CN103635256B - 制备含钴的费-托合成催化剂的方法 - Google Patents

制备含钴的费-托合成催化剂的方法 Download PDF

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Publication number
CN103635256B
CN103635256B CN201280032354.3A CN201280032354A CN103635256B CN 103635256 B CN103635256 B CN 103635256B CN 201280032354 A CN201280032354 A CN 201280032354A CN 103635256 B CN103635256 B CN 103635256B
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catalyst
precursor
subsequently
cobalt
cobalt compound
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CN201280032354.3A
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Chinese (zh)
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CN103635256A (zh
Inventor
H·范伦斯博戈
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Sasol Technology Pty Ltd
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Sasol Technology Pty Ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/12—Oxidising
    • B01J37/14—Oxidising with gases containing free oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0213—Preparation of the impregnating solution
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
CN201280032354.3A 2011-09-21 2012-08-31 制备含钴的费-托合成催化剂的方法 Active CN103635256B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ZA2011/06909 2011-09-21
ZA201106909 2011-09-21
PCT/IB2012/054493 WO2013041997A1 (en) 2011-09-21 2012-08-31 Process for preparing a cobalt - containing fischer tropsch catalyst

Publications (2)

Publication Number Publication Date
CN103635256A CN103635256A (zh) 2014-03-12
CN103635256B true CN103635256B (zh) 2016-08-17

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Country Status (14)

Country Link
US (1) US9248435B2 (enExample)
EP (1) EP2758170B1 (enExample)
JP (1) JP5961694B2 (enExample)
CN (1) CN103635256B (enExample)
AP (1) AP2013007293A0 (enExample)
AR (1) AR087975A1 (enExample)
AU (1) AU2012311175B2 (enExample)
BR (1) BR112013032165B8 (enExample)
CA (1) CA2838233C (enExample)
MY (1) MY164214A (enExample)
PE (1) PE20140735A1 (enExample)
RU (1) RU2602803C2 (enExample)
WO (1) WO2013041997A1 (enExample)
ZA (1) ZA201309045B (enExample)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013041997A1 (en) 2011-09-21 2013-03-28 Sasol Technology (Proprietary) Limited Process for preparing a cobalt - containing fischer tropsch catalyst
CA2971297C (en) * 2014-12-19 2023-06-20 Bp P.L.C. Process for preparation of a supported cobalt-containing fischer-tropsch synthesis catalyst
WO2017108791A1 (en) * 2015-12-21 2017-06-29 Shell Internationale Research Maatschappij B.V. Hydrogenation catalyst and method for preparing the same
JP6916219B2 (ja) 2016-08-11 2021-08-11 サソル サウス アフリカ リミティド コバルト含有触媒組成物

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4413064A (en) * 1981-10-13 1983-11-01 Gulf Research & Development Company Fluid bed catalyst for synthesis gas conversion and utilization thereof for preparation of diesel fuel
US7012104B2 (en) * 2002-10-16 2006-03-14 Conocophillips Company Fischer-Tropsch processes and catalysts made from a material comprising boehmite
CN101052466A (zh) * 2005-01-11 2007-10-10 萨索尔技术(控股)有限公司 费-托合成用的负载型钴催化剂的制造
WO2010097754A2 (en) * 2009-02-26 2010-09-02 Sasol Technology (Proprietary) Limited Catalysts

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3839580C1 (enExample) 1988-11-24 1990-07-05 Condea Chemie Gmbh, 2212 Brunsbuettel, De
DZ2013A1 (fr) 1995-04-07 2002-10-23 Sastech Ltd Catalyseurs.
RU2223821C2 (ru) 1998-10-05 2004-02-20 Сэсол Текнолоджи (Проприетери) Лимитед Способ приготовления предшественника катализатора фишера-тропша
RU2340394C2 (ru) * 2002-10-16 2008-12-10 Конокофиллипс Кампэни Способ получения носителя для катализатора с повышенной гидротермальной стабильностью (варианты), катализатор для синтеза углеводородов и способ синтеза углеводородов из синтез-газа
US20060223693A1 (en) * 2003-04-07 2006-10-05 Kenichiro Fujimoto Catalyst for producing hydrocarbon from synthsis gas and method for producing catalyst
US7524787B2 (en) 2005-01-11 2009-04-28 Sasol Technology (Proprietary Limited) Producing supported cobalt catalysts for the Fisher-Tropsch synthesis
EP1947073A1 (de) 2007-01-22 2008-07-23 Phillip Mertens Zubreitungsform mit verzögerter Freisetzungsrate für wasserlösliche und/oder wasserunlösliche Stoffe
US20100160464A1 (en) * 2008-12-24 2010-06-24 Chevron U.S.A. Inc. Zeolite Supported Cobalt Hybrid Fischer-Tropsch Catalyst
US7943674B1 (en) * 2009-11-20 2011-05-17 Chevron U.S.A. Inc. Zeolite supported cobalt hybrid fischer-tropsch catalyst
WO2013041997A1 (en) 2011-09-21 2013-03-28 Sasol Technology (Proprietary) Limited Process for preparing a cobalt - containing fischer tropsch catalyst

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4413064A (en) * 1981-10-13 1983-11-01 Gulf Research & Development Company Fluid bed catalyst for synthesis gas conversion and utilization thereof for preparation of diesel fuel
US7012104B2 (en) * 2002-10-16 2006-03-14 Conocophillips Company Fischer-Tropsch processes and catalysts made from a material comprising boehmite
CN101052466A (zh) * 2005-01-11 2007-10-10 萨索尔技术(控股)有限公司 费-托合成用的负载型钴催化剂的制造
WO2010097754A2 (en) * 2009-02-26 2010-09-02 Sasol Technology (Proprietary) Limited Catalysts

Also Published As

Publication number Publication date
RU2013154968A (ru) 2015-10-27
AU2012311175B2 (en) 2016-09-01
BR112013032165A2 (pt) 2016-12-13
CA2838233A1 (en) 2013-03-28
US20140155501A1 (en) 2014-06-05
BR112013032165B8 (pt) 2019-11-05
WO2013041997A1 (en) 2013-03-28
AR087975A1 (es) 2014-04-30
JP2014527908A (ja) 2014-10-23
JP5961694B2 (ja) 2016-08-02
RU2602803C2 (ru) 2016-11-20
MY164214A (en) 2017-11-30
US9248435B2 (en) 2016-02-02
NZ618839A (en) 2015-10-30
EP2758170B1 (en) 2015-10-07
EP2758170A1 (en) 2014-07-30
PE20140735A1 (es) 2014-06-30
CA2838233C (en) 2019-08-06
CN103635256A (zh) 2014-03-12
AP2013007293A0 (en) 2013-12-31
AU2012311175A1 (en) 2014-01-09
BR112013032165B1 (pt) 2019-09-03
ZA201309045B (en) 2014-08-27

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