CN103749462B - Containing pyrrole metsulfovax and antibiotic bactericidal composition - Google Patents
Containing pyrrole metsulfovax and antibiotic bactericidal composition Download PDFInfo
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- CN103749462B CN103749462B CN201410038784.7A CN201410038784A CN103749462B CN 103749462 B CN103749462 B CN 103749462B CN 201410038784 A CN201410038784 A CN 201410038784A CN 103749462 B CN103749462 B CN 103749462B
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- 239000000203 mixture Substances 0.000 title claims abstract description 51
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 title claims abstract description 48
- UDSJPFPDKCMYBD-UHFFFAOYSA-N Metsulfovax Chemical compound S1C(C)=NC(C)=C1C(=O)NC1=CC=CC=C1 UDSJPFPDKCMYBD-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 13
- 230000003115 biocidal effect Effects 0.000 title claims abstract description 6
- 241000221785 Erysiphales Species 0.000 claims abstract description 12
- 241000233679 Peronosporaceae Species 0.000 claims abstract description 6
- 238000005507 spraying Methods 0.000 claims abstract description 3
- 240000003768 Solanum lycopersicum Species 0.000 claims description 10
- 201000010099 disease Diseases 0.000 claims description 10
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims description 10
- 235000007688 Lycopersicon esculentum Nutrition 0.000 claims description 9
- 235000021307 Triticum Nutrition 0.000 claims description 9
- 206010039509 Scab Diseases 0.000 claims description 8
- 229930182764 Polyoxin Natural products 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- YEBIHIICWDDQOL-YBHNRIQQSA-N polyoxin Polymers O[C@@H]1[C@H](O)[C@@H](C(C=O)N)O[C@H]1N1C(=O)NC(=O)C(C(O)=O)=C1 YEBIHIICWDDQOL-YBHNRIQQSA-N 0.000 claims description 4
- 240000008067 Cucumis sativus Species 0.000 claims description 3
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 claims description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 3
- 241000233652 Chytridiomycota Species 0.000 claims description 2
- 244000241235 Citrullus lanatus Species 0.000 claims description 2
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 claims description 2
- 241000675108 Citrus tangerina Species 0.000 claims description 2
- 241000233866 Fungi Species 0.000 claims description 2
- 241000220225 Malus Species 0.000 claims description 2
- 235000011430 Malus pumila Nutrition 0.000 claims description 2
- 235000015103 Malus silvestris Nutrition 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims description 2
- 235000007164 Oryza sativa Nutrition 0.000 claims description 2
- 241000582441 Peronospora tabacina Species 0.000 claims description 2
- 241000220324 Pyrus Species 0.000 claims description 2
- 235000009754 Vitis X bourquina Nutrition 0.000 claims description 2
- 235000012333 Vitis X labruscana Nutrition 0.000 claims description 2
- 240000006365 Vitis vinifera Species 0.000 claims description 2
- 235000014787 Vitis vinifera Nutrition 0.000 claims description 2
- 241000607479 Yersinia pestis Species 0.000 claims description 2
- 235000021017 pears Nutrition 0.000 claims description 2
- 235000009566 rice Nutrition 0.000 claims description 2
- 244000098338 Triticum aestivum Species 0.000 claims 1
- 230000003449 preventive effect Effects 0.000 abstract description 15
- -1 alkene oxime amine Chemical class 0.000 abstract description 3
- 239000000839 emulsion Substances 0.000 abstract description 2
- 239000004530 micro-emulsion Substances 0.000 abstract description 2
- 239000000843 powder Substances 0.000 abstract description 2
- 239000000375 suspending agent Substances 0.000 abstract description 2
- 239000004562 water dispersible granule Substances 0.000 abstract description 2
- 238000009736 wetting Methods 0.000 abstract description 2
- 239000005784 Fluoxastrobin Substances 0.000 abstract 1
- 208000031888 Mycoses Diseases 0.000 abstract 1
- 239000005869 Pyraclostrobin Substances 0.000 abstract 1
- UFEODZBUAFNAEU-NLRVBDNBSA-N fluoxastrobin Chemical compound C=1C=CC=C(OC=2C(=C(OC=3C(=CC=CC=3)Cl)N=CN=2)F)C=1C(=N/OC)\C1=NOCCO1 UFEODZBUAFNAEU-NLRVBDNBSA-N 0.000 abstract 1
- HZRSNVGNWUDEFX-UHFFFAOYSA-N pyraclostrobin Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NN(C=2C=CC(Cl)=CC=2)C=C1 HZRSNVGNWUDEFX-UHFFFAOYSA-N 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 9
- 241000209140 Triticum Species 0.000 description 8
- 239000003814 drug Substances 0.000 description 7
- 239000002131 composite material Substances 0.000 description 5
- 230000002195 synergetic effect Effects 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 244000052769 pathogen Species 0.000 description 3
- 230000001717 pathogenic effect Effects 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 239000003899 bactericide agent Substances 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- 239000012452 mother liquor Substances 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 125000000168 pyrrolyl group Chemical group 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- AMNAZJFEONUVTD-KEWDHRJRSA-N (2s,3s,4s,5r,6r)-6-(4-amino-2-oxopyrimidin-1-yl)-4,5-dihydroxy-3-[[(2s)-3-hydroxy-2-[[2-(methylamino)acetyl]amino]propanoyl]amino]oxane-2-carboxamide Chemical compound O1[C@H](C(N)=O)[C@@H](NC(=O)[C@H](CO)NC(=O)CNC)[C@H](O)[C@@H](O)[C@@H]1N1C(=O)N=C(N)C=C1 AMNAZJFEONUVTD-KEWDHRJRSA-N 0.000 description 1
- FEACDOXQOYCHKU-UHFFFAOYSA-N Gougerotin Natural products CNCC(=O)NC1=NC(=O)N(C=C1)C2OC(C(O)C(NC(=O)C(N)CO)C2O)C(=O)N FEACDOXQOYCHKU-UHFFFAOYSA-N 0.000 description 1
- 241000221696 Sclerotinia sclerotiorum Species 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides a kind of containing pyrrole metsulfovax and antibiotic bactericidal composition and the purposes of preventing and treating agricultural fungal diseases thereof.Said composition mainly includes component A and B component two kinds of active components of effective amount, and component A is pyrrole metsulfovax, and B component is selected from the one in Fluoxastrobin, pyraclostrobin, ZEN 90160, alkene oxime amine etc.Make suspending agent, wetting powder, water dispersible granules, aqua, microemulsion or aqueous emulsion during present composition application, for spraying, fill with root, seed dressing, the preventive effect excellent to gray mold, downy mildew, powdery mildew tool.
Description
The application is the divisional application of patent of invention " bactericidal composition containing pyrrole metsulfovax ", and former number of patent application is 2013100910407, and the applying date is on March 20th, 2013.
Technical field
The present invention relates to containing pyrrole metsulfovax and antibiotic bactericidal composition, belong to plant protection art, relate to the bactericidal composition containing pyrrole metsulfovax, said composition is used for preventing and treating gray mold, powdery mildew, downy mildew, stalk break, rust disease, scab etc.
Background technology
Pyrrole metsulfovax is the new type bactericide of amide containing structure, to multiple kinds of crops disease there is excellent preventive effect, especially to gray mold, powdery mildew, downy mildew, there is very high effect.For Reasonable Protection medicament, delay germ to the drug-fast generation of new medicament and the control efficiency improving medicament, be necessary to carry out rational composition research.Had at present the complex preparation of pyrrole metsulfovax and other bactericide, the present invention found through experiments the good bactericidal composition containing pyrrole metsulfovax of other effectiveness comparison that prior art also do not find.These bactericidal compositions have unforeseeable technique effect.
Summary of the invention
The object of the present invention is to provide containing pyrrole metsulfovax and antibiotic bactericidal composition, it is undertaken composite by two kinds of different structures, but the effective way of expanding prevention spectrum and raising drug effect, the more important thing is and avoid or delay the generation of disease to new composition resistance.For realizing object of the present invention, inventor is composite with the compound with sterilization component by pyrrole metsulfovax, for preventing and treating the disease of crop.
The object of the invention is to be realized by following measures.
The invention provides a kind of bactericidal composition containing pyrrole metsulfovax, it is characterized in that said composition includes component A and B component two kinds of active components of effective amount, component A is pyrrole metsulfovax, and B component is selected from the one in jinggangmeisu, kasugarnycin, polyoxin, Ningnanmycin.
In above-mentioned composition, preferably, the ratio of quality and the number of copies of component A and B component is 1:40-40:1, and preferably, the ratio of quality and the number of copies of component A and B component is 10:1-1:20.
In above-mentioned composition of the present invention, preferably, B component is selected from the one in kasugarnycin, polyoxin.
In above-mentioned composition of the present invention, the quality sum of component A and B component accounts for the 1-90% of composition gross mass.
Above-mentioned composition of the present invention can be made into suspending agent, wetting powder, water dispersible granules, aqua, microemulsion or aqueous emulsion.
Present invention also offers above-mentioned composition for preventing and treating the method for crop pest, it is characterized in that composition to be applied to crop or crop part by spraying, filling root or seed dressing.。
The present invention also finds, above-mentioned composition is when respective active component uses total amount to reduce, and have excellent control efficiency to graw mold of tomato, cucumber downy mildew, wheat powdery mildew, synergistic effect is obvious.
Present invention also offers above-mentioned composition for preventing and treating the purposes of the various agricultural disease of crop, it is characterized in that described disease is the fungus-caused graw mold of tomato of Fungi Imperfecti, scab etc., the fungus-caused downy mildew of Mastigomycotina, late blight, peronospora tabacina etc., the fungus-caused powdery mildew of Ascomycotina, anthracnose, leaf spot etc., the rust that Basidiomycotina causes, smut etc.
In such use, described crop is preferably tomato, cucumber, wheat, paddy rice, watermelon, apple, grape, oranges and tangerines, pears, lichee or flowers etc.
Beneficial effect of the present invention is:
1, synergistic effect is obvious: composition shows good synergistic effect in certain ratio range, improves the protection effect of composition.
2, expanding prevention spectrum: composition can prevent and treat the multiple diseases in agricultural production.
3, use cost is reduced: because of composite, there is raising preventive effect, the increase of control spectrum, decrease access times, reduce use cost;
4, delay pesticide resistance: the composition of two kinds of different mechanism of action is composite, and pathogen not easily develops immunity to drugs, delay pathogen to the drug-fast generation of single dose.
Embodiment
Following examples further illustrate of the present invention, but the present invention is not confined to composition in present embodiment and purposes.
Embodiment 1 pyrrole metsulfovax composition is to the control efficiency of graw mold of tomato
Single compound or composition organic solvent dissolution are prepared into the mother liquor of 1000mg/L.According to biological activity determination trial test, a certain amount of above-mentioned mother liquor 0.1% Tween 80 is diluted, is mixed with the concentration of needs.During mensuration, first liquid medicine jet is imposed on potted tomato plant, then inoculate pathogen, moisturizing is placed in greenhouse and cultivates, measure the percentage that plant leaf surface infects after certain hour after cultivating 24h.Use Abbot formula, convert percentage to preventive effect.
The preventive effect of the active component A that x is working concentration when being a, the preventive effect of the active component B that y is working concentration when being b.Relatively theoretical effect and actual effect, evaluates the synergy of composition, for synergistic effect when being greater than theoretical preventive effect with actual preventive effect.The results are shown in Table 1.
Table 1 pyrrole metsulfovax composition is to the control efficiency of graw mold of tomato
By potted plant test, as seen from Table 1, pyrrole metsulfovax and kasugarnycin composition to the effect of graw mold of tomato all higher than composition theoretical preventive effect.Obviously, pyrrole metsulfovax and the composite of above-mentioned Fungicidal compounds are synergy to graw mold of tomato.
Embodiment 2 pyrrole metsulfovax composition is to wheat powdery mildew field trial
Carried out wheat powdery mildew field trial with composition, and established corresponding single dose and blank, community 30m established by every medicament
2.Adopt the conventional conventional spray of knapsack sprayer, test respectively sprays 1 time in booting and flowering initial stage, 7 ~ 10d before medicine and after the 2nd dispenser, often process is by 5 samplings, often 50 strains, whole blade is investigated in every strain, and record investigation total number of sheets, the sick number of sheets, calculate disease index and preventive effect according to following stage division.
Blade staging:
0 grade: anosis
1 grade: the scab area that is connected accounts for less than 1% of whole leaf area;
3 grades: the scab area that is connected accounts for the 1%-5% of whole leaf area;
5 grades: the scab area that is connected accounts for the 6%-25% of whole leaf area;
7 grades: the scab area that is connected accounts for the 26%-50% of whole leaf area;
9 grades: the scab area that is connected accounts for more than 51% of whole leaf area;
The preventive effect of the active component A that x is working concentration when being a, the preventive effect of the active component B that y is working concentration when being b.Relatively theoretical effect and actual effect, evaluates the synergy of composition, for synergistic effect when being greater than theoretical preventive effect with actual preventive effect.Control efficiency is in table 3.
The composition pesticide of table 2 containing pyrrole metsulfovax is to wheat powdery mildew field efficacy
By pyrrole metsulfovax composition, wheat powdery mildew test is found, the composition of pyrrole metsulfovax and polyoxin to the effect of wheat powdery mildew all higher than the theoretical preventive effect of correspondent composition.Obviously, the composition of pyrrole metsulfovax and above-mentioned Fungicidal compounds is synergy to wheat powdery mildew.
Claims (4)
1. one kind contains pyrrole metsulfovax and antibiotic bactericidal composition, it is characterized in that said composition includes component A and B component two kinds of active components of effective amount, component A is pyrrole metsulfovax, B component is selected from polyoxin, the ratio of quality and the number of copies of component A and B component is 1:1-1:2, the quality sum of component A and B component accounts for the 1-90% of composition gross mass, and described composition is made into aqua.
2. composition according to claim 1 is for preventing and treating the method for crop pest, it is characterized in that composition to be applied to crop or crop part by spraying, filling root or seed dressing.
3. composition according to claim 2 is for preventing and treating the purposes of the various agricultural disease of crop, it is characterized in that described disease is the fungus-caused graw mold of tomato of Fungi Imperfecti, scab, the fungus-caused downy mildew of Mastigomycotina, late blight, peronospora tabacina, the fungus-caused powdery mildew of Ascomycotina, anthracnose, leaf spot, or rust, smut that Basidiomycotina causes.
4. purposes according to claim 3, wherein said crop is tomato, cucumber, wheat, paddy rice, watermelon, apple, grape, oranges and tangerines, pears, lichee or flowers.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410038784.7A CN103749462B (en) | 2013-03-20 | 2013-03-20 | Containing pyrrole metsulfovax and antibiotic bactericidal composition |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310091040.7A CN103141484B (en) | 2013-03-20 | 2013-03-20 | Sterilizing composition containing penthiopyrad |
| CN201410038784.7A CN103749462B (en) | 2013-03-20 | 2013-03-20 | Containing pyrrole metsulfovax and antibiotic bactericidal composition |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201310091040.7A Division CN103141484B (en) | 2013-03-20 | 2013-03-20 | Sterilizing composition containing penthiopyrad |
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| Publication Number | Publication Date |
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| CN103749462A CN103749462A (en) | 2014-04-30 |
| CN103749462B true CN103749462B (en) | 2016-01-06 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410036205.5A Active CN103798240B (en) | 2013-03-20 | 2013-03-20 | Composition containing pyrrole metsulfovax and methoxy acrylic sterilization component |
| CN201310091040.7A Active CN103141484B (en) | 2013-03-20 | 2013-03-20 | Sterilizing composition containing penthiopyrad |
| CN201410038784.7A Active CN103749462B (en) | 2013-03-20 | 2013-03-20 | Containing pyrrole metsulfovax and antibiotic bactericidal composition |
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| CN201410036205.5A Active CN103798240B (en) | 2013-03-20 | 2013-03-20 | Composition containing pyrrole metsulfovax and methoxy acrylic sterilization component |
| CN201310091040.7A Active CN103141484B (en) | 2013-03-20 | 2013-03-20 | Sterilizing composition containing penthiopyrad |
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| CN103141496A (en) * | 2013-04-02 | 2013-06-12 | 海利尔药业集团股份有限公司 | Sterilizing composite containing pyraclostrobin and penthiopyrad |
| CN104247710B (en) * | 2013-06-29 | 2016-02-24 | 深圳诺普信农化股份有限公司 | Health composition containing pyraclostrobin |
| US9788544B2 (en) * | 2013-11-26 | 2017-10-17 | Upl Limited | Method for controlling rust |
| WO2015160619A1 (en) * | 2014-04-16 | 2015-10-22 | Bayer Cropscience Lp | Compositions comprising ningnanmycin and a fungicide |
| CN104137833B (en) * | 2014-07-18 | 2016-05-18 | 江苏丘陵地区镇江农业科学研究所 | One is prevented and treated the biological composite bactericide of wheat scab and application thereof |
| CN104126595B (en) * | 2014-08-21 | 2016-04-13 | 陕西上格之路生物科学有限公司 | A kind of microbicide compositions containing pyraclostrobin |
| CN104186486B (en) * | 2014-09-22 | 2017-01-11 | 江苏省绿盾植保农药实验有限公司 | Sterilizing composition containing fluopicolide and metconazole and application thereof |
| CN104381293B (en) * | 2014-11-03 | 2016-05-25 | 安徽省农业科学院植物保护与农产品质量安全研究所 | A kind of bactericidal composition containing Silthiopham and jinggangmeisu |
| CN104823976A (en) * | 2015-04-09 | 2015-08-12 | 江门市植保有限公司 | Pesticide composition containing bromothalonil and kasugamycin |
| CN104770381A (en) * | 2015-04-24 | 2015-07-15 | 常熟市植保植检站 | Fungicidal composition for prevention and treatment of crop diseases and applications of fungicidal composition |
| CN107006500A (en) * | 2017-04-28 | 2017-08-04 | 广东广康生化科技股份有限公司 | Composition pesticide comprising folpet and pyrrole metsulfovax |
| CN109418270A (en) * | 2017-09-01 | 2019-03-05 | 浙江省化工研究院有限公司 | A kind of bactericidal composition of fluorine-containing phenylate amide |
| CN108576029A (en) * | 2018-06-05 | 2018-09-28 | 深圳诺普信农化股份有限公司 | A kind of bactericidal composition containing pyrrole metsulfovax and its application |
| CN109042677A (en) * | 2018-08-24 | 2018-12-21 | 广东顾地丰生物科技有限公司 | A kind of bactericidal composition, fungicide and its application of the metsulfovax containing pyrrole |
| CN108794075A (en) * | 2018-08-28 | 2018-11-13 | 陕西省生物农业研究所 | The feces of livestock and poultry base-material preparation method cured based on separating dry space from moist space and microbial deodorant |
| CN112438269A (en) * | 2019-08-30 | 2021-03-05 | 佛山市海力盈生物科技有限公司 | Sterilization composition containing penthiopyrad and amino-oligosaccharin and application thereof |
| CN113412838A (en) * | 2021-06-01 | 2021-09-21 | 四川瑞象农业科技发展有限公司 | Bactericidal composition for citrus brown spot and control method |
| CN114208566A (en) * | 2021-12-27 | 2022-03-22 | 云南省农业科学院药用植物研究所 | Prevention and treatment method for anthracnose of tsaoko amomum fruits |
| CN114916552B (en) * | 2022-05-16 | 2023-10-31 | 中农立华生物科技股份有限公司 | Compound agricultural bactericide containing penthiopyrad and application thereof |
| CN116076519B (en) * | 2023-03-08 | 2024-08-16 | 福建省农业科学院植物保护研究所 | Sterilization composition containing pyraclostrobin and myclobutanil and application thereof |
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- 2013-03-20 CN CN201410036205.5A patent/CN103798240B/en active Active
- 2013-03-20 CN CN201310091040.7A patent/CN103141484B/en active Active
- 2013-03-20 CN CN201410038784.7A patent/CN103749462B/en active Active
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| CN101184391A (en) * | 2005-04-06 | 2008-05-21 | 拜尔农作物科学股份公司 | Synergistic fungicidal active substance combinations |
| CN103651539A (en) * | 2012-09-11 | 2014-03-26 | 陕西美邦农药有限公司 | Pesticide composition containing penthiopyrad |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103798240B (en) | 2016-03-02 |
| CN103749462A (en) | 2014-04-30 |
| CN103141484B (en) | 2014-07-09 |
| CN103141484A (en) | 2013-06-12 |
| CN103798240A (en) | 2014-05-21 |
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