CN105907332A - A cigarette mouth building adhesive based on Chinese date polysaccharide-soybean protein modified starch and a preparing method thereof - Google Patents

A cigarette mouth building adhesive based on Chinese date polysaccharide-soybean protein modified starch and a preparing method thereof Download PDF

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Publication number
CN105907332A
CN105907332A CN201610242214.9A CN201610242214A CN105907332A CN 105907332 A CN105907332 A CN 105907332A CN 201610242214 A CN201610242214 A CN 201610242214A CN 105907332 A CN105907332 A CN 105907332A
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CN
China
Prior art keywords
weight
soybean protein
adhesive
red jujube
building adhesive
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610242214.9A
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Chinese (zh)
Inventor
李勇
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Chuzhou City Guang Wei Chemical Co Ltd
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Chuzhou City Guang Wei Chemical Co Ltd
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Publication date
Application filed by Chuzhou City Guang Wei Chemical Co Ltd filed Critical Chuzhou City Guang Wei Chemical Co Ltd
Priority to CN201610242214.9A priority Critical patent/CN105907332A/en
Publication of CN105907332A publication Critical patent/CN105907332A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J103/00Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
    • C09J103/02Starch; Degradation products thereof, e.g. dextrin
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

A cigarette mouth building adhesive based on Chinese date polysaccharide-soybean protein modified starch is disclosed. The adhesive is prepared from 30-40 parts by weight of cassava starch, 1-2 parts by weight of fresh ginger powder, 0.3-0.5 part by weight of licorice, 0.3-0.5 part by weight of hawthorn fruit, 0.3-0.5 part by weight of sodium polyacrylate, 0.3-0.5 part by weight of Chinese date polysaccharides, 3-5 parts by weight of soybean protein, 0.5-1 part by weight of fructose, 0.05-0.1 part by weight of papain, 1-2 parts by weight of borax, 3-5 parts by weight of glycerol, 0.3-0.5 part by weight of xanthan gum, 0.1-0.2 part by weight of glucono delta-lactone and 0.3-0.5 part by weight of potassium bitartrate. The adhesive has good adhesive performance, rheological performance and stability, is suitable for high-speed cigarette making machines, is capable of increasing a flavor of alcohol fragrance and sweetness to cigarettes, improving taste of the cigarettes, and reducing harm of harmful components in the cigarettes to human bodies, and is high in using value and high in practicability.

Description

A kind of red jujube polysaccharide - Soybean Protein Modification starch base cigarette mouth building adhesive and preparation method thereof
Technical field
The present invention relates to cigarette material technical field, particularly relate to a kind of red jujube polysaccharide-Soybean Protein Modification starch base cigarette mouth building adhesive and preparation method thereof.
Background technology
Adhesive is one of raw and auxiliary material important in production of cigarettes manufacture process, all refers to adhesive in a lot of production of cigarettes operations, mainly includes overlapping glue, spigot joint glue, filter stick centre-line glue, packaging glue and aluminum foil composite glue etc..At present, using most common cigarette glue stick is polyvinyl acetate emulsion class adhesive, and it possesses the adhesive property of excellence, rheological property etc., it is possible to adapts to the requirement of high-speed cigarette machine, meets the needs of large-scale production.But the special odor that the residual monomer of synthetic latex and plasticizer etc. have can bring certain impact to Sensory Quality of Cigarette, and affects the biological safety of cigarette product simultaneously.
Starchiness adhesive belongs to natural class adhesive, has environmental protection, cheap, the advantage of wide material sources, has had been subjected to increasing concern as cigarette glue stick.But, the most a lot of starchiness adhesive bonds performance, mobile performance and rate of drying are the most undesirable, the problem such as when there is production, speed is low, viscosity is poor, glue poor stability, it is difficult to adapt to the demand that high-speed cigarette machine mass rapid produces.Simultaneously, owing to overlapping glue stick directly participates in the burning of cigarette, the suction taste of Medicated cigarette can be produced impact, therefore, for making starchiness cigarette mouth building adhesive obtain widely promotion and application, it is necessary to improve its viscosity, mobility and stability, reduces the negative effect to cigarette odor-absorbing simultaneously, promote suction comfortableness.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of gumminess is good, stability is high, be suitable for high-speed cigarette machine uses, and red jujube polysaccharide-Soybean Protein Modification starch base cigarette mouth building adhesive that cigarette odor-absorbing can be improved and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of red jujube polysaccharide-Soybean Protein Modification starch base cigarette mouth building adhesive, it is to be prepared by the raw material of following weight parts:
Tapioca 30-40, Rhizoma Zingiberis Recens powder 1-2, Radix Glycyrrhizae 0.3-0.5, Fructus Crataegi 0.3-0.5, sodium polyacrylate 0.3-0.5, red jujube polysaccharide 0.3-0.5, soybean protein 3-5, fructose 0.5-1, papain 0.05-0.1, Borax 1-2, glycerol 3-5, xanthan gum 0.3-0.5, glucono-δ-lactone 0.1-0.2, potassium hydrogen tartrate 0.3-0.5.
The preparation method of a kind of red jujube polysaccharide-Soybean Protein Modification starch base cigarette mouth building adhesive, comprises the following steps:
(1) raw material is weighed by weight, by Radix Glycyrrhizae, Fructus Crataegi grind into powder and mix with Rhizoma Zingiberis Recens powder, tapioca, mix homogeneously with the sodium hydroxide solution of 3-5% by solid-liquid weight ratio 1:1-1:1.5, it is subsequently adding sodium polyacrylate, xanthan gum 60-70 DEG C stirring 20-30min, after cooling, obtains modified tapioca starch;
(2) soybean protein is added to the water by solid-liquid weight ratio 1:6-1:8 stirs, it is subsequently adding papain prior to 40-50 DEG C of stirring 1-2h, add red jujube polysaccharide and stir 5-10min in 90-95 DEG C, be subsequently adding fructose, glycerol stirs 1-2h in 70-80 DEG C, obtains compound protein modifying agent after cooling;
(3) after being mixed with the compound protein modifying agent in (2) by the modified tapioca starch in (1), 50-70 DEG C of stirring 0.5-1h, adds remaining raw material mix homogeneously, obtains red jujube polysaccharide-Soybean Protein Modification starch base cigarette mouth building adhesive after cooling.
The invention have the advantage that
The present invention is utilized respectively red jujube polysaccharide, the soybean protein of fructose and papain partial hydrolysis carries out Maillard reaction makes sugar obtain sugar-albumen composition with albumen grafting, sodium polyacrylate and alkali is utilized to carry out tapioca mixed and modified obtaining modified starch, then both are mixed, under the assosting effect of the raw material such as sodium polyacrylate, Borax, sugar-can form firm network structure between albumen composition and modified starch, is therefore effectively improved adhesion strength and the stability of adhesive;And owing to Maillard reaction produces certain flavor substance, effect of Medicated cigarette flavouring can be played, promote the smoking quality of Medicated cigarette;Simultaneously, utilize Rhizoma Zingiberis Recens powder, Radix Glycyrrhizae, the interpolation of Fructus Crataegi isoreactivity composition and compound, the cigarette mouth building adhesive obtained is made not only to have good glueability and rheological property, good stability, it is applicable to high-speed cigarette machine, moreover it is possible to increase, for Medicated cigarette, the local flavor that sweet-smelling is sweet, improves cigarette odor-absorbing the harmful components harm to human body alleviating in Medicated cigarette, use value is high, practical.
Detailed description of the invention
A kind of red jujube polysaccharide-Soybean Protein Modification starch base cigarette mouth building adhesive, it is to be prepared by the raw material of following weight parts:
Tapioca 30, Rhizoma Zingiberis Recens powder 1, Radix Glycyrrhizae 0.3, Fructus Crataegi 0.3, sodium polyacrylate 0.3, red jujube polysaccharide 0.3, soybean protein 3, fructose 0.5, papain 0.05, Borax 1, glycerol 3, xanthan gum 0.3, glucono-δ-lactone 0.1, potassium hydrogen tartrate 0.3.
The preparation method of a kind of red jujube polysaccharide-Soybean Protein Modification starch base cigarette mouth building adhesive, comprises the following steps:
(1) raw material is weighed by weight, by Radix Glycyrrhizae, Fructus Crataegi grind into powder and mix with Rhizoma Zingiberis Recens powder, tapioca, by solid-liquid weight ratio 1:1 and the sodium hydroxide solution mix homogeneously of 3%, it is subsequently adding sodium polyacrylate, xanthan gum 60 DEG C stirring 20min, after cooling, obtains modified tapioca starch;
(2) soybean protein is added to the water by solid-liquid weight ratio 1:6 stirs, it is subsequently adding papain prior to 40 DEG C of stirring 1h, add red jujube polysaccharide in 90 DEG C stir 5min, be subsequently adding fructose, glycerol in 70 DEG C stir 1h, after cooling compound protein modifying agent;
(3) modified tapioca starch in (1) is mixed rear 50 DEG C of stirring 0.5h with the compound protein modifying agent in (2), add remaining raw material mix homogeneously after cooling, obtain red jujube polysaccharide-Soybean Protein Modification starch base cigarette mouth building adhesive.
Above-mentioned prepared cigarette mouth building adhesive has good viscosity and mobility, at normal temperatures, can keep stable within three months.Under the conditions of the cigarette machine of speed of operation 10000/minute uses, equipment normal operation, steadily, it is firmly neat that the even patch of mouth taken by the cigarette sample rolled, and does not has alice phenomenon.Obtained cigarette sample sensory evaluating smoking's result is better than common overlapping glue cigarette sample.

Claims (2)

1. red jujube polysaccharide-Soybean Protein Modification starch base cigarette mouth building adhesive, it is characterised in that it is to be prepared by the raw material of following weight parts:
Tapioca 30-40, Rhizoma Zingiberis Recens powder 1-2, Radix Glycyrrhizae 0.3-0.5, Fructus Crataegi 0.3-0.5, sodium polyacrylate 0.3-0.5, red jujube polysaccharide 0.3-0.5, soybean protein 3-5, fructose 0.5-1, papain 0.05-0.1, Borax 1-2, glycerol 3-5, xanthan gum 0.3-0.5, glucono-δ-lactone 0.1-0.2, potassium hydrogen tartrate 0.3-0.5.
The preparation method of a kind of red jujube polysaccharide the most according to claim 1-Soybean Protein Modification starch base cigarette mouth building adhesive, it is characterised in that comprise the following steps:
(1) raw material is weighed by weight, by Radix Glycyrrhizae, Fructus Crataegi grind into powder and mix with Rhizoma Zingiberis Recens powder, tapioca, mix homogeneously with the sodium hydroxide solution of 3-5% by solid-liquid weight ratio 1:1-1:1.5, it is subsequently adding sodium polyacrylate, xanthan gum 60-70 DEG C stirring 20-30min, after cooling, obtains modified tapioca starch;
(2) soybean protein is added to the water by solid-liquid weight ratio 1:6-1:8 stirs, it is subsequently adding papain prior to 40-50 DEG C of stirring 1-2h, add red jujube polysaccharide and stir 5-10min in 90-95 DEG C, be subsequently adding fructose, glycerol stirs 1-2h in 70-80 DEG C, obtains compound protein modifying agent after cooling;
(3) after being mixed with the compound protein modifying agent in (2) by the modified tapioca starch in (1), 50-70 DEG C of stirring 0.5-1h, adds remaining raw material mix homogeneously, obtains red jujube polysaccharide-Soybean Protein Modification starch base cigarette mouth building adhesive after cooling.
CN201610242214.9A 2016-04-19 2016-04-19 A cigarette mouth building adhesive based on Chinese date polysaccharide-soybean protein modified starch and a preparing method thereof Pending CN105907332A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610242214.9A CN105907332A (en) 2016-04-19 2016-04-19 A cigarette mouth building adhesive based on Chinese date polysaccharide-soybean protein modified starch and a preparing method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610242214.9A CN105907332A (en) 2016-04-19 2016-04-19 A cigarette mouth building adhesive based on Chinese date polysaccharide-soybean protein modified starch and a preparing method thereof

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CN105907332A true CN105907332A (en) 2016-08-31

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101629019A (en) * 2009-01-21 2010-01-20 郑州佰沃生物质材料有限公司 Basic biomass synthetic resin and preparation method and application thereof
CN103773276A (en) * 2014-01-16 2014-05-07 常州大学 Preparation method for environment-friendly starch cigarette adhesive
CN103773269A (en) * 2012-10-20 2014-05-07 中国烟草总公司郑州烟草研究院 Novel amyloid cigarette adhesive containing synthetic polymer
CN103865645A (en) * 2012-12-11 2014-06-18 爱普香料集团股份有限公司 Preparation method of fruit concentrate Maillard reaction product, and application of product in tobacco perfuming

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101629019A (en) * 2009-01-21 2010-01-20 郑州佰沃生物质材料有限公司 Basic biomass synthetic resin and preparation method and application thereof
CN103773269A (en) * 2012-10-20 2014-05-07 中国烟草总公司郑州烟草研究院 Novel amyloid cigarette adhesive containing synthetic polymer
CN103865645A (en) * 2012-12-11 2014-06-18 爱普香料集团股份有限公司 Preparation method of fruit concentrate Maillard reaction product, and application of product in tobacco perfuming
CN103773276A (en) * 2014-01-16 2014-05-07 常州大学 Preparation method for environment-friendly starch cigarette adhesive

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
曾晓鹰 等: "《卷烟调香体系构建 以云烟品牌为例》", 28 February 2013, 西南交通大学出版社 *

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Application publication date: 20160831