CA2838233C - Process for preparing a cobalt - containing fischer tropsch catalyst - Google Patents

Process for preparing a cobalt - containing fischer tropsch catalyst Download PDF

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Publication number
CA2838233C
CA2838233C CA2838233A CA2838233A CA2838233C CA 2838233 C CA2838233 C CA 2838233C CA 2838233 A CA2838233 A CA 2838233A CA 2838233 A CA2838233 A CA 2838233A CA 2838233 C CA2838233 C CA 2838233C
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CA
Canada
Prior art keywords
catalyst precursor
cobalt compound
cobalt
catalyst
subsequent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CA2838233A
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English (en)
French (fr)
Other versions
CA2838233A1 (en
Inventor
Hendrik Van Rensburg
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sasol Technology Pty Ltd
Original Assignee
Sasol Technology Pty Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sasol Technology Pty Ltd filed Critical Sasol Technology Pty Ltd
Publication of CA2838233A1 publication Critical patent/CA2838233A1/en
Application granted granted Critical
Publication of CA2838233C publication Critical patent/CA2838233C/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/12—Oxidising
    • B01J37/14—Oxidising with gases containing free oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0213—Preparation of the impregnating solution
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
CA2838233A 2011-09-21 2012-08-31 Process for preparing a cobalt - containing fischer tropsch catalyst Active CA2838233C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ZA2011/06909 2011-09-21
ZA201106909 2011-09-21
PCT/IB2012/054493 WO2013041997A1 (en) 2011-09-21 2012-08-31 Process for preparing a cobalt - containing fischer tropsch catalyst

Publications (2)

Publication Number Publication Date
CA2838233A1 CA2838233A1 (en) 2013-03-28
CA2838233C true CA2838233C (en) 2019-08-06

Family

ID=47018331

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2838233A Active CA2838233C (en) 2011-09-21 2012-08-31 Process for preparing a cobalt - containing fischer tropsch catalyst

Country Status (14)

Country Link
US (1) US9248435B2 (enExample)
EP (1) EP2758170B1 (enExample)
JP (1) JP5961694B2 (enExample)
CN (1) CN103635256B (enExample)
AP (1) AP2013007293A0 (enExample)
AR (1) AR087975A1 (enExample)
AU (1) AU2012311175B2 (enExample)
BR (1) BR112013032165B8 (enExample)
CA (1) CA2838233C (enExample)
MY (1) MY164214A (enExample)
PE (1) PE20140735A1 (enExample)
RU (1) RU2602803C2 (enExample)
WO (1) WO2013041997A1 (enExample)
ZA (1) ZA201309045B (enExample)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013041997A1 (en) 2011-09-21 2013-03-28 Sasol Technology (Proprietary) Limited Process for preparing a cobalt - containing fischer tropsch catalyst
CA2971297C (en) * 2014-12-19 2023-06-20 Bp P.L.C. Process for preparation of a supported cobalt-containing fischer-tropsch synthesis catalyst
WO2017108791A1 (en) * 2015-12-21 2017-06-29 Shell Internationale Research Maatschappij B.V. Hydrogenation catalyst and method for preparing the same
JP6916219B2 (ja) 2016-08-11 2021-08-11 サソル サウス アフリカ リミティド コバルト含有触媒組成物

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4413064A (en) * 1981-10-13 1983-11-01 Gulf Research & Development Company Fluid bed catalyst for synthesis gas conversion and utilization thereof for preparation of diesel fuel
DE3839580C1 (enExample) 1988-11-24 1990-07-05 Condea Chemie Gmbh, 2212 Brunsbuettel, De
DZ2013A1 (fr) 1995-04-07 2002-10-23 Sastech Ltd Catalyseurs.
RU2223821C2 (ru) 1998-10-05 2004-02-20 Сэсол Текнолоджи (Проприетери) Лимитед Способ приготовления предшественника катализатора фишера-тропша
WO2004035193A2 (en) * 2002-10-16 2004-04-29 Conocophillips Company Fischer-tropsch processes and catalysts made from a material comprising boehmite
RU2340394C2 (ru) * 2002-10-16 2008-12-10 Конокофиллипс Кампэни Способ получения носителя для катализатора с повышенной гидротермальной стабильностью (варианты), катализатор для синтеза углеводородов и способ синтеза углеводородов из синтез-газа
US20060223693A1 (en) * 2003-04-07 2006-10-05 Kenichiro Fujimoto Catalyst for producing hydrocarbon from synthsis gas and method for producing catalyst
CN100537025C (zh) 2005-01-11 2009-09-09 萨索尔技术(控股)有限公司 费-托合成用的负载型钴催化剂的制造
US7524787B2 (en) 2005-01-11 2009-04-28 Sasol Technology (Proprietary Limited) Producing supported cobalt catalysts for the Fisher-Tropsch synthesis
EP1947073A1 (de) 2007-01-22 2008-07-23 Phillip Mertens Zubreitungsform mit verzögerter Freisetzungsrate für wasserlösliche und/oder wasserunlösliche Stoffe
US20100160464A1 (en) * 2008-12-24 2010-06-24 Chevron U.S.A. Inc. Zeolite Supported Cobalt Hybrid Fischer-Tropsch Catalyst
UA106739C2 (uk) 2009-02-26 2014-10-10 Сесол Текнолоджі (Пропрайєтері) Лімітед Спосіб одержання каталізаторів фішера-тропша та їх застосування
US7943674B1 (en) * 2009-11-20 2011-05-17 Chevron U.S.A. Inc. Zeolite supported cobalt hybrid fischer-tropsch catalyst
WO2013041997A1 (en) 2011-09-21 2013-03-28 Sasol Technology (Proprietary) Limited Process for preparing a cobalt - containing fischer tropsch catalyst

Also Published As

Publication number Publication date
RU2013154968A (ru) 2015-10-27
AU2012311175B2 (en) 2016-09-01
BR112013032165A2 (pt) 2016-12-13
CA2838233A1 (en) 2013-03-28
US20140155501A1 (en) 2014-06-05
BR112013032165B8 (pt) 2019-11-05
WO2013041997A1 (en) 2013-03-28
AR087975A1 (es) 2014-04-30
JP2014527908A (ja) 2014-10-23
JP5961694B2 (ja) 2016-08-02
RU2602803C2 (ru) 2016-11-20
MY164214A (en) 2017-11-30
US9248435B2 (en) 2016-02-02
NZ618839A (en) 2015-10-30
EP2758170B1 (en) 2015-10-07
EP2758170A1 (en) 2014-07-30
PE20140735A1 (es) 2014-06-30
CN103635256A (zh) 2014-03-12
AP2013007293A0 (en) 2013-12-31
AU2012311175A1 (en) 2014-01-09
BR112013032165B1 (pt) 2019-09-03
ZA201309045B (en) 2014-08-27
CN103635256B (zh) 2016-08-17

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