the amylan be applicable to be more than etc.
In the cigarette machine of 7000/minute.However, still there is car during production for many starch cigarette glues arrived involved in existing patent
Speed it is low in addition do not refer to start speed, viscosity it is poor, glue stability is poor the problems such as, and at present the country not yet occur meeting cigarette
The starchiness adhesive product of the commercialization of industrial practical application request.Therefore, there is still a need for it can meet existing cigarette machine
High speed etc. is numerous to be required and with good viscosity, mobility, the starchiness cigarette adhesive of stability.
The content of the invention
It disclosure satisfy that existing cigarette machine normally produces it is an object of the invention to overcome the deficiencies of the prior art and provide one kind
Demand（Single 7000/minute of rifle speed and with first-class）, and one kind with good viscosity, mobility and stability is based on non-
It is gelatinized amyloid novel starch matter cigarette glue.
The purpose of the present invention is what is be achieved through the following technical solutions：
Based on the non-amyloid novel starch matter cigarette glue of gelatinization, it is made of the component of following weight ratio：
Water 35%-85%
Non- gelatinization kind of starch 10%-60%
Preservative 0.05%-1%
Defoamer 0.05%-1%
Function additive 0-5%
The non-gelatinization kind of starch refers to the modified starch without gelatinization reaction, including degraded class-crosslinking -ester starch
With degraded class-crosslinking-etherification starch.
Degraded class-crosslinking -ester the starch refers to pyrolysis-crosslinking-Acetylated potato starch, pyrolysis-crosslinking-Phosphation
Starch, enzymolysis-crosslinking-Acetylated potato starch, enzymolysis-crosslinking-organic phosphate starch, Acid denaturation-crosslinking-Acetylated potato starch,
Acid denaturation-crosslinking-organic phosphate starch, oxidation-crosslinking-Acetylated potato starch, oxidation-crosslinking-organic phosphate starch, it is preferably hot
Solution-crosslinking-organic phosphate starch.
Degraded class-crosslinking-the etherification starch refers to pyrolysis-crosslinking-hydroxyethyl starch, pyrolysis-crosslinking-hydroxypropylation
Starch, pyrolysis-cross-linking carboxymethyl starch, enzymolysis-crosslinking-hydroxyethyl starch, enzymolysis-crosslinking-hydroxypropyl starch, enzyme
Solution-cross-linking carboxymethyl starch, Acid denaturation-crosslinking-hydroxyethyl starch, Acid denaturation-crosslinking-hydroxypropyl starch, acid become
Property-cross-linking carboxymethyl starch, oxidation-crosslinking-hydroxyethyl starch, oxidation-crosslinking-hydroxypropyl starch, oxidation-crosslinking-
Carboxymethylated starch, preferably pyrolysis-crosslinking-hydroxyethyl starch, pyrolysis-cross-linking carboxymethyl starch.
In addition, it is above-mentioned it is non-gelatinization kind of starch can use ative starch, crosslinked starch, Acetylated potato starch, organic phosphate starch,
Any one or more in hydroxyethyl starch, hydroxypropul starch, carboxymethyl starch and preferred crosslinked starch and hydroxypropul starch
The equivalent substitution of part is carried out, it is about 5 with the non-amyloid proportion of gelatinization:1~0:1.
Modified starch in the present invention to ative starch by being modified to obtain, and wherein ative starch is selected in following species
Any one or more：Cornstarch, rice starch, wheaten starch, barley starch, sorghum starch, farina, cassava
Starch, starch from sweet potato, green starch, pea starch, bajiao banana starch, sago starch and waxy starch such as waxy corn starch,
Waxy Rice Starch, wax sorghum starch etc..
Non- gelatinization kind of starch in the present invention refers to the product to ative starch modification for composite using a variety of method of modifying,
As pyrolysis-crosslinking-organic phosphate starch refers to carry out three to ative starch using method for pyrolysis, cross-linking method and Phosphation method
Secondary composite modified product, pyrolysis-cross-linking carboxymethyl starch refer to using method for pyrolysis, cross-linking method and carboxymethylated
Product of the etherification method to ative starch modification for composite.
Preservative in the present invention selects any one or more in following species：Benzoic acid and its esters, sorbic acid
Potassium, dehydroactic acid sodium, calcium propionate, sodium Diacetate, sodium lactate, nisin, natamycin etc..
Defoamer in the present invention selects any one or more in following species：The alcohols such as propane diols, dimethyl-silicon
Esters, the mineral oil such as polyethers, Tweens, the Tripolyglycerol monostearates such as oil etc. is polysiloxane-based, polypropylene glycerol aether
And composite anti-foaming agent etc..
Function additive in the present invention selects any one or more in following species：Glycerin monostearate, tristearin
Acyl calcium lactate sodium；The polyalcohols such as glycerine, sorbierite；The carbohydrates such as sucrose；Some mineral matter classes such as bentonite, silica；Beans
Some natural plant gum such as glue, gelatine, animal glue class.By selecting suitable function additive, can play thickening, improve mobility and
Stability etc. acts on.
The solid content of starchiness cigarette glue in the present invention is about 15%-65%（Weight）, pH value is about 3-9 and preferred 5-8,
Viscosity is about 100cps-20000cps（25℃）, and it at normal temperatures can with good viscosity, mobility and stability
It is enough to stablize more than the three months time of storage.
Starchiness cigarette glue in the present invention can be used as the adhesive of any one in production of cigarettes, such as take mouth
Glue, connect mouth glue, filter stick centre-line glue, packaging glue and aluminum foil composite glue etc., and can be adapted for the cigarette machine of any type, especially
It is that more than single 7000/minute of rifle speed cigarette machine and speed are more than the faster cigarette machine such as 10000/minute.
Starchiness cigarette glue in the present invention is equally applicable to other occasions such as binding papers, bottle label, packing box etc.
It is related to the occasion of paper bonding.
Embodiment
Further detailed description is done to the present invention below in conjunction with embodiment, but the scope of the invention is not limited to these.
Embodiment 1
Using 10% pyrolysis-crosslinking-organic phosphate starch, 18% pyrolysis-crosslinking-hydroxyethyl starch, 5% crosslinking
Starch, 0.5% sodium benzoate, 0.5% propane diols, 5% sucrose and 61% water prepare starchiness cigarette glue, wherein all
Modified starch be prepared by cornstarch.The preparation flow of starchiness cigarette glue is：First by pyrolysis-crosslinking-phosphoric acid
Esterification starch, pyrolysis-crosslinking-hydroxyethyl starch and crosslinked starch are added to the water, and then sequentially add sodium benzoate, the third two
Alcohol and sucrose, be stirred by.
After testing：Products obtained therefrom has 37% solid content, and at 25 DEG C, brookfield viscosity is 2430cps, the production
The viscosity of product was stable in three months, and with good viscosity and mobility etc..
Embodiment 2
Using 5% Acid denaturation-crosslinking-Acetylated potato starch, 22% Acid denaturation-crosslinking-hydroxypropyl starch, 15%
Hydroxypropul starch, 1% sodium benzoate, 1% dimethicone, 2% attapulgite and 54% water prepare starchiness cigarette
Glue, wherein Acid denaturation-crosslinking-Acetylated potato starch are prepared by tapioca, and Acid denaturation-crosslinking-hydroxypropylation forms sediment
Powder is prepared by farina.The preparation flow of starchiness cigarette glue is：First by Acid denaturation-crosslinking-acetate
Change starch, Acid denaturation-crosslinking-hydroxypropyl starch and hydroxypropul starch to be added to the water, then sequentially add sodium benzoate, two
Methyl-silicone oil and attapulgite, are uniformly mixed.
After testing：Products obtained therefrom has 44% solid content, and at 25 DEG C, brookfield viscosity is 4940cps, the production
The viscosity of product was stable in three months, and with good viscosity and mobility etc..
Embodiment 3
Using 22% oxidation-crosslinking-hydroxyethyl starch, 25% oxidation-crosslinking-hydroxypropyl starch, 10% former shallow lake
Powder, 1% potassium sorbate, 1% silicone emulsion, 1% diatomite and 40% water prepare starchiness cigarette glue, all modified shallow lakes
Powder is prepared by starch from sweet potato.The preparation flow of starchiness cigarette glue is：First by oxidation-crosslinking-hydroxyethyl starch,
Oxidation-crosslinking-hydroxypropyl starch and ative starch are added to the water, and then sequentially add potassium sorbate, silicone emulsion and diatom
Soil, is uniformly mixed.
After testing：Products obtained therefrom has 58% solid content, and at 25 DEG C, brookfield viscosity is 19340cps, should
The viscosity of product was stable in three months, and with good viscosity and mobility etc..
Embodiment 4
Using 15% pyrolysis-cross-linking carboxymethyl starch, 5% enzymolysis-crosslinking-organic phosphate starch, 10% oxidation-
Crosslinking-Acetylated potato starch, 10% acetate starch, 1% dehydroactic acid sodium, 1% silicone emulsion, 1% gelatin and 57%
Water prepare starchiness cigarette glue, all starch are prepared by sorghum starch.The preparation flow of starchiness cigarette glue is：It is first
First by pyrolysis-cross-linking carboxymethyl starch, enzymolysis-crosslinking-organic phosphate starch, oxidation-crosslinking-Acetylated potato starch and vinegar
Acid esters starch is added to the water, and then sequentially adds dehydroactic acid sodium, silicone emulsion and gelatin, be stirred by.
After testing：Products obtained therefrom has 40% solid content, and at 25 DEG C, brookfield viscosity is 3920cps, the production
The viscosity of product was stable in three months, and with good viscosity and mobility etc..
Embodiment 5
Using 5% pyrolysis-crosslinking-organic phosphate starch, 4% pyrolysis-crosslinking-hydroxypropyl starch, 3% Acid denaturation-
Crosslinking-Acetylated potato starch, 12% Acid denaturation-cross-linking carboxymethyl starch, 1% sodium Diacetate.1% mineral oil and
74% water prepares starchiness cigarette glue, and all modified starches are prepared by rice starch.The preparation stream of starchiness cigarette glue
Cheng Wei：First by pyrolysis-crosslinking-organic phosphate starch, pyrolysis-crosslinking-hydroxypropyl starch, Acid denaturation-crosslinking-acetic acid esterified
Starch and Acid denaturation-cross-linking carboxymethyl starch are added to the water, and then sequentially add sodium Diacetate and mineral oil, and stirring is mixed
Close uniform.
After testing：Products obtained therefrom has 25% solid content, and at 25 DEG C, brookfield viscosity is 730cps, the production
The viscosity of product was stable in three months, and with good viscosity and mobility etc..
Embodiment 6
Using 20% oxidation-crosslinking-organic phosphate starch, 18% oxidation-cross-linking carboxymethyl starch, 10% crosslinking
Starch, 1% sodium lactate, 1% Tween-40,5% glycerine and 45% water prepare starchiness cigarette glue, wherein oxidation-friendship
Connection-organic phosphate starch is prepared by tapioca, and oxidation-cross-linking carboxymethyl starch is prepared by cornstarch
Obtain, crosslinked starch is prepared by rice starch.The preparation flow of starchiness cigarette glue is：First by oxidation-friendship
Connection-organic phosphate starch, oxidation-cross-linking carboxymethyl starch and crosslinked starch are added to the water, and then sequentially add lactic acid
Sodium, Tween-40 and glycerine, are uniformly mixed.
After testing：Products obtained therefrom has 53% solid content, and at 25 DEG C, brookfield viscosity is 7430cps, the production
The viscosity of product was stable in three months, and with good viscosity and mobility etc..
Claims (6)
1. based on the non-amyloid novel starch matter cigarette glue of gelatinization, it is characterised in that：It is made of the component of following weight ratio：
Water 35%-85%
Non- gelatinization kind of starch 10%-60%
Preservative 0.05%-1%
Defoamer 0.05%-1%
Function additive 1-5%
The non-gelatinization kind of starch refers to the modified starch without gelatinization reaction, including degraded class-crosslinking -ester starch and drop
Solve class-crosslinking-etherification starch；
Degraded class-crosslinking -ester the starch refers to that pyrolysis-crosslinking-Acetylated potato starch, pyrolysis-crosslinking-Phosphation form sediment
Powder, enzymolysis-crosslinking-Acetylated potato starch, enzymolysis-crosslinking-organic phosphate starch, Acid denaturation-crosslinking-Acetylated potato starch, acid
Denaturation-crosslinking-organic phosphate starch, oxidation-crosslinking-Acetylated potato starch, oxidation-crosslinking-organic phosphate starch；
Degraded class-crosslinking-the etherification starch refers to that pyrolysis-crosslinking-hydroxyethyl starch, pyrolysis-crosslinking-hydroxypropylation form sediment
Powder, pyrolysis-cross-linking carboxymethyl starch, enzymolysis-crosslinking-hydroxyethyl starch, enzymolysis-crosslinking-hydroxypropyl starch, enzymolysis-
Cross-linking carboxymethyl starch, Acid denaturation-crosslinking-hydroxyethyl starch, Acid denaturation-crosslinking-hydroxypropyl starch, Acid denaturation-friendship
Connection-carboxymethylated starch, oxidation-crosslinking-hydroxyethyl starch, oxidation-crosslinking-hydroxypropyl starch, oxidation-crosslinking-carboxylic first
Base starch；
Above-mentioned non-gelatinization kind of starch can use ative starch, crosslinked starch, Acetylated potato starch, organic phosphate starch, ethoxy to form sediment
Any one or more equivalent substitution in powder, hydroxypropul starch, carboxymethyl starch；
The novel starch matter cigarette glue is made by following preparation flow：The non-gelatinized starch is included into degraded
Class-crosslinking -ester starch and degraded class-crosslinking-etherification starch, be added to the water, then sequentially add preservative, defoamer and
Function additive, is uniformly mixed.
It is 2. according to claim 1 based on the non-amyloid novel starch matter cigarette glue of gelatinization, it is characterised in that：It is described to change
Property starch by being modified to obtain to ative starch, wherein ative starch selects any one or more in following species：It is beautiful
Rice starch, rice starch, wheaten starch, barley starch, sorghum starch, farina, tapioca, starch from sweet potato, mung bean
Starch, pea starch, bajiao banana starch, sago starch and waxy corn starch, Waxy Rice Starch, wax sorghum starch.
It is 3. according to claim 1 based on the non-amyloid novel starch matter cigarette glue of gelatinization, it is characterised in that：Preservative
Select any one or more in following species：Benzoic acid and its esters, potassium sorbate, dehydroactic acid sodium, calcium propionate, double second
Sour sodium, sodium lactate, nisin, natamycin.
It is 4. according to claim 1 based on the non-amyloid novel starch matter cigarette glue of gelatinization, it is characterised in that：It is described to disappear
Infusion selects any one or more in following species：Propane diols, dimethicone are polysiloxane-based, polypropylene glycerol aether
Polyethers, Tweens, Tripolyglycerol monostearates esters, mineral oil and composite anti-foaming agent.
It is 5. according to claim 1 based on the non-amyloid novel starch matter cigarette glue of gelatinization, it is characterised in that：The work(
Energy auxiliary agent selects any one or more in following species：Glycerin monostearate, stearyl lactate sodium；Glycerine, sorb
Alcohol；Sucrose；Bentonite, silicon dioxide mine material class；Natural plant gum, animal glue class.
It is 6. according to claim 1 based on the non-amyloid novel starch matter cigarette glue of gelatinization, it is characterised in that：The shallow lake
The solid content of silty cigarette glue is 15%-65%, pH value 3-9, viscosity 100cps-20000cps.
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| CN201210400095.7A CN103773272B (en) | 2012-10-20 | 2012-10-20 | Based on the non-amyloid novel starch matter cigarette glue of gelatinization |
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| CN201210400095.7A CN103773272B (en) | 2012-10-20 | 2012-10-20 | Based on the non-amyloid novel starch matter cigarette glue of gelatinization |
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| CN103773272B true CN103773272B (en) | 2018-04-17 |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1135231A (en) * | 1993-11-18 | 1996-11-06 | 赖克霍德化学公司 | Starch-based adhesive |
| CN1769361A (en) * | 2004-11-03 | 2006-05-10 | 胡正水 | Starchiness adhesives and preparation method |
-
2012
- 2012-10-20 CN CN201210400095.7A patent/CN103773272B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1135231A (en) * | 1993-11-18 | 1996-11-06 | 赖克霍德化学公司 | Starch-based adhesive |
| CN1769361A (en) * | 2004-11-03 | 2006-05-10 | 胡正水 | Starchiness adhesives and preparation method |
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| Publication number | Publication date |
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| CN103773272A (en) | 2014-05-07 |
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