CN1053318C - Pesticide for control of crop disease - Google Patents
Pesticide for control of crop disease Download PDFInfo
- Publication number
- CN1053318C CN1053318C CN97101203A CN97101203A CN1053318C CN 1053318 C CN1053318 C CN 1053318C CN 97101203 A CN97101203 A CN 97101203A CN 97101203 A CN97101203 A CN 97101203A CN 1053318 C CN1053318 C CN 1053318C
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- Prior art keywords
- pesticide
- crops
- control
- preventing
- crop disease
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- 201000010099 disease Diseases 0.000 title claims abstract description 27
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 title claims abstract description 27
- 239000000575 pesticide Substances 0.000 title claims abstract description 18
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 9
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 9
- 239000003899 bactericide agent Substances 0.000 claims abstract description 9
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 12
- FFSJPOPLSWBGQY-UHFFFAOYSA-N triazol-4-one Chemical compound O=C1C=NN=N1 FFSJPOPLSWBGQY-UHFFFAOYSA-N 0.000 claims description 9
- OICGFSUWXCJLCO-UHFFFAOYSA-N 1-ethylsulfonylsulfanylethane Chemical compound CCSS(=O)(=O)CC OICGFSUWXCJLCO-UHFFFAOYSA-N 0.000 claims description 8
- 239000003995 emulsifying agent Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- DQJCHOQLCLEDLL-UHFFFAOYSA-N tricyclazole Chemical compound CC1=CC=CC2=C1N1C=NN=C1S2 DQJCHOQLCLEDLL-UHFFFAOYSA-N 0.000 claims description 4
- 238000009472 formulation Methods 0.000 claims description 3
- 239000005846 Triadimenol Substances 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- BAZVSMNPJJMILC-UHFFFAOYSA-N triadimenol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC1=CC=C(Cl)C=C1 BAZVSMNPJJMILC-UHFFFAOYSA-N 0.000 claims description 2
- 229920000742 Cotton Polymers 0.000 abstract description 13
- 230000000694 effects Effects 0.000 abstract description 8
- 230000012010 growth Effects 0.000 abstract description 6
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 abstract description 4
- 241000918585 Pythium aphanidermatum Species 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- 230000001954 sterilising effect Effects 0.000 abstract description 4
- 239000007788 liquid Substances 0.000 abstract description 2
- 239000000843 powder Substances 0.000 abstract description 2
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 2
- JDLKFOPOAOFWQN-VIFPVBQESA-N Allicin Natural products C=CCS[S@](=O)CC=C JDLKFOPOAOFWQN-VIFPVBQESA-N 0.000 abstract 1
- 244000299906 Cucumis sativus var. sativus Species 0.000 abstract 1
- 231100000674 Phytotoxicity Toxicity 0.000 abstract 1
- 235000010081 allicin Nutrition 0.000 abstract 1
- 244000052616 bacterial pathogen Species 0.000 abstract 1
- 230000006806 disease prevention Effects 0.000 abstract 1
- 239000004495 emulsifiable concentrate Substances 0.000 abstract 1
- -1 ethyl allicin Chemical compound 0.000 abstract 1
- 238000001228 spectrum Methods 0.000 abstract 1
- TWFZGCMQGLPBSX-UHFFFAOYSA-N carbendazim Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 description 22
- 230000003449 preventive effect Effects 0.000 description 15
- 230000003115 biocidal effect Effects 0.000 description 14
- 239000003905 agrochemical Substances 0.000 description 13
- 231100000572 poisoning Toxicity 0.000 description 13
- 230000000607 poisoning effect Effects 0.000 description 13
- 239000003814 drug Substances 0.000 description 11
- 239000006013 carbendazim Substances 0.000 description 10
- 241000196324 Embryophyta Species 0.000 description 9
- 239000000126 substance Substances 0.000 description 7
- 238000005507 spraying Methods 0.000 description 6
- YFNCATAIYKQPOO-UHFFFAOYSA-N thiophanate Chemical compound CCOC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OCC YFNCATAIYKQPOO-UHFFFAOYSA-N 0.000 description 5
- 239000005746 Carboxin Substances 0.000 description 4
- 241000209094 Oryza Species 0.000 description 4
- 235000007164 Oryza sativa Nutrition 0.000 description 4
- GYSSRZJIHXQEHQ-UHFFFAOYSA-N carboxin Chemical group S1CCOC(C)=C1C(=O)NC1=CC=CC=C1 GYSSRZJIHXQEHQ-UHFFFAOYSA-N 0.000 description 4
- 230000000855 fungicidal effect Effects 0.000 description 4
- 239000000417 fungicide Substances 0.000 description 4
- 235000009566 rice Nutrition 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 208000024891 symptom Diseases 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- 240000008067 Cucumis sativus Species 0.000 description 3
- 239000002917 insecticide Substances 0.000 description 3
- 238000011835 investigation Methods 0.000 description 3
- 241000219112 Cucumis Species 0.000 description 2
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- 239000005842 Thiophanate-methyl Substances 0.000 description 2
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 230000000857 drug effect Effects 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 230000008635 plant growth Effects 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 230000009885 systemic effect Effects 0.000 description 2
- 230000001225 therapeutic effect Effects 0.000 description 2
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical group COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- UHPMCKVQTMMPCG-UHFFFAOYSA-N 5,8-dihydroxy-2-methoxy-6-methyl-7-(2-oxopropyl)naphthalene-1,4-dione Chemical compound CC1=C(CC(C)=O)C(O)=C2C(=O)C(OC)=CC(=O)C2=C1O UHPMCKVQTMMPCG-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000223218 Fusarium Species 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 239000005867 Iprodione Substances 0.000 description 1
- 241001361634 Rhizoctonia Species 0.000 description 1
- 241001558929 Sclerotium <basidiomycota> Species 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- RIOXQFHNBCKOKP-UHFFFAOYSA-N benomyl Chemical compound C1=CC=C2N(C(=O)NCCCC)C(NC(=O)OC)=NC2=C1 RIOXQFHNBCKOKP-UHFFFAOYSA-N 0.000 description 1
- MITFXPHMIHQXPI-UHFFFAOYSA-N benzoxaprofen Natural products N=1C2=CC(C(C(O)=O)C)=CC=C2OC=1C1=CC=C(Cl)C=C1 MITFXPHMIHQXPI-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- ONUFESLQCSAYKA-UHFFFAOYSA-N iprodione Chemical compound O=C1N(C(=O)NC(C)C)CC(=O)N1C1=CC(Cl)=CC(Cl)=C1 ONUFESLQCSAYKA-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 238000003359 percent control normalization Methods 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000007619 statistical method Methods 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention discloses a pesticide for preventing and treating diseases of agricultural crops, which mainly comprises emulsifiable concentrate, suspending liquid or powder of the following components and weight percentage content: 5 to 80% of 402 ethyl allicin and 1 to 40% of bactericide, and the pesticide is mixed with the hypertonic auxiliary agent of the pesticide. The pesticide can enhance the capabilities of sterilization and disease prevention to prevent the crops from getting ill in the process of growth, and thus, the yield of the crops is improved. The pesticide has wide-spectrum sterilizing capability, and can be used for preventing and treating diseases caused by various germs; especially, the effect of preventing and treating cotton blight and cucumber damping-off can achieve 95%. The consumption of the single component is reduced, the phytotoxicity for the crops is reduced, and the cost is relatively low.
Description
The present invention relates to a kind of agricultural chemicals, relate in particular to the pesticide for control of crop disease that a kind of fusarium wilt, damping off, rice blast that crops such as cotton, cucumber, rice is caused because of the fungi bacterium has preventive and therapeutic effect.
Crop multiple diseases can occur in process of growth, as damping off, damping off, the angular leaf spot of cotton, the bakanae disease of paddy rice, root rot, rice blast, vegetable epidemic disease, anthracnose, fruit tree putrefaction disease, root rot all are by bacterium, fungus-caused disease.At these diseases; many kinds of bactericide class agricultural chemicals have also appearred in agricultural chemicals market; existing sterilization pesticide can be divided into protective fungicide and systemic fungicide two big classes substantially; all kinds of agricultural chemicals use its performance single separately; the ability of preventing and curing diseases has bigger limitation; the copper agent of protective fungicide class i.e. " " shuang xiao ling " ", " Copoloid "; can only kill the top layer germ or stop the pathogen spore to enter plant corpus; the bacterium that does in the object for intrusion can't kill, and does not have due therapeutic action.Systemic fungicide has the effect that stops the germ normal growth to be grown, and easily produces poisoning, and as " benomyl ", " topsin ", though interior absorption is good, the effect of curing the disease is obvious, but limitation is big, and causes crop pest easily.Pharmaceutical preparations " iprodione ", " sclerotium is peaceful " though etc. preferable to preventing and treating the disease effect, it costs an arm and a leg, and is difficult for being accepted by vast farmers.
Deficiency at above-mentioned agricultural chemicals existence, someone proposes S-Ethyl ethylthio sulfonate and antibiotic are re-dubbed the imagination of agricultural chemicals (referring to CN94116054.8 application for a patent for invention " a kind of specific pesticide of preventing and treating disease ", application on December 4th, 1994, on May 8th, 1996 is open), aqua and finish are only arranged, there is not pulvis, and still undesirable through the test drug effect.
It is a kind of good to fungi, bacterial crop multiple diseases result of treatment to the purpose of this invention is to provide, and the poisoning of making deposits yields is alleviated the pesticide for control of crop disease that price is lower.
Technical scheme of the present invention realizes in the following manner:
A kind of pesticide for control of crop disease, it mainly is missible oil, suspension or the pulvis that contains 402 S-Ethyl ethylthio sulfonates, bactericide, weight percentage is 402 S-Ethyl ethylthio sulfonate 5-80%, bactericide 1-40%.
For improving this pesticide efficacy, also be furnished with hypertonic assistant 0-40%, emulsifier 0-20% in the prescription.Bactericide is carboxin, carbendazim, tricyclazole, triazolone, Triadimenol, topsin, thiophanate methyl.
Bactericide is preferably carboxin, carbendazim, topsin.
Auxiliary agent be in auxiliary agent, 885 auxiliary agents.
The solvent of missible oil formulation is toluene, dimethylbenzene.
Good effect of the present invention is:
1, produces higher synergistic effect with antibiotic and bactericide compounded energy, strengthen bactericide diseases prevention ability, make crop in process of growth, avoid sick, improve the output of crop.
2, tool broad spectrum activity sterilizing ability can be prevented and treated multiple germ disease, and especially to cotton wilt, cucumber rhizoctonia rot reaches as high as 95% control efficiency.
3, the one-component usage amount reduces, and the poisoning that crop produced is reduced.
4, cost is relatively low.
The invention will be further described below in conjunction with implementing prescription:
Prescription 1:402 antibiotic 25%, carboxin 5%, in finish 40%, emulsifier 10%, surplus is a dimethylbenzene.
Prescription 2:402 antibiotic 30%, topsin 10%, in finish 10%, emulsifier 15%, surplus is a toluene.
Prescription 3:402 antibiotic 20%, tricyclazole 20%, emulsifier 20%, surplus is a dimethylbenzene.
Prescription 4: antibiotic 60%, thiophanate methyl 10%, surplus is a toluene.
Prescription 5:402 antibiotic 60%, triazolone 10%, in finish 30%, emulsifier 10%, surplus is a dimethylbenzene.
Prescription 6:402 antibiotic 30%, triazolone 20%, 885 auxiliary agent 10%, emulsifier 5%, surplus is a dimethylbenzene.
Prescription 7:402 antibiotic 15%, triazolone 1% after two groups mixed, mixes, dries, pulverizes with solid carrier.
Prescription 8:402 antibiotic 10%, carbendazim 5%, in auxiliary agent 5%, after three components are mixed, mix, dry, pulverize with solid carrier.
Prescription 9:402 antibiotic 5%, tricyclazole 15%, in auxiliary agent 5%, after three components are mixed, mix, dry, pulverize with solid carrier.
Prescription 10:402 antibiotic 5%, topsin 10% after two components are mixed, mixes, dries, pulverizes with solid carrier.
Prescription 11:402 antibiotic 60%, carboxin 40% mixes two components and gets final product.
Prescription 12:402 antibiotic 60%, carbendazim 40% mixes two components and gets final product.
This agricultural chemicals cotton experiment field piece to long-term morbidity under variable concentrations carries out and other agricultural chemicals crop comparative trial, and test drug is divided into 7 groups, and every group of experimental concentration is respectively:
1,4000 times of 80% S-Ethyl ethylthio sulfonate missible oil (Pinghu, Zhejiang insecticide factory).
2,32% medicine missible oil
3,32% medicine missible oil is 2000 times.
4,32% medicine missible oil is 1000 times.
5,1000 times of 20% triazolone missible oil (Jiangsu Jianhu insecticide factory).
6,1000 times of 50% carbendazol wettable powders (Xinyi insecticide factory)
7, clear water.
Handle for every group and divide I, II, III, IV4 repetition, randomized arrangement, the cultivation condition of all sub-districts is all consistent in the test, and the sub-district area is 66.6M
2, supplier's kind is 86-1.
Spraying time and number of times:
Spraying time for the first time: be two leaves spray medicines when launching seedling stage.
Spraying time for the second time: the preceding spraying of buddingging.
Investigation method:
1, in cotton flowering and boll-setting period investigation: each handles the disease index that 100 strains are investigated in each sub-district.
2, disease index grade scale:
0 grade: healthy tree
1 grade: the diseased plant blade has the leaf color of performance below 25% to deepen, shrinkage, and it is yellow netted that vein is, and the blade that has is classical symptoms such as yellow or reddish violet.
2 grades: the diseased plant blade has 25-50% performance symptom, and plant type is obviously downgraded.
3 grades: the diseased plant blade has 50-90% performance symptom, and plant type is obviously downgraded.
4 grades: the diseased plant blade almost all shows symptom, even dried-up coming off, and acute wilting death appears in the withered or whole strain of stem branch.
3, drug effect is calculated:
4, poisoning investigation and grade scale:
After spraying 1,3,7 day and investigate the influence of medicament harvest time, the poisoning grade scale to cotton:
-: no poisoning.
+: slight poisoning.
++: obviously poisoning, can restore, can not cause the cotton underproduction.
The poisoning of +++: height influences the cotton normal growth, causes to a certain degree output and mass loss.
++ ++: serious poisoning, plant growth is obstructed, and output and mass loss are serious.
The time efficacy survey data list 1 of different chemical control cotton wilts.
Table 1:
| Chemicals treatment | Preventive effect between repetition (%) | Average preventive effect (%) | The poisoning situation | |||
| I | II | III | IV | |||
| S-Ethyl ethylthio sulfonate 4000X 3000X of the present invention 2000X of the present invention 1000X triazolone of the present invention 1000X carbendazim 1000X | 61.0 70.8 89.3 93.4 2.7 40.7 | 53.1 69.3 86.4 90.5 3.5 46.9 | 54.0 73.2 86.9 92.0 3.3 42.0 | 58.0 71.5 81.3 95.3 6.9 39.1 | 56.5 71.1 86.0 91.9 4.1 42.3 | - - - + - - |
This test is shown by table 1 result: the preventive effect of the anti-cotton wilt of 1000 times of field sprays of the present invention's 32% missible oil is the highest, reaches 91.9%, but blade is had slight poisoning.This concentration not too is fit to do the cotton field spraying and uses.The preventive effect of 32%2000 times of missible oil is respectively 86% and 71.1%, and does not have poisoning.The preventive effect of 80% S-Ethyl ethylthio sulfonate missible oil and 20% triazolone missible oil contrast medicament, 50% carbendazol wettable powder is respectively 56.5%, 4.1%, 41.3%, all is starkly lower than the present invention's 32% missible oil.
Statistical analysis: the preventive effect of 6 chemicals treatment is carried out variance analysis and new range assay again tabulation 2.
Table 2: the preventive effect significance test of difference table of different chemical control cotton wilts
Table 2:
0.05 0.0132% agricultural chemicals EC1000 of the average preventive effect arcsine of chemicals treatment significance test of difference transformed value, 74.5 this agricultural chemicals of a A32% EC2000,68.1 this agricultural chemicals of a A32% EC3000,57.5 a A82% S-Ethyl ethylthio sulfonate EC4000,48.8 ab A50% carbendazim WPs, 1,000 40.6 b AB20% triazolone EC1000,11.8 c B tables 2 show that the preventive effect difference of 1000 times and 2000 times liquid of the present invention's 32% missible oil is not remarkable, but with two single doses and the contrast carbendazim preventive effect difference reach 0.05 level.
The result data of the present invention's cucumber sprout term disease in the control canopy is listed in table 3.
Table 3:
Result of treatment is respectively handled in calculating and preventive effect is:
Respectively handle control efficiency data (%) after the dispenser and list in table 4 table 4
| Chemicals treatment | Handle the strain number | Dispenser diseased plant number | Diseased plant is several three days seven days after the dispenser | |
| This agricultural chemicals 3000X | 258 | 86 | 51 | 12 |
| Carbendazim 3000X | 274 | 82 | 54 | 34 |
| The clear water contrast | 42 | 14 | 18 | 24 |
| Chemicals treatment | Behind the medicine three days | Behind the medicine seven days | ||
| The result of treatment preventive effect | The result of treatment preventive effect | |||
| This agricultural chemicals 3000X | 40.7 | 55.7 | 86.0 | 92.4 |
| Carbendazim 800X | 34.1 | 53.7 | 59.6 | 76.8 |
As can be seen from Table 4, three kinds of control efficiency have certain difference, and curative effect of the present invention is best, and 7 days results of treatment and preventive effect reach 86% and 92.4% respectively after the dispenser.Contrast medicament carbendazim has only 59.6% and 76.7%, and by the contrast of melon seedling growing state, the present invention has the plant growth of stimulation effect again, and the growth of melon seedling is obviously accelerated behind the medicine, and the leaf look turns green.
Claims (4)
1, a kind of pesticide for control of crop disease, its composition contains:
(1) 402 S-Ethyl ethylthio sulfonate 5-80%;
(2) bactericide tricyclazole＞1% is to＜10%, or triazolone＞1% is to＜10%, or Triadimenol＞1% is to＜10%;
(3) emulsifier 0-20%;
All percentages are percetage by weight.
2, pesticide for control of crop disease according to claim 1 is characterized in that also having hypertonic assistant 0-40% in this formulation of pesticide.
3, pesticide for control of crop disease according to claim 2, it is characterized in that hypertonic assistant be in auxiliary agent or 885 auxiliary agents.
4, pesticide for control of crop disease according to claim 1, the solvent that it is characterized in that the missible oil formulation is toluene, dimethylbenzene.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97101203A CN1053318C (en) | 1997-01-03 | 1997-01-03 | Pesticide for control of crop disease |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97101203A CN1053318C (en) | 1997-01-03 | 1997-01-03 | Pesticide for control of crop disease |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99122235 Division CN1250599A (en) | 1999-11-04 | 1999-11-04 | Agricultural chemical for preventing and treating diseases of agricultural crops |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1167569A CN1167569A (en) | 1997-12-17 |
| CN1053318C true CN1053318C (en) | 2000-06-14 |
Family
ID=5165577
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97101203A Expired - Fee Related CN1053318C (en) | 1997-01-03 | 1997-01-03 | Pesticide for control of crop disease |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1053318C (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101361485B (en) * | 2008-09-19 | 2010-07-07 | 江苏丘陵地区镇江农业科学研究所 | Compound bactericidal agent containing zincpolyanemine and ethylicin |
| CN101816307B (en) * | 2010-05-13 | 2012-11-21 | 江苏丘陵地区镇江农业科学研究所 | Bactericide for preventing and treating fruit diseases |
| CN103749462B (en) * | 2013-03-20 | 2016-01-06 | 海南正业中农高科股份有限公司 | Containing pyrrole metsulfovax and antibiotic bactericidal composition |
| CN106538552A (en) * | 2016-09-30 | 2017-03-29 | 许海波 | A kind of thiophene containing first lures the complex composition and preparation of amine and S-Ethyl ethylthio sulfonate |
-
1997
- 1997-01-03 CN CN97101203A patent/CN1053318C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1167569A (en) | 1997-12-17 |
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