CN103141484B - Sterilizing composition containing penthiopyrad - Google Patents
Sterilizing composition containing penthiopyrad Download PDFInfo
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- CN103141484B CN103141484B CN201310091040.7A CN201310091040A CN103141484B CN 103141484 B CN103141484 B CN 103141484B CN 201310091040 A CN201310091040 A CN 201310091040A CN 103141484 B CN103141484 B CN 103141484B
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- pyrrole metsulfovax
- crop
- fungus
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- 239000000203 mixture Substances 0.000 title claims abstract description 86
- 230000001954 sterilising effect Effects 0.000 title abstract description 3
- PFFIDZXUXFLSSR-UHFFFAOYSA-N 1-methyl-N-[2-(4-methylpentan-2-yl)-3-thienyl]-3-(trifluoromethyl)pyrazole-4-carboxamide Chemical compound S1C=CC(NC(=O)C=2C(=NN(C)C=2)C(F)(F)F)=C1C(C)CC(C)C PFFIDZXUXFLSSR-UHFFFAOYSA-N 0.000 title abstract 3
- 239000005816 Penthiopyrad Substances 0.000 title abstract 3
- 241000233679 Peronosporaceae Species 0.000 claims abstract description 13
- 241000221785 Erysiphales Species 0.000 claims abstract description 12
- 239000000839 emulsion Substances 0.000 claims abstract description 3
- 239000004530 micro-emulsion Substances 0.000 claims abstract description 3
- 238000005507 spraying Methods 0.000 claims abstract description 3
- 239000004562 water dispersible granule Substances 0.000 claims abstract description 3
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims description 97
- UDSJPFPDKCMYBD-UHFFFAOYSA-N Metsulfovax Chemical compound S1C(C)=NC(C)=C1C(=O)NC1=CC=CC=C1 UDSJPFPDKCMYBD-UHFFFAOYSA-N 0.000 claims description 51
- 206010039509 Scab Diseases 0.000 claims description 13
- 201000010099 disease Diseases 0.000 claims description 11
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims description 11
- 240000008067 Cucumis sativus Species 0.000 claims description 10
- 240000003768 Solanum lycopersicum Species 0.000 claims description 10
- 230000000844 anti-bacterial effect Effects 0.000 claims description 10
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 claims description 9
- 235000007688 Lycopersicon esculentum Nutrition 0.000 claims description 9
- 235000021307 Triticum Nutrition 0.000 claims description 9
- -1 aqua Substances 0.000 claims description 7
- OICGFSUWXCJLCO-UHFFFAOYSA-N 1-ethylsulfonylsulfanylethane Chemical group CCSS(=O)(=O)CC OICGFSUWXCJLCO-UHFFFAOYSA-N 0.000 claims description 5
- 125000000168 pyrrolyl group Chemical group 0.000 claims description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 241000233652 Chytridiomycota Species 0.000 claims description 2
- 244000241235 Citrullus lanatus Species 0.000 claims description 2
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 claims description 2
- 241000675108 Citrus tangerina Species 0.000 claims description 2
- 241000233866 Fungi Species 0.000 claims description 2
- 241000220225 Malus Species 0.000 claims description 2
- 235000011430 Malus pumila Nutrition 0.000 claims description 2
- 235000015103 Malus silvestris Nutrition 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims description 2
- 235000007164 Oryza sativa Nutrition 0.000 claims description 2
- 241000582441 Peronospora tabacina Species 0.000 claims description 2
- 241000220324 Pyrus Species 0.000 claims description 2
- 235000009754 Vitis X bourquina Nutrition 0.000 claims description 2
- 235000012333 Vitis X labruscana Nutrition 0.000 claims description 2
- 240000006365 Vitis vinifera Species 0.000 claims description 2
- 235000014787 Vitis vinifera Nutrition 0.000 claims description 2
- 241000607479 Yersinia pestis Species 0.000 claims description 2
- 235000021017 pears Nutrition 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 235000009566 rice Nutrition 0.000 claims description 2
- 239000000375 suspending agent Substances 0.000 claims description 2
- 238000009736 wetting Methods 0.000 claims description 2
- 244000098338 Triticum aestivum Species 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 13
- 239000005869 Pyraclostrobin Substances 0.000 abstract description 5
- HZRSNVGNWUDEFX-UHFFFAOYSA-N pyraclostrobin Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NN(C=2C=CC(Cl)=CC=2)C=C1 HZRSNVGNWUDEFX-UHFFFAOYSA-N 0.000 abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- 239000005730 Azoxystrobin Substances 0.000 abstract 1
- 208000031888 Mycoses Diseases 0.000 abstract 1
- 239000005818 Picoxystrobin Substances 0.000 abstract 1
- WFDXOXNFNRHQEC-GHRIWEEISA-N azoxystrobin Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1OC1=CC(OC=2C(=CC=CC=2)C#N)=NC=N1 WFDXOXNFNRHQEC-GHRIWEEISA-N 0.000 abstract 1
- RBWGTZRSEOIHFD-UHUFKFKFSA-N fenaminstrobin Chemical compound CNC(=O)C(=N\OC)\C1=CC=CC=C1CO\N=C(/C)\C=C\C1=C(Cl)C=CC=C1Cl RBWGTZRSEOIHFD-UHUFKFKFSA-N 0.000 abstract 1
- IBSNKSODLGJUMQ-SDNWHVSQSA-N picoxystrobin Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1COC1=CC=CC(C(F)(F)F)=N1 IBSNKSODLGJUMQ-SDNWHVSQSA-N 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- 239000004563 wettable powder Substances 0.000 abstract 1
- 230000003449 preventive effect Effects 0.000 description 20
- 239000003814 drug Substances 0.000 description 9
- 241000209140 Triticum Species 0.000 description 8
- 238000012360 testing method Methods 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 6
- 239000007921 spray Substances 0.000 description 6
- 230000002195 synergetic effect Effects 0.000 description 6
- 150000003851 azoles Chemical class 0.000 description 5
- 229920001542 oligosaccharide Polymers 0.000 description 5
- 150000002482 oligosaccharides Chemical class 0.000 description 5
- 241000894006 Bacteria Species 0.000 description 4
- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 4
- 239000006013 carbendazim Substances 0.000 description 4
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 239000012452 mother liquor Substances 0.000 description 4
- QNBTYORWCCMPQP-JXAWBTAJSA-N (Z)-dimethomorph Chemical compound C1=C(OC)C(OC)=CC=C1C(\C=1C=CC(Cl)=CC=1)=C/C(=O)N1CCOCC1 QNBTYORWCCMPQP-JXAWBTAJSA-N 0.000 description 3
- 239000005758 Cyprodinil Substances 0.000 description 3
- 239000005760 Difenoconazole Substances 0.000 description 3
- 239000005761 Dimethomorph Substances 0.000 description 3
- 239000005784 Fluoxastrobin Substances 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- 229930182764 Polyoxin Natural products 0.000 description 3
- 239000005820 Prochloraz Substances 0.000 description 3
- 239000005822 Propiconazole Substances 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- HAORKNGNJCEJBX-UHFFFAOYSA-N cyprodinil Chemical compound N=1C(C)=CC(C2CC2)=NC=1NC1=CC=CC=C1 HAORKNGNJCEJBX-UHFFFAOYSA-N 0.000 description 3
- BQYJATMQXGBDHF-UHFFFAOYSA-N difenoconazole Chemical compound O1C(C)COC1(C=1C(=CC(OC=2C=CC(Cl)=CC=2)=CC=1)Cl)CN1N=CN=C1 BQYJATMQXGBDHF-UHFFFAOYSA-N 0.000 description 3
- UFEODZBUAFNAEU-NLRVBDNBSA-N fluoxastrobin Chemical group C=1C=CC=C(OC=2C(=C(OC=3C(=CC=CC=3)Cl)N=CN=2)F)C=1C(=N/OC)\C1=NOCCO1 UFEODZBUAFNAEU-NLRVBDNBSA-N 0.000 description 3
- 230000000855 fungicidal effect Effects 0.000 description 3
- 238000011835 investigation Methods 0.000 description 3
- 150000002825 nitriles Chemical class 0.000 description 3
- JHIPUJPTQJYEQK-ZLHHXESBSA-N orysastrobin Chemical compound CNC(=O)C(=N\OC)\C1=CC=CC=C1CO\N=C(/C)\C(=N\OC)\C(\C)=N\OC JHIPUJPTQJYEQK-ZLHHXESBSA-N 0.000 description 3
- UWVQIROCRJWDKL-UHFFFAOYSA-N oxadixyl Chemical compound CC=1C=CC=C(C)C=1N(C(=O)COC)N1CCOC1=O UWVQIROCRJWDKL-UHFFFAOYSA-N 0.000 description 3
- 244000052769 pathogen Species 0.000 description 3
- 230000001717 pathogenic effect Effects 0.000 description 3
- YEBIHIICWDDQOL-YBHNRIQQSA-N polyoxin Polymers O[C@@H]1[C@H](O)[C@@H](C(C=O)N)O[C@H]1N1C(=O)NC(=O)C(C(O)=O)=C1 YEBIHIICWDDQOL-YBHNRIQQSA-N 0.000 description 3
- TVLSRXXIMLFWEO-UHFFFAOYSA-N prochloraz Chemical compound C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl TVLSRXXIMLFWEO-UHFFFAOYSA-N 0.000 description 3
- STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 239000005805 Mepanipyrim Substances 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 230000004071 biological effect Effects 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- CIFWZNRJIBNXRE-UHFFFAOYSA-N mepanipyrim Chemical compound CC#CC1=CC(C)=NC(NC=2C=CC=CC=2)=N1 CIFWZNRJIBNXRE-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 2
- 229920000053 polysorbate 80 Polymers 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- QXJKBPAVAHBARF-BETUJISGSA-N procymidone Chemical compound O=C([C@]1(C)C[C@@]1(C1=O)C)N1C1=CC(Cl)=CC(Cl)=C1 QXJKBPAVAHBARF-BETUJISGSA-N 0.000 description 2
- ZMYFCFLJBGAQRS-IRXDYDNUSA-N (2R,3S)-epoxiconazole Chemical compound C1=CC(F)=CC=C1[C@@]1(CN2N=CN=C2)[C@H](C=2C(=CC=CC=2)Cl)O1 ZMYFCFLJBGAQRS-IRXDYDNUSA-N 0.000 description 1
- AMNAZJFEONUVTD-KEWDHRJRSA-N (2s,3s,4s,5r,6r)-6-(4-amino-2-oxopyrimidin-1-yl)-4,5-dihydroxy-3-[[(2s)-3-hydroxy-2-[[2-(methylamino)acetyl]amino]propanoyl]amino]oxane-2-carboxamide Chemical compound O1[C@H](C(N)=O)[C@@H](NC(=O)[C@H](CO)NC(=O)CNC)[C@H](O)[C@@H](O)[C@@H]1N1C(=O)N=C(N)C=C1 AMNAZJFEONUVTD-KEWDHRJRSA-N 0.000 description 1
- LDVVMCZRFWMZSG-OLQVQODUSA-N (3ar,7as)-2-(trichloromethylsulfanyl)-3a,4,7,7a-tetrahydroisoindole-1,3-dione Chemical compound C1C=CC[C@H]2C(=O)N(SC(Cl)(Cl)Cl)C(=O)[C@H]21 LDVVMCZRFWMZSG-OLQVQODUSA-N 0.000 description 1
- PPDBOQMNKNNODG-NTEUORMPSA-N (5E)-5-(4-chlorobenzylidene)-2,2-dimethyl-1-(1,2,4-triazol-1-ylmethyl)cyclopentanol Chemical compound C1=NC=NN1CC1(O)C(C)(C)CC\C1=C/C1=CC=C(Cl)C=C1 PPDBOQMNKNNODG-NTEUORMPSA-N 0.000 description 1
- PXMNMQRDXWABCY-UHFFFAOYSA-N 1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC=C(Cl)C=C1 PXMNMQRDXWABCY-UHFFFAOYSA-N 0.000 description 1
- DHVLDKHFGIVEIP-UHFFFAOYSA-N 2-bromo-2-(bromomethyl)pentanedinitrile Chemical compound BrCC(Br)(C#N)CCC#N DHVLDKHFGIVEIP-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 239000005741 Bromuconazole Substances 0.000 description 1
- 239000005745 Captan Substances 0.000 description 1
- 239000005767 Epoxiconazole Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IWDQPCIQCXRBQP-UHFFFAOYSA-M Fenaminosulf Chemical compound [Na+].CN(C)C1=CC=C(N=NS([O-])(=O)=O)C=C1 IWDQPCIQCXRBQP-UHFFFAOYSA-M 0.000 description 1
- 239000005782 Fluopicolide Substances 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000005789 Folpet Substances 0.000 description 1
- FEACDOXQOYCHKU-UHFFFAOYSA-N Gougerotin Natural products CNCC(=O)NC1=NC(=O)N(C=C1)C2OC(C(O)C(NC(=O)C(N)CO)C2O)C(=O)N FEACDOXQOYCHKU-UHFFFAOYSA-N 0.000 description 1
- 239000005802 Mancozeb Substances 0.000 description 1
- 239000005807 Metalaxyl Substances 0.000 description 1
- 239000005868 Metconazole Substances 0.000 description 1
- 239000005823 Propineb Substances 0.000 description 1
- 241000221696 Sclerotinia sclerotiorum Species 0.000 description 1
- 239000005839 Tebuconazole Substances 0.000 description 1
- 239000005842 Thiophanate-methyl Substances 0.000 description 1
- 239000005846 Triadimenol Substances 0.000 description 1
- 239000005859 Triticonazole Substances 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- GAMFEMAXLMWCRG-UHFFFAOYSA-N bis(dimethylcarbamothioylsulfanyl)arsanyl n,n-dimethylcarbamodithioate Chemical compound CN(C)C(=S)S[As](SC(=S)N(C)C)SC(=S)N(C)C GAMFEMAXLMWCRG-UHFFFAOYSA-N 0.000 description 1
- HJJVPARKXDDIQD-UHFFFAOYSA-N bromuconazole Chemical compound ClC1=CC(Cl)=CC=C1C1(CN2N=CN=C2)OCC(Br)C1 HJJVPARKXDDIQD-UHFFFAOYSA-N 0.000 description 1
- 229940117949 captan Drugs 0.000 description 1
- CWVRPJSBNHNJSI-XQNSMLJCSA-N coumoxystrobin Chemical compound C1=C2OC(=O)C(CCCC)=C(C)C2=CC=C1OCC1=CC=CC=C1\C(=C/OC)C(=O)OC CWVRPJSBNHNJSI-XQNSMLJCSA-N 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000005669 field effect Effects 0.000 description 1
- GBOYJIHYACSLGN-UHFFFAOYSA-N fluopicolide Chemical compound ClC1=CC(C(F)(F)F)=CN=C1CNC(=O)C1=C(Cl)C=CC=C1Cl GBOYJIHYACSLGN-UHFFFAOYSA-N 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- FQKUGOMFVDPBIZ-UHFFFAOYSA-N flusilazole Chemical compound C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 FQKUGOMFVDPBIZ-UHFFFAOYSA-N 0.000 description 1
- HKIOYBQGHSTUDB-UHFFFAOYSA-N folpet Chemical compound C1=CC=C2C(=O)N(SC(Cl)(Cl)Cl)C(=O)C2=C1 HKIOYBQGHSTUDB-UHFFFAOYSA-N 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- FCOAHACKGGIURQ-UHFFFAOYSA-N iprobenfos Chemical compound CC(C)OP(=O)(OC(C)C)SCC1=CC=CC=C1 FCOAHACKGGIURQ-UHFFFAOYSA-N 0.000 description 1
- UFHLMYOGRXOCSL-UHFFFAOYSA-N isoprothiolane Chemical compound CC(C)OC(=O)C(C(=O)OC(C)C)=C1SCCS1 UFHLMYOGRXOCSL-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- XWPZUHJBOLQNMN-UHFFFAOYSA-N metconazole Chemical compound C1=NC=NN1CC1(O)C(C)(C)CCC1CC1=CC=C(Cl)C=C1 XWPZUHJBOLQNMN-UHFFFAOYSA-N 0.000 description 1
- ZQEIXNIJLIKNTD-UHFFFAOYSA-N methyl N-(2,6-dimethylphenyl)-N-(methoxyacetyl)alaninate Chemical compound COCC(=O)N(C(C)C(=O)OC)C1=C(C)C=CC=C1C ZQEIXNIJLIKNTD-UHFFFAOYSA-N 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- KKMLIVYBGSAJPM-UHFFFAOYSA-L propineb Chemical compound [Zn+2].[S-]C(=S)NC(C)CNC([S-])=S KKMLIVYBGSAJPM-UHFFFAOYSA-L 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical compound COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 description 1
- BAZVSMNPJJMILC-UHFFFAOYSA-N triadimenol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC1=CC=C(Cl)C=C1 BAZVSMNPJJMILC-UHFFFAOYSA-N 0.000 description 1
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides a sterilizing composition containing penthiopyrad and use thereof for preventing and controlling agricultural fungal diseases. The composition mainly comprises two active components A and B in effective quantity, wherein the component A is penthiopyrad, while the component B is selected from one of azoxystrobin, pyraclostrobin, picoxystrobin, SYP-1620 and the like. When applied, the composition provided by the invention is prepared into suspensions, wettable powder, water dispersible granules, water aqua, microemulsions or emulsions in water for spraying, irrigating roots and stirring seeds; and the composition has the excellent effect of preventing gray mold, downy mildew and powdery mildew.
Description
Technical field
The present invention relates to the bactericidal composition that contains pyrrole metsulfovax, belong to plant protection field, relate to the bactericidal composition that contains pyrrole metsulfovax, said composition is used for preventing and treating gray mold, powdery mildew, downy mildew, stalk break, rust disease, scab etc.
Background technology
Pyrrole metsulfovax is the new type bactericide of amide containing structure, to multiple kinds of crops disease there is good preventive effect, especially gray mold, powdery mildew, downy mildew are had to very high effect.For Reasonable Protection medicament, delay germ to the drug-fast generation of new medicament and improve the control efficiency of medicament, be necessary to carry out rational composition research.The complex preparation that has had at present pyrrole metsulfovax and other bactericide, the present invention found through experiments the reasonable bactericidal composition that contains pyrrole metsulfovax of other effects that prior art is not also found.These bactericidal compositions have unforeseeable technique effect.
Summary of the invention
The object of the present invention is to provide the bactericidal composition that contains pyrrole metsulfovax, it be two kinds of different structures are carried out composite, but expanding prevention spectrum and improve the effective way of drug effect be the more important thing is and avoided or delay the generation of disease to new composition resistance.For realizing object of the present invention, inventor is composite with the compound with sterilization component by pyrrole metsulfovax, for preventing and treating the disease of crop.
The object of the invention is to realize by following measures.
The invention provides a kind of bactericidal composition that contains pyrrole metsulfovax, it is characterized in that said composition comprises A component and two kinds of active components of B component of effective dose, A component is pyrrole metsulfovax, and B component is selected from Fluoxastrobin, pyraclostrobin, ZEN 90160, alkene oxime amine, orysastrobin, ZJ0712, SSF 126, SYP-3375, azoles bacterium ester, 2-cyano-3-amino-3-phenylancryic acetate, propiconazole, Tebuconazole, Difenoconazole, nitrile bacterium azoles, bromuconazole, own azoles alcohol, metconazole, Triadimenol, epoxiconazole, Flusilazole, triticonazole, tpn, sulphur, carbendazim, mancozeb, Propineb, S-Ethyl ethylthio sulfonate, thiophanate-methyl, tmtd, asomate, captan, folpet, sulfonat, fenaminosulf, phonetic mould amine, procymidone, iprobenfos, Isoprothiolane, dimethomorph, metalaxyl, efficient M 9834, fluopicolide, the phonetic phenol of second, cyprodinil, fluorine mepanipyrim, mepanipyrim, jinggangmeisu, kasugarnycin, polyoxin, oligosaccharides, Ningnanmycin, Prochloraz, Wakil, one in bromothalonil.
In above-mentioned composition, preferred, the ratio of quality and the number of copies of A component and B component is 1:40-40:1, and preferred, the ratio of quality and the number of copies of A component and B component is 10:1-1:20.
In above-mentioned composition of the present invention, preferably, B component is selected from the one in Fluoxastrobin, pyraclostrobin, ZEN 90160, alkene oxime amine, orysastrobin, propiconazole, Difenoconazole, nitrile bacterium azoles, tpn, sulphur, carbendazim, S-Ethyl ethylthio sulfonate, phonetic mould amine, dimethomorph, the phonetic phenol of second, cyprodinil, jinggangmeisu, kasugarnycin, oligosaccharides, polyoxin, Prochloraz, Wakil.
In above-mentioned composition of the present invention, the quality sum of A component and B component accounts for the 1-90% of composition gross mass.
Above-mentioned composition of the present invention can be made into suspending agent, wetting powder, water dispersible granules, aqua, microemulsion or aqueous emulsion.
The present invention also provides above-mentioned composition for preventing and treating the method for crop pest, it is characterized in that composition to be applied to crop or crop part by spraying, filling root or seed dressing.。
The present invention also finds, above-mentioned composition, in the situation that active component uses total amount to reduce separately, has good control efficiency to graw mold of tomato, cucumber downy mildew, wheat powdery mildew, and synergistic effect is obvious.
The present invention also provides above-mentioned composition for preventing and treating the purposes of various agricultural disease of crop, it is characterized in that described disease is the fungus-caused graw mold of tomato of Fungi Imperfecti, scab etc., the fungus-caused downy mildew of Mastigomycotina, late blight, peronospora tabacina etc., the fungus-caused powdery mildew of Ascomycotina, anthracnose, leaf spot etc., rust, smut etc. that Basidiomycotina causes.
In such use, described crop is preferably tomato, cucumber, wheat, paddy rice, watermelon, apple, grape, oranges and tangerines, pears, lichee or flowers etc.
Beneficial effect of the present invention is:
1, synergistic effect is obvious: composition shows good synergistic effect in certain ratio range, has improved the protection effect of composition.
2, expanding prevention spectrum: composition can be prevented and treated the multiple diseases in agricultural production.
3, reduce use cost: because compositely thering is the preventive effect of raising, control spectrum increases, and has reduced access times, has reduced use cost;
4, delay pesticide resistance: the composition of two kinds of different mechanism of action is composite, pathogen is difficult for developing immunity to drugs, and delays pathogen to the drug-fast generation of single dose.
Embodiment
Following examples are to further illustrate of the present invention, but the present invention is not confined to composition and purposes in present embodiment.
The control efficiency of embodiment 1 pyrrole metsulfovax composition to graw mold of tomato
Single compound or composition are prepared into the mother liquor of 1000mg/L with organic solvent dissolution.According to biological activity determination trial test, a certain amount of above-mentioned mother liquor is diluted with 0.1% Tween 80, be mixed with the concentration needing.When mensuration, first liquid medicine jet is imposed on to potted tomato plant, then inoculate pathogen, moisturizing is cultivated after 24h, is placed in greenhouse and cultivates, and measures the percentage that plant leaf surface infects after certain hour.Use Abbot formula, convert percentage to preventive effect.
X is the preventive effect of the active component A of working concentration while being a, and y is the preventive effect of the active component B of working concentration while being b.Relatively theoretical effect and actual effect, evaluates the synergy of composition, while being greater than theoretical preventive effect take actual preventive effect as synergistic effect.The results are shown in Table 1.
The control efficiency of table 1 pyrrole metsulfovax composition to graw mold of tomato
By potted plant test, as seen from Table 1, the composition of the composition of the composition of the composition of the composition of the composition of the composition of the composition of the composition of pyrrole metsulfovax and Fluoxastrobin, pyrrole metsulfovax and pyraclostrobin, pyrrole metsulfovax and propiconazole, pyrrole metsulfovax and S-Ethyl ethylthio sulfonate, pyrrole metsulfovax and phonetic mould amine, pyrrole metsulfovax and procymidone, pyrrole metsulfovax and kasugarnycin, pyrrole metsulfovax and oligosaccharides, pyrrole metsulfovax and Prochloraz to the effect of graw mold of tomato all higher than composition theoretical preventive effect.Obviously, the composite of pyrrole metsulfovax and above-mentioned Fungicidal compounds is synergy to graw mold of tomato.
The control efficiency of embodiment 2 pyrrole metsulfovax compositions to cucumber downy mildew
Single compound or composition are prepared into the mother liquor of 1000mg/L with organic solvent dissolution.According to biological activity determination trial test, a certain amount of above-mentioned mother liquor is diluted with 0.1% Tween 80, be mixed with the concentration needing.When test, cucumber plant, substantially in 4 leaf phases, is investigated downy mildew incidence before the 1st medicine.Carried out cucumber downy mildew pot experiment with pyrrole metsulfovax composition, and established corresponding single dose and blank, adopted the conventional conventional spray of manual sprayer, every medicament sprays 10 strains, and the 7-10d after 1 time that sprays sprays 1 time again.10-14d investigation after the 2nd dispenser, whole blades are investigated in every strain, and the total number of sheets of record investigation, the sick number of sheets, calculate disease index and preventive effect according to following stage division.
Blade staging:
0 grade: anosis
1 grade: the connected area of scab accounts for below 1% of whole leaf area;
3 grades: the connected area of scab accounts for the 1%-10% of whole leaf area;
5 grades: the connected area of scab accounts for the 11%-20% of whole leaf area;
7 grades: the connected area of scab accounts for the 21%-50% of whole leaf area;
9 grades: the connected area of scab accounts for the more than 51% of whole leaf area;
X is the preventive effect of the active component A of working concentration while being a, and y is the preventive effect of the active component B of working concentration while being b.Relatively theoretical effect and actual effect, evaluates the synergy of composition, while being greater than theoretical preventive effect take actual preventive effect as synergistic effect.The results are shown in Table 2.
The control efficiency of table 2 pyrrole metsulfovax composition to cucumber downy mildew
By pyrrole metsulfovax composition, the potted plant test of cucumber downy mildew is found, the composition of composition, pyrrole metsulfovax and the oligosaccharides of composition, pyrrole metsulfovax and the dimethomorph of composition, pyrrole metsulfovax and the S-Ethyl ethylthio sulfonate of composition, pyrrole metsulfovax and the tpn of composition, pyrrole metsulfovax and the carbendazim of composition, pyrrole metsulfovax and the Difenoconazole of composition, pyrrole metsulfovax and the ZEN 90160 of pyrrole metsulfovax and pyraclostrobin to the effect of cucumber downy mildew all higher than the theoretical preventive effect of correspondent composition.Obviously, the composition of pyrrole metsulfovax and above-mentioned Fungicidal compounds is synergy to cucumber downy mildew.
Embodiment tri-: pyrrole metsulfovax composition is to wheat powdery mildew field trial
Carried out wheat powdery mildew field trial with composition, and established corresponding single dose and blank, every medicament is established community 30m
2.Adopt the conventional conventional spray of knapsack sprayer, test is booting and each spray 1 time of flowering initial stage, 7～10d before medicine and after the 2nd dispenser, every processing is by 5 samplings, every 50 strains, whole blades are investigated in every strain, and the total number of sheets of record investigation, the sick number of sheets, calculate disease index and preventive effect according to following stage division.
Blade staging:
0 grade: anosis
1 grade: the connected area of scab accounts for below 1% of whole leaf area;
3 grades: the connected area of scab accounts for the 1%-5% of whole leaf area;
5 grades: the connected area of scab accounts for the 6%-25% of whole leaf area;
7 grades: the connected area of scab accounts for the 26%-50% of whole leaf area;
9 grades: the connected area of scab accounts for the more than 51% of whole leaf area;
X is the preventive effect of the active component A of working concentration while being a, and y is the preventive effect of the active component B of working concentration while being b.Relatively theoretical effect and actual effect, evaluates the synergy of composition, while being greater than theoretical preventive effect take actual preventive effect as synergistic effect.Control efficiency is in table 3.
The composition pesticide that table 3 contains pyrrole metsulfovax is to wheat powdery mildew field effect
By pyrrole metsulfovax composition, wheat powdery mildew test is found, the composition of composition, pyrrole metsulfovax and the Wakil of composition, pyrrole metsulfovax and the oligosaccharides of composition, pyrrole metsulfovax and the polyoxin of composition, pyrrole metsulfovax and the cyprodinil of composition, pyrrole metsulfovax and the phonetic phenol of second of composition, pyrrole metsulfovax and the carbendazim of composition, pyrrole metsulfovax and the sulphur of composition, pyrrole metsulfovax and the nitrile bacterium azoles of composition, pyrrole metsulfovax and the orysastrobin of pyrrole metsulfovax and alkene oxime amine to the effect of wheat powdery mildew all higher than the theoretical preventive effect of correspondent composition.Obviously, the composition of pyrrole metsulfovax and above-mentioned Fungicidal compounds is synergy to wheat powdery mildew.
Claims (6)
1. contain a bactericidal composition for pyrrole metsulfovax, it is characterized in that said composition comprises A component and two kinds of active components of B component of effective dose, A component is pyrrole metsulfovax, and B component is S-Ethyl ethylthio sulfonate, and wherein the ratio of quality and the number of copies of A component and B component is 2:1-1:3.
2. composition according to claim 1, wherein the quality sum of A component and B component accounts for the 1-90% of composition gross mass.
3. composition according to claim 2, wherein said composition is made into suspending agent, wetting powder, water dispersible granules, aqua, microemulsion or aqueous emulsion.
4. composition claimed in claim 3, for preventing and treating the method for crop pest, is characterized in that composition to be applied to crop by spraying, filling root or seed dressing.
5. composition claimed in claim 4 is used for the purposes of the various agricultural disease of preventing and treating crop, it is characterized in that described disease is the fungus-caused graw mold of tomato of Fungi Imperfecti, scab, the fungus-caused downy mildew of Mastigomycotina, late blight, peronospora tabacina, the fungus-caused powdery mildew of Ascomycotina, anthracnose, leaf spot, or the Basidiomycotina rust, the smut that cause.
6. purposes according to claim 5, wherein said crop is tomato, cucumber, wheat, paddy rice, watermelon, apple, grape, oranges and tangerines, pears, lichee or flowers.
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| CN201410038784.7A CN103749462B (en) | 2013-03-20 | 2013-03-20 | Containing pyrrole metsulfovax and antibiotic bactericidal composition |
| CN201410036205.5A CN103798240B (en) | 2013-03-20 | 2013-03-20 | Composition containing pyrrole metsulfovax and methoxy acrylic sterilization component |
| CN201310091040.7A CN103141484B (en) | 2013-03-20 | 2013-03-20 | Sterilizing composition containing penthiopyrad |
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| CN201410260319.8A Division CN103988840A (en) | 2013-03-20 | 2013-03-20 | Fungicidal composition containing penthiopyrad and prochloraz |
| CN201410038784.7A Division CN103749462B (en) | 2013-03-20 | 2013-03-20 | Containing pyrrole metsulfovax and antibiotic bactericidal composition |
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| CN103141496A (en) * | 2013-04-02 | 2013-06-12 | 海利尔药业集团股份有限公司 | Sterilizing composite containing pyraclostrobin and penthiopyrad |
| CN104247710B (en) * | 2013-06-29 | 2016-02-24 | 深圳诺普信农化股份有限公司 | Health composition containing pyraclostrobin |
| RU2649180C1 (en) * | 2013-11-26 | 2018-03-30 | Юпл Лимитед | Method of soybean rust control |
| WO2015160619A1 (en) * | 2014-04-16 | 2015-10-22 | Bayer Cropscience Lp | Compositions comprising ningnanmycin and a fungicide |
| CN104137833B (en) * | 2014-07-18 | 2016-05-18 | 江苏丘陵地区镇江农业科学研究所 | One is prevented and treated the biological composite bactericide of wheat scab and application thereof |
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| CN104186486B (en) * | 2014-09-22 | 2017-01-11 | 江苏省绿盾植保农药实验有限公司 | Sterilizing composition containing fluopicolide and metconazole and application thereof |
| CN104381293B (en) * | 2014-11-03 | 2016-05-25 | 安徽省农业科学院植物保护与农产品质量安全研究所 | A kind of bactericidal composition containing Silthiopham and jinggangmeisu |
| CN104823976A (en) * | 2015-04-09 | 2015-08-12 | 江门市植保有限公司 | Pesticide composition containing bromothalonil and kasugamycin |
| CN104770381A (en) * | 2015-04-24 | 2015-07-15 | 常熟市植保植检站 | Fungicidal composition for prevention and treatment of crop diseases and applications of fungicidal composition |
| CN107006500A (en) * | 2017-04-28 | 2017-08-04 | 广东广康生化科技股份有限公司 | Composition pesticide comprising folpet and pyrrole metsulfovax |
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| CN108576029A (en) * | 2018-06-05 | 2018-09-28 | 深圳诺普信农化股份有限公司 | A kind of bactericidal composition containing pyrrole metsulfovax and its application |
| CN109042677A (en) * | 2018-08-24 | 2018-12-21 | 广东顾地丰生物科技有限公司 | A kind of bactericidal composition, fungicide and its application of the metsulfovax containing pyrrole |
| CN108794075A (en) * | 2018-08-28 | 2018-11-13 | 陕西省生物农业研究所 | The feces of livestock and poultry base-material preparation method cured based on separating dry space from moist space and microbial deodorant |
| CN112438269A (en) * | 2019-08-30 | 2021-03-05 | 佛山市海力盈生物科技有限公司 | Sterilization composition containing penthiopyrad and amino-oligosaccharin and application thereof |
| CN113412838A (en) * | 2021-06-01 | 2021-09-21 | 四川瑞象农业科技发展有限公司 | Bactericidal composition for citrus brown spot and control method |
| CN114208566A (en) * | 2021-12-27 | 2022-03-22 | 云南省农业科学院药用植物研究所 | Prevention and treatment method for anthracnose of tsaoko amomum fruits |
| CN114916552B (en) * | 2022-05-16 | 2023-10-31 | 中农立华生物科技股份有限公司 | Compound agricultural bactericide containing penthiopyrad and application thereof |
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| CN103749462A (en) | 2014-04-30 |
| CN103798240B (en) | 2016-03-02 |
| CN103798240A (en) | 2014-05-21 |
| CN103141484A (en) | 2013-06-12 |
| CN103749462B (en) | 2016-01-06 |
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