CN107869064A - 一种微胶囊整理剂及其制备方法 - Google Patents

一种微胶囊整理剂及其制备方法 Download PDF

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CN107869064A
CN107869064A CN201711204099.7A CN201711204099A CN107869064A CN 107869064 A CN107869064 A CN 107869064A CN 201711204099 A CN201711204099 A CN 201711204099A CN 107869064 A CN107869064 A CN 107869064A
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胡晓荣
俞娟
胡瑜
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Wuxi Haoyu Energy Saving Environmental Protection Equipment Co Ltd
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Abstract

本发明公开了一种微胶囊整理剂及其制备方法，所述整理剂包括：水35～50份、微胶囊12～25份、分散剂3～8份、润湿剂4～9份、甘油1～3份；其中，微胶囊包含胶囊芯和胶囊壳，胶囊芯为功能性成分，胶囊壳为热固性树脂。与现有技术相比，本发明具有以下优点：(1)本发明所述微胶囊整理剂能够与织物表面稳定结合，经多次水洗后依然不脱落；(2)本发明所述微胶囊整理剂在织物表面分散均匀，无团聚现象发生。

Description

一种微胶囊整理剂及其制备方法
技术领域
本发明属于纺织技术领域，涉及一种纺织面料整理剂，具体为一种微胶囊整理剂及其制备方法。
背景技术
为了对纺织面料进行整理，越来越多的使用含有多种内含物的微胶囊。微胶囊的功效是在织物表面上延迟释放活性物质，以便得到持久的整理效果。
但是现有技术中采用微胶囊来整理织物，特别是在整理部分或完全用现代合成纤维如聚酯、聚酰胺或者弹性纤维织造的纺织织物或成品缝制纺织物时，具有以下缺陷：首先，未被织物吸收的微胶囊会丢失，这样导致材料的浪费和成本的提高；其次，微胶囊在织物表面吸附不均匀，易在织物表面遗留下不美观的斑痕或团聚物。
发明内容
本发明的目的是：为了克服现有技术的缺陷，获得一种能够与织物表面稳定结合，且分布均匀的整理剂，本发明提供了一种微胶囊整理剂及其制备方法。
技术方案：一种微胶囊整理剂，按重量份计，所述整理剂包括：水35～50份、微胶囊12～25份、分散剂3～8份、润湿剂4～9份、甘油1～3份；其中，微胶囊包含胶囊芯和胶囊壳，胶囊芯为功能性成分，胶囊壳为热固性树脂。
优选的，所述功能性成分为溶菌酶、季铵盐表面活性剂、六亚甲基双胍、全氟磺酸盐、酰化羊毛脂、烷氧基化羊毛脂中的至少一种。
优选的，所述热固性树脂为酚醛树脂、脲醛树脂、聚氨酯、聚酰亚胺中的一种。
优选的，所述分散剂为黄原胶、瓜尔胶、聚丙烯酸酯中的一种。
优选的，所述润湿剂为烷基硫酸盐、琥珀酸烷基酯磺酸盐、烷基磺基琥珀酰胺中的一种。
优选的，所述微胶囊的直径为0.5～100μm。
以上任一所述微胶囊整理剂的制备方法，所述方法包括以下步骤：
(1)将胶囊芯灌装于胶囊壳中，形成微胶囊；
(2)将微胶囊分散于水中，加入分散剂、润湿剂和甘油，在30～65℃条件下，采用磁力搅拌器搅拌3～8min。
有益效果：(1)本发明所述微胶囊整理剂能够与织物表面稳定结合，经多次水洗后依然不脱落；(2)本发明所述微胶囊整理剂在织物表面分散均匀，无团聚现象发生。
具体实施方式
实施例1
一种微胶囊整理剂，按重量份计，所述整理剂包括：水35份、微胶囊12份、分散剂3份、润湿剂4份、甘油1份；其中，微胶囊包含胶囊芯和胶囊壳，胶囊芯为功能性成分，胶囊壳为热固性树脂。
所述功能性成分为溶菌酶和季铵盐表面活性剂。
所述热固性树脂为酚醛树脂。
所述分散剂为黄原胶。
所述润湿剂为烷基硫酸盐。
所述微胶囊的直径为0.5μm。
以上任一所述微胶囊整理剂的制备方法，所述方法包括以下步骤：
(1)将胶囊芯灌装于胶囊壳中，形成微胶囊；
(2)将微胶囊分散于水中，加入分散剂、润湿剂和甘油，在30℃条件下，采用磁力搅拌器搅拌3min。
实施例2
一种微胶囊整理剂，按重量份计，所述整理剂包括：水40份、微胶囊18份、分散剂5份、润湿剂6份、甘油2份；其中，微胶囊包含胶囊芯和胶囊壳，胶囊芯为功能性成分，胶囊壳为热固性树脂。
所述功能性成分为六亚甲基双胍。
所述热固性树脂为脲醛树脂。
所述分散剂为瓜尔胶。
所述润湿剂为琥珀酸烷基酯磺酸盐。
所述微胶囊的直径为10μm。
以上任一所述微胶囊整理剂的制备方法，所述方法包括以下步骤：
(1)将胶囊芯灌装于胶囊壳中，形成微胶囊；
(2)将微胶囊分散于水中，加入分散剂、润湿剂和甘油，在45℃条件下，采用磁力搅拌器搅拌5min。
实施例3
一种微胶囊整理剂，按重量份计，所述整理剂包括：水40份、微胶囊20份、分散剂6份、润湿剂7份、甘油3份；其中，微胶囊包含胶囊芯和胶囊壳，胶囊芯为功能性成分，胶囊壳为热固性树脂。
所述功能性成分为全氟磺酸盐。
所述热固性树脂为聚氨酯。
所述分散剂为聚丙烯酸酯。
所述润湿剂为烷基磺基琥珀酰胺。
所述微胶囊的直径为20μm。
以上任一所述微胶囊整理剂的制备方法，所述方法包括以下步骤：
(1)将胶囊芯灌装于胶囊壳中，形成微胶囊；
(2)将微胶囊分散于水中，加入分散剂、润湿剂和甘油，在50℃条件下，采用磁力搅拌器搅拌6min。
实施例4
一种微胶囊整理剂，按重量份计，所述整理剂包括：水50份、微胶囊25份、分散剂8份、润湿剂9份、甘油3份；其中，微胶囊包含胶囊芯和胶囊壳，胶囊芯为功能性成分，胶囊壳为热固性树脂。
所述功能性成分为酰化羊毛脂和烷氧基化羊毛脂。
所述热固性树脂为聚酰亚胺。
所述分散剂为聚丙烯酸酯。
所述润湿剂为烷基磺基琥珀酰胺。
所述微胶囊的直径为100μm。
以上任一所述微胶囊整理剂的制备方法，所述方法包括以下步骤：
(1)将胶囊芯灌装于胶囊壳中，形成微胶囊；
(2)将微胶囊分散于水中，加入分散剂、润湿剂和甘油，在65℃条件下，采用磁力搅拌器搅拌8min。
对实施例1～4制备获得的微胶囊整理剂进行性能测试，试验方法为：选取黑色真丝织物，取微胶囊整理剂加入0.5～3倍体积的水制成整理液，然后泵式喷涂瓶将整理液喷雾至织物上，喷雾量为织物重量的15～30％，然后室温干燥织物，观察，并记录结果。结果如下：
斑痕 30次水洗后微胶囊结合率/％
实施例1 无 93.5
实施例2 无 96.2
实施例3 无 99.8
实施例4 无 97.2

Claims (7)

1.一种微胶囊整理剂，其特征在于，按重量份计，所述整理剂包括：水35～50份、微胶囊12～25份、分散剂3～8份、润湿剂4～9份、甘油1～3份；其中，微胶囊包含胶囊芯和胶囊壳，胶囊芯为功能性成分，胶囊壳为热固性树脂。
2.根据权利要求1所述的一种微胶囊整理剂，其特征在于，所述功能性成分为溶菌酶、季铵盐表面活性剂、六亚甲基双胍、全氟磺酸盐、酰化羊毛脂、烷氧基化羊毛脂中的至少一种。
3.根据权利要求1所述的一种微胶囊整理剂，其特征在于，所述热固性树脂为酚醛树脂、脲醛树脂、聚氨酯、聚酰亚胺中的一种。
4.根据权利要求1所述的一种微胶囊整理剂，其特征在于，所述分散剂为黄原胶、瓜尔胶、聚丙烯酸酯中的一种。
5.根据权利要求1所述的一种微胶囊整理剂，其特征在于，所述润湿剂为烷基硫酸盐、琥珀酸烷基酯磺酸盐、烷基磺基琥珀酰胺中的一种。
6.根据权利要求1所述的一种微胶囊整理剂，其特征在于，所述微胶囊的直径为0.5～100μm。
7.权利要求1～6任一所述微胶囊整理剂的制备方法，其特征在于，所述方法包括以下步骤：
(1)将胶囊芯灌装于胶囊壳中，形成微胶囊；
(2)将微胶囊分散于水中，加入分散剂、润湿剂和甘油，在30～65℃条件下，采用磁力搅拌器搅拌3～8min。
CN201711204099.7A 2017-11-27 2017-11-27 一种微胶囊整理剂及其制备方法 Pending CN107869064A (zh)

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CN109322165B (zh) * 2018-11-20 2019-11-05 武汉纺织大学 一种防水透湿型棉织物涂层剂的制备方法与应用

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