CN103748157A - 含甾醇和/或其衍生物的抗污组合物 - Google Patents
含甾醇和/或其衍生物的抗污组合物 Download PDFInfo
- Publication number
- CN103748157A CN103748157A CN201280039052.9A CN201280039052A CN103748157A CN 103748157 A CN103748157 A CN 103748157A CN 201280039052 A CN201280039052 A CN 201280039052A CN 103748157 A CN103748157 A CN 103748157A
- Authority
- CN
- China
- Prior art keywords
- sterol
- weight
- lanolin
- composition
- soil composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229930182558 Sterol Natural products 0.000 title claims abstract description 128
- 235000003702 sterols Nutrition 0.000 title claims abstract description 128
- 150000003432 sterols Chemical class 0.000 title claims abstract description 92
- 239000000203 mixture Substances 0.000 title claims abstract description 80
- 239000004166 Lanolin Substances 0.000 claims abstract description 75
- 229940039717 lanolin Drugs 0.000 claims abstract description 75
- 235000019388 lanolin Nutrition 0.000 claims abstract description 75
- -1 sterol ester Chemical class 0.000 claims description 65
- 239000002689 soil Substances 0.000 claims description 45
- 239000000463 material Substances 0.000 claims description 29
- 239000000126 substance Substances 0.000 claims description 28
- 125000000217 alkyl group Chemical group 0.000 claims description 16
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 claims description 16
- 125000003545 alkoxy group Chemical group 0.000 claims description 11
- 150000002148 esters Chemical class 0.000 claims description 11
- LGJMUZUPVCAVPU-UHFFFAOYSA-N beta-Sitostanol Natural products C1CC2CC(O)CCC2(C)C2C1C1CCC(C(C)CCC(CC)C(C)C)C1(C)CC2 LGJMUZUPVCAVPU-UHFFFAOYSA-N 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- 239000001257 hydrogen Substances 0.000 claims description 9
- 125000005375 organosiloxane group Chemical group 0.000 claims description 9
- 235000012000 cholesterol Nutrition 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- OILXMJHPFNGGTO-UHFFFAOYSA-N (22E)-(24xi)-24-methylcholesta-5,22-dien-3beta-ol Natural products C1C=C2CC(O)CCC2(C)C2C1C1CCC(C(C)C=CC(C)C(C)C)C1(C)CC2 OILXMJHPFNGGTO-UHFFFAOYSA-N 0.000 claims description 7
- BQPPJGMMIYJVBR-UHFFFAOYSA-N (10S)-3c-Acetoxy-4.4.10r.13c.14t-pentamethyl-17c-((R)-1.5-dimethyl-hexen-(4)-yl)-(5tH)-Delta8-tetradecahydro-1H-cyclopenta[a]phenanthren Natural products CC12CCC(OC(C)=O)C(C)(C)C1CCC1=C2CCC2(C)C(C(CCC=C(C)C)C)CCC21C BQPPJGMMIYJVBR-UHFFFAOYSA-N 0.000 claims description 6
- CHGIKSSZNBCNDW-UHFFFAOYSA-N (3beta,5alpha)-4,4-Dimethylcholesta-8,24-dien-3-ol Natural products CC12CCC(O)C(C)(C)C1CCC1=C2CCC2(C)C(C(CCC=C(C)C)C)CCC21 CHGIKSSZNBCNDW-UHFFFAOYSA-N 0.000 claims description 6
- XYTLYKGXLMKYMV-UHFFFAOYSA-N 14alpha-methylzymosterol Natural products CC12CCC(O)CC1CCC1=C2CCC2(C)C(C(CCC=C(C)C)C)CCC21C XYTLYKGXLMKYMV-UHFFFAOYSA-N 0.000 claims description 6
- FPTJELQXIUUCEY-UHFFFAOYSA-N 3beta-Hydroxy-lanostan Natural products C1CC2C(C)(C)C(O)CCC2(C)C2C1C1(C)CCC(C(C)CCCC(C)C)C1(C)CC2 FPTJELQXIUUCEY-UHFFFAOYSA-N 0.000 claims description 6
- OQMZNAMGEHIHNN-UHFFFAOYSA-N 7-Dehydrostigmasterol Natural products C1C(O)CCC2(C)C(CCC3(C(C(C)C=CC(CC)C(C)C)CCC33)C)C3=CC=C21 OQMZNAMGEHIHNN-UHFFFAOYSA-N 0.000 claims description 6
- BKLIAINBCQPSOV-UHFFFAOYSA-N Gluanol Natural products CC(C)CC=CC(C)C1CCC2(C)C3=C(CCC12C)C4(C)CCC(O)C(C)(C)C4CC3 BKLIAINBCQPSOV-UHFFFAOYSA-N 0.000 claims description 6
- LOPKHWOTGJIQLC-UHFFFAOYSA-N Lanosterol Natural products CC(CCC=C(C)C)C1CCC2(C)C3=C(CCC12C)C4(C)CCC(C)(O)C(C)(C)C4CC3 LOPKHWOTGJIQLC-UHFFFAOYSA-N 0.000 claims description 6
- CAHGCLMLTWQZNJ-UHFFFAOYSA-N Nerifoliol Natural products CC12CCC(O)C(C)(C)C1CCC1=C2CCC2(C)C(C(CCC=C(C)C)C)CCC21C CAHGCLMLTWQZNJ-UHFFFAOYSA-N 0.000 claims description 6
- QBSJHOGDIUQWTH-UHFFFAOYSA-N dihydrolanosterol Natural products CC(C)CCCC(C)C1CCC2(C)C3=C(CCC12C)C4(C)CCC(C)(O)C(C)(C)C4CC3 QBSJHOGDIUQWTH-UHFFFAOYSA-N 0.000 claims description 6
- CAHGCLMLTWQZNJ-RGEKOYMOSA-N lanosterol Chemical compound C([C@]12C)C[C@@H](O)C(C)(C)[C@H]1CCC1=C2CC[C@]2(C)[C@H]([C@H](CCC=C(C)C)C)CC[C@@]21C CAHGCLMLTWQZNJ-RGEKOYMOSA-N 0.000 claims description 6
- 229940058690 lanosterol Drugs 0.000 claims description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
- NLQLSVXGSXCXFE-UHFFFAOYSA-N sitosterol Natural products CC=C(/CCC(C)C1CC2C3=CCC4C(C)C(O)CCC4(C)C3CCC2(C)C1)C(C)C NLQLSVXGSXCXFE-UHFFFAOYSA-N 0.000 claims description 6
- KZJWDPNRJALLNS-VPUBHVLGSA-N (-)-beta-Sitosterol Natural products O[C@@H]1CC=2[C@@](C)([C@@H]3[C@H]([C@H]4[C@@](C)([C@H]([C@H](CC[C@@H](C(C)C)CC)C)CC4)CC3)CC=2)CC1 KZJWDPNRJALLNS-VPUBHVLGSA-N 0.000 claims description 5
- CSVWWLUMXNHWSU-UHFFFAOYSA-N (22E)-(24xi)-24-ethyl-5alpha-cholest-22-en-3beta-ol Natural products C1CC2CC(O)CCC2(C)C2C1C1CCC(C(C)C=CC(CC)C(C)C)C1(C)CC2 CSVWWLUMXNHWSU-UHFFFAOYSA-N 0.000 claims description 5
- ZBFPGLKEWSMWSG-BQNIITSRSA-N (3S,5R,10S,13R,14R,17R)-4,4,10,13,14-pentamethyl-17-[(2R)-6-methylhept-5-en-2-yl]-2,3,5,6,12,15,16,17-octahydro-1H-cyclopenta[a]phenanthren-3-ol Chemical compound CC1(C)[C@@H](O)CC[C@]2(C)C3=CC[C@]4(C)[C@@H]([C@@H](CCC=C(C)C)C)CC[C@@]4(C)C3=CC[C@H]21 ZBFPGLKEWSMWSG-BQNIITSRSA-N 0.000 claims description 5
- KLEXDBGYSOIREE-UHFFFAOYSA-N 24xi-n-propylcholesterol Natural products C1C=C2CC(O)CCC2(C)C2C1C1CCC(C(C)CCC(CCC)C(C)C)C1(C)CC2 KLEXDBGYSOIREE-UHFFFAOYSA-N 0.000 claims description 5
- XZEUYTKSAYNYPK-UHFFFAOYSA-N 3beta-29-Norcycloart-24-en-3-ol Natural products C1CC2(C)C(C(CCC=C(C)C)C)CCC2(C)C2CCC3C(C)C(O)CCC33C21C3 XZEUYTKSAYNYPK-UHFFFAOYSA-N 0.000 claims description 5
- SGNBVLSWZMBQTH-FGAXOLDCSA-N Campesterol Natural products O[C@@H]1CC=2[C@@](C)([C@@H]3[C@H]([C@H]4[C@@](C)([C@H]([C@H](CC[C@H](C(C)C)C)C)CC4)CC3)CC=2)CC1 SGNBVLSWZMBQTH-FGAXOLDCSA-N 0.000 claims description 5
- LPZCCMIISIBREI-MTFRKTCUSA-N Citrostadienol Natural products CC=C(CC[C@@H](C)[C@H]1CC[C@H]2C3=CC[C@H]4[C@H](C)[C@@H](O)CC[C@]4(C)[C@H]3CC[C@]12C)C(C)C LPZCCMIISIBREI-MTFRKTCUSA-N 0.000 claims description 5
- RRTBTJPVUGMUNR-UHFFFAOYSA-N Cycloartanol Natural products C12CCC(C(C(O)CC3)(C)C)C3C2(CC)CCC2(C)C1(C)CCC2C(C)CCCC(C)C RRTBTJPVUGMUNR-UHFFFAOYSA-N 0.000 claims description 5
- ARVGMISWLZPBCH-UHFFFAOYSA-N Dehydro-beta-sitosterol Natural products C1C(O)CCC2(C)C(CCC3(C(C(C)CCC(CC)C(C)C)CCC33)C)C3=CC=C21 ARVGMISWLZPBCH-UHFFFAOYSA-N 0.000 claims description 5
- BTEISVKTSQLKST-UHFFFAOYSA-N Haliclonasterol Natural products CC(C=CC(C)C(C)(C)C)C1CCC2C3=CC=C4CC(O)CCC4(C)C3CCC12C BTEISVKTSQLKST-UHFFFAOYSA-N 0.000 claims description 5
- HVXLSFNCWWWDPA-UHFFFAOYSA-N Isocycloartenol Natural products C1CC(O)C(C)(C)C2C31CC13CCC3(C)C(C(CCCC(C)=C)C)CCC3(C)C1CC2 HVXLSFNCWWWDPA-UHFFFAOYSA-N 0.000 claims description 5
- HXQRIQXPGMPSRW-UHZRDUGNSA-N Pollinastanol Natural products O[C@@H]1C[C@H]2[C@@]3([C@]4([C@H]([C@@]5(C)[C@@](C)([C@H]([C@H](CCCC(C)C)C)CC5)CC4)CC2)C3)CC1 HXQRIQXPGMPSRW-UHZRDUGNSA-N 0.000 claims description 5
- HZYXFRGVBOPPNZ-UHFFFAOYSA-N UNPD88870 Natural products C1C=C2CC(O)CCC2(C)C2C1C1CCC(C(C)=CCC(CC)C(C)C)C1(C)CC2 HZYXFRGVBOPPNZ-UHFFFAOYSA-N 0.000 claims description 5
- ZBFPGLKEWSMWSG-UHFFFAOYSA-N agnosterone Natural products CC1(C)C(O)CCC2(C)C3=CCC4(C)C(C(CCC=C(C)C)C)CCC4(C)C3=CCC21 ZBFPGLKEWSMWSG-UHFFFAOYSA-N 0.000 claims description 5
- MJVXAPPOFPTTCA-UHFFFAOYSA-N beta-Sistosterol Natural products CCC(CCC(C)C1CCC2C3CC=C4C(C)C(O)CCC4(C)C3CCC12C)C(C)C MJVXAPPOFPTTCA-UHFFFAOYSA-N 0.000 claims description 5
- NJKOMDUNNDKEAI-UHFFFAOYSA-N beta-sitosterol Natural products CCC(CCC(C)C1CCC2(C)C3CC=C4CC(O)CCC4C3CCC12C)C(C)C NJKOMDUNNDKEAI-UHFFFAOYSA-N 0.000 claims description 5
- SGNBVLSWZMBQTH-PODYLUTMSA-N campesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CC[C@@H](C)C(C)C)[C@@]1(C)CC2 SGNBVLSWZMBQTH-PODYLUTMSA-N 0.000 claims description 5
- 235000000431 campesterol Nutrition 0.000 claims description 5
- ONQRKEUAIJMULO-YBXTVTTCSA-N cycloartenol Chemical compound CC(C)([C@@H](O)CC1)[C@H]2[C@@]31C[C@@]13CC[C@]3(C)[C@@H]([C@@H](CCC=C(C)C)C)CC[C@@]3(C)[C@@H]1CC2 ONQRKEUAIJMULO-YBXTVTTCSA-N 0.000 claims description 5
- YNBJLDSWFGUFRT-UHFFFAOYSA-N cycloartenol Natural products CC(CCC=C(C)C)C1CCC2(C)C1(C)CCC34CC35CCC(O)C(C)(C)C5CCC24C YNBJLDSWFGUFRT-UHFFFAOYSA-N 0.000 claims description 5
- FODTZLFLDFKIQH-UHFFFAOYSA-N cycloartenol trans-ferulate Natural products C1=C(O)C(OC)=CC(C=CC(=O)OC2C(C3CCC4C5(C)CCC(C5(C)CCC54CC53CC2)C(C)CCC=C(C)C)(C)C)=C1 FODTZLFLDFKIQH-UHFFFAOYSA-N 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- KZJWDPNRJALLNS-VJSFXXLFSA-N sitosterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CC[C@@H](CC)C(C)C)[C@@]1(C)CC2 KZJWDPNRJALLNS-VJSFXXLFSA-N 0.000 claims description 5
- 235000015500 sitosterol Nutrition 0.000 claims description 5
- 229950005143 sitosterol Drugs 0.000 claims description 5
- HCXVJBMSMIARIN-PHZDYDNGSA-N stigmasterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)/C=C/[C@@H](CC)C(C)C)[C@@]1(C)CC2 HCXVJBMSMIARIN-PHZDYDNGSA-N 0.000 claims description 5
- 235000016831 stigmasterol Nutrition 0.000 claims description 5
- 229940032091 stigmasterol Drugs 0.000 claims description 5
- BFDNMXAIBMJLBB-UHFFFAOYSA-N stigmasterol Natural products CCC(C=CC(C)C1CCCC2C3CC=C4CC(O)CCC4(C)C3CCC12C)C(C)C BFDNMXAIBMJLBB-UHFFFAOYSA-N 0.000 claims description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- MBZYKEVPFYHDOH-BQNIITSRSA-N 24,25-dihydrolanosterol Chemical compound C([C@@]12C)C[C@H](O)C(C)(C)[C@@H]1CCC1=C2CC[C@]2(C)[C@@H]([C@H](C)CCCC(C)C)CC[C@]21C MBZYKEVPFYHDOH-BQNIITSRSA-N 0.000 claims description 2
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 229920001971 elastomer Polymers 0.000 abstract description 7
- 239000000806 elastomer Substances 0.000 abstract description 4
- 230000003373 anti-fouling effect Effects 0.000 description 32
- 239000008199 coating composition Substances 0.000 description 28
- 239000011248 coating agent Substances 0.000 description 23
- 238000000576 coating method Methods 0.000 description 23
- 239000003921 oil Substances 0.000 description 20
- 235000019198 oils Nutrition 0.000 description 20
- 229920001296 polysiloxane Polymers 0.000 description 19
- 239000003973 paint Substances 0.000 description 18
- 239000003795 chemical substances by application Substances 0.000 description 15
- 229920005989 resin Polymers 0.000 description 14
- 239000011347 resin Substances 0.000 description 14
- 229910052799 carbon Inorganic materials 0.000 description 13
- 239000007788 liquid Substances 0.000 description 11
- 238000012360 testing method Methods 0.000 description 10
- 230000037452 priming Effects 0.000 description 9
- 239000003139 biocide Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 150000001721 carbon Chemical group 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- 241000196324 Embryophyta Species 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- 238000007046 ethoxylation reaction Methods 0.000 description 6
- 238000012986 modification Methods 0.000 description 6
- 230000004048 modification Effects 0.000 description 6
- 239000000049 pigment Substances 0.000 description 6
- 239000000945 filler Substances 0.000 description 5
- 229920002313 fluoropolymer Polymers 0.000 description 5
- 235000015112 vegetable and seed oil Nutrition 0.000 description 5
- FFWSICBKRCICMR-UHFFFAOYSA-N 5-methyl-2-hexanone Chemical compound CC(C)CCC(C)=O FFWSICBKRCICMR-UHFFFAOYSA-N 0.000 description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 4
- 230000032683 aging Effects 0.000 description 4
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000004811 fluoropolymer Substances 0.000 description 4
- 238000001640 fractional crystallisation Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- XMTQQYYKAHVGBJ-UHFFFAOYSA-N 3-(3,4-DICHLOROPHENYL)-1,1-DIMETHYLUREA Chemical compound CN(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XMTQQYYKAHVGBJ-UHFFFAOYSA-N 0.000 description 3
- 239000005660 Abamectin Substances 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 239000005870 Ziram Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 125000002252 acyl group Chemical group 0.000 description 3
- 230000003115 biocidal effect Effects 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
- 229920001083 polybutene Polymers 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229920005992 thermoplastic resin Polymers 0.000 description 3
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 3
- OSELKOCHBMDKEJ-UHFFFAOYSA-N (10R)-3c-Hydroxy-10r.13c-dimethyl-17c-((R)-1-methyl-4-isopropyl-hexen-(4c)-yl)-(8cH.9tH.14tH)-Delta5-tetradecahydro-1H-cyclopenta[a]phenanthren Natural products C1C=C2CC(O)CCC2(C)C2C1C1CCC(C(C)CCC(=CC)C(C)C)C1(C)CC2 OSELKOCHBMDKEJ-UHFFFAOYSA-N 0.000 description 2
- MCWVPSBQQXUCTB-UHFFFAOYSA-N (24Z)-5alpha-Stigmasta-7,24(28)-dien-3beta-ol Natural products C1C(O)CCC2(C)C(CCC3(C(C(C)CCC(=CC)C(C)C)CCC33)C)C3=CCC21 MCWVPSBQQXUCTB-UHFFFAOYSA-N 0.000 description 2
- AZSNMRSAGSSBNP-UHFFFAOYSA-N 22,23-dihydroavermectin B1a Natural products C1CC(C)C(C(C)CC)OC21OC(CC=C(C)C(OC1OC(C)C(OC3OC(C)C(O)C(OC)C3)C(OC)C1)C(C)C=CC=C1C3(C(C(=O)O4)C=C(C)C(O)C3OC1)O)CC4C2 AZSNMRSAGSSBNP-UHFFFAOYSA-N 0.000 description 2
- XUGISPSHIFXEHZ-UHFFFAOYSA-N 3beta-acetoxy-cholest-5-ene Natural products C1C=C2CC(OC(C)=O)CCC2(C)C2C1C1CCC(C(C)CCCC(C)C)C1(C)CC2 XUGISPSHIFXEHZ-UHFFFAOYSA-N 0.000 description 2
- YEYCQJVCAMFWCO-UHFFFAOYSA-N 3beta-cholesteryl formate Natural products C1C=C2CC(OC=O)CCC2(C)C2C1C1CCC(C(C)CCCC(C)C)C1(C)CC2 YEYCQJVCAMFWCO-UHFFFAOYSA-N 0.000 description 2
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 description 2
- SPBDXSGPUHCETR-JFUDTMANSA-N 8883yp2r6d Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O[C@@H]([C@@H](C)CC4)C(C)C)O3)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1C[C@H](C)[C@@H]([C@@H](C)CC)O[C@@]21O[C@H](C\C=C(C)\[C@@H](O[C@@H]1O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C1)[C@@H](C)\C=C\C=C/1[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\1)O)C[C@H]4C2 SPBDXSGPUHCETR-JFUDTMANSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 2
- 239000005510 Diuron Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 2
- 241000237852 Mollusca Species 0.000 description 2
- 229920000459 Nitrile rubber Polymers 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 235000019498 Walnut oil Nutrition 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 239000011717 all-trans-retinol Substances 0.000 description 2
- 235000019169 all-trans-retinol Nutrition 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 125000003368 amide group Chemical group 0.000 description 2
- MCWVPSBQQXUCTB-OQTIOYDCSA-N avenasterol Chemical compound C1[C@@H](O)CC[C@]2(C)[C@@H](CC[C@@]3([C@@H]([C@H](C)CC/C(=C/C)C(C)C)CC[C@H]33)C)C3=CC[C@H]21 MCWVPSBQQXUCTB-OQTIOYDCSA-N 0.000 description 2
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical group [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- XUGISPSHIFXEHZ-VEVYEIKRSA-N cholesteryl acetate Chemical compound C1C=C2C[C@@H](OC(C)=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 XUGISPSHIFXEHZ-VEVYEIKRSA-N 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 2
- WURGXGVFSMYFCG-UHFFFAOYSA-N dichlofluanid Chemical compound CN(C)S(=O)(=O)N(SC(F)(Cl)Cl)C1=CC=CC=C1 WURGXGVFSMYFCG-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- PYZSVQVRHDXQSL-UHFFFAOYSA-N dithianon Chemical compound S1C(C#N)=C(C#N)SC2=C1C(=O)C1=CC=CC=C1C2=O PYZSVQVRHDXQSL-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 125000004185 ester group Chemical group 0.000 description 2
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 2
- 238000007667 floating Methods 0.000 description 2
- 229910021485 fumed silica Inorganic materials 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- GWVMLCQWXVFZCN-UHFFFAOYSA-N isoindoline Chemical compound C1=CC=C2CNCC2=C1 GWVMLCQWXVFZCN-UHFFFAOYSA-N 0.000 description 2
- 229960002418 ivermectin Drugs 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229940043265 methyl isobutyl ketone Drugs 0.000 description 2
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 2
- 125000002524 organometallic group Chemical group 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 210000000582 semen Anatomy 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 230000035882 stress Effects 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 2
- HYVWIQDYBVKITD-UHFFFAOYSA-N tolylfluanid Chemical compound CN(C)S(=O)(=O)N(SC(F)(Cl)Cl)C1=CC=C(C)C=C1 HYVWIQDYBVKITD-UHFFFAOYSA-N 0.000 description 2
- 150000003648 triterpenes Chemical class 0.000 description 2
- 239000002966 varnish Substances 0.000 description 2
- QYSXJUFSXHHAJI-YRZJJWOYSA-N vitamin D3 Chemical compound C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)CCCC(C)C)=C\C=C1\C[C@@H](O)CCC1=C QYSXJUFSXHHAJI-YRZJJWOYSA-N 0.000 description 2
- 239000008170 walnut oil Substances 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- 150000003751 zinc Chemical class 0.000 description 2
- RQOCXCFLRBRBCS-UHFFFAOYSA-N (22E)-cholesta-5,7,22-trien-3beta-ol Natural products C1C(O)CCC2(C)C(CCC3(C(C(C)C=CCC(C)C)CCC33)C)C3=CC=C21 RQOCXCFLRBRBCS-UHFFFAOYSA-N 0.000 description 1
- IZVFFXVYBHFIHY-UHFFFAOYSA-N (3alpha, 5alpha)-Cholest-7-en-3-ol, 9CI Natural products C1C(O)CCC2(C)C(CCC3(C(C(C)CCCC(C)C)CCC33)C)C3=CCC21 IZVFFXVYBHFIHY-UHFFFAOYSA-N 0.000 description 1
- QYIXCDOBOSTCEI-QCYZZNICSA-N (5alpha)-cholestan-3beta-ol Chemical compound C([C@@H]1CC2)[C@@H](O)CC[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@H]([C@H](C)CCCC(C)C)[C@@]2(C)CC1 QYIXCDOBOSTCEI-QCYZZNICSA-N 0.000 description 1
- VADOODYHZOZZPH-UHFFFAOYSA-N 1,3,4,5-tetrachlorocyclohexa-3,5-diene-1,2-dicarbonitrile Chemical compound ClC1=CC(Cl)(C#N)C(C#N)C(Cl)=C1Cl VADOODYHZOZZPH-UHFFFAOYSA-N 0.000 description 1
- VHZJMAJCUAWIHV-UHFFFAOYSA-N 1-(2,4,6-trichlorophenyl)pyrrole-2,5-dione Chemical compound ClC1=CC(Cl)=CC(Cl)=C1N1C(=O)C=CC1=O VHZJMAJCUAWIHV-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- QPPOABGLLLVLBF-UHFFFAOYSA-N 2-(dithiocarboxyamino)ethylcarbamodithioic acid;manganese Chemical compound [Mn].SC(=S)NCCNC(S)=S QPPOABGLLLVLBF-UHFFFAOYSA-N 0.000 description 1
- RGALBBQJPFDFCB-UHFFFAOYSA-N 2-(dithiocarboxyamino)ethylcarbamodithioic acid;zinc Chemical compound [Zn].SC(=S)NCCNC([S-])=[SH+] RGALBBQJPFDFCB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229940099451 3-iodo-2-propynylbutylcarbamate Drugs 0.000 description 1
- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 description 1
- ULVDMKRXBIKOMK-UHFFFAOYSA-N 4,5,6,7-tetrachloro-2,3-dihydroisoindol-1-one Chemical compound ClC1=C(Cl)C(Cl)=C2CNC(=O)C2=C1Cl ULVDMKRXBIKOMK-UHFFFAOYSA-N 0.000 description 1
- AOUHFEIUEQRKFF-UHFFFAOYSA-N 4,5-dioctyl-1,2-thiazol-3-one Chemical class C(CCCCCCC)C1=C(C(NS1)=O)CCCCCCCC AOUHFEIUEQRKFF-UHFFFAOYSA-N 0.000 description 1
- IZVFFXVYBHFIHY-SKCNUYALSA-N 5alpha-cholest-7-en-3beta-ol Chemical compound C1[C@@H](O)CC[C@]2(C)[C@@H](CC[C@@]3([C@@H]([C@H](C)CCCC(C)C)CC[C@H]33)C)C3=CC[C@H]21 IZVFFXVYBHFIHY-SKCNUYALSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- 244000144725 Amygdalus communis Species 0.000 description 1
- 235000011437 Amygdalus communis Nutrition 0.000 description 1
- 235000014698 Brassica juncea var multisecta Nutrition 0.000 description 1
- 235000006008 Brassica napus var napus Nutrition 0.000 description 1
- 235000006618 Brassica rapa subsp oleifera Nutrition 0.000 description 1
- 244000188595 Brassica sinapistrum Species 0.000 description 1
- 235000004977 Brassica sinapistrum Nutrition 0.000 description 1
- OILXMJHPFNGGTO-NRHJOKMGSA-N Brassicasterol Natural products O[C@@H]1CC=2[C@@](C)([C@@H]3[C@H]([C@H]4[C@](C)([C@H]([C@@H](/C=C/[C@H](C(C)C)C)C)CC4)CC3)CC=2)CC1 OILXMJHPFNGGTO-NRHJOKMGSA-N 0.000 description 1
- 229910000906 Bronze Inorganic materials 0.000 description 1
- VVZAYGACXHYHMZ-UHFFFAOYSA-N C(CCC)[Sn]CCCC.C(C)C(=O)C(=O)C Chemical compound C(CCC)[Sn]CCCC.C(C)C(=O)C(=O)C VVZAYGACXHYHMZ-UHFFFAOYSA-N 0.000 description 1
- 241000238586 Cirripedia Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910000570 Cupronickel Inorganic materials 0.000 description 1
- UCTLRSWJYQTBFZ-UHFFFAOYSA-N Dehydrocholesterol Natural products C1C(O)CCC2(C)C(CCC3(C(C(C)CCCC(C)C)CCC33)C)C3=CC=C21 UCTLRSWJYQTBFZ-UHFFFAOYSA-N 0.000 description 1
- BDCFUHIWJODVNG-UHFFFAOYSA-N Desmosterol Natural products C1C=C2CC(O)C=CC2(C)C2C1C1CCC(C(C)CCC(CC)C(C)C)C1(C)CC2 BDCFUHIWJODVNG-UHFFFAOYSA-N 0.000 description 1
- JGFDZZLUDWMUQH-UHFFFAOYSA-N Didecyldimethylammonium Chemical compound CCCCCCCCCC[N+](C)(C)CCCCCCCCCC JGFDZZLUDWMUQH-UHFFFAOYSA-N 0.000 description 1
- 241000790917 Dioxys <bee> Species 0.000 description 1
- 239000005764 Dithianon Substances 0.000 description 1
- DNVPQKQSNYMLRS-NXVQYWJNSA-N Ergosterol Natural products CC(C)[C@@H](C)C=C[C@H](C)[C@H]1CC[C@H]2C3=CC=C4C[C@@H](O)CC[C@]4(C)[C@@H]3CC[C@]12C DNVPQKQSNYMLRS-NXVQYWJNSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- VHOQXEIFYTTXJU-UHFFFAOYSA-N Isobutylene-isoprene copolymer Chemical group CC(C)=C.CC(=C)C=C VHOQXEIFYTTXJU-UHFFFAOYSA-N 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- 239000005802 Mancozeb Substances 0.000 description 1
- 241000237536 Mytilus edulis Species 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- UYSRSLSTXYYNEW-UHFFFAOYSA-N NS(=O)(=O)S(O)(=O)=O Chemical compound NS(=O)(=O)S(O)(=O)=O UYSRSLSTXYYNEW-UHFFFAOYSA-N 0.000 description 1
- 241000219925 Oenothera Species 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 235000019483 Peanut oil Nutrition 0.000 description 1
- 229920006169 Perfluoroelastomer Polymers 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004696 Poly ether ether ketone Substances 0.000 description 1
- 229920002614 Polyether block amide Polymers 0.000 description 1
- 239000004695 Polyether sulfone Substances 0.000 description 1
- 239000004697 Polyetherimide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 229910004283 SiO 4 Inorganic materials 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 235000019486 Sunflower oil Nutrition 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- GCTFWCDSFPMHHS-UHFFFAOYSA-M Tributyltin chloride Chemical compound CCCC[Sn](Cl)(CCCC)CCCC GCTFWCDSFPMHHS-UHFFFAOYSA-M 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- OILXMJHPFNGGTO-ZRUUVFCLSA-N UNPD197407 Natural products C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)C=C[C@H](C)C(C)C)[C@@]1(C)CC2 OILXMJHPFNGGTO-ZRUUVFCLSA-N 0.000 description 1
- 208000036142 Viral infection Diseases 0.000 description 1
- QYSXJUFSXHHAJI-XFEUOLMDSA-N Vitamin D3 Natural products C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)CCCC(C)C)=C/C=C1\C[C@@H](O)CCC1=C QYSXJUFSXHHAJI-XFEUOLMDSA-N 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- 229950008167 abamectin Drugs 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- LCJHLOJKAAQLQW-UHFFFAOYSA-N acetic acid;ethane Chemical compound CC.CC(O)=O LCJHLOJKAAQLQW-UHFFFAOYSA-N 0.000 description 1
- WETWJCDKMRHUPV-UHFFFAOYSA-N acetyl chloride Chemical compound CC(Cl)=O WETWJCDKMRHUPV-UHFFFAOYSA-N 0.000 description 1
- 239000012346 acetyl chloride Substances 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 150000001263 acyl chlorides Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000003302 alkenyloxy group Chemical group 0.000 description 1
- 125000001118 alkylidene group Chemical group 0.000 description 1
- QYIXCDOBOSTCEI-UHFFFAOYSA-N alpha-cholestanol Natural products C1CC2CC(O)CCC2(C)C2C1C1CCC(C(C)CCCC(C)C)C1(C)CC2 QYIXCDOBOSTCEI-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229940115440 aluminum sodium silicate Drugs 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- GHPGOEFPKIHBNM-UHFFFAOYSA-N antimony(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Sb+3].[Sb+3] GHPGOEFPKIHBNM-UHFFFAOYSA-N 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- MYONAGGJKCJOBT-UHFFFAOYSA-N benzimidazol-2-one Chemical compound C1=CC=CC2=NC(=O)N=C21 MYONAGGJKCJOBT-UHFFFAOYSA-N 0.000 description 1
- XKXHCNPAFAXVRZ-UHFFFAOYSA-N benzylazanium;chloride Chemical compound [Cl-].[NH3+]CC1=CC=CC=C1 XKXHCNPAFAXVRZ-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 235000021324 borage oil Nutrition 0.000 description 1
- 229910000085 borane Inorganic materials 0.000 description 1
- OILXMJHPFNGGTO-ZAUYPBDWSA-N brassicasterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)/C=C/[C@H](C)C(C)C)[C@@]1(C)CC2 OILXMJHPFNGGTO-ZAUYPBDWSA-N 0.000 description 1
- 235000004420 brassicasterol Nutrition 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- VIHAEDVKXSOUAT-UHFFFAOYSA-N but-2-en-4-olide Chemical class O=C1OCC=C1 VIHAEDVKXSOUAT-UHFFFAOYSA-N 0.000 description 1
- RHDGNLCLDBVESU-UHFFFAOYSA-N but-3-en-4-olide Chemical compound O=C1CC=CO1 RHDGNLCLDBVESU-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- YKPUWZUDDOIDPM-SOFGYWHQSA-N capsaicin Chemical compound COC1=CC(CNC(=O)CCCC\C=C\C(C)C)=CC=C1O YKPUWZUDDOIDPM-SOFGYWHQSA-N 0.000 description 1
- 229960002504 capsaicin Drugs 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000010073 coating (rubber) Methods 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229940116318 copper carbonate Drugs 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- QHNCWVQDOPICKC-UHFFFAOYSA-N copper;1-hydroxypyridine-2-thione Chemical compound [Cu].ON1C=CC=CC1=S.ON1C=CC=CC1=S QHNCWVQDOPICKC-UHFFFAOYSA-N 0.000 description 1
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 description 1
- LBJNMUFDOHXDFG-UHFFFAOYSA-N copper;hydrate Chemical compound O.[Cu].[Cu] LBJNMUFDOHXDFG-UHFFFAOYSA-N 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 229960003280 cupric chloride Drugs 0.000 description 1
- 229960004643 cupric oxide Drugs 0.000 description 1
- NMCCNOZOBBWFMN-UHFFFAOYSA-N davicil Chemical compound CS(=O)(=O)C1=C(Cl)C(Cl)=NC(Cl)=C1Cl NMCCNOZOBBWFMN-UHFFFAOYSA-N 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- AVSXSVCZWQODGV-DPAQBDIFSA-N desmosterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@@H](CCC=C(C)C)C)[C@@]1(C)CC2 AVSXSVCZWQODGV-DPAQBDIFSA-N 0.000 description 1
- HRLIOXLXPOHXTA-NSHDSACASA-N dexmedetomidine Chemical compound C1([C@@H](C)C=2C(=C(C)C=CC=2)C)=CN=C[N]1 HRLIOXLXPOHXTA-NSHDSACASA-N 0.000 description 1
- 229960004253 dexmedetomidine Drugs 0.000 description 1
- 229940078672 didecyldimethylammonium Drugs 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- QLFZZSKTJWDQOS-YDBLARSUSA-N doramectin Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C3CCCCC3)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C QLFZZSKTJWDQOS-YDBLARSUSA-N 0.000 description 1
- 229960003997 doramectin Drugs 0.000 description 1
- GCKZANITAMOIAR-XWVCPFKXSA-N dsstox_cid_14566 Chemical compound [O-]C(=O)C1=CC=CC=C1.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H]([NH2+]C)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 GCKZANITAMOIAR-XWVCPFKXSA-N 0.000 description 1
- 239000008393 encapsulating agent Substances 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- DNVPQKQSNYMLRS-SOWFXMKYSA-N ergosterol Chemical compound C1[C@@H](O)CC[C@]2(C)[C@H](CC[C@]3([C@H]([C@H](C)/C=C/[C@@H](C)C(C)C)CC[C@H]33)C)C3=CC=C21 DNVPQKQSNYMLRS-SOWFXMKYSA-N 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 235000019439 ethyl acetate Nutrition 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229920001973 fluoroelastomer Polymers 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229920001002 functional polymer Polymers 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 229920005555 halobutyl Polymers 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 1
- 238000006459 hydrosilylation reaction Methods 0.000 description 1
- 229920002681 hypalon Polymers 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 235000019239 indanthrene blue RS Nutrition 0.000 description 1
- UHOKSCJSTAHBSO-UHFFFAOYSA-N indanthrone blue Chemical compound C1=CC=C2C(=O)C3=CC=C4NC5=C6C(=O)C7=CC=CC=C7C(=O)C6=CC=C5NC4=C3C(=O)C2=C1 UHOKSCJSTAHBSO-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- FRVCGRDGKAINSV-UHFFFAOYSA-L iron(2+);octadecanoate Chemical compound [Fe+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O FRVCGRDGKAINSV-UHFFFAOYSA-L 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- OOYGSFOGFJDDHP-KMCOLRRFSA-N kanamycin A sulfate Chemical group OS(O)(=O)=O.O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CN)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O[C@@H]2[C@@H]([C@@H](N)[C@H](O)[C@@H](CO)O2)O)[C@H](N)C[C@@H]1N OOYGSFOGFJDDHP-KMCOLRRFSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- VQPKAMAVKYTPLB-UHFFFAOYSA-N lead;octanoic acid Chemical compound [Pb].CCCCCCCC(O)=O VQPKAMAVKYTPLB-UHFFFAOYSA-N 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000003120 macrolide antibiotic agent Substances 0.000 description 1
- HRLIOXLXPOHXTA-UHFFFAOYSA-N medetomidine Chemical compound C=1C=CC(C)=C(C)C=1C(C)C1=CN=C[N]1 HRLIOXLXPOHXTA-UHFFFAOYSA-N 0.000 description 1
- 229960002140 medetomidine Drugs 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000113 methacrylic resin Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 235000020638 mussel Nutrition 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 150000001282 organosilanes Chemical class 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 239000010702 perfluoropolyether Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920002493 poly(chlorotrifluoroethylene) Polymers 0.000 description 1
- 229920001652 poly(etherketoneketone) Polymers 0.000 description 1
- 229920000747 poly(lactic acid) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920006260 polyaryletherketone Polymers 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000005023 polychlorotrifluoroethylene (PCTFE) polymer Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920002530 polyetherether ketone Polymers 0.000 description 1
- 229920001601 polyetherimide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920001470 polyketone Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- WJSXSXUHWBSPEP-UHFFFAOYSA-N pyridine;triphenylborane Chemical compound C1=CC=NC=C1.C1=CC=CC=C1B(C=1C=CC=CC=1)C1=CC=CC=C1 WJSXSXUHWBSPEP-UHFFFAOYSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- AFJYYKSVHJGXSN-KAJWKRCWSA-N selamectin Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1C(/C)=C/C[C@@H](O[C@]2(O[C@@H]([C@@H](C)CC2)C2CCCCC2)C2)C[C@@H]2OC(=O)[C@@H]([C@]23O)C=C(C)C(=N\O)/[C@H]3OC\C2=C/C=C/[C@@H]1C AFJYYKSVHJGXSN-KAJWKRCWSA-N 0.000 description 1
- 229960002245 selamectin Drugs 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 description 1
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 239000000429 sodium aluminium silicate Substances 0.000 description 1
- 235000012217 sodium aluminium silicate Nutrition 0.000 description 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 125000002328 sterol group Chemical group 0.000 description 1
- 229920000638 styrene acrylonitrile Polymers 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 239000004308 thiabendazole Substances 0.000 description 1
- 235000010296 thiabendazole Nutrition 0.000 description 1
- WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 description 1
- 229960004546 thiabendazole Drugs 0.000 description 1
- 239000010496 thistle oil Substances 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- XNFIRYXKTXAHAC-UHFFFAOYSA-N tralopyril Chemical compound BrC1=C(C(F)(F)F)NC(C=2C=CC(Cl)=CC=2)=C1C#N XNFIRYXKTXAHAC-UHFFFAOYSA-N 0.000 description 1
- 125000004953 trihalomethyl group Chemical group 0.000 description 1
- UORVGPXVDQYIDP-UHFFFAOYSA-N trihydridoboron Substances B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 1
- 238000007039 two-step reaction Methods 0.000 description 1
- 235000005282 vitamin D3 Nutrition 0.000 description 1
- 239000011647 vitamin D3 Substances 0.000 description 1
- 229940021056 vitamin d3 Drugs 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229940043810 zinc pyrithione Drugs 0.000 description 1
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 description 1
- CHNQZRKUZPNOOH-UHFFFAOYSA-J zinc;manganese(2+);n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[Zn+2].[S-]C(=S)NCCNC([S-])=S.[S-]C(=S)NCCNC([S-])=S CHNQZRKUZPNOOH-UHFFFAOYSA-J 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
- C09D183/06—Polysiloxanes containing silicon bound to oxygen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1625—Non-macromolecular compounds organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1675—Polyorganosiloxane-containing compositions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Fats And Perfumes (AREA)
Abstract
本发明提供了一种包含弹性体和含甾醇和/或甾醇衍生物的组分的抗污组合物,其中所述组分选自酰化羊毛脂、烷氧基化羊毛脂,或羊毛脂油,或包含至少20重量%的一种或多种甾醇、至少20重量%的一种或多种C1-C12甾醇酯或至少20重量%的烷氧基化甾醇的组合物,其中重量%为所述甾醇或甾醇衍生物对所述组分总重量的百分比。
Description
本发明涉及一种抗污组合物、所述抗污组合物在水生环境中的用途、一种抑制水生环境中结垢的方法以及一种涂覆有所述抗污组合物的基材。
人造结构如船壳、浮标、钻探平台、干船坞设备、采油钻机、水产业设备以及浸于水中的网和管道易被水生生物如绿藻和褐藻、藤壶、蛤贝等污染。该类结构通常为金属的,但也可包含其他结构材料如混凝土。该污垢对船壳造成困扰,因为其提高了在水中运动期间的摩擦阻力,其结果是降低速度并提高燃料成本。其对静态结构如钻探平台的支架、采油气设备、精炼和储存设备造成困扰,首先是因为厚污垢层对波流的阻力可在所述结构中导致不可预测且潜在的危险应力,其次是因为污垢使得难以检查结构缺陷如应力开裂和腐蚀。其对管道如冷却水入口和出口造成困扰,因为有效横截面积因结垢而降低,其结果是降低流动速率。
商业化最成功的抑制结垢的方法涉及使用含有对水生生物具有毒性的物质如氯化三丁基锡或氧化亚铜的防污涂料。然而,由于该类毒素在释放至水生环境中时可能具有的破坏性影响,因此该类涂料越来越不欢迎。因此,需要不会大量释放有毒物质的非污染涂料。
多年来已知聚硅氧烷橡胶涂料可阻止水生生物的污染,例如如GB1,307,001和US3,702,778所公开的那样。据信该类涂料提供生物不能轻易附着的表面,因此其可称为污垢松脱涂料或抗污涂料,而非防污涂料。聚硅氧烷橡胶和聚硅氧烷类化合物通常具有极低的毒性。当施加至船壳上时,该防污体系的缺点在于,尽管海洋生物的累积有所减少,但需要较高的船速以移除所有污垢物种。因此,在一些情况下已显示有必要以至少14节的速度航行,从而有效从用该类聚合物处理的外壳松脱。为此,聚硅氧烷橡胶在商业上的成功有限,且需提高这些环境良性涂料的防污以及污垢松脱性能。
WO02/074870描述了一种具有低表面能和合适弹性性能的替代抗污组合物。该防污组合物包含不含全氟聚醚结构部分的固化或交联的聚合物,以及含有氟化烷基或烷氧基的聚合物或低聚物。发现该抗污组合物由于减少污染生物的聚居和降低其粘附强度而优于其他已知的抗污组合物。
现已发现一种如下抗污组合物具有优异的抗污性能,所述组合物包含弹性体和含甾醇和/或甾醇衍生物的组分,其中所述组分选自酰化羊毛脂、烷氧基化羊毛脂、羊毛脂油或包含至少20重量%的一种或多种甾醇、至少20重量%的一种或多种C1-C12甾醇酯或至少20重量%的烷氧基化甾醇的组合物,其中重量%为所述甾醇或甾醇衍生物对所述组分总重量的百分比。
已发现本发明的组合物具有优于WO02/074870的组合物的抗污性能。
抗污性能可通过测量污染生物聚居的量及其粘附强度而比较。
未改性的羊毛脂是包含一种或多种甾醇和甾醇衍生物的天然产物的实例,但并非本发明抗污组合物的组分。这是因为其未经酰化、烷氧基化或者为油,且不包含超过20重量%的甾醇、超过20重量%的甾醇C1-C12甾醇酯,或超过20重量%的烷氧基化甾醇(基于未改性羊毛脂的总重量)。市售羊毛脂通常包含约97重量%的长链脂肪酯。这些酯大多(>90%)具有超过12个碳原子的脂族尾部。已发现羊毛脂中的甾醇含量在未改性的羊毛脂中存在至多约5重量%。未改性的羊毛脂包含甚至更少的烷氧基化甾醇。
本发明人已发现一种包含与弹性体组合的已通过酰化、烷氧基化改性的羊毛脂或者羊毛脂油(有时称为“液态羊毛脂”)的抗污组合物与使用未改性羊毛脂的相同组合物相比具有更好的抗污性能。
还发现当抗污组合物包含弹性体且包含含至少20重量%的甾醇、其酰化或烷氧基化衍生物(其中重量%为甾醇或甾醇衍生物对该组分总重量的百分比)时,具有优异的抗污性能。因此,所述甾醇或甾醇衍生物并非必须源自经改性的羊毛脂,而是可源自包含该量的甾醇、其酰化或烷氧基化衍生物的其他源。
WO2004/0588552、KR2009068485、US1960252和US2009/0197003公开了各种防污组合物,且提及可将羊毛脂(未改性的)作为许多替代性添加剂之一用于防污组合物中。这些文献中均未教导或启示读者从这些长添加剂列表中选择羊毛脂,更不用说在用于防污组合物中之前对羊毛脂进行改性。
日本专利申请JP2005263975A公开了包含羊毛脂或羊毛脂衍生物的防污漆组合物。其公开了必须使用以制备该防污漆的长树脂列表,但未教导当将特定羊毛脂衍生物与弹性体组合以制备抗污涂料组合物时对抗污性的协同增效效应。事实上,JP2005263975指导读者制备包含较硬的非弹性聚合物—丙烯酸酯树脂的抗污涂料组合物。此外,JP2005263975教导丙烯酸酯树脂应与聚丁烯组合。添加聚丁烯是为了提高漆膜的塑性。
本发明人出乎意料地发现包含“较软”弹性体和特定羊毛脂衍生物的本发明抗污组合物的涂层与JP2005263975所建议并例示的精心设计的较硬且非弹性体涂层相比,具有对宽范围污垢(粘泥污垢、杂草污垢、软质污垢和硬质污垢)的优异抗污性能。
日本专利申请JP201009026A公开了包含羊毛脂或羊毛脂衍生物且无生物杀伤剂的防污漆组合物。其教导所述防污漆必须包含热塑性树脂,且需要该热塑性树脂以增强漆的硬度。公开了大量热塑性树脂,且实施例的涂料组合物包含热塑性石油树脂。因此,JP2005263975A、JP201009026A也教导使用“硬质”树脂,而非本发明组合物所需的“较软”弹性体树脂。出乎意料地发现本发明的抗污组合物形成与JP201009026A所建议并例示的精心设计的较硬涂层相比具有对宽范围污垢(粘泥污垢、杂草污垢、软质污垢和硬质污垢)的优异抗污性能的涂层。
本文所公开的新颖抗污组合物的一个优点在于,由于羊毛脂/甾醇和甾醇衍生物可生物降解,因此预期这些物质在抗污组合物中的使用对海洋和水生环境具有很小的环境影响(若存在的话)。
出乎意料地显示,本发明的污垢松脱涂料组合物在低速度(例如在0-12节)下有效地松脱污垢。
本发明的一个方面涉及一种抗污组合物,其包含弹性体和包含甾醇和/或甾醇衍生物的组分,其中所述组分选自酰化羊毛脂、烷氧基化羊毛脂、羊毛脂油或包含至少20重量%的一种或多种甾醇、至少20重量%的一种或多种C1-C12甾醇酯或至少20重量%的烷氧基化甾醇的组合物,其中重量%为所述甾醇或甾醇衍生物对所述组分总重量的百分比。
甾醇和甾醇酯是三萜系化合物,其为一类衍生自三萜分子的有机分子。本领域已知的是甾醇和甾醇衍生物具有如图1所示的骨架碳结构。
图1所示的甾醇碳骨架可完全饱和,或者可包含烯属不饱和双键。例如,胆甾醇在碳5与6之间具有烯属不饱和双键。甾醇骨架还包含多个手性碳原子;因此甾醇存在不同的异构形式。
甾醇和甾醇衍生物可源自天然来源,如动物和植物。甾醇的实例包括:胆甾醇、羊毛甾醇、羔甾醇、7-脱氢胆甾醇、胆骨化醇、链甾醇、7-烯胆甾烷醇、胆甾烷醇、coprastanol、菜油甾醇、豆甾醇、谷甾醇、燕麦甾醇(avenasterol)、豆甾烯醇、菜子甾醇、4-去甲甾醇(即碳4上无取代基)、4α-单甲基甾醇和4,4-二甲基甾醇、植物甾烷醇(完全饱和)、麦角甾醇、香树素和环阿屯醇(cylcoartenol)。
包含甾醇和甾醇衍生物的种子油的实例包括月见草油、鳄梨油、菜籽油、卡诺拉(canola)油、玉米油、花生油、向日葵油、琉璃苣油、橄榄油、芝麻油、椰油、棉籽油、红花油、棕榈油、核桃油、胡桃油、杏仁油和大豆油。因此,所述抗污组合物中所用的组分可源自种子油,例如上文所述的那些。然而,为了使种子油包含所需量的甾醇、甾醇酯或烷氧基化甾醇,可能必须通过水解(以提高甾醇的量)、酰化(以提高甾醇酯的量)或烷氧基化(以提高烷氧基化甾醇的量)来改性种子油的组成。因此,所述组分可包含水解、酰化或烷氧基化的种子油。
在本发明的一个实施方案中,所述组分包含图1所示的甾醇和/或甾醇衍生物,其中Y选自-OH(甾醇)、-O-(CO)R3(甾醇酯)或-O-R4-(OR5)xOR6(烷氧基化甾醇),其中:
R3为包含1-12个碳原子的支化或直链烷基,且
R4和R5独立地为C2-6亚烷基,
R6为氢或C1-4伯或仲烷基,
X为1-100的整数。
当Y为R3(CO)O-且R3为包含1-12个碳原子的烷基结构部分时,所述甾醇酯在本文中称为C1-C12酰化的甾醇酯。
优选地,R3为直链烷基结构部分。优选地,R3为包含1-5个碳原子的烷基(本文称作“C1-C5酰化的甾醇酯”)或1-3个碳原子的烷基(本文称作“C1-C3酰化的甾醇酯”)。最优选地,R3包含1个碳原子且为CH3-基团。若R3为CH3-基团,则所述甾醇酯在本文中称为乙酰化的甾醇酯。
优选地,R4和R5为亚乙基。
优选地,R6为氢或甲基。
优选地,X为1-80的整数,更优选为1-50,甚至更优选为1-30,最优选为1-15的整数。
所述组分可包含一种或多种甾醇。所述包含一种或多种甾醇的组分可包含至少30重量%、至少40重量%、至少50重量%、至少60重量%、至少70重量%、至少80重量%或至少90重量%的一种或多种甾醇,其中重量%为所述甾醇对该组分总重量的百分比。
所述组分可包含一种或多种甾醇酯。所述包含一种或多种甾醇酯的组分可包含至少30重量%、至少40重量%、至少50重量%、至少60重量%、至少70重量%、至少80重量%或至少90重量%的一种或多种甾醇酯,其中重量%为所述甾醇酯对该组分总重量的百分比。
所述抗污组合物的所述组分中的一种或多种C1-C12甾醇酯可为一种或多种C1-C5酰化的甾醇酯,甚至更优选为一种或多种C1-C3酰化的甾醇酯,最优选为乙酰化的甾醇酯。
所述组分可为酰化的羊毛脂。在一些实施方案中,酰化的羊毛脂可为C1-C12酰化的羊毛脂,例如C1-C5酰化的羊毛脂,最优选为乙酰化的羊毛脂。乙酰化的羊毛脂可进一步改性成油形式(例如通过分级结晶)。
可将包含甾醇和/或甾醇衍生物的组合物(如羊毛脂)酰化以制备用于所述抗污组合物中的组分。所述组合物可通过将其与酰化剂(酸或酰氯/酸酐)混合而直接酰化(一步反应),或者可先水解且随后用酰化剂使随后形成的醇酰化(两步反应)。在这两种反应中,所述组合物中所存在的游离羟基(例如甾醇上的羟基)部分或完全转化成酰酯基。此外,既有的酯基(例如在羊毛脂中大量存在的长链脂肪酸的甾醇酯)部分或完全转化成该酰化剂的相同酰基。例如,如果用乙酰氯或乙酸酐使羊毛脂乙酰化,则游离甾醇和大比例长链脂肪甾醇酯均变为乙酰化的甾醇酯。
对本领域技术人员人员显而易见的是,酰酯的烷基链长度取决于所用的酰化剂。例如,可使用具有包含5个碳原子的酰基的酰化剂(“C5酰化剂”)来制备C5酰化的甾醇酯。
乙酰化的羊毛脂可为商业来源的,例如:Acetylated Lanolin Standard(NK Chemicals)、Acylan(Croda)、Modulan(Lubrizol)、YOFCO AC-25(Nipon Fine Chemical Co.)、RolanACE(Rolex Lanolin Products Limited)和Acetylated Lanolin(Wujiang Xinyi Chemical Co.)。
所述组分可包含烷氧基化的甾醇。所述包含烷氧基化甾醇的组分可包含至少30重量%、至少40重量%、至少50重量%、至少60重量%、至少70重量%、至少80重量%或至少90重量%的一种或多种烷氧基化甾醇,其中重量%为所述甾醇对该组分总重量的百分比。
烷氧基化甾醇可为乙氧基化的甾醇。在一个实施方案中,乙氧基化的甾醇具有图1的结构,其中Y为-O-R4-(OR5)xOR6,R4和R5均为亚乙基。优选地,R6为氢或C1-4伯或仲烷基,如甲基。
所述组分可为烷氧基化的羊毛脂。优选地,聚氧化烯链中的氧化烯单元的数量在1-100之间变化,例如在1-80之间,更优选在1-50之间,更优选在1-30之间,最优选在1-15之间变化。烷氧基化羊毛脂可为包含聚氧化乙烯链的乙氧基化羊毛脂。乙氧基化羊毛脂可具有800-450道尔顿的分子量(MW)。
乙氧基化的羊毛脂可任选溶于水性介质或有机介质中,如二甲苯、三甲基苯、丁醇、甲基异丁基酮和甲基异戊基酮。
乙氧基化的羊毛脂可为商业来源的,例如获自NK Chemicals(PEG-30羊毛脂)。
所述组分可为羊毛脂油(“液态羊毛脂”)。羊毛脂油可通过分级结晶制备。当通过分级结晶对羊毛脂改性时,较低分子量的组分以液体形式收集。较高分子量组分形成固体;这统称为羊毛脂蜡。液体级分的平均分子量取决于分级结晶方法中所用的溶剂。例如,当使用异丙醇萃取时,平均分子量为约360。
就液体而言,我们意指按照ASTM(1996)D4359-90:确定材料为液体或固体的标准测试方法所定义的液体物质,不同之处在于测试是在15℃下进行的,而非在如ASTM方法所规定的38℃下进行。为了测试所述组分是否包含一种或多种甾醇和/或其酯,将接受测试的组分保持在15℃的紧密密闭的罐中。移去盖子并翻转罐子。观察所述物质从罐中的流动以确定其为固体还是液体。将在3分钟内总共流动50mm或更少的物质视为固体。否则将其视为液体。
羊毛脂油可为商业来源的,例如Fluilan(Croda)、EWALAN FL-50(H.Erhard Wagner GmbH)、Lanogene(Lubrizol)、YOFCO Liquid Lanolin(Nipon Fine Chemical Co.)、Liquid Lanolin Standard(NK Chemicals)和RolanOIL(Rolex Lanolin Products Limited)。
所述组分可包含一种或多种如下物质:胆甾醇、羊毛甾醇、羔甾醇和二氢羊毛甾醇、环阿屯醇、菜油甾醇、豆甾醇、谷甾醇、香树素和/或其酯或烷氧基化衍生物。优选地,所述组分包含胆甾醇或羊毛甾醇和/或其酯或烷氧基化衍生物,例如乙酸胆甾醇酯。
在一个实施方案中,所述组分可包含纯或基本上纯的甾醇或其酰化或烷氧基化衍生物。所述组分可为纯或基本上纯的甾醇酯衍生物,或纯的或基本上纯的烷氧基化甾醇衍生物,例如以下甾醇之一的甾醇酯/烷氧基化甾醇衍生物:胆甾醇、羊毛甾醇、环阿屯醇、菜油甾醇、谷甾醇、豆甾醇、香树素或羔甾醇。甾醇或其衍生物并非必须源自羊毛脂。例如,甾醇或甾醇衍生物可源自上文所述的种子油或其他植物或动物来源。
就基本上纯的而言,我们意指所述组分的至少70重量%,优选至少80重量%,更优选至少90重量%为甾醇或其酰化/烷氧基化衍生物,其中重量%为甾醇/甾醇衍生物对该组分总重量的百分比。
特别地,本发明人发现当将包含纯的以及基本上纯的甾醇酯(例如如下甾醇之一的甾醇酯:胆甾醇、羊毛甾醇、环阿屯醇、菜油甾醇、谷甾醇、豆甾醇、香树素或羔甾醇(尤其是甾醇乙酸酯))的组合物用作所述抗污涂料组合物中的所述组分时,出乎意料地具有与其他已知抗污组合物相比的优异抗污性能。
如果所述组分为羊毛脂的改性形式,则其优选为无水的。就无水而言,我们意指羊毛脂包含少于1重量%、0.5重量%、0.2重量%的水。
在本发明的所有实施方案中,所述抗污组合物中的所述组分对所述聚合物的重量比可为约1-30%,优选为1-10%。
用于制备本发明涂料的涂料组合物可包含一种或多种在干燥、固化或交联时形成“弹性体”的聚合物。本文将这些聚合物称为“弹性体”。
就“弹性体”而言,我们意指可干燥、可固化或可交联且当干燥、固化或交联时为呈现出很少的塑性流动、快速且几乎完全从张力回复的橡胶状材料的聚合物。当在室温(25℃)下测试时,干燥、固化或交联的聚合物能拉伸25%(应变速率30mm/分钟),且在拉伸25%、保持5分钟且然后释放之后,能在释放后5分钟内收缩至其原长的10%。伸长率测量可按照ASTMD638-10使用Zwick拉伸试验机和激光伸长仪进行。供测试的空白膜应具有90×15×0.5mm的样品尺寸,其通过ASTM D2370-98第8.2.2部分给定的程序制备。
在所有实施方案中,所述弹性体优选为一种有机硅氧烷聚合物或其混合物。
有机硅烷(在本领域中有时称为含有机硅氧烷的聚合物)为本发明上下文中的弹性体。
优选地,聚有机硅氧烷具有一个或多个,更优选两个或更多个反应性官能团如羟基、烷氧基、乙酰氧基、羧基、氢化硅烷基(hydrosilyl)、胺基、环氧基、乙烯基或肟官能团。
所述含有机硅氧烷的聚合物可包含一般结构-[SiR1R2-O]-的重复单元,其中R1和R2独立地选自含氢、烷基、芳基、芳烷基和乙烯基的结构部分。优选地,R1和R2独立地选自选自C1-C6烷基的烷基、苯基、C1-C6烷基苯基或C1-C6亚烷基。
R1和R2可独立地选自甲基和苯基。或者,所述含有机硅氧烷的聚合物为其中R1和R2均为甲基的聚合物。
例如,可使用可缩合固化的聚二甲基硅氧烷(二羟基官能的),其用原硅酸四乙酯交联(二月桂酸二丁基锡催化)。
优选的聚合物包含在主链中基本上不含碳的硅氧烷基团,例如聚二甲基硅氧烷(其中基本上不含碳意指存在少于1重量%的碳)。其他合适的聚合物为WO99/33927中所公开的那些,尤其是在第12页第23-31行中所公开的聚合物,即有机氢聚硅氧烷或聚二有机硅氧烷。聚硅氧烷可包括例如二有机硅氧烷单元与有机氢硅氧烷单元和/或与其他二有机硅氧烷单元的共聚物,或者有机氢硅氧烷单元或二有机硅氧烷单元的均聚物。
也可使用可通过氢化硅烷化反应交联的聚硅氧烷。该类聚合物称为“氢化聚硅氧烷(hydride silicone)”,且例如公开于EP874032A2第3页中,即式R'-(SiOR'2)-SiR'3的聚二有机硅氧烷,其中各R'独立地为烃基或氟化烃基,其中每分子中至少两个R'基团为不饱和的或者为氢,每分子中至少两个R'基团为氢,且m具有约10-1,500的平均值。也可使用与上式那些类似的环状聚二有机硅氧烷。氢化聚硅氧烷优选为氢聚二甲基硅氧烷。
此外,聚有机硅氧烷也可包含两种或更多种具有不同粘度的聚有机硅氧烷。
或者,弹性体可为WO2008132196中所述的聚合物,其中所述聚合物为PS-(A-PO-A-PS)n形式的聚有机硅氧烷聚氧亚烷基嵌段共聚物,其中PS表示聚有机硅氧烷嵌段,PO表示聚氧亚烷基嵌段,A表示二价结构部分,且n具有至少为1的值。
所述聚合物每分子在聚有机硅氧烷嵌段上具有两个或三个反应性基团X,其可自缩合且在存在或不存在催化剂下交联,其可任选用其他包含两个或更多个与可与所述基团X反应的基团Y的有机硅交联剂交联。
优选地,所述聚有机硅氧烷聚合物以基于所述涂料组合物总重量为30-90重量%的量存在。
优选地,所述聚合物是可交联的。取决于可交联聚合物的类型,所述涂料组合物可能需要交联剂。
所述弹性体也可包含被视为非弹性体的树脂,条件是弹性体树脂与非弹性体树脂的相对比例使得当干燥、固化或交联时,弹性体和非弹性体树脂的干燥/固化/交联的混合物满足根据上述测试的“弹性体”的要求。
非弹性体和弹性体树脂的实例包括:丙烯腈-丁二烯-苯乙烯、丙烯酸类树脂、甲基丙烯酸类树脂、乙酸酯、氟塑料、聚丙烯腈、聚酰胺、聚芳醚酮、聚丁二烯、聚丁烯、聚对苯二甲酸酯、聚己内酯、聚氯三氟乙烯、聚碳酸酯、聚酮、聚酯、聚乙烯、聚醚醚酮、聚醚酮酮、聚醚酰亚胺、聚醚砜、聚酰亚胺、聚乳酸、聚丙烯、聚苯乙烯、聚砜、聚氨酯、聚乙酸乙烯酯、聚氯乙烯、聚偏氯乙烯、苯乙烯-丙烯腈、聚异戊二烯、聚异丁烯、丁基橡胶、卤代丁基橡胶、苯乙烯-丁二烯橡胶、腈橡胶、氢化腈橡胶、乙烯-丙烯橡胶、乙烯-丙烯-二烯橡胶、有机聚硅氧烷树脂、氟聚硅氧烷、氟弹性体、全氟弹性体、聚醚嵌段酰胺、氯磺化聚乙烯或乙烯-乙酸乙烯酯树脂。
所述涂料组合物也可包含填料。
合适填料的实例为硫酸钡、硫酸钙、碳酸钙、二氧化硅或硅酸盐(如滑石、长石和瓷土),包括热解法二氧化硅、膨润土和其他粘土,以及通常为缩合支化聚硅氧烷的固态聚硅氧烷树脂,如包含式SiO4/2的Q单元和式Rm 3SiO1/2的M单元的聚硅氧烷树脂,其中Rm取代基选自具有1-6个碳原子的烷基,且M单元与Q单元之比为0.4:1-1:1。一些填料如热解法二氧化硅可能对涂料组合物具有触变效应。填料比例可基于涂料组合物总重量为0-25重量%。优选地,粘土以0-1重量%的量存在,优选地触变胶以0-5重量%的量存在,基于涂料组合物的总重量。
所述涂料组合物可包含颜料。
颜料的实例包括氧化铁黑、氧化铁红、氧化铁黄、二氧化钛、氧化锌、碳黑、石墨、红色钼酸盐、黄色钼酸盐、硫化锌、氧化锑、磺基硅酸钠铝、喹吖啶酮、酞菁蓝、酞菁绿、氧化铁黑、阴丹酮蓝、氧化钴铝、咔唑二嗪、氧化铬、异吲哚啉橙、双乙酰乙酰邻联甲苯胺(tolidiole)、苯并咪唑酮、喹酞酮黄、异吲哚啉黄、四氯异吲哚啉酮和喹酞酮黄、片状金属材料(例如铝薄片)或其他所谓的阻隔颜料或抗腐蚀性颜料如锌粉或锌合金。颜料的体积浓度优选为0.5-25%。颜料的比例可为0-25重量%,基于涂料组合物的总重量。
当所述弹性体是可交联的时,所述组合物可包含催化剂。
可使用的催化剂实例包括各种金属(如锡、锌、铁、铅、钡和锆)的羧酸盐。所述盐优选为长链羧酸的盐,例如二月桂酸二丁基锡、二辛酸二丁基锡、硬脂酸铁、辛酸锡(II)和辛酸铅。合适催化剂的其他实例包括有机铋和有机钛化合物以及有机磷酸化物如磷酸氢双(2-乙基己基)酯。其他可能的催化剂包括螯合物,例如乙酰丙酮二丁基锡。此外,所述催化剂可包括在相对于酸基团的α-位碳原子上具有至少一个卤素取代基和/或在相对于酸基团的β-位碳原子上具有至少一个卤素取代基的卤代有机酸,或可在缩合反应条件下水解以形成该类酸的衍生物。或者,所述催化剂可为任何如下所述的催化剂:WO2007122325A1、WO2008055985A1、WO2009106717A2、WO2009106718A2、WO2009106719A1、WO2009106720A1、WO2009106721A1、WO2009106722A1、WO2009106723A1、WO2009106724A1、WO2009103894A1、WO2009118307A1、WO2009133084A1、WO2009133085A1、WO2009156608A2和WO2009156609A2。
优选地,所述催化剂以基于该涂料组合物总重量为0.05-4重量%的量存在。
当所述弹性体是可交联的时,所述组合物可包含交联剂。
任选存在的交联剂可为包含官能硅烷和/或一个或多个乙酰氧基、烷氧基、酰胺基、链烯氧基和肟基中任一种的交联剂,优选包含一个或多个肟基。该类交联剂的实例在WO99/33927中给出。也可使用不同交联剂的混合物。
适合用于所述抗污涂料组合物中的溶剂包括芳族烃、醇、酮、酯以及以上物质彼此的混合物或脂族烃。优选的溶剂包括酮如甲基异戊基酮和/或二甲苯。
在优选实施方案中,本发明的抗污组合物可不含或基本上不含生物杀伤剂。出乎意料的是,与商业上领先的包含如WO02/074870所述的氟聚合物的无生物杀伤剂的抗污涂料相比,本发明人发现不含生物杀伤剂的本发明抗污组合物具有优异的防污性能。
或者,本发明的抗污组合物可包含一种或多种生物杀伤剂。
所述生物杀伤剂可为一种或多种用于海洋或淡水生物的无机、有机金属、金属-有机或有机生物杀伤剂。无机生物杀伤剂的实例包括铜盐如氧化铜、硫氰酸铜、青铜、碳酸铜、氯化铜、铜镍合金;和银盐如氯化银或硝酸银;有机金属和金属-有机生物杀伤剂包括吡啶硫酮锌(2-吡啶巯基-1-氧化物的锌盐)、吡啶硫酮铜、双(N-环己基二氮烯(diazenium)二氧基)铜、亚乙基双(二硫代氨基甲酸)锌(即代森锌(zineb))、二甲基二硫代氨基甲酸锌(福美锌(ziram))以及与锌盐配合的亚乙基双(二硫代氨基甲酸)锰(即代森锰锌(mancozeb));有机生物杀伤剂包括甲醛、十二烷基胍单盐酸盐、涕必灵(thiabendazole)、N-三卤代甲基硫代邻苯二甲酰亚胺、三卤代甲基硫代磺酰胺、N-芳基马来酰亚胺如N-(2,4,6-三氯苯基)马来酰亚胺、3-(3,4-二氯苯基)-1,1-二甲脲(敌草隆(diuron))、2,3,5,6-四氯-4-(甲基磺酰基)吡啶、2-甲硫基-4-丁基氨基-6-环丙基氨基-s-三嗪、3-苯并[b]噻吩基-5,6-二氢-1,4,2-噻嗪4-氧化物、4,5-二氯-2-正辛基-3(2H)-异噻唑酮、2,4,5,6-四氯邻苯二甲腈、对甲抑菌灵(tolylfluanid)、抑菌灵(dichlofluanid)、二碘代甲基对甲苯砜、辣椒素、N-环丙基-N'-(1,1-二甲基乙基)-6-甲硫基-1,3,5-三嗪-2,4-二胺、3-碘代-2-丙炔基丁基氨基甲酸酯、美托咪啶(medetomidine)、1,4-二硫杂蒽醌(thiaanthraquinone)-2,3-二甲腈(二噻农(dithianon))、硼烷如吡啶三苯基硼烷、在5位且任选在1位被取代的2-三卤代甲基-3-卤-4-氰基吡咯衍生物如2-(对氯苯基)-3-氰基-4-溴-5-三氟甲基吡咯(溴代吡咯腈(tralopyril))、呋喃酮如3-丁基-5-(二溴亚甲基)-2(5H)-呋喃酮,及其混合物,大环内酯如阿维菌素(avermectin),例如阿维菌素B1、伊维菌素(ivermectin)、2,4-滴丙酸(doramectin)、齐墩螨素(abamectin)、甲氨基阿维菌素苯甲酸盐(amamectin)和塞拉菌素(selamectin),和季铵盐如氯化二癸基二甲基铵和氯化烷基二甲基苄基铵。
如果所述抗污组合物包含生物杀伤剂,我们意指生物杀伤剂存在于干燥、固化或交联的涂层体内部(就此而言,在干燥、固化或交联之前将其混入所述涂料组合物中)。
任选地,所述抗污组合物包含其他已知具有抗污作用的物质,例如WO02/074870所述的含氟化烷基或烷氧基的聚合物或低聚物。
所述涂料组合物优选具有35重量%,更优选至少50重量%,甚至更优选至少70重量%的固含量(定义为涂料组合物中非挥发性物质的重量百分比)。固含量可至多为80重量%、90重量%、95重量%,优选至多为100重量%。固含量可按照ASTM方法D2697测定。
所述涂料组合物可通过常规技术施加,如刷涂、辊涂或喷涂(无空气和常规的)。为了适当地粘附至基材上,优选将所述抗污涂料组合物施加至涂有底漆的基材上。
底漆可为任何常规的底漆/封闭剂涂料体系。特别是就粘合性而言,发现当使用包含丙烯酸类硅氧基官能团聚合物、溶剂、触变剂、填料和任选的水分清除剂的底漆时,获得良好的结果。该类底漆公开于WO99/33927中。也可将本发明的涂料组合物施加至含老化的防污涂层的基材上。在将本发明的涂料组合物施加至该老化层上之前,通过高压水清洗以清洁该老化层,从而移除任何污垢。WO99/33927所公开的底漆可用作老化涂层与本发明涂料组合物之间的结合涂层。在该涂层干燥、固化或交联之后,可立即将其浸没并立即获得防污和污垢松脱防护。如上文所述,本发明的涂料组合物具有非常好的抗污和污垢松脱性能。这使得这些涂料组合物非常适合用作海洋和水产业应用的防污、无污或抗污涂料。该涂料可用于动态和静态结构,如船只和船舶外壳、浮标、钻探平台、采油钻机、浮式生产储油轮(FPSO)、浮式储存及再气化设备(FSRU)、电厂中的冷却水入口、渔网或鱼笼及浸于水中的管。
可将所述涂料可施加至用于这些结构的任何基材上,如金属、混凝土、木材或纤维增强树脂上。
在一个实施方案中,本发明涉及一种涂覆有本文所述的抗污涂料组合物的基材或结构。
本发明的另一实施方案为一种抑制水生环境中基材结垢的方法,包括将本文所述且请求保护的抗污组合物施加至基材上,随后将该基材置于水生环境中。
本发明的另一实施方案是本文所述且请求保护的抗污组合物用于抑制水生环境中基材上结垢的用途。
实施例
参照如下实施例阐述本发明。
实施例1-5
通过将表1中所示组分混合而制备七种不同的涂料组合物。
表1
*对比实施例
(1)E10-H(Solvay Solexis)TM。
(2)Acetylated Lanolin Standard(NK Chemicals)TM。
(3)Anhydrous Lanolin TG(NK Chemicals)TM。
(4)Fluilan(Croda)。在25℃下使用Sheen粘度计(锥板式粘度计)测得该羊毛脂油的粘度为26泊。
(5)Argowax(Croda)TM。
(6)胆甾醇(Sigma-Aldrich)TM。
(7)乙酸胆甾醇酯(Sigma-Aldrich)TM。
(8)3-0213聚合物(Dow Corning)TM。
(9)Aerosil R972(Evonik)TM。
(10)Molsiv5A(OMYA)TM。
(11)Tioxide TR92(Huntsman)TM。
(12)Bayferrox318M(Lanxess)TM。
污垢松脱测试(1)
借助刷子将实施例的涂料组合物施加至用合适底漆打底的玻璃基材上。将该涂覆的基材浸入海洋污染生物可在其中生长的环境中。在七天后,将污染的基材置于流动槽中。槽中的水流速度由零递增至19节。记录所述经涂覆的基材的污垢覆盖程度。
表2
在所有情况下,如对抗污组合物所预期的那样,随着流动速度的增大,污垢覆盖程度降低。
选择包含含氟聚合物的对比抗污实施例,这是因为在WO02/074870中将其描述为与其他已知组合物相比具有优异抗污性能的抗污组合物。
这些结果显示当与包含未改性的羊毛脂、羊毛脂蜡或含氟聚合物的组合物相比时,包含乙酰化的羊毛脂和羊毛脂油的组合物(实施例2和4)在所有流动速度下均具有优异的抗污性。
污垢松脱测试(2)
借助辊筒将实施例1和2的涂料组合物施加至位于英国Hartlepool码头的适当地涂有底漆的船壳上。该码头以其杂草、粘泥、硬体动物和软体动物污垢著称。在10个月后检查船只,观察到用实施例2涂覆的区域上的结垢程度轻于用实施例1涂覆的那些。
这些结果显示,当施加至活动游船上时,包含乙酰化羊毛脂的组合物具有非常好的污垢松脱性能。包含乙酰化羊毛脂的组合物具有比包含含氟聚合物的领先商业组合物(标准)更好的总体抗污性能。
污垢松脱测试(3)
借助刷子将实施例的涂料组合物施加至用合适底漆打底的木质基材上。将涂覆的基材浸入两个已知发生海洋污染(粘泥、杂草、软体动物和硬体动物污染)(UK Burnham-upon-Crouch和Singapore Changi)的海洋环境中。定期评估所述涂覆的基材,并记录污垢覆盖程度。
位置1:Burnham-upon-Crouch,UK
位置2:Changi,Singapore
在两个位置处,在数个月后,3种涂料均显示出良好的抗污性。当涂料包含含乙酰化甾醇的组分(实施例1和7)时,结果显示出特别优异的抗污性。
Claims (12)
1.一种包含弹性体和含甾醇和/或甾醇衍生物的组分的抗污组合物,其中所述组分选自酰化羊毛脂、烷氧基化羊毛脂、羊毛脂油或包含至少20重量%的一种或多种甾醇、至少20重量%的一种或多种C1-C12甾醇酯或至少20重量%的烷氧基化甾醇的组合物,其中重量%为所述甾醇或甾醇衍生物对所述组分总重量的百分比。
2.如权利要求1的抗污组合物,其中一种或多种甾醇酯为一种或多种C1-C5酰化的甾醇酯,例如一种或多种乙酰化的甾醇酯。
3.如权利要求1或2的抗污组合物,其中所述组分包含至少50重量%的一种或多种甾醇、至少50重量%的一种或多种C1-C12甾醇酯或至少50重量%的烷氧基化甾醇,其中重量%为所述甾醇或甾醇衍生物对所述组分总重量的百分比。
4.如权利要求1的抗污组合物,其中酰化羊毛脂为C1-C12酰化羊毛脂,例如乙酰化的羊毛脂。
5.如前述权利要求中任一项的抗污组合物,其中所述甾醇和甾醇衍生物包括一种或多种胆甾醇、羊毛甾醇、羔甾醇、环阿屯醇、菜油甾醇、谷甾醇、豆甾醇、香树素和二氢羊毛甾醇和/或其酯或烷氧基化衍生物。
6.如前述权利要求中任一项的抗污组合物,其中所述组分与所述弹性体的重量比为约1-30%。
7.如前述权利要求中任一项的抗污组合物,其中所述弹性体为一种有机硅氧烷聚合物或其混合物。
8.如前述权利要求中任一项的抗污组合物,其中所述弹性体为包含一般结构-[SiR1R2-O]-的重复单元的聚合物,其中R1和R2独立地选自氢、烷基、芳基、芳烷基和乙烯基。
9.如权利要求8的抗污组合物,其中R1和R2独立地选自甲基和苯基,优选其中R1和R2为甲基。
10.一种抑制水生环境中基材结垢的方法,包括将如前述权利要求中任一项的抗污组合物施加至基材上,然后将该基材置于水生环境中。
11.如权利要求1-9中任一项所定义的抗污组合物用于抑制水生环境中基材上结垢的用途。
12.一种涂覆有如权利要求1-9中任一项所定义的抗污组合物的基材。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710186379.3A CN107011793A (zh) | 2011-08-18 | 2012-08-15 | 含酰化羊毛脂、烷氧基化羊毛脂或羊毛脂油的抗污组合物 |
Applications Claiming Priority (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201161524990P | 2011-08-18 | 2011-08-18 | |
US201161525016P | 2011-08-18 | 2011-08-18 | |
EP11177897.3 | 2011-08-18 | ||
EP11177899.9 | 2011-08-18 | ||
EP11177897 | 2011-08-18 | ||
EP11177899 | 2011-08-18 | ||
US61/524,990 | 2011-08-18 | ||
US61/525,016 | 2011-08-18 | ||
PCT/EP2012/065920 WO2013024106A1 (en) | 2011-08-18 | 2012-08-15 | Fouling-resistant composition comprising sterols and/or derivatives thereof |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201710186379.3A Division CN107011793A (zh) | 2011-08-18 | 2012-08-15 | 含酰化羊毛脂、烷氧基化羊毛脂或羊毛脂油的抗污组合物 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN103748157A true CN103748157A (zh) | 2014-04-23 |
Family
ID=47714803
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201280039052.9A Pending CN103748157A (zh) | 2011-08-18 | 2012-08-15 | 含甾醇和/或其衍生物的抗污组合物 |
CN201710186379.3A Pending CN107011793A (zh) | 2011-08-18 | 2012-08-15 | 含酰化羊毛脂、烷氧基化羊毛脂或羊毛脂油的抗污组合物 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201710186379.3A Pending CN107011793A (zh) | 2011-08-18 | 2012-08-15 | 含酰化羊毛脂、烷氧基化羊毛脂或羊毛脂油的抗污组合物 |
Country Status (16)
Country | Link |
---|---|
US (1) | US9388316B2 (zh) |
EP (1) | EP2744856B1 (zh) |
JP (1) | JP5860536B2 (zh) |
KR (1) | KR101881965B1 (zh) |
CN (2) | CN103748157A (zh) |
AU (1) | AU2012296827B2 (zh) |
BR (1) | BR112014003211B1 (zh) |
CL (1) | CL2014000366A1 (zh) |
ES (1) | ES2978887T3 (zh) |
MX (1) | MX2014001831A (zh) |
MY (1) | MY166871A (zh) |
SA (1) | SA112330788B1 (zh) |
SG (1) | SG2014012421A (zh) |
TW (1) | TWI550040B (zh) |
WO (1) | WO2013024106A1 (zh) |
ZA (1) | ZA201401024B (zh) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106349928A (zh) * | 2016-08-29 | 2017-01-25 | 中国船舶重工集团公司第七二五研究所 | 一种单组分螺旋桨可剥离防污涂料及其制备方法 |
CN106661352A (zh) * | 2014-07-11 | 2017-05-10 | 汉伯公司 | 含聚(氧亚烷基)改性的醇的新型聚硅氧烷基污垢释放涂层 |
CN106810957A (zh) * | 2016-12-26 | 2017-06-09 | 芜湖乐普汽车科技有限公司 | 绝缘涂料 |
CN111448267A (zh) * | 2017-12-14 | 2020-07-24 | 阿克佐诺贝尔国际涂料股份有限公司 | 污损脱附涂料组合物、涂有此涂料组合物的基材及此涂料组合物的用途 |
CN112402920A (zh) * | 2020-11-20 | 2021-02-26 | 廊坊师范学院 | 一种基于自清洁材料的抑菌五指握力器 |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9388316B2 (en) | 2011-08-18 | 2016-07-12 | Akzo Nobel Coatings International B.V. | Fouling-resistant composition comprising sterols and/or derivatives thereof |
BR102013022262A2 (pt) * | 2013-05-10 | 2016-04-26 | Oxifree Holdings Corp | sistema de revestimento para proteção de estruturas de metal complexas em ambientes submersos |
WO2016036550A1 (en) * | 2014-09-05 | 2016-03-10 | Ekomarine Paint Inc. | A method for treating surfaces on marine objects with anti-fouling paint |
JP6913757B2 (ja) | 2017-01-19 | 2021-08-04 | ヨトゥン アーエス | 防汚組成物 |
EP3489310A1 (en) | 2017-11-24 | 2019-05-29 | Jotun A/S | Antifouling composition |
EP3489311A1 (en) | 2017-11-24 | 2019-05-29 | Jotun A/S | Antifouling composition |
CN107869064A (zh) * | 2017-11-27 | 2018-04-03 | 无锡昊瑜节能环保设备有限公司 | 一种微胶囊整理剂及其制备方法 |
CN107841872A (zh) * | 2017-11-27 | 2018-03-27 | 无锡昊瑜节能环保设备有限公司 | 一种羊毛织物防污抗菌整理工艺 |
EP3828240A1 (en) | 2019-11-29 | 2021-06-02 | Jotun A/S | Fouling release coating |
GB2592921B (en) | 2020-03-09 | 2024-04-17 | Jotun As | Hull cleaning robot |
EP3974481A1 (en) | 2020-09-29 | 2022-03-30 | Jotun A/S | Fouling release coating composition |
EP3974482A1 (en) | 2020-09-29 | 2022-03-30 | Jotun A/S | Fouling release coating composition |
GB202107159D0 (en) | 2021-03-23 | 2021-06-30 | Jotun As | Monitoring a vessel |
US20240166315A1 (en) | 2021-03-23 | 2024-05-23 | Jotun A/S | Monitoring the cleanliness of an underwater surface of a stationary object |
WO2023111191A1 (en) | 2021-12-15 | 2023-06-22 | Jotun A/S | Fouling release coating composition |
WO2024115765A1 (en) | 2022-12-02 | 2024-06-06 | Jotun A/S | Process |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001094487A2 (en) * | 2000-06-02 | 2001-12-13 | Microphase Coatings, Inc. | Antifouling coating composition |
JP2005263975A (ja) * | 2004-03-18 | 2005-09-29 | Tokyo Fine Chem Kk | 防汚塗料組成物 |
CN101299990A (zh) * | 2005-11-17 | 2008-11-05 | 陶氏康宁东丽株式会社 | 控制硅橡胶粉末吸油性能的方法 |
WO2010103209A1 (fr) * | 2009-03-13 | 2010-09-16 | Seawax Marine Coatings | Formulation aqueuse d'un systeme de revetement antisalissure de supports immerges, son procede de traitement et son utilisation |
Family Cites Families (37)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1960252A (en) | 1930-01-06 | 1934-05-29 | Hosnoler Corp | Base for coating, cementing, molding, and the like compositions |
GB1307001A (en) | 1970-01-12 | 1973-02-14 | Kroyer K K K | Marine structure having a surface coating for the prevention of accumulation of marine organisms |
US3702778A (en) | 1970-03-23 | 1972-11-14 | Battelle Memorial Institute | Ship's hull coated with antifouling silicone rubber |
JP3210815B2 (ja) * | 1994-10-31 | 2001-09-25 | 中国塗料株式会社 | 常温硬化性オルガノポリシロキサン組成物及びその硬化物 |
DE19537316A1 (de) | 1995-10-06 | 1997-04-10 | Leinos Naturfarben Gmbh | Antifouling-Mittel |
US5906893A (en) | 1997-04-25 | 1999-05-25 | General Electric Company | Sprayable, addition curable silicone foul release coatings and articles coated therewith |
GB9727261D0 (en) | 1997-12-23 | 1998-02-25 | Courtaulds Coatings Holdings | Fouling inhibition |
US6653378B2 (en) * | 2000-12-18 | 2003-11-25 | Dow Corning Corporation | Silicone elastomer compositions |
AU2002257684B2 (en) | 2001-03-21 | 2007-01-18 | Akzo Nobel N.V. | Anti-fouling compositions with a fluorinated alkyl- or alkoxy-containing polymer or oligomer |
DE10261484A1 (de) | 2002-12-23 | 2004-07-01 | Basf Ag | Verfahren zur Polymerisation cyclischer Ether |
DE10314201A1 (de) | 2003-03-28 | 2004-10-14 | Schönherr, Andreas | Biologisch verträgliches Mittel zur Verhinderung von Bewuchs durch Süß- oder Meerwasserorganismen |
US20040228821A1 (en) * | 2003-05-16 | 2004-11-18 | The Procter & Gamble Company | Personal care products comprising active agents in a gel network |
US20080107679A1 (en) * | 2003-08-14 | 2008-05-08 | Natalie Dilallo | Skin care compositions including hexapeptide complexes and methods of their manufacture |
WO2005027642A1 (en) * | 2003-09-25 | 2005-03-31 | Darren Wayne Eade | Repellent preparations |
FR2900153B1 (fr) | 2006-04-21 | 2008-07-18 | Rhodia Recherches & Tech | Procede de condensation de motifs silyles a l'aide d'un catalyseur de type carbene |
FR2908420A1 (fr) | 2006-11-09 | 2008-05-16 | Rhodia Recherches & Tech | Composition silicone monocomposante sans etain reticulable en elastomere |
EP2142607B1 (en) | 2007-05-01 | 2020-04-08 | Akzo Nobel Coatings International B.V. | Antifouling coating composition based on curable polyorganosiloxane polyoxyalkylene copolymers |
FR2925511A1 (fr) | 2007-12-20 | 2009-06-26 | Bluestar Silicones France Soc | Composition organopolysiloxanique vulcanisable a temperature ambiante en elastomere et nouveaux catalyseurs de polycondensation d'organopolysiloxanes. |
FR2925514A1 (fr) | 2007-12-20 | 2009-06-26 | Bluestar Silicones France Soc | Composition organopolysiloxanique vulcanisable a temperature ambiante en elastomere et nouveaux catalyseurs de polycondensation d'organopolysiloxanes. |
FR2925510A1 (fr) | 2007-12-20 | 2009-06-26 | Bluestar Silicones France Soc | Composition organopolysiloxanique vulcanisable a temperature ambiante en elastomere et nouveaux catalyseurs de polycondensation d'organopolysiloxanes. |
FR2925496A1 (fr) | 2007-12-20 | 2009-06-26 | Bluestar Silicones France Soc | Composes a structure guanidine et leurs utilisations comme catalyseurs de polycondensation d'organopolysiloxanes. |
FR2925512A1 (fr) | 2007-12-20 | 2009-06-26 | Bluestar Silicones France Soc | Composition organopolysiloxanique vulcanisable a temperature ambiante en elastomere et nouveaux catalyseurs de polycondensation d'organopolysiloxanes. |
FR2925513A1 (fr) | 2007-12-20 | 2009-06-26 | Bluestar Silicones France Soc | Composition organopolysiloxanique vulcanisable a temperature ambiante en elastomere et nouveaux catalyseurs de polycondensation d'organopolysiloxanes. |
FR2925515A1 (fr) | 2007-12-20 | 2009-06-26 | Bluestar Silicones France Soc | Composition organopolysiloxanique vulcanisable a temperature ambiante en elastomere et nouveaux catalyseurs de polycondensation d'organopolysiloxanes. |
FR2925516A1 (fr) | 2007-12-20 | 2009-06-26 | Bluestar Silicones France Soc | Composition organopolysiloxanique vulcanisable a temperature ambiante en elastomere et nouveaux catalyseurs de polycondensation d'organopolysiloxanes. |
CN101932546A (zh) | 2007-12-20 | 2010-12-29 | 蓝星有机硅法国公司 | 在环境温度下可硫化成弹性体的有机聚硅氧烷组合物以及新的有机聚硅氧烷缩聚催化剂 |
KR20090068485A (ko) | 2007-12-24 | 2009-06-29 | 동우 화인켐 주식회사 | 방현성 하드코팅 조성물, 방현성 하드코팅 필름, 편광판 및표시장치 |
US20090197003A1 (en) | 2008-02-01 | 2009-08-06 | Thomas Van Zandt | Anti-fouling coatings, Compounds, and methods |
FR2929286A1 (fr) | 2008-03-28 | 2009-10-02 | Bluestar Silicones France Soc | Composes a structure guanidine et leurs utilisations comme catalyseurs de polycondensation d'organopolysiloxanes |
EP2291463B1 (fr) | 2008-04-30 | 2016-03-23 | Bluestar Silicones France | Article presentant des proprietes antisalissures et destine a etre utilise dans des applications aquatiques en particulier marines. |
FR2930778A1 (fr) | 2008-04-30 | 2009-11-06 | Bluestar Silicones France Soc | Article presentant des proprietes antisalissures et destine a etre utilise dans des applications aquatiques en particulier marines |
JP5444832B2 (ja) | 2008-05-28 | 2014-03-19 | コニカミノルタ株式会社 | 画像形成方法 |
JP5502075B2 (ja) | 2008-05-29 | 2014-05-28 | ブルースター・シリコーンズ・フランス・エスアエス | 防汚特性を有し、水中用途、特に海洋用途に用いるための物品 |
US9744527B2 (en) | 2008-05-29 | 2017-08-29 | Bluestar Silicones France Sas | Article having antifouling properties for aquatic and particularly sea use |
JP2010090246A (ja) * | 2008-10-07 | 2010-04-22 | Nippon Fine Chem Co Ltd | 防汚塗料組成物およびそれを用いた防汚方法 |
CN101445543B (zh) * | 2008-12-25 | 2011-01-19 | 中国科学院南海海洋研究所 | 一种柳珊瑚多羟基甾醇及其制备方法和应用 |
US9388316B2 (en) | 2011-08-18 | 2016-07-12 | Akzo Nobel Coatings International B.V. | Fouling-resistant composition comprising sterols and/or derivatives thereof |
-
2012
- 2012-08-15 US US14/238,985 patent/US9388316B2/en active Active
- 2012-08-15 EP EP12750581.6A patent/EP2744856B1/en active Active
- 2012-08-15 MX MX2014001831A patent/MX2014001831A/es unknown
- 2012-08-15 CN CN201280039052.9A patent/CN103748157A/zh active Pending
- 2012-08-15 MY MYPI2014700306A patent/MY166871A/en unknown
- 2012-08-15 WO PCT/EP2012/065920 patent/WO2013024106A1/en active Application Filing
- 2012-08-15 BR BR112014003211-4A patent/BR112014003211B1/pt active IP Right Grant
- 2012-08-15 JP JP2014525438A patent/JP5860536B2/ja active Active
- 2012-08-15 AU AU2012296827A patent/AU2012296827B2/en not_active Ceased
- 2012-08-15 CN CN201710186379.3A patent/CN107011793A/zh active Pending
- 2012-08-15 SG SG2014012421A patent/SG2014012421A/en unknown
- 2012-08-15 ES ES12750581T patent/ES2978887T3/es active Active
- 2012-08-15 KR KR1020147005834A patent/KR101881965B1/ko active IP Right Grant
- 2012-08-16 SA SA112330788A patent/SA112330788B1/ar unknown
- 2012-08-17 TW TW101130044A patent/TWI550040B/zh not_active IP Right Cessation
-
2014
- 2014-02-10 ZA ZA2014/01024A patent/ZA201401024B/en unknown
- 2014-02-13 CL CL2014000366A patent/CL2014000366A1/es unknown
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001094487A2 (en) * | 2000-06-02 | 2001-12-13 | Microphase Coatings, Inc. | Antifouling coating composition |
JP2005263975A (ja) * | 2004-03-18 | 2005-09-29 | Tokyo Fine Chem Kk | 防汚塗料組成物 |
CN101299990A (zh) * | 2005-11-17 | 2008-11-05 | 陶氏康宁东丽株式会社 | 控制硅橡胶粉末吸油性能的方法 |
WO2010103209A1 (fr) * | 2009-03-13 | 2010-09-16 | Seawax Marine Coatings | Formulation aqueuse d'un systeme de revetement antisalissure de supports immerges, son procede de traitement et son utilisation |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106661352A (zh) * | 2014-07-11 | 2017-05-10 | 汉伯公司 | 含聚(氧亚烷基)改性的醇的新型聚硅氧烷基污垢释放涂层 |
CN106661352B (zh) * | 2014-07-11 | 2021-03-30 | 汉伯公司 | 含聚(氧亚烷基)改性的醇的新型聚硅氧烷基污垢释放涂层 |
CN106349928A (zh) * | 2016-08-29 | 2017-01-25 | 中国船舶重工集团公司第七二五研究所 | 一种单组分螺旋桨可剥离防污涂料及其制备方法 |
CN106349928B (zh) * | 2016-08-29 | 2018-08-10 | 中国船舶重工集团公司第七二五研究所 | 一种单组分螺旋桨可剥离防污涂料及其制备方法 |
CN106810957A (zh) * | 2016-12-26 | 2017-06-09 | 芜湖乐普汽车科技有限公司 | 绝缘涂料 |
CN111448267A (zh) * | 2017-12-14 | 2020-07-24 | 阿克佐诺贝尔国际涂料股份有限公司 | 污损脱附涂料组合物、涂有此涂料组合物的基材及此涂料组合物的用途 |
CN111448267B (zh) * | 2017-12-14 | 2022-11-04 | 阿克佐诺贝尔国际涂料股份有限公司 | 污损脱附涂料组合物、涂有此涂料组合物的基材及此涂料组合物的用途 |
CN112402920A (zh) * | 2020-11-20 | 2021-02-26 | 廊坊师范学院 | 一种基于自清洁材料的抑菌五指握力器 |
Also Published As
Publication number | Publication date |
---|---|
US20140155530A1 (en) | 2014-06-05 |
ES2978887T3 (es) | 2024-09-23 |
KR20140064832A (ko) | 2014-05-28 |
US9388316B2 (en) | 2016-07-12 |
MY166871A (en) | 2018-07-24 |
ZA201401024B (en) | 2017-08-30 |
CL2014000366A1 (es) | 2014-08-22 |
AU2012296827B2 (en) | 2016-03-10 |
TW201313847A (zh) | 2013-04-01 |
CN107011793A (zh) | 2017-08-04 |
SA112330788B1 (ar) | 2015-10-22 |
BR112014003211A2 (pt) | 2017-03-01 |
MX2014001831A (es) | 2014-02-27 |
EP2744856A1 (en) | 2014-06-25 |
BR112014003211B1 (pt) | 2021-03-09 |
JP5860536B2 (ja) | 2016-02-16 |
WO2013024106A1 (en) | 2013-02-21 |
AU2012296827A1 (en) | 2014-02-20 |
TWI550040B (zh) | 2016-09-21 |
KR101881965B1 (ko) | 2018-07-25 |
SG2014012421A (en) | 2014-06-27 |
JP2014528981A (ja) | 2014-10-30 |
EP2744856B1 (en) | 2024-03-20 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103748157A (zh) | 含甾醇和/或其衍生物的抗污组合物 | |
AU2014222855B2 (en) | Anti-fouling compositions with a fluorinated oxyalkylene-containing polymer or oligomer | |
EP3126458B1 (en) | An erodible antifouling coating composition | |
JP2017507194A (ja) | 塗料組成物 | |
JP2010254832A (ja) | 防汚塗料組成物及び防汚方法 | |
DK3077468T3 (en) | PROCEDURE FOR COATING AN OLD COATING LAYER ON A SUBSTRATE AND COATING COMPOSITION SUITABLE FOR USE IN THIS PROCEDURE | |
TW201527454A (zh) | 於基板上塗佈老化塗層之方法及適用於該方法中之塗料組合物 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140423 |