CN103756302B - 一种尼龙垫圈用纳米荧光材料组合物料 - Google Patents

一种尼龙垫圈用纳米荧光材料组合物料 Download PDF

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CN103756302B
CN103756302B CN201310713421.4A CN201310713421A CN103756302B CN 103756302 B CN103756302 B CN 103756302B CN 201310713421 A CN201310713421 A CN 201310713421A CN 103756302 B CN103756302 B CN 103756302B
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钱胜利
凌巧
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ANHUI MENGLING PRECISION ELECTRONIC Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
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    • B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/92—Measuring, controlling or regulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
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    • B29C2948/92704—Temperature
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08K2201/011—Nanostructured additives
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

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Abstract

本发明公开了一种尼龙垫圈用纳米荧光材料组合物料，其是由下述重量份的原料制得：尼龙PA12 520-550、YAG荧光粉2-3、N-甲基吡咯烷酮1-2、茂金属聚乙烯14-18、十溴二苯醚4-6、正硅酸乙酯0.3-0.6、滑石粉16-19、偏硼酸钡5-6、纳米三氧化二铝1-2、助剂8-10、白油膏1-2。

Description

一种尼龙垫圈用纳米荧光材料组合物料
技术领域
本发明涉及尼龙材料领域，确切地说是一种尼龙垫圈用纳米荧光材料组合物料。
背景技术
尼龙是合成树脂的同义语，是以高分子物质为主原料，经过人工方式加工成有用的形状的固体,但不包括纤维、橡胶、涂料和粘结剂等。可以说塑料具备以下3个条件：在素材上是高分子物质，其形状经过人工加工后形成了有用的形状，在常态下是固体。顾名思义，尼龙垫圈是由尼龙制成的，在国内，尼龙垫圈通常也被称作尼龙华司（Washers），树脂垫圈，塑胶垫圈或尼龙垫圈（国内市场最常见的塑料垫圈大多是用尼龙66制成的）。
尼龙垫圈具备优异的绝缘性能，无磁性，隔热，重量轻，个别材料的塑料垫圈还具备耐高温，高强度，耐腐蚀性能，部分产品具备防落功能，广泛应用于各工业领域。
发明内容
本发明的目的在于提供一种尼龙垫圈用纳米荧光材料组合物料。
上述目的通过以下方案实现：
一种尼龙垫圈用纳米荧光材料组合物料，其特征在于：其是由下述重量份的原料制得：尼龙PA12520-550、YAG荧光粉2-3、N-甲基吡咯烷酮1-2、茂金属聚乙烯14-18、十溴二苯醚4-6、正硅酸乙酯0.3-0.6、滑石粉16-19、偏硼酸钡5-6、纳米三氧化二铝1-2、助剂8-10、白油膏1-2;
所述的助剂由下列重量份的原料制成：硅藻土15-10，高岭土10-15，氧化锌1-2、硅灰石粉20-30、氢氧化镁10-12、钛白粉1-2、二甲基硅油1-2，硅烷偶联剂KH5601-3、二氧化硅2-3、抗氧剂10101-2、无卤无碱玻纤1-2、三聚氰胺2-4、脂肪酸1-2；
所述的助剂的制备方法是将硅藻土、高岭土、硅灰石粉放入煅烧炉中在700-750℃下煅烧3-4小时，取出，放入10-15%的氢氧化钠溶液中浸泡3-6小时，过滤后，去离子水洗涤3-4次，烘干，加入水中，再加入氢氧化镁、二氧化硅、硅烷偶联剂KH560、脂肪酸，研磨得到浆料，喷雾干燥得干燥粉末，再与剩余原料混合均匀即得。
所述的一种尼龙垫圈用纳米荧光材料组合物料，其特征在于：制备方法为：将尼龙PA12、YAG荧光粉、助剂、纳米三氧化二铝混合均匀后，再加入其余原料混合均匀，在双螺杆挤出机上熔融挤出造粒后即得，挤出机的各区间温度为220-225℃，挤出机转速230-240r/min。
本发明的有益效果为：本发明添加纳米三氧化二铝，相容性好，拉伸强度高，使用YAG荧光粉，可以使本发明具有荧光效应，适合一些特殊场合使用。
具体实施方式
一种尼龙垫圈用纳米荧光材料组合物料，其是由下述重量kg的原料制得：尼龙PA12550、YAG荧光粉3、N-甲基吡咯烷酮2、茂金属聚乙烯18、十溴二苯醚6、正硅酸乙酯0.6、滑石粉19、偏硼酸钡6、纳米三氧化二铝2、助剂8、白油膏2;
所述的助剂由下列重量kg的原料制成：硅藻土10，高岭土15，氧化锌2、硅灰石粉20、氢氧化镁12、钛白粉2、二甲基硅油1，硅烷偶联剂KH5603、二氧化硅3、抗氧剂10102、无卤无碱玻纤2、三聚氰胺4、脂肪酸2；
所述的助剂的制备方法是将硅藻土、高岭土、硅灰石粉放入煅烧炉中在750℃下煅烧4小时，取出，放入15%的氢氧化钠溶液中浸泡6小时，过滤后，去离子水洗涤4次，烘干，加入水中，再加入氢氧化镁、二氧化硅、硅烷偶联剂KH560、脂肪酸，研磨得到浆料，喷雾干燥得干燥粉末，再与剩余原料混合均匀即得。
所述的一种尼龙垫圈用纳米荧光材料组合物料，制备方法为：将尼龙PA12、YAG荧光粉、助剂、纳米三氧化二铝混合均匀后，再加入其余原料混合均匀，在双螺杆挤出机上熔融挤出造粒后即得，挤出机的各区间温度为220-225℃，挤出机转速240r/min。
本实施例制得的尼龙垫圈的性能检测：

Claims (2)

1.一种尼龙垫圈用纳米荧光材料组合物料，其特征在于：其是由下述重量份的原料制得：尼龙PA12  520-550、YAG荧光粉2-3、N-甲基吡咯烷酮1-2、茂金属聚乙烯14-18、十溴二苯醚4-6、正硅酸乙酯0.3-0.6、滑石粉16-19、偏硼酸钡5-6、纳米三氧化二铝1-2、助剂8-10、白油膏1-2 ;
所述的助剂由下列重量份的原料制成：硅藻土15-10，高岭土10-15，氧化锌1-2、硅灰石粉20-30、氢氧化镁10-12、钛白粉1-2、二甲基硅油1-2，硅烷偶联剂KH560  1-3、二氧化硅 2-3、抗氧剂1010  1-2、无卤无碱玻纤1-2、三聚氰胺2-4、脂肪酸1-2；
所述的助剂的制备方法是将硅藻土、高岭土、硅灰石粉放入煅烧炉中在700-750℃下煅烧3-4小时，取出，放入10-15%的氢氧化钠溶液中浸泡3-6小时，过滤后，去离子水洗涤3-4次，烘干，加入水中，再加入氢氧化镁、二氧化硅 、硅烷偶联剂KH560、脂肪酸，研磨得到浆料，喷雾干燥得干燥粉末，再与剩余原料混合均匀即得。
2.根据权利要求1所述的一种尼龙垫圈用纳米荧光材料组合物料，其特征在于：制备方法为：将尼龙PA12、YAG荧光粉、助剂、纳米三氧化二铝混合均匀后，再加入其余原料混合均匀，在双螺杆挤出机上熔融挤出造粒后即得，挤出机的各区间温度为220-225℃，挤出机转速230-240r/min。
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CN106947243A (zh) * 2017-03-24 2017-07-14 合肥羿振电力设备有限公司 一种灯具外壳及其制备方法
CN109251516A (zh) * 2017-07-10 2019-01-22 合肥杰事杰新材料股份有限公司 一种车用尼龙荧光内饰条材料及其制备方法

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* Cited by examiner, † Cited by third party
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EP2660268A1 (en) * 2010-12-28 2013-11-06 Shanghai Genius Advanced Material (Group) Co. Ltd Nano particle/polyamide composite material, preparation method therefor, and use thereof
CN102690438A (zh) * 2012-06-14 2012-09-26 东华大学 聚合物基荧光功能复合材料及其熔融加工方法
CN102731997A (zh) * 2012-06-15 2012-10-17 苏州宇度医疗器械有限责任公司 阻燃的碳化硅填充的尼龙6和聚乙烯合金复合材料
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