CN105802536A - High-toughness and waterproof modified starch-base cigarette lapping adhesive and preparing method thereof - Google Patents
High-toughness and waterproof modified starch-base cigarette lapping adhesive and preparing method thereof Download PDFInfo
- Publication number
- CN105802536A CN105802536A CN201610242184.1A CN201610242184A CN105802536A CN 105802536 A CN105802536 A CN 105802536A CN 201610242184 A CN201610242184 A CN 201610242184A CN 105802536 A CN105802536 A CN 105802536A
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- Prior art keywords
- cigarette
- adhesive
- modified starch
- toughness
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09J103/02—Starch; Degradation products thereof, e.g. dextrin
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Manufacturing Of Cigar And Cigarette Tobacco (AREA)
Abstract
The invention discloses a high-toughness and waterproof modified starch-base cigarette lapping adhesive. The high-toughness and waterproof modified starch-base cigarette lapping adhesive is prepared from, by weight, 30-40 parts of cassava starch, 0.2-0.4 part of soybean phospholipid, 0.1-0.2 part of beewax, 0.5-1 part of sodium polyacrylate, 3-5 parts of corn protein, 0.5-1 part of fructose, 0.3-0.5 part of bamboo leaf polysaccharide, 0.05-0.1 part of papain, 0.5-1 part of ethylene diamine tetraacetic acid, 1-2 parts of borax, 3-5 parts of glycerol and 1-2 parts of silica sol of 20%-30%. The cigarette lapping adhesive has good adhesive performance and rheological performance, and is good in stability and suitable for a high-speed cigarette making machine, the sapor of cigarette can be improved, injuries of injurious ingredients in cigarettes to the human body are reduced, and the cigarette lapping adhesive has the advantages of being high in toughness, durability and water resistance, and is high in use value and practicability.
Description
Technical field
The present invention relates to cigarette material technical field, particularly relate to a kind of high tenacity water-fast modified starch base cigarette mouth building adhesive and preparation method thereof.
Background technology
Adhesive is one of raw and auxiliary material important in production of cigarettes manufacture process, all refers to adhesive in a lot of production of cigarettes operations, mainly includes overlapping glue, spigot joint glue, filter stick centre-line glue, packaging glue and aluminum foil composite glue etc..At present, using most common cigarette glue stick is polyvinyl acetate emulsion class adhesive, and it possesses the adhesive property of excellence, rheological property etc., it is possible to adapts to the requirement of high-speed cigarette machine, meets the needs of large-scale production.But the special odor that the residual monomer of synthetic latex and plasticizer etc. have can bring certain impact to Sensory Quality of Cigarette, and affects the biological safety of cigarette product simultaneously.
Starchiness adhesive belongs to natural class adhesive, has environmental protection, cheap, the advantage of wide material sources, has had been subjected to increasing concern as cigarette glue stick.But, the most a lot of starchiness adhesive bonds performance, mobile performance and rate of drying are the most undesirable, the problem such as when there is production, speed is low, viscosity is poor, glue poor stability, it is difficult to adapt to the demand that high-speed cigarette machine mass rapid produces.Simultaneously, owing to overlapping glue stick directly participates in the burning of cigarette, the suction taste of Medicated cigarette can be produced impact, therefore, for making starchiness cigarette mouth building adhesive obtain widely promotion and application, it is necessary to improve its viscosity, mobility and stability, reduces the negative effect to cigarette odor-absorbing simultaneously, promote suction comfortableness.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of gumminess is good, stability is high, be suitable for high-speed cigarette machine uses, and the high tenacity water-fast modified starch base cigarette mouth building adhesive that cigarette odor-absorbing can be improved and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of high tenacity water-fast modified starch base cigarette mouth building adhesive, it is to be prepared by the raw material of following weight parts:
Tapioca 30-40, soybean phospholipid 0.2-0.4, Cera Flava 0.1-0.2, sodium polyacrylate 0.5-1, zein 3-5, fructose 0.5-1, Polysaccharides in Bamboo Leaves 0.3-0.5, papain 0.05-0.1, disodiumedetate 0.5-1, Borax 1-2, glycerol 3-5,20-30% Ludox 1-2.
The preparation method of a kind of high tenacity is water-fast modified starch base cigarette mouth building adhesive, comprises the following steps:
(1) weigh raw material by weight, first tapioca is pressed solid-liquid weight ratio 1:1-1:1.5 and mixs homogeneously with the sodium hydroxide solution of 3-5%, be subsequently adding sodium polyacrylate, soybean phospholipid, 60-70 DEG C of Cera Flava stirring 20-30min, after cooling, obtain modified tapioca starch；
(2) zein is added to the water by solid-liquid weight ratio 1:6-1:8 stirs, it is subsequently adding papain prior to 40-50 DEG C of stirring 1-2h, add Polysaccharides in Bamboo Leaves and stir 5-10min in 90-95 DEG C, be subsequently adding fructose, glycerol stirs 1-2h in 70-80 DEG C, obtains compound protein modifying agent after cooling；
(3) after being mixed with the compound protein modifying agent in (2) by the modified tapioca starch in (1), 50-70 DEG C of stirring 0.5-1h, adds remaining raw material mix homogeneously, obtains high tenacity water-fast modified starch base cigarette mouth building adhesive after cooling.
The invention have the advantage that
The present invention is utilized respectively Polysaccharides in Bamboo Leaves, the zein of fructose and papain partial hydrolysis carries out Maillard reaction makes sugar obtain sugar-albumen composition with albumen grafting, sodium polyacrylate and alkali is utilized to carry out tapioca mixed and modified obtaining modified starch, then both are mixed, under the assosting effect of the raw material such as sodium polyacrylate, Borax, sugar-can form firm network structure between albumen composition and modified starch, is therefore effectively improved adhesion strength and the stability of adhesive；And owing to Maillard reaction produces certain flavor substance, effect of Medicated cigarette flavouring can be played, promote the smoking quality of Medicated cigarette；Simultaneously, remaining raw material is utilized to add with compounding, the cigarette mouth building adhesive obtained is made not only to have good glueability and rheological property, good stability, be applicable to high-speed cigarette machine, and cigarette odor-absorbing can be improved, the harm to human body of the harmful components that alleviate in Medicated cigarette, the feature that also high tenacity, durability and water resistance are good, use value is high, practical.
Detailed description of the invention
A kind of high tenacity water-fast modified starch base cigarette mouth building adhesive, it is to be prepared by the raw material of following weight parts:
Tapioca 30, soybean phospholipid 0.2, Cera Flava 0.1, sodium polyacrylate 0.5, zein 3, fructose 0.5, Polysaccharides in Bamboo Leaves 0.3, papain 0.05, disodiumedetate 0.5, Borax 1, glycerol 3,20% Ludox 1.
The preparation method of a kind of high tenacity is water-fast modified starch base cigarette mouth building adhesive, comprises the following steps:
(1) weigh raw material by weight, first tapioca is pressed the sodium hydroxide solution mix homogeneously of solid-liquid weight ratio 1:1 and 3%, be subsequently adding sodium polyacrylate, soybean phospholipid, 60 DEG C of Cera Flava stirring 20min, after cooling, obtain modified tapioca starch；
(2) zein is added to the water by solid-liquid weight ratio 1:6 stirs, it is subsequently adding papain prior to 40 DEG C of stirring 1h, add Polysaccharides in Bamboo Leaves in 90 DEG C stir 5min, be subsequently adding fructose, glycerol in 70 DEG C stir 1h, after cooling compound protein modifying agent；
(3) modified tapioca starch in (1) is mixed rear 50 DEG C of stirring 0.5h with the compound protein modifying agent in (2), add remaining raw material mix homogeneously after cooling, obtain high tenacity water-fast modified starch base cigarette mouth building adhesive.
Above-mentioned prepared cigarette mouth building adhesive has good viscosity and mobility, at normal temperatures, can keep stable within three months.Under the conditions of the cigarette machine of speed of operation 10000/minute uses, equipment normal operation, steadily, it is firmly neat that the even patch of mouth taken by the cigarette sample rolled, and does not has alice phenomenon.Obtained cigarette sample sensory evaluating smoking's result is better than common overlapping glue cigarette sample.
Claims (2)
1. a high tenacity water-fast modified starch base cigarette mouth building adhesive, it is characterised in that it is to be prepared by the raw material of following weight parts:
Tapioca 30-40, soybean phospholipid 0.2-0.4, Cera Flava 0.1-0.2, sodium polyacrylate 0.5-1, zein 3-5, fructose 0.5-1, Polysaccharides in Bamboo Leaves 0.3-0.5, papain 0.05-0.1, disodiumedetate 0.5-1, Borax 1-2, glycerol 3-5,20-30% Ludox 1-2.
The preparation method of a kind of high tenacity the most according to claim 1 water-fast modified starch base cigarette mouth building adhesive, it is characterised in that comprise the following steps:
(1) weigh raw material by weight, first tapioca is pressed solid-liquid weight ratio 1:1-1:1.5 and mixs homogeneously with the sodium hydroxide solution of 3-5%, be subsequently adding sodium polyacrylate, soybean phospholipid, 60-70 DEG C of Cera Flava stirring 20-30min, after cooling, obtain modified tapioca starch；
(2) zein is added to the water by solid-liquid weight ratio 1:6-1:8 stirs, it is subsequently adding papain prior to 40-50 DEG C of stirring 1-2h, add Polysaccharides in Bamboo Leaves and stir 5-10min in 90-95 DEG C, be subsequently adding fructose, glycerol stirs 1-2h in 70-80 DEG C, obtains compound protein modifying agent after cooling；
(3) after being mixed with the compound protein modifying agent in (2) by the modified tapioca starch in (1), 50-70 DEG C of stirring 0.5-1h, adds remaining raw material mix homogeneously, obtains high tenacity water-fast modified starch base cigarette mouth building adhesive after cooling.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610242184.1A CN105802536A (en) | 2016-04-19 | 2016-04-19 | High-toughness and waterproof modified starch-base cigarette lapping adhesive and preparing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610242184.1A CN105802536A (en) | 2016-04-19 | 2016-04-19 | High-toughness and waterproof modified starch-base cigarette lapping adhesive and preparing method thereof |
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| Publication Number | Publication Date |
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| CN105802536A true CN105802536A (en) | 2016-07-27 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610242184.1A Pending CN105802536A (en) | 2016-04-19 | 2016-04-19 | High-toughness and waterproof modified starch-base cigarette lapping adhesive and preparing method thereof |
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| CN (1) | CN105802536A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106520014A (en) * | 2016-10-31 | 2017-03-22 | 南宁珀源能源材料有限公司 | Starch anaerobic glue having good storage stability and preparation method thereof |
| CN112480844A (en) * | 2020-11-26 | 2021-03-12 | 四川轻化工大学 | Preparation method of mildew-proof wallpaper adhesive and product thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103773276A (en) * | 2014-01-16 | 2014-05-07 | 常州大学 | Preparation method for environment-friendly starch cigarette adhesive |
| CN103865645A (en) * | 2012-12-11 | 2014-06-18 | 爱普香料集团股份有限公司 | Preparation method of fruit concentrate Maillard reaction product, and application of product in tobacco perfuming |
-
2016
- 2016-04-19 CN CN201610242184.1A patent/CN105802536A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103865645A (en) * | 2012-12-11 | 2014-06-18 | 爱普香料集团股份有限公司 | Preparation method of fruit concentrate Maillard reaction product, and application of product in tobacco perfuming |
| CN103773276A (en) * | 2014-01-16 | 2014-05-07 | 常州大学 | Preparation method for environment-friendly starch cigarette adhesive |
Non-Patent Citations (1)
| Title |
|---|
| 詹益兴: "《绿色精细化工 天然产品制造法 第2集》", 30 July 2006, 科学技术文献出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106520014A (en) * | 2016-10-31 | 2017-03-22 | 南宁珀源能源材料有限公司 | Starch anaerobic glue having good storage stability and preparation method thereof |
| CN106520014B (en) * | 2016-10-31 | 2018-05-29 | 南宁珀源能源材料有限公司 | Good starch anaerobic adhesive of storage stability and preparation method thereof |
| CN112480844A (en) * | 2020-11-26 | 2021-03-12 | 四川轻化工大学 | Preparation method of mildew-proof wallpaper adhesive and product thereof |
| CN112480844B (en) * | 2020-11-26 | 2022-06-17 | 四川轻化工大学 | Preparation method of mildew-proof wallpaper adhesive and product thereof |
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Application publication date: 20160727 |