CN103773273A - Novel amyloid cigarette adhesive based on esterified gelatinized starch and non-gelatinized starch - Google Patents

Novel amyloid cigarette adhesive based on esterified gelatinized starch and non-gelatinized starch Download PDF

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Publication number
CN103773273A
CN103773273A CN201210400078.3A CN201210400078A CN103773273A CN 103773273 A CN103773273 A CN 103773273A CN 201210400078 A CN201210400078 A CN 201210400078A CN 103773273 A CN103773273 A CN 103773273A
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starch
gelatinization
class
esterification
cigarette
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CN103773273B (en
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贾云祯
刘惠民
张晓兵
王宜鹏
赵乐
谢复炜
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Zhengzhou Tobacco Research Institute of CNTC
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Zhengzhou Tobacco Research Institute of CNTC
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Abstract

The invention relates to a novel amyloid cigarette adhesive based on esterified gelatinized starch and non-gelatinized starch. The novel amyloid cigarette adhesive based on the non-gelatinized starch is characterized by comprising the following components by weight: 35%-85% of water, 5%-45% of the esterified gelatinized starch, 5%-45% of the non-gelatinized starch, 0.05%-1% of a preservative, 0.05%-1% of a defoaming agent and 0-5% of a functional assistant. The gelatinized starch is obtained by gelatinizing any one or more of esterified starch and degradable esterified starch; and the non-gelatinized starch is the modified starch without being subjected to gelatinization reaction. The cigarette adhesive provided by the invention has good viscosity, fluidity and stability, can be stably stored for more than three months at a room temperature, can be used as any adhesive such as lap adhesive, tipping adhesive, filter rod central line adhesive, packaging adhesive and aluminum foil laminated adhesive in cigarette production, and is applicable to any cigarette machine, particularly a cigarette machine with a single-gun speed higher than 7,000 cigarettes/minute.

Description

A kind of based on esterification class-pasted starch and the amyloid novel starch matter of non-gelatinization cigarette glue
Technical field
The present invention relates to starchiness sizing agent, be particularly applicable to one that production of cigarettes uses based on esterification class-pasted starch and the amyloid novel starch matter of non-gelatinization cigarette glue.
Background technology
Sizing agent is one of raw and auxiliary material important in production of cigarettes manufacturing processed, in a lot of production of cigarettes operations, all relates to sizing agent, mainly comprises: overlapping glue, connect mouth glue, filter stick centre-line glue, packing glue and aluminum foil composite glue etc.At present, the domestic main flow cigarette machine list rifle speed of a motor vehicle is about 7000/minute (speed of a motor vehicle of some new cigarette machine reaches 14000-16000 props up/minute) substantially, calculate with this cigarette speed, the speed that rolls out of plume is about 500 ms/min of left and right, for example, concerning overlapping glue, be coated in cigarette tissue the time of plume out from it and be less than 0.1 second, time of drying is only less than 0.1 second, otherwise cigarette machine just there will be " race bar " phenomenon and quits work; Therefore, this just requires cigarette glue to have excellent adhesive property, rheological property etc.
Because polyvinyl acetate emulsion class sizing agent possesses above-mentioned performance characteristics, can adapt to high-speed cigarette machine requirement, thereby cigarette industry is generally used at home and abroad.But be non-natural sizing agent take polyvinyl acetate emulsion as basic sizing agent, at present, people are interested in the sizing agent of natural class, as starchiness sizing agent etc. because the raw material sources of natural class tackiness agent more extensively, more environmental protection.
Abroad since the 80s and 90s in last century developing starch High Speed Cigarette Adhesives, for example United States Patent (USP) 5085228 has proposed the mixture that one comprises cross-linking starch and modified starch (referring in particular to denaturated starch by acid), mixture is carried out obtaining starch cigarette glue after gelatinization, wherein the amylopection content of special requirement ative starch is at least 70%(weight), and this mixture can select to carry out etherificate, esterification and oxidation modification before gelatinization, this starch cigarette glue is applicable to the production of 6000/minute of the speed of a motor vehicle and above cigarette machine.United States Patent (USP) 5155140 has proposed a kind of tackiness agent, mainly contains by the mixture of 100 parts of water, 4-120 part gum arabic, 3-80 part water soluble starch degraded product, carboxymethyl starch, gelling starch and forms.United States Patent (USP) 5329004 has proposed a kind of take at least 90%(weight of amylopection content) ative starch as raw material, obtained a kind of starch cigarette glue by sour sex change (or enzymolysis, oxidation), Phosphation, gelatinization, this starch cigarette glue is applicable to the production of 6000/minute of the speed of a motor vehicle and above cigarette machine.United States Patent (USP) 5490875 has proposed a kind of take at least 70%(weight of amylopection content) ative starch as raw material, prepared respectively white dextrin and hydrolyzed starch (by enzyme and/or acid), then carried out gelatinization, obtained starch adhesive.Chinese patent CN 1095864C has proposed a kind of starch cigarette glue of unmodified starch, 5-60% treated starch, 0-5% rheology modifier, about 0-1% sanitas and 0-1% defoamer composition of the 2-25% of comprising dispersiveness, and this amylan is greater than 7000 cigarette of per minute applicable to production rate and is sometimes greater than the cigarette machine of 10000 cigarette of per minute.Chinese patent CN 100556973C has proposed the starch-based adhesive that a kind of treated starch with one or more (acetylated starch, acetylize two cross-linking starchs, etherification starch, etherificate cross-linking starch) obtains after modification for the second time again; the modification for the second time of treated starch is to carry out in the process of gelatinization plastic; be acylation modification or etherification modifiedly synchronize and carry out with degraded, this amylan is applicable to the cigarette machine that is more than or equal to 7000/minute.But, the a lot of starch cigarette glues that relate in existing patent still exist the problems such as the speed of a motor vehicle low even not mentioned start speed of a motor vehicle while production, viscosity are poor, glue poor stability, and the domestic commercial starchiness sizing agent product that not yet occurs meeting cigarette industry practical application request at present.Therefore the starchiness cigarette sizing agent that, still needs to meet numerous requirements such as the high speed of a motor vehicle of existing cigarette machine and there is good viscosity, mobility, stability.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, provide one can meet the normal Production requirement of existing cigarette machine (7000/minute of single rifle speed of a motor vehicle and with first-class), and the one with good viscosity, mobility and stability is based on esterification class-pasted starch and the amyloid novel starch matter of non-gelatinization cigarette glue.
The object of the invention is to be achieved through the following technical solutions:
A kind of based on esterification class-pasted starch and the amyloid novel starch matter of non-gelatinization cigarette glue, be grouped into by the one-tenth of following weight ratio:
Water 35%-85%
Esterification class-pasted starch 5%-45%
Non-gelatinization kind of starch 5%-45%
Sanitas 0.05%-1%
Defoamer 0.05%-1%
Functional agent 0-5%
Described esterification class-pasted starch refer to by esterification starch, degraded class-ester starch any one or multiplely obtain through gelatinization.Described esterification starch comprises Acetylated potato starch, organic phosphate starch, preferably phosphoric acid esterification starch.Described degraded class-ester starch comprises in pyrolysis-Acetylated potato starch, pyrolysis-organic phosphate starch, enzymolysis-Acetylated potato starch, enzymolysis-organic phosphate starch, sour sex change-Acetylated potato starch, sour sex change-organic phosphate starch, oxidation-Acetylated potato starch, oxidation-organic phosphate starch, wherein preferred pyrolysis-phosphate ester starch, enzymolysis-phosphate ester starch.
Described non-gelatinization kind of starch refers to without the treated starch of gelatinization reaction, comprise ative starch, cross-linking starch, Acetylated potato starch, organic phosphate starch, hydroxyethyl starch, hydroxypropyl starch, carboxymethylated starch, wherein preferred acetate starch, hydroxypropylated starch.
Treated starch in the present invention is all by ative starch, modification obtains, wherein ative starch select in following kind any one or multiple: W-Gum, Starch rice, wheat starch, barley starch, sorghum starch, yam starch, tapioca (flour), sweet potato starch, green starch, pea starch, bajiao banana starch, sago starch and waxy starch are as waxy corn starch, Waxy Rice Starch, wax sorghum starch etc.
The composite modified starch such as pyrolysis-Acetylated potato starch, pyrolysis-organic phosphate starch in the present invention refers to and adopts the multipair ative starch of multiple method of modifying to carry out composite modified product, adopts the esterification process of method for pyrolysis and acetic acid esterified to carry out composite modified product to ative starch as pyrolysis-Acetylated potato starch refers to.
" gelatinization " in the present invention claims again " αization ", and its essence is that water molecules enters in starch small grain, and the hydrogen bond rupture between crystallization phases and the starch molecule of unformed phase has destroyed the association state between starch molecule, is dispersed in water and becomes hydrophilic colloidal solution.According to the difference of equipment used, have multiple production method, the present invention can select cooking process, heat roll in the methods such as method, spray method, extruding puffing method, microwave method, pulse jet method any one or multiple.
Sanitas in the present invention select in following kind any one or multiple: phenylformic acid and its esters, potassium sorbate, Sodium dehydroacetate, calcium propionate, sodium Diacetate, Sodium.alpha.-hydroxypropionate, nisin, tennecetin etc.
Defoamer in the present invention select in following kind any one or multiple: ester class, mineral oil and the compound defoamers etc. such as polyethers, Tweens, Tripolyglycerol monostearates such as the alcohols such as propylene glycol, dimethyl-silicon wet goods are polysiloxane-based, polypropylene glycerol aether.
Functional agent in the present invention select in following kind any one or multiple: glyceryl monostearate, CSL sodium; The polyalcohols such as glycerine, sorbyl alcohol; The carbohydrates such as sucrose; Some mineral substance classes such as wilkinite, silicon-dioxide; Some vegetable jelly such as bean gum, gelatine, gelatin class.By selecting suitable functional agent, can play tackify, improve liquidity and the effect such as stability.
The solid content of the starchiness cigarette glue in the present invention is about 15%-65%(weight), pH value is about 3-9 and preferred 5-8, viscosity is about 100cps-20000cps(25 ℃), and it has good viscosity, mobility and stability, can stablize more than three months time of depositing at normal temperatures.
Any one sizing agent that starchiness cigarette glue in the present invention can be used as in production of cigarettes uses, as overlapping glue, connect mouth glue, filter stick centre-line glue, packing glue and aluminum foil composite glue etc., and go for the cigarette machine of any type, particularly the above cigarette machines of 7000/minute of single rifle speed of a motor vehicle and the speed of a motor vehicle are greater than the cigarette machines faster such as 10000/minute.
Starchiness cigarette glue in the present invention also relates to the occasion of paper bonding applicable to other occasion as binding papers, bottle label, packing box etc.
Embodiment
Below in conjunction with embodiment, the present invention is done to further detailed description, but the scope of the invention is not limited to these embodiment.
Embodiment 1
Adopt gelatinization thing, 15% Acetylated potato starch, 0.75% Sodium Benzoate, 0.75% dimethyl silicone oil, 3% glyceryl monostearate and 54.5% the water of the mixture of the pyrolysis-organic phosphate starch of 10% phosphate ester starch and 15% to prepare starchiness cigarette glue, wherein phosphate ester starch and pyrolysis-organic phosphate starch are prepared by W-Gum, and acetate starch is prepared by green starch.The preparation flow of starchiness cigarette glue is: first gelatinization thing and the acetate starch of the mixture of phosphate ester starch and pyrolysis-organic phosphate starch are added to the water, then add successively Sodium Benzoate, dimethyl silicone oil and glyceryl monostearate, be uniformly mixed.
After testing: the product of making has 42% solid content, in the time of 25 ℃, brookfield viscosity is 5320cps, and the viscosity of this product was stable in three months, and has good viscosity and mobility etc.
Embodiment 2
Adopt gelatinization thing, 10% Acetylated potato starch, 1% potassium sorbate, 1% dimethyl silicone oil, 5% sorbyl alcohol and 59% the water of the mixture of the enzymolysis-organic phosphate starch of 1% Acetylated potato starch, 8% organic phosphate starch and 15% to prepare starchiness cigarette glue, wherein all treated starches prepare by tapioca (flour).The preparation flow of starchiness cigarette glue is: first gelatinization thing and the Acetylated potato starch of the mixture of Acetylated potato starch, organic phosphate starch and enzymolysis-organic phosphate starch are added to the water, then add successively potassium sorbate, dimethyl silicone oil and sorbyl alcohol, be uniformly mixed.
After testing: the product of making has 39% solid content, in the time of 25 ℃, brookfield viscosity is 3260cps, and the viscosity of this product was stable in three months, and has good viscosity and mobility etc.
Embodiment 3
Adopt pyrolysis-Phosphation-pasted starch of 15%, 10% ative starch, 1% Sodium dehydroacetate, 1% mineral oil, 2% CSL sodium and 71% water to prepare starchiness cigarette glue, pyrolysis-Phosphation-pasted starch is prepared by wheat starch, and ative starch is pea starch.The preparation flow of starchiness cigarette glue is: first pyrolysis-Phosphation-pasted starch and ative starch are added to the water, then add successively Sodium dehydroacetate, mineral oil and CSL sodium, be uniformly mixed.
After testing: the product of making has 26% solid content, in the time of 25 ℃, brookfield viscosity is 1420cps, and the viscosity of this product was stable in three months, and has good viscosity and mobility etc.
Embodiment 4
Adopt gelatinization thing, 10% hydroxypropylated starch, 1% Sodium dehydroacetate, 1% mineral oil, 1% wilkinite and 77% the water of the mixture of the oxidation-organic phosphate starch of sour sex change-Acetylated potato starch of 5% and 5% to prepare starchiness cigarette glue, wherein all treated starches prepare by Starch rice.The preparation flow of starchiness cigarette glue is: first gelatinization thing and the hydroxypropylated starch of the mixture of sour sex change-Acetylated potato starch and oxidation-organic phosphate starch are added to the water, then add successively Sodium dehydroacetate, mineral oil and wilkinite, be uniformly mixed.
After testing: the product of making has 20% solid content, in the time of 25 ℃, brookfield viscosity is 480cps, and the viscosity of this product was stable in three months, and has good viscosity and mobility etc.
Embodiment 5
Adopt gelatinization thing, 15% hydroxypropylated starch, 1% sodium Diacetate, 1% propylene glycol and 44% the water of the mixture of the oxidation-organic phosphate starch of pyrolysis-organic phosphate starch of 14%, sour sex change-organic phosphate starch of 15% and 10% to prepare starchiness cigarette glue, all treated starches prepare by Waxy Rice Starch.The preparation flow of starchiness cigarette glue is: first gelatinization thing and the hydroxypropylated starch of the mixture of pyrolysis-organic phosphate starch, sour sex change-organic phosphate starch and oxidation-organic phosphate starch are added to the water, then add successively sodium Diacetate and propylene glycol, be uniformly mixed.
After testing: the product of making has 54% solid content, in the time of 25 ℃, brookfield viscosity is 16340cps, and the viscosity of this product was stable in three months, and has good viscosity and mobility etc.
Embodiment 6
Adopt enzymolysis-Phosphation-pasted starch of 20%, 20% cross-linking starch, 0.5% Sodium.alpha.-hydroxypropionate, 0.5% nisin, 1% Tween-60,5% glucose and 53% water to prepare starchiness cigarette glue, all treated starches prepare by sweet potato starch.The preparation flow of starchiness cigarette glue is: first enzymolysis-Phosphation-pasted starch and cross-linking starch are added to the water, then add successively Sodium.alpha.-hydroxypropionate, nisin, Tween-60 and glucose, be uniformly mixed.
After testing: the product of making has 45% solid content, in the time of 25 ℃, brookfield viscosity is 8320cps, and the viscosity of this product was stable in three months, and has good viscosity and mobility etc.

Claims (9)

1. based on esterification class-pasted starch and the amyloid novel starch matter of a non-gelatinization cigarette glue, it is characterized in that: the one-tenth by following weight ratio is grouped into:
Water 35%-85%
Esterification class-pasted starch 5%-45%
Non-gelatinization kind of starch 5%-45%
Sanitas 0.05%-1%
Defoamer 0.05%-1%
Functional agent 0-5%
Described esterification class-pasted starch refer to by esterification starch, degraded class-ester starch any one or multiplely obtain through gelatinization;
Described non-gelatinization kind of starch refers to without the treated starch of gelatinization reaction.
2. one according to claim 1, based on esterification class-pasted starch and the amyloid novel starch matter of non-gelatinization cigarette glue, is characterized in that: described esterification starch comprises Acetylated potato starch, organic phosphate starch preferably phosphoric acid esterification starch; Described degraded class-ester starch comprises in pyrolysis-Acetylated potato starch, pyrolysis-organic phosphate starch, enzymolysis-Acetylated potato starch, enzymolysis-organic phosphate starch, sour sex change-Acetylated potato starch, sour sex change-organic phosphate starch, oxidation-Acetylated potato starch, oxidation-organic phosphate starch, wherein preferred pyrolysis-phosphate ester starch, enzymolysis-phosphate ester starch.
3. one according to claim 2 is based on esterification class-pasted starch and the amyloid novel starch matter of non-gelatinization cigarette glue, it is characterized in that: the composite modified starch such as pyrolysis-Acetylated potato starch, pyrolysis-organic phosphate starch in the present invention refers to and adopts the multipair ative starch of multiple method of modifying to carry out composite modified product, adopts the esterification process of method for pyrolysis and acetic acid esterified to carry out composite modified product to ative starch as pyrolysis-Acetylated potato starch refers to.
4. one according to claim 1 is based on esterification class-pasted starch and the amyloid novel starch matter of non-gelatinization cigarette glue, it is characterized in that: described non-gelatinization kind of starch comprises ative starch, cross-linking starch, Acetylated potato starch, organic phosphate starch, hydroxyethyl starch, hydroxypropyl starch, carboxymethylated starch, wherein preferred acetate starch, hydroxypropylated starch.
5. one according to claim 1 is based on esterification class-pasted starch and the amyloid novel starch matter of non-gelatinization cigarette glue, it is characterized in that: described treated starch is all by ative starch, modification obtains, wherein ative starch select in following kind any one or multiple: W-Gum, Starch rice, wheat starch, barley starch, sorghum starch, yam starch, tapioca (flour), sweet potato starch, green starch, pea starch, bajiao banana starch, sago starch, and waxy starch is as waxy corn starch, Waxy Rice Starch, wax sorghum starch.
6. one according to claim 1, based on esterification class-pasted starch and the amyloid novel starch matter of non-gelatinization cigarette glue, is characterized in that: sanitas select in following kind any one or multiple: phenylformic acid and its esters, potassium sorbate, Sodium dehydroacetate, calcium propionate, sodium Diacetate, Sodium.alpha.-hydroxypropionate, nisin, tennecetin.
7. one according to claim 1, based on esterification class-pasted starch and the amyloid novel starch matter of non-gelatinization cigarette glue, is characterized in that: described defoamer select in following kind any one or multiple: ester class, mineral oil and the compound defoamers such as polyethers, Tweens, Tripolyglycerol monostearates such as the alcohols such as propylene glycol, dimethyl-silicon wet goods are polysiloxane-based, polypropylene glycerol aether.
8. one according to claim 1, based on esterification class-pasted starch and the amyloid novel starch matter of non-gelatinization cigarette glue, is characterized in that: described functional agent select in following kind any one or multiple: glyceryl monostearate, CSL sodium; The polyalcohols such as glycerine, sorbyl alcohol; The carbohydrates such as sucrose; Some mineral substance classes such as wilkinite, silicon-dioxide; Some vegetable jelly such as bean gum, gelatine, gelatin class.
9. one according to claim 1 is based on esterification class-pasted starch and the amyloid novel starch matter of non-gelatinization cigarette glue, it is characterized in that: the solid content of described starchiness cigarette glue is about 15%-65%, pH value is about 3-9 and preferred 5-8, and viscosity is about 100cps-20000cps.
CN201210400078.3A 2012-10-20 2012-10-20 A kind of based on esterification class-pasted starch and the amyloid starchiness cigarette glue of non-gelatinization Active CN103773273B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110003817A (en) * 2019-02-25 2019-07-12 朱东洋 A kind of starch type cigarette glue and preparation method thereof
CN114108384A (en) * 2021-11-19 2022-03-01 青岛嘉泽包装有限公司 Processing and production method for composite laser aluminum foil lining paper

Citations (2)

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Publication number Priority date Publication date Assignee Title
CN101962518A (en) * 2010-02-03 2011-02-02 内蒙古奈伦农业科技股份有限公司 Starch bonding agent, and preparation method and use thereof
CN102031075A (en) * 2009-09-27 2011-04-27 曲靖宏程工贸有限公司 Environmentally-friendly energy-saving cigarette adhesive and production method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102031075A (en) * 2009-09-27 2011-04-27 曲靖宏程工贸有限公司 Environmentally-friendly energy-saving cigarette adhesive and production method thereof
CN101962518A (en) * 2010-02-03 2011-02-02 内蒙古奈伦农业科技股份有限公司 Starch bonding agent, and preparation method and use thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110003817A (en) * 2019-02-25 2019-07-12 朱东洋 A kind of starch type cigarette glue and preparation method thereof
CN114108384A (en) * 2021-11-19 2022-03-01 青岛嘉泽包装有限公司 Processing and production method for composite laser aluminum foil lining paper
CN114108384B (en) * 2021-11-19 2023-03-24 青岛嘉泽包装有限公司 Processing and production method for composite laser aluminum foil lining paper

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