CN103550108A - Hair nourishing and damage repairing shampoo - Google Patents
Hair nourishing and damage repairing shampoo Download PDFInfo
- Publication number
- CN103550108A CN103550108A CN201310574280.2A CN201310574280A CN103550108A CN 103550108 A CN103550108 A CN 103550108A CN 201310574280 A CN201310574280 A CN 201310574280A CN 103550108 A CN103550108 A CN 103550108A
- Authority
- CN
- China
- Prior art keywords
- sodium
- hair
- shampoo
- parts
- percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention discloses hair nourishing and damage repairing shampoo. The hair nourishing and damage repairing shampoo comprises the components in percentage by weight: 0.5-5.0 percent of a medicinal plant extract, 0.1-3.0 percent of keratin, 8-12 percent of a surfactant, 4-8 percent of a conditioner, 0.3-1.5 percent of an acid-base regulator, 1-2 percent of a thickener, 0.5-2.0 percent of a pearlescing agent, 0.1-0.4 percent of salt and 68-80 percent of deionized water, wherein the medicinal plant extract is obtained by crushing medicinal plants, carrying out extraction or circulating extraction on the crushed medicinal plants with the water or ethyl alcohol as an extractant under the room temperature and ordinary pressure to obtain an extract solution, and concentrating the extract solution; the medicinal plant extract comprises the components in parts by weight: 10-25 parts of ligusticum wallichii, 15-30 parts of eclipta alba, 10-25 parts of astragalus membranaceus and 15-30 parts of cacumen biotae; the molecular weight of the keratin is no more than 40000 Daltons. With the adoption of the hair nourishing and damage repairing shampoo, damaged hairs can be relatively rapidly and effectively repaired, the uncooling feeling in the using process and after the use is avoided, a formula is also simplified, and the cost is lowered.
Description
Technical field
The invention belongs to shampoo field, particularly a kind of have nourishing hair and repair the shampoo of damaged hair function.
Background technology
Everybody wishes to have health, beautiful hair, but general people's hair all exists following problem:
(1) being subject to the increased popularity of the impact of air ambient and hair-waving, hair dyeing, there is damage in various degree and very general in people's hair.Chemical composition in hair-waving liquid medicine can make the scale on hair top layer suffer to destroy, come off, make hair internal structure in unprotect state, moisture and nutrient loss, keratoprotein generation degeneration, loss, make that hair easily turns to be yellow, embrittlement, lackluster, there is no elasticity, coarse grain raising, in addition the impact of air ambient, hair damage is serious and general;
(2) due to root of hair and hair malnutrition, root of hair forms thromboembolism, affect the nutrition of hair follicle, makes hair follicle atrophy breaking-up gradually, and then hair is tapered, dryly even becomes fragile and come off;
(3) along with hair lengths increases, its hair scale sheet cell partly comes off, and hair compliance variation, is easy to distortion, causes hair knotting and fracture very easily occur in combing and washing process.
For the variety of issue of hair and people's different demands, existing a variety of shampoos in prior art, but the formula of various shampoos is different, effect is difference to some extent also.Chinese patent ZL20071004987.5 discloses the shampoo of a kind of nourishing hair and anti-breaking anti-avulsion, the mass percent of contained component and each component is as follows: medicinal plant extract 10%～30%, keratin 2%～10%, surfactant 13%～20.5%, submissive conditioner 4.2%～7.5%, acid-base modifier 0.3%～1.5%, deionized water 32%～65%: described medicinal plant extract is that medicinal plants is pulverized, the extracting solution that the ethanol of take under room temperature normal pressure is extractant lixiviate or circulation extraction acquisition concentrates and forms, the component that medicinal plants contains and the mass parts of each component are as follows: 15～30 parts of the Radixs Polygoni Multiflori, 15～30 parts of Radix Angelicae Sinensis, 15～30 parts of the Radixs Astragali, 10～30 parts of Cacumen Platycladis, 10～30 parts of Semen Sesami Nigrums, 10～30 parts of Fructus Ligustri Lucidi, 10～30 parts of Radix Ginsengs, 10～30 parts, Pericarpium Zanthoxyli.What mainly solve due to this kind of shampoo is alopecia and easily from the problem of fracture of root, thereby has much room for improvement for the effect of hair damage reparation and the efficiency of reparation; Moreover this kind of shampoo needs the medicinal plant extract of high level and keratin just can reach the effect of nourishing hair and anti-breaking anti-avulsion, and medicinal plant extract various complexity of filling a prescription, thereby cost is relatively high.The medicinal plant extract of high-load and keratin are easily in hair surface deposition, and in shampoo, keratin molecule amount is higher, and then affect the cleaning performance of shampoo, when hair washing is used and after using, have clouding sense.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, a kind of shampoo with nourishing hair and injury repairing is provided, so that reparation damaged hair more rapidly and efficiently, formula is simplified in the clouding sense while avoiding using and after using simultaneously, reduces costs.
Nourishing hair of the present invention and injury repairing shampoo, its component comprises medicinal plant extract, keratin, surfactant, submissive conditioner, acid-base modifier, thickening agent, pearling agent, salt, deionized water, the mass percent of each component is as follows:
Described medicinal plant extract is that medicinal plants is pulverized, and under room temperature, normal pressure, take water or ethanol is that extractant lixiviate or circulation extract that the extracting solution obtaining is concentrated to be formed, and the component that medicinal plants contains and the mass parts of each component are as follows:
10～25 parts of Rhizoma Chuanxiongs, 15～30 parts of Herba Ecliptaes, 10～25 parts of the Radixs Astragali, 15～30 parts of Cacumen Platycladis;
Described keratic molecular weight≤40000 dalton, keratin can extract from hair, also can buy from market.
For making above-mentioned nourishing hair and injury repairing shampoo there is anti-corrosion function, and fragrant odour, can in formula, add essence and antiseptic, the mass percent of described essence is 0.5%～1.0%, the mass percent of described antiseptic is 0.05%～0.1%, and described antiseptic is at least one in Methylisothiazolinone, methylchloroisothiazandnone, DMDM Hydantoin, phenoxyethanol, sodium benzoate, benzoic acid, benzyl alcohol.
Above-mentioned nourishing hair and injury repairing shampoo, described pearling agent be ethylene glycol stearate, at least one in glycol distearate, pearl mica powder, Margarita powder.
Above-mentioned nourishing hair and injury repairing shampoo, described thickening agent is at least two kinds in coconut oil alkylamide, coconut oleoyl amine DEA, coconut oleoyl amine MEA, coconut oleoyl amine methyl MEA, coconut oleoyl amine MIPA, cocamido propyl betaine, lauryl betaine, lauryl hydroxyl sulphur betanin, lauryl glucoside, glyceryl laurate ester, LA, LAA, cetearyl alcohol, octadecanol, xanthan gum, carbomer and acrylic acid.
Above-mentioned nourishing hair and injury repairing shampoo, described salt is at least one in sodium chloride, ammonium chloride.
Above-mentioned nourishing hair and injury repairing shampoo, described surfactant is at least two kinds in laureth ammonium sulfate, ammonium lauryl sulfate, sodium laureth sulfate, laureth carboxylic acid sodium, sodium lauroyl sarcosine, lauroyl glycine potassium, sodium lauryl sulfate, laureth sodium sulfosuccinate.
Above-mentioned nourishing hair and injury repairing shampoo, described submissive conditioner is at least two kinds in polydimethylsiloxane, dimethiconol, ammonia end polydimethylsiloxane, amino two propyl group polydimethylsiloxane, Polyquaternium-10, polyquaternary ammonium salt-7, polyquaternary ammonium salt-47, PEG-7 glyceryl cocoate, guar hydroxypropyltrimonium chloride, hydroxypropyl guar hydroxypropyltrimonium chloride, Polyethylene Glycol-14M, Polyethylene Glycol-7M;
Above-mentioned nourishing hair and injury repairing shampoo, described soda acid mediator agent is at least one in citric acid, sodium citrate, EDETATE SODIUM.
The preparation method of shampoo of the present invention:
By surfactant, submissive conditioner, acid-base modifier, thickening agent, pearling agent and salt join in the reactor that part deionized water (quality of the deionized water that metering draws deducts 10kg and adds in this link) is housed, under agitation in normal heating to 60～80 ℃, after all dissolving, each component stops heating, mixed liquor is cooled to 40 ℃, add successively medicinal plant extract, keratin, essence (if having this component), antiseptic (if having this component), add again remaining deionized water, and continue to stir at least 10 minutes, then use homogenizer homogenizing at least 5 minutes, after homogenizing finishes, be cooled to room temperature and obtain shampoo.
With prior art, compare, the present invention has following beneficial effect:
1, due to keratic molecular weight≤40000 dalton in shampoo of the present invention, for low-molecular-weight keratin, compare the high molecular weight keratin in ZL20071004987.5, the keratin on itself and hair fiber surface has better reactivity worth, faster with the speed of action of hair surface horn cell, thereby within a short period of time can be incorporated in the horn cell of hair surface, realize the quick reparation that horn cell is damaged.Test shows, after using 5 minutes, the repair rate of impaired hair scale sheet cell can reach 65%～76%(and see embodiment 14).Keratin and four kinds of Chinese herbal medicine is composite simultaneously, further promote the effect of keratin to hair surface horn cell, make more rapid to the damaged reparation of hair surface horn cell, complete, after in shampoo of the present invention, continuous four immersions are also cleaned for 5 minutes, the repair rate of damaged hair hair scale sheet cell can reach 81%, compare ZL20071004987.5, repair rate improves more than 25% (sees comparative example).Thereby can avoid root of hair and hair malnutrition, root of hair forms thromboembolism, affect the nutrition of hair follicle, make hair follicle atrophy breaking-up gradually, thereby more comprehensive and efficient reparation because boiling hotly dying the hair jaundice, the embrittlement that bring with environmental effect, there is no the impaired problems such as elasticity, coarse grain raising, when particularly hair lengths increases, also can reduce fast its hair scale sheet cell detachment.
2, due to four kinds of medicinal plants and keratin composite after, can promote the effect of low-molecular-weight keratin and hair surface horn cell, simultaneously to higher molecular weight keratin in the certain obstruction of depositing of hair surface, thereby can to a certain degree alleviate keratin film forming and pile up the clouding sense bringing to user.
3, because medicinal plant extract in shampoo of the present invention is four kinds of medicinal plants, ZL20071004987.5 compares with patent, and composition and engineering is simple, cost-saving, but can reach same expansion scalp blood capillary, promote scalp blood circulation, strengthen the effect of scalp nutrition.
4, because medicinal plant extract in shampoo of the present invention and keratic content reduce greatly, medicinal plant extract is only 0.5%～5%, keratin is only 0.1%～3%, compare patent ZL20071004987.5 " medicinal plant extract 10%～30%; keratin 2%～10% ", consumption greatly reduces, and in medicinal plant extract, the component formula of Chinese herbal medicine is simple, thereby do not reducing product efficacy, can be cost-saving when strengthening damaged products repair function, simplify technique, there is significant economic implications.
5, owing to being added with pearling agent in shampoo of the present invention, can produce obvious pearl effect, there is stable pearl effect, add thickening agent, can strengthen the dry brightness of sending out, soft bright moistening, and there is hair care hair care and antistatic property.The viscosity that can also increase product simultaneously, has thickening conditioning functions, non-stimulated to skin, to hair not damaged.
6, through check, shampoo of the present invention meets sanitary index, and concrete data see the following form:
The specific embodiment
Embodiment 1
1, the preparation of medicinal plant extract
(1) batching
The component of medicinal plants and the mass parts of each component are: 25 parts of Rhizoma Chuanxiongs, 30 parts of Herba Ecliptaes, 25 parts of the Radixs Astragali, 30 parts of Cacumen Platycladis.
(2) circulation is extracted
After being pulverized, medicinal plants puts into Soxhlet extractor, under room temperature (20 ℃), normal pressure, take ethanol as extractant circulation extraction 3 hours, the extracting solution obtaining adopts distillation and concentration, and the time of distillation and concentration completely volatilizees and is limited with ethanol, and the product of distillation and concentration is medicinal plant extract.
Embodiment 2
The preparation of medicinal plant extract, step is as follows:
(1) batching
The component of medicinal plants and the mass parts of each component are: 10 parts of Rhizoma Chuanxiongs, 15 parts of Herba Ecliptaes, 10 parts of the Radixs Astragali, 15 parts of Cacumen Platycladis.
(2) lixiviate
After medicinal plants is pulverized, put into the container that ethanol is housed soaks under room temperature (28 ℃), normal pressure, the amount of ethanol is flooded medicinal plants, soak time is 1.0 hours, soak and finish to obtain after filtration extracting solution, filtering residue is repeated to aforementioned operation 3 times, merge each extracting solution obtaining and carry out distillation and concentration, the time of distillation and concentration completely volatilizees and is limited with ethanol, and the product of distillation and concentration is medicinal plant extract.
Embodiment 3
The preparation of medicinal plant extract, step is as follows:
(1) batching
The component of medicinal plants and the mass parts of each component are: 15 parts of Rhizoma Chuanxiongs, 20 parts of Herba Ecliptaes, 15 parts of the Radixs Astragali, 20 parts of Cacumen Platycladis.
(2) circulation is extracted
After being pulverized, medicinal plants puts into Soxhlet extractor, under room temperature (25 ℃), normal pressure, take deionized water as extractant circulation extraction 4 hours, the extracting solution that obtains adopts distillation and concentration, be concentrated into solid (phase) thing both occur can, the product of distillation and concentration is medicinal plant extract.
Embodiment 4
The preparation of medicinal plant extract, step is as follows:
(1) batching
The component of medicinal plants and the mass parts of each component are: 20 parts of Rhizoma Chuanxiongs, 25 parts of Herba Ecliptaes, 20 parts of the Radixs Astragali, 25 parts of Cacumen Platycladis.
(2) lixiviate
After medicinal plants is pulverized, put into the container that deionized water is housed soaks under room temperature (23 ℃), normal pressure, the amount of deionized water is flooded medicinal plants, soak time is 2 hours, soak and finish to obtain after filtration extracting solution, filtering residue is repeated to aforementioned operation 4 times, merge each extracting solution obtaining and carry out distillation and concentration, the time concentration of distillation and concentration to have solid (phase) thing both occur can, the product of distillation and concentration is medicinal plant extract.
Embodiment 5
Keratin preparation, step is as follows:
Human hair's water is cleaned up and pulverized, then the human hair after pulverizing being regulated to pH value with sodium hydroxide is 11, the TGA sodium solution of concentration 0.5mol/L (2 times that consumption is hair weight) is at normal pressure, room temperature (20 ℃) is soaked 3 hours, in described soak, add carbamide again, the addition of carbamide is that the concentration in soak reaches 7mol/L, continue after at normal pressure, room temperature (20 ℃) reduction reaction 25 hours, after response time arrives, splash into the pH value to 7 that acetic acid regulates reactant liquor, then in solution, pass into oxygen (being advisable with continuous bubbling), room temperature (20 ℃) sustained response 0.5 hour, response time filters after expiring, filtrate is carried out to dialysis with holding back the daltonian dialysis bag of relative molecular weight 40000, centrifugalize obtains the daltonian keratin solution first product in molecular weight≤40000, keratin solution first product is saltoutd and obtained keratin solid, in room temperature vacuum drying (vacuum: 6 kPas, baking temperature: 20 ℃, drying time: 12 hours), obtain keratin, yield 43%.
Embodiment 6
Keratin preparation
Pilus Caprae seu Ovis water is cleaned up and pulverized, then the Pilus Caprae seu Ovis after pulverizing being regulated to pH value with sodium hydroxide is 11, the TGA sodium solution of concentration 0.5mol/L (2 times that consumption is hair weight) is at normal pressure, room temperature (30 ℃) is soaked 3 hours, in described soak, add carbamide again, the addition of carbamide is that the concentration in soak reaches 7mol/L, continue after at normal pressure, room temperature (30 ℃) reduction reaction 25 hours, after response time expires, splash into the pH value to 7 that acetic acid regulates reactant liquor, then to passing into oxygen (being advisable with continuous bubbling) in solution room temperature (30 ℃) sustained response 0.5 hour, response time filters after expiring, filtrate is carried out to dialysis with holding back the daltonian dialysis bag of relative molecular weight 40000, it is≤40000 daltonian keratin solution first products that centrifugalize obtains molecular weight, keratin solution first product is saltoutd and obtained keratin solid, in room temperature vacuum drying (vacuum: 6 kPas, baking temperature: 20 ℃, drying time: 12 hours), obtain keratin, yield 39%.
Embodiment 7
The preparation of shampoo
(1) batching
The component of shampoo and the mass percent of each component are as follows:
Surfactant: laureth ammonium sulfate 6Kg, ammonium lauryl sulfate 2.65Kg;
Submissive conditioner: polydimethylsiloxane 5Kg, Polyquaternium-10 3Kg;
Acid-base modifier: citric acid 0.15Kg, sodium citrate 0.15Kg;
Thickening agent: coconut oil alkylamide 0.5Kg, lauryl betaine 0.5Kg;
Pearling agent: glycol distearate 0.5Kg;
Salt: ammonium chloride 0.4Kg;
The medicinal plant extract 0.5Kg of embodiment 1 preparation;
The keratin 0.1Kg of embodiment 6 preparations;
Fragrant Qian 0.5Kg;
Antiseptic: methylchloroisothiazandnone 0.05Kg;
Deionized water: 80kg
Surfactant, submissive conditioner, acid-base modifier, thickening agent, pearling agent and salt are joined in the reactor that deionized water 70Kg is housed, under agitation in normal heating to 60 ℃, after all dissolving completely, each component stops heating, mixed liquor is cooled to 40 ℃, adds successively medicinal plant extract, keratin, fragrant Qian, antiseptic, add again remaining deionized water 10Kg, continue to stir 15 minutes, then use homogenizer homogenizing 6 minutes, be then cooled to room temperature and be shampoo.
Embodiment 8
The preparation of shampoo
(1) batching
The component of shampoo and the mass percent of each component are as follows:
Surfactant: sodium laureth sulfate 5Kg, laureth carboxylic acid sodium 6Kg;
Submissive conditioner: polyquaternary ammonium salt-74Kg, polyquaternary ammonium salt-472.3Kg;
Acid-base modifier: citric acid 0.5Kg, sodium citrate 0.5Kg, EDETATE SODIUM 0.5Kg;
Thickening agent: coconut oleoyl amine DEA1Kg, cocamido propyl betaine 1Kg,
Pearling agent: pearl mica powder 1Kg, glycol distearate 1Kg
Salt: sodium chloride 0.1Kg;
The medicinal plant extract 5Kg of embodiment 2 preparations;
The keratin 3Kg of embodiment 5 preparations;
Fragrant Qian 1Kg;
Antiseptic: Methylisothiazolinone 0.1Kg;
Deionized water: 68g
Surfactant, submissive conditioner, acid-base modifier, thickening agent, pearling agent and salt are joined in the reactor that deionized water 58Kg is housed, under agitation in normal heating to 70 ℃, after all dissolving completely, each component stops heating, mixed liquor is cooled to 40 ℃, adds successively medicinal plant extract, keratin, fragrant Qian, antiseptic, add again remaining deionized water 10Kg, continue to stir 12 minutes, then use homogenizer homogenizing 5 minutes, be then cooled to room temperature and be shampoo.
Embodiment 9
Surfactant: laureth ammonium sulfate 6Kg, sodium lauroyl sarcosine 2Kg, laureth sodium sulfosuccinate 2Kg;
Submissive conditioner: ammonia end polydimethylsiloxane 1Kg, amino two propyl group polydimethylsiloxane 3Kg, guar hydroxypropyltrimonium chloride 2Kg;
Acid-base modifier: citric acid 0.25Kg, sodium citrate 0.25Kg, EDETATE SODIUM 0.5Kg;
Thickening agent: lauryl hydroxyl sulphur betanin 1.0Kg, xanthan gum 0.5Kg;
Pearling agent: Margarita powder 1.5Kg;
Salt: sodium chloride 0.2Kg;
The medicinal plant extract 4Kg of embodiment 3 preparations;
The keratin 2Kg of embodiment 5 preparations;
Fragrant Qian 0.8Kg;
Antiseptic: DMDM Hydantoin 0.08Kg;
Deionized water: 72.92Kg g
Surfactant, submissive conditioner, acid-base modifier, thickening agent, pearling agent and salt are joined in the reactor that deionized water 62.92Kg is housed, under agitation in normal heating to 80 ℃, after all dissolving completely, each component stops heating, mixed liquor is cooled to 40 ℃, adds successively medicinal plant extract, keratin, fragrant Qian, antiseptic, add again remaining deionized water 10Kg, continue to stir 10 minutes, then use homogenizer homogenizing 5 minutes, be then cooled to room temperature and be shampoo.
Embodiment 10
Surfactant: laureth ammonium sulfate 4Kg, lauroyl glycine potassium 3Kg, sodium laureth sulfate 3Kg;
Submissive conditioner: PEG-7 glyceryl cocoate 2Kg, hydroxypropyl guar hydroxypropyltrimonium chloride 2Kg;
Acid-base modifier: EDETATE SODIUM 0.6Kg;
Thickening agent: lauryl glucoside 0.5Kg, glyceryl laurate ester 0.4Kg, LA 0.4Kg;
Pearling agent: pearl mica powder 1Kg;
Salt: sodium chloride 0.1Kg, ammonium chloride 0.2Kg;
The medicinal plant extract 2Kg of embodiment 4 preparations;
The Keratin 1 Kg of embodiment 6 preparations;
Fragrant Qian 0.7Kg;
Antiseptic: phenoxyethanol 0.06Kg;
Deionized water: 79.04Kg g;
Surfactant, submissive conditioner, acid-base modifier, thickening agent, pearling agent and salt are joined in the reactor that deionized water 69.04Kg is housed, under agitation in normal heating to 60 ℃, after all dissolving completely, each component stops heating, mixed liquor is cooled to 40 ℃, adds successively medicinal plant extract, keratin, fragrant Qian, antiseptic, add again remaining deionized water 10Kg, continue to stir 10 minutes, then use homogenizer homogenizing 5 minutes, be then cooled to room temperature and be shampoo.
Embodiment 11
Surfactant: ammonium lauryl sulfate 6Kg, laureth carboxylic acid sodium 4Kg, sodium lauryl sulfate 2Kg;
Submissive conditioner: hydroxypropyl guar hydroxypropyltrimonium chloride 4Kg, Polyethylene Glycol-14M4Kg;
Acid-base modifier: citric acid 0.6Kg, sodium citrate 0.6Kg;
Thickening agent: coconut oleoyl amine MEA0.6Kg, coconut oleoyl amine methyl MEA0.5Kg, coconut oleoyl amine MIPA0.6Kg;
Pearling agent: ethylene glycol stearate 0.7Kg, pearl mica powder 0.6Kg;
Salt: sodium chloride 0.2Kg;
The medicinal plant extract 1Kg of embodiment 3 preparations;
The keratin 0.5Kg of embodiment 6 preparations;
Fragrant Qian 0.7Kg;
Antiseptic: sodium benzoate 0.03Kg, benzoic acid 0.03Kg;
Deionized water: 73.34Kg;
Surfactant, submissive conditioner, acid-base modifier, thickening agent, pearling agent and salt are joined in the reactor that deionized water 63.34Kg is housed, under agitation in normal heating to 60 ℃, after all dissolving completely, each component stops heating, mixed liquor is cooled to 40 ℃, adds successively medicinal plant extract, keratin, fragrant Qian, antiseptic, add again remaining deionized water 10Kg, continue to stir 10 minutes, then use homogenizer homogenizing 5 minutes, be then cooled to room temperature and be shampoo.
Embodiment 12
Surfactant: laureth sodium sulfosuccinate 5Kg, sodium laureth sulfate 4Kg;
Submissive conditioner: Polyethylene Glycol-7M2Kg, dimethiconol 4Kg;
Acid-base modifier: citric acid 0.7Kg, sodium citrate 0.7Kg;
Thickening agent: LAA 0.5Kg, cetearyl alcohol 0.4Kg, carbomer 0.4Kg;
Pearling agent: glycol distearate 0.7Kg;
Salt: sodium chloride 0.3Kg;
The medicinal plant extract 3Kg of embodiment 1 preparation;
The keratin 0.8Kg of embodiment 5 preparations;
Fragrant Qian 0.9Kg;
Antiseptic: benzyl alcohol 0.07Kg;
Deionized water: 76.53Kg;
Surfactant, submissive conditioner, acid-base modifier, thickening agent, pearling agent and salt are joined in the reactor that deionized water 66.53Kg is housed, under agitation in normal heating to 70 ℃, after all dissolving completely, each component stops heating, mixed liquor is cooled to 40 ℃, adds successively medicinal plant extract, keratin, fragrant Qian, antiseptic, add again remaining deionized water 10Kg, continue to stir 15 minutes, then use homogenizer homogenizing 8 minutes, be then cooled to room temperature and be shampoo.
Embodiment 13
Surfactant: laureth ammonium sulfate 4Kg, laureth sodium sulfosuccinate 4Kg;
Submissive conditioner: Polyethylene Glycol-7M3Kg, guar hydroxypropyltrimonium chloride 4Kg;
Acid-base modifier: citric acid 0.7Kg, sodium citrate 0.7Kg;
Thickening agent: octadecanol 0.5Kg, acrylate copolymer 0.7Kg;
Pearling agent: ethylene glycol stearate 0.7Kg;
Salt: sodium chloride 0.3Kg;
The medicinal plant extract 1.5Kg of embodiment 4 preparations;
The Keratin 1 .5Kg of embodiment 6 preparations;
Fragrant Qian 1Kg;
Antiseptic: benzyl alcohol 0.07Kg;
Deionized water: 77.33Kg;
Surfactant, submissive conditioner, acid-base modifier, thickening agent, pearling agent and salt are joined in the reactor that deionized water 67.33Kg is housed, under agitation in normal heating to 70 ℃, after all dissolving completely, each component stops heating, mixed liquor is cooled to 40 ℃, adds successively medicinal plant extract, keratin, fragrant Qian, antiseptic, add again remaining deionized water 10Kg, continue to stir 10 minutes, then use homogenizer homogenizing 5 minutes, be then cooled to room temperature and be shampoo.
Embodiment 14: the impact of keratin molecule amount on repairing effect
In the present embodiment, the daltonian keratin in molecular weight≤40000 is embodiment 6 preparation, and molecular weight≤10000 dalton, molecular weight≤80000 dalton, the daltonian keratin in molecular weight≤90000 adopt method described in embodiment 6 to take the dialysis bag dialysis preparation of PSPP.
Experimental procedure:
(1) get sub-thirty human hair, length is 10cm, and every 10 is one group, totally 16 groups.Use respectively the sodium dodecyl sulfate solution 2g of mass concentration 3% to clean in the hair of respectively organizing of choosing, and each group hair is carried out to machinery rubbing 5 minutes, then examine under a microscope and respectively organize hair surface hair scale sheet cellularity destruction situation also counting, labelling.
(2) the above-mentioned hair of respectively organizing is soaked in respectively to keratin with different molecular weight and (according to the difference of holding back relative molecular weight, changes the dialysis bag of different size, method according to embodiment 6 is prepared gained) in the shampoo prepared by method described in embodiment 10, and constantly stir, after 5 minutes, 10 minutes, 15 minutes, 20 minutes, take out respectively, with clear water, rinse 3 times, each 1 minute, then naturally dry.
(3) hair of respectively organizing after drying is examined under a microscope respectively, in counting step (1), the impaired hair scale sheet of mark hair surface cellularity is repaired situation and calculates repair rate:
The impaired hair scale sheet of hair surface cellularity is repaired result (in table, percent is repair rate) and is seen the following form:
From above test result, keratic molecular weight is when≤40000 dalton, and repairing effect is better.
Embodiment 15
1, sample preparation
(1) shampoo sample A is the shampoo of embodiment 10 preparations.
(2) component of control sample B and the content of each component are as follows:
Surfactant: laureth ammonium sulfate 4Kg, lauroyl glycine potassium 3Kg, sodium laureth sulfate 3Kg;
Submissive conditioner: PEG-7 glyceryl cocoate 2Kg, hydroxypropyl guar hydroxypropyltrimonium chloride 2Kg;
Acid-base modifier: EDETATE SODIUM 0.6Kg;
Thickening agent: lauryl glucoside 0.5Kg, glyceryl laurate ester 0.4Kg, LA 0.4Kg;
Pearling agent: pearl mica powder 1Kg;
Salt: sodium chloride 0.1Kg, ammonium chloride 0.2Kg;
The medicinal plant extract 2Kg of embodiment 4 preparations;
Fragrant Qian 0.7Kg;
Antiseptic: phenoxyethanol 0.06Kg;
Deionized water: 80.04Kg g;
Preparation method is identical with embodiment 10.
(3) component of control sample C and the content of each component are as follows:
Surfactant: laureth ammonium sulfate 4Kg, lauroyl glycine potassium 3Kg, sodium laureth sulfate 3Kg;
Submissive conditioner: PEG-7 glyceryl cocoate 2Kg, hydroxypropyl guar hydroxypropyltrimonium chloride 2Kg;
Acid-base modifier: EDETATE SODIUM 0.6Kg;
Thickening agent: lauryl glucoside 0.5Kg, glyceryl laurate ester 0.4Kg, LA 0.4Kg;
Pearling agent: pearl mica powder 1Kg;
Salt: sodium chloride 0.1Kg, ammonium chloride 0.2Kg;
The Keratin 1 Kg of embodiment 6 preparations;
Fragrant Qian 0.7Kg;
Antiseptic: phenoxyethanol 0.06Kg;
Deionized water: 81.04Kg g;
Preparation method is identical with embodiment 10.
(4) component of control sample D and the content of each component are as follows:
Surfactant: laureth ammonium sulfate 4Kg, lauroyl glycine potassium 3Kg, sodium laureth sulfate 3Kg;
Submissive conditioner: PEG-7 glyceryl cocoate 2Kg, hydroxypropyl guar hydroxypropyltrimonium chloride 2Kg;
Acid-base modifier: EDETATE SODIUM 0.6Kg;
Thickening agent: lauryl glucoside 0.5Kg, glyceryl laurate ester 0.4Kg, LA 0.4Kg;
Pearling agent: pearl mica powder 1Kg;
Salt: sodium chloride 0.1Kg, ammonium chloride 0.2Kg;
Fragrant Qian 0.7Kg;
Antiseptic: phenoxyethanol 0.06Kg;
Deionized water: 82.04Kg g;
Preparation method is identical with embodiment 10.
2, topknot pretreatment:
(1) after large topknot (sub-thirty human hair) is cleaned with the sodium dodecyl sulfate solution of mass concentration 3%, in ether, soak 24 hours, topknot after ether is processed is made the little topknot of the long 23cm of multi beam, heavy 3g, each little topknot is used after distilled water moistening, with the sodium dodecyl sulfate solution 2g of mass concentration 3%, rub and wash 2～3 minutes respectively, then with flowing water, rinse well, naturally dry stand-by.
(2) wet comb resistance measurement: by shampoo sample A, each 3 grams of control sample B, C, D are respectively used to rub the long 23cm washing after a branch of step (1) is processed, the little topknot of weight 3g, rubbing the time of washing is 5 minutes, then with 40 ℃ of lasting current, rinse 2 minutes respectively, by four washed bundle Hair grooming matter structure instrument (BROOKFIELD, CT3-2K) tests.
(3) dry comb resistance measurement: by shampoo sample A, each 3 grams of control sample B, C, D are respectively used to rub the long 23cm washing after a branch of step (1) is processed, the little topknot of weight 3g, rubbing the time of washing is 5 minutes, then with 40 ℃ of lasting current, rinse 2 minutes respectively, reusable heat hair-dryer is by hair dryer, continue after by dry up four bundle Hair grooming matter structure instrument (BROOKFIELD, CT3-2K) test.
(4) average tensile strength test: by shampoo sample A, each 3 grams of control sample B, C, D are respectively used to rub the long 23cm washing after a branch of step (1) is processed, the little topknot of weight 3g, rubbing the time of washing is 5 minutes, then with 40 ℃ of lasting current, rinse 2 minutes respectively, reusable heat hair-dryer is hair dryer, continue after respectively get respectively 5 hairs the topknot that dries up from four bundles and be fixed on matter structure instrument (BROOKFIELD, CT3-2K) two ends, start upper end and upwards stretch, to hairs break.
(5) brightness test: by shampoo sample A, each 3 grams of control sample B, C, D are respectively used to rub the long 23cm washing after a branch of step (1) is processed, the little topknot of weight 3g, rubbing the time of washing is 5 minutes, then with 40 ℃ of lasting current, rinse 2 minutes respectively, reusable heat hair-dryer is by hair dryer, continue after topknot that four bundles are dried up with after comb combing, being organized into respectively wide is the tabular of 2cm, be fixed in standard light source VERIVIDE COLOR ASSESMENT CABINET, the brightness of respectively restrainting hair by code of points evaluation processed in 5 minutes by the evaluator who trained, 1 be divided into dark, 5 be divided into bright.
Test result is shown in following each table:
Shi Shu resistance unit: newton
| Sample | A | B | C | D |
| Resistance | 36 | 49 | 41 | 53 |
Gan Shu resistance unit: newton
| Sample | A | B | C | D |
| Resistance | 47 | 57 | 51 | 61 |
Tensile strength unit: newton
| Sample | A | B | C | D |
| Resistance | 156 | 124 | 143 | 109 |
Brightness
| Sample | A | B | C | D |
| Mark | 5 | 4 | 5 | 3 |
From above test result, shampoo of the present invention, with respect to control sample, can make dry, the wet comb resistance of hair decline, and tensile strength increases, and the dry brightness of sending out also obviously increases.
Comparative example
Experimental procedure:
1, get sub-thirty human hair, length is 10cm, and every 10 is one group, totally 5 groups.Each group hair is cleaned with the sodium dodecyl sulfate solution 2g of mass concentration 3% respectively, then each group hair is carried out to machinery rubbing 5 minutes, then examine under a microscope and respectively organize hair surface hair scale sheet cellularity destruction situation, and counting, labelling.
2, prepare shampoo
(1) shampoo A is the shampoo of embodiment 10 preparations.
(2) component of shampoo B and the content of each component are as follows:
Surfactant: laureth ammonium sulfate 4Kg, lauroyl glycine potassium 3Kg, sodium laureth sulfate 3Kg;
Submissive conditioner: PEG-7 glyceryl cocoate 2Kg, hydroxypropyl guar hydroxypropyltrimonium chloride 2Kg;
Acid-base modifier: EDETATE SODIUM 0.6Kg;
Thickening agent: lauryl glucoside 0.5Kg, glyceryl laurate ester 0.4Kg, LA 0.4Kg;
Pearling agent: pearl mica powder 1Kg;
Salt: sodium chloride 0.1Kg, ammonium chloride 0.2Kg;
The medicinal plant extract 2Kg of embodiment 4 preparations;
Fragrant Qian 0.7Kg;
Antiseptic: phenoxyethanol 0.06Kg;
Deionized water: 80.04Kg g;
Preparation method is identical with embodiment 10.
(3) component of shampoo C and the content of each component are as follows:
Surfactant: laureth ammonium sulfate 4Kg, lauroyl glycine potassium 3Kg, sodium laureth sulfate 3Kg;
Submissive conditioner: PEG-7 glyceryl cocoate 2Kg, hydroxypropyl guar hydroxypropyltrimonium chloride 2Kg;
Acid-base modifier: EDETATE SODIUM 0.6Kg;
Thickening agent: lauryl glucoside 0.5Kg, glyceryl laurate ester 0.4Kg, LA 0.4Kg;
Pearling agent: pearl mica powder 1Kg;
Salt: sodium chloride 0.1Kg, ammonium chloride 0.2Kg;
The Keratin 1 Kg of embodiment 6 preparations;
Fragrant Qian 0.7Kg;
Antiseptic: phenoxyethanol 0.06Kg;
Deionized water: 81.04Kg g;
Preparation method is identical with embodiment 10.
(4) component of shampoo D and the content of each component are as follows:
Surfactant: laureth ammonium sulfate 4Kg, lauroyl glycine potassium 3Kg, sodium laureth sulfate 3Kg;
Submissive conditioner: PEG-7 glyceryl cocoate 2Kg, hydroxypropyl guar hydroxypropyltrimonium chloride 2Kg;
Acid-base modifier: EDETATE SODIUM 0.6Kg;
Thickening agent: lauryl glucoside 0.5Kg, glyceryl laurate ester 0.4Kg, LA 0.4Kg;
Pearling agent: pearl mica powder 1Kg;
Salt: sodium chloride 0.1Kg, ammonium chloride 0.2Kg;
Fragrant Qian 0.7Kg;
Antiseptic: phenoxyethanol 0.06Kg;
Deionized water: 82.04Kg g;
Preparation method is identical with embodiment 10.
(5) shampoo E: shampoo E is the shampoo of ZL20071004987.5 embodiment 1 preparation.
In shampoo E, the component of medicinal plant extract and the content of each component are as follows:
15 parts of the Radixs Polygoni Multiflori, 15 parts of Radix Angelicae Sinensis, 15 parts of the Radixs Astragali, 10 parts of Cacumen Platycladis, 10 parts of Semen Sesami Nigrums, 10 parts of Radix Ginsengs, 15 parts, Pericarpium Zanthoxyli.
The component of shampoo E and the content of each component are as follows:
Above-mentioned medicinal plant extract: 15.5%;
Procom keratin: 2%;
Surfactant: lauryl alcohol ammonium sulfate (70%) 12%, glycol stearate 0.5%, coconut oil alkylamide 0.5%;
Submissive conditioner: emulsified silicone oil (50%) 4%, Polyquaternium-10 0.2%;
Acid-base modifier: citric acid 0.1%, sodium citrate 0.2%;
Deionized water: 65%.
3, the above-mentioned hair of respectively organizing is soaked in respectively in shampoo A, B, C, D, E, and constantly stirs, after 5 minutes, take out, with clear water, rinse 3 times, each 1 minute, natural airing then.Repetitive operation 4 times.
4, the hair of respectively organizing after 4 soaking and washing, airing is examined under a microscope respectively, in counting step (1), the impaired hair scale sheet of the hair surface cellularity of mark is repaired situation, calculates repair rate:
Test result sees the following form:
| Shampoo | A | B | C | D | E |
| Repair rate | 81% | 18% | 68% | 5% | 56% |
As can be known from the above table, shampoo Chinese medicine extract of the present invention and the keratic composite repair rate that can effectively improve damaged hair, compare ZL20071004987.5, and repair rate improves 25%.
Claims (10)
1. a nourishing hair and injury repairing shampoo, it is characterized in that component comprises medicinal plant extract, keratin, surfactant, submissive conditioner, acid-base modifier, thickening agent, pearling agent, salt, deionized water, the mass percent of each component is as follows:
Described medicinal plant extract is that medicinal plants is pulverized, and under room temperature, normal pressure, take water or ethanol is that extractant lixiviate or circulation extract that the extracting solution obtaining is concentrated to be formed, and the component that medicinal plants contains and the mass parts of each component are as follows:
10～25 parts of Rhizoma Chuanxiongs, 15～30 parts of Herba Ecliptaes, 10～25 parts of the Radixs Astragali, 15～30 parts of Cacumen Platycladis;
Described keratic molecular weight≤40000 dalton.
2. nourishing hair and injury repairing shampoo according to claim 1, characterized by further comprising essence and antiseptic, the mass percent of described essence is 0.5%～1.0%, the mass percent of described antiseptic is 0.05%～0.1%, and described antiseptic is at least one in Methylisothiazolinone, methylchloroisothiazandnone, DMDM Hydantoin, phenoxyethanol, sodium benzoate, benzoic acid, benzyl alcohol.
3. according to described nourishing hair described in claim 1 or 2 and injury repairing shampoo, it is characterized in that described pearling agent be ethylene glycol stearate, at least one in glycol distearate, pearl mica powder, Margarita powder.
4. according to described nourishing hair described in claim 1 or 2 and injury repairing shampoo, it is characterized in that described thickening agent is at least two kinds in coconut oil alkylamide, coconut oleoyl amine DEA, coconut oleoyl amine MEA, coconut oleoyl amine methyl MEA, coconut oleoyl amine MIPA, cocamido propyl betaine, lauryl betaine, lauryl hydroxyl sulphur betanin, lauryl glucoside, glyceryl laurate ester, LA, LAA, cetearyl alcohol, octadecanol, xanthan gum, carbomer and acrylic acid.
5. described nourishing hair and injury repairing shampoo according to claim 3, is characterized in that described thickening agent is at least two kinds in coconut oil alkylamide, coconut oleoyl amine DEA, coconut oleoyl amine MEA, coconut oleoyl amine methyl MEA, coconut oleoyl amine MIPA, cocamido propyl betaine, lauryl betaine, lauryl hydroxyl sulphur betanin, lauryl glucoside, glyceryl laurate ester, LA, LAA, cetearyl alcohol, octadecanol, xanthan gum, carbomer and acrylic acid.
6. according to described nourishing hair described in claim 1 or 2 and injury repairing shampoo, it is characterized in that described salt is at least one in sodium chloride, ammonium chloride.
7. described nourishing hair and injury repairing shampoo according to claim 3, is characterized in that described salt is at least one in sodium chloride, ammonium chloride.
8. described nourishing hair and injury repairing shampoo according to claim 4, is characterized in that described salt is at least one in sodium chloride, ammonium chloride.
9. described nourishing hair and injury repairing shampoo according to claim 5, is characterized in that described salt is at least one in sodium chloride, ammonium chloride.
10. according to nourishing hair described in claim 1 or 2 and injury repairing shampoo, it is characterized in that described surfactant is at least two kinds in laureth ammonium sulfate, ammonium lauryl sulfate, sodium laureth sulfate, laureth carboxylic acid sodium, sodium lauroyl sarcosine, lauroyl glycine potassium, sodium lauryl sulfate, laureth sodium sulfosuccinate;
Described submissive conditioner is at least two kinds in polydimethylsiloxane, dimethiconol, ammonia end polydimethylsiloxane, amino two propyl group polydimethylsiloxane, Polyquaternium-10, polyquaternary ammonium salt-7, polyquaternary ammonium salt-47, PEG-7 glyceryl cocoate, guar hydroxypropyltrimonium chloride, hydroxypropyl guar hydroxypropyltrimonium chloride, Polyethylene Glycol-14M, Polyethylene Glycol-7M;
Described soda acid mediator agent is at least one in citric acid, sodium citrate, EDETATE SODIUM.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310574280.2A CN103550108B (en) | 2013-11-15 | 2013-11-15 | Nourishing hair and injury repairing shampoo |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310574280.2A CN103550108B (en) | 2013-11-15 | 2013-11-15 | Nourishing hair and injury repairing shampoo |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103550108A true CN103550108A (en) | 2014-02-05 |
| CN103550108B CN103550108B (en) | 2016-01-20 |
Family
ID=50004595
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310574280.2A Active CN103550108B (en) | 2013-11-15 | 2013-11-15 | Nourishing hair and injury repairing shampoo |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103550108B (en) |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104095792A (en) * | 2014-07-22 | 2014-10-15 | 广州好迪集团有限公司 | Hair conditioner capable of nourishing hair and repairing damage |
| CN104958204A (en) * | 2015-06-18 | 2015-10-07 | 湖南炎帝生物工程有限公司 | Liquid shampoo containing common nostoc extracts and preparation method of liquid shampoo |
| CN105919900A (en) * | 2016-06-27 | 2016-09-07 | 北京普世安生物科技有限公司 | Hair re-growing and hair loss preventing shampoo and preparation method thereof |
| CN105997567A (en) * | 2016-06-22 | 2016-10-12 | 广州好迪集团有限公司 | Silicone-oil-free conditioning and refreshing shampoo |
| CN106137852A (en) * | 2016-08-17 | 2016-11-23 | 禹州市合同泰药业有限公司 | A kind of Traditional Chinese herbal liquid shampoo of growing and blacking hair and preparation method thereof |
| CN106344445A (en) * | 2016-08-26 | 2017-01-25 | 广州舒泰生物技术有限公司 | Amino acid shampoo and preparation method thereof |
| CN106726869A (en) * | 2016-11-18 | 2017-05-31 | 广州环亚化妆品科技有限公司 | A kind of shampoo of natural no stimulation and preparation method thereof |
| CN107019789A (en) * | 2017-05-27 | 2017-08-08 | 云南白药集团股份有限公司 | Hair-loss preventing and hair-restoring Chinese medicine composition, its preparation method and application |
| CN107320358A (en) * | 2017-08-25 | 2017-11-07 | 安庆徽云博冠化妆品科技有限公司 | A kind of Ai Xiang mildy wash and preparation method thereof |
| CN107362104A (en) * | 2017-09-04 | 2017-11-21 | 上海张苍生物科技有限公司 | A kind of alopecia-stopping, the leaves shampoo of hair tonic |
| CN107789242A (en) * | 2017-09-25 | 2018-03-13 | 吉安市御美丽健康产业股份有限公司 | It is a kind of suitable for ginseng shampoo of damaged hair and preparation method thereof |
| CN108085155A (en) * | 2017-12-27 | 2018-05-29 | 安徽金润发制品有限公司 | A kind of wig cleaning maintenance liquid |
| CN108283599A (en) * | 2017-01-09 | 2018-07-17 | 唐玲妹 | Herbaceous plant boils dandruff-removing itching-relieve stoste |
| CN108392452A (en) * | 2018-06-01 | 2018-08-14 | 韩兴旺 | A kind of shampoo of nourishing hair and anti-breaking anti-avulsion |
| CN108741563A (en) * | 2018-05-07 | 2018-11-06 | 肖忠波 | A kind of 50 degree of low temperature Nursing health method for permanent waving hair |
| CN109646352A (en) * | 2019-01-10 | 2019-04-19 | 澳宝化妆品（惠州）有限公司 | A kind of hair-washing composition with anti-dandruff performance containing pomegranate rind extract |
| CN109875951A (en) * | 2019-03-29 | 2019-06-14 | 杭州伊瑟奇生物科技有限公司 | A kind of hair cleaning and nursing liquid |
| CN110227048A (en) * | 2019-07-22 | 2019-09-13 | 广州好迪集团有限公司 | Efficient anti-dandruff and itching-relieving shampoo, hair lotion and hair film |
| CN110799246A (en) * | 2017-05-10 | 2020-02-14 | 罗地亚经营管理公司 | Hair repair composition |
| CN110809463A (en) * | 2017-09-28 | 2020-02-18 | 株式会社漫丹 | Semi-solid cleaning agent |
| CN112791041A (en) * | 2021-03-01 | 2021-05-14 | 李岳勿 | Plant shampoo and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003192546A (en) * | 2001-12-25 | 2003-07-09 | Lion Corp | Hair cosmetic |
| CN102274152A (en) * | 2011-09-07 | 2011-12-14 | 山东盛宏医药科技有限公司 | Hair blackening and nourishing solution and preparation method thereof |
| CN102631424A (en) * | 2012-05-09 | 2012-08-15 | 广州市娇兰化妆品有限公司 | Compound traditional Chinese medicinal extract with anti-hair loss function and preparation method and applications thereof |
-
2013
- 2013-11-15 CN CN201310574280.2A patent/CN103550108B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003192546A (en) * | 2001-12-25 | 2003-07-09 | Lion Corp | Hair cosmetic |
| CN102274152A (en) * | 2011-09-07 | 2011-12-14 | 山东盛宏医药科技有限公司 | Hair blackening and nourishing solution and preparation method thereof |
| CN102631424A (en) * | 2012-05-09 | 2012-08-15 | 广州市娇兰化妆品有限公司 | Compound traditional Chinese medicinal extract with anti-hair loss function and preparation method and applications thereof |
Cited By (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104095792A (en) * | 2014-07-22 | 2014-10-15 | 广州好迪集团有限公司 | Hair conditioner capable of nourishing hair and repairing damage |
| CN104958204A (en) * | 2015-06-18 | 2015-10-07 | 湖南炎帝生物工程有限公司 | Liquid shampoo containing common nostoc extracts and preparation method of liquid shampoo |
| CN105997567A (en) * | 2016-06-22 | 2016-10-12 | 广州好迪集团有限公司 | Silicone-oil-free conditioning and refreshing shampoo |
| CN105997567B (en) * | 2016-06-22 | 2019-03-05 | 广州好迪集团有限公司 | A kind of light shampoo of no silicone oil conditioning |
| CN105919900A (en) * | 2016-06-27 | 2016-09-07 | 北京普世安生物科技有限公司 | Hair re-growing and hair loss preventing shampoo and preparation method thereof |
| CN106137852A (en) * | 2016-08-17 | 2016-11-23 | 禹州市合同泰药业有限公司 | A kind of Traditional Chinese herbal liquid shampoo of growing and blacking hair and preparation method thereof |
| CN106344445A (en) * | 2016-08-26 | 2017-01-25 | 广州舒泰生物技术有限公司 | Amino acid shampoo and preparation method thereof |
| CN106726869A (en) * | 2016-11-18 | 2017-05-31 | 广州环亚化妆品科技有限公司 | A kind of shampoo of natural no stimulation and preparation method thereof |
| CN108283599A (en) * | 2017-01-09 | 2018-07-17 | 唐玲妹 | Herbaceous plant boils dandruff-removing itching-relieve stoste |
| CN110799246B (en) * | 2017-05-10 | 2023-11-28 | 罗地亚经营管理公司 | Hair restoration composition |
| CN110799246A (en) * | 2017-05-10 | 2020-02-14 | 罗地亚经营管理公司 | Hair repair composition |
| CN107019789A (en) * | 2017-05-27 | 2017-08-08 | 云南白药集团股份有限公司 | Hair-loss preventing and hair-restoring Chinese medicine composition, its preparation method and application |
| CN107019789B (en) * | 2017-05-27 | 2020-09-11 | 云南白药集团股份有限公司 | Anti-hair loss and hair-growing traditional Chinese medicine composition, preparation method and application thereof |
| CN107320358A (en) * | 2017-08-25 | 2017-11-07 | 安庆徽云博冠化妆品科技有限公司 | A kind of Ai Xiang mildy wash and preparation method thereof |
| CN107362104A (en) * | 2017-09-04 | 2017-11-21 | 上海张苍生物科技有限公司 | A kind of alopecia-stopping, the leaves shampoo of hair tonic |
| CN107789242A (en) * | 2017-09-25 | 2018-03-13 | 吉安市御美丽健康产业股份有限公司 | It is a kind of suitable for ginseng shampoo of damaged hair and preparation method thereof |
| CN110809463B (en) * | 2017-09-28 | 2022-09-09 | 株式会社漫丹 | Semi-solid cleaning agent |
| CN110809463A (en) * | 2017-09-28 | 2020-02-18 | 株式会社漫丹 | Semi-solid cleaning agent |
| CN108085155B (en) * | 2017-12-27 | 2020-04-28 | 安徽金润发制品有限公司 | Cleaning and maintaining liquid for wig |
| CN108085155A (en) * | 2017-12-27 | 2018-05-29 | 安徽金润发制品有限公司 | A kind of wig cleaning maintenance liquid |
| CN108741563A (en) * | 2018-05-07 | 2018-11-06 | 肖忠波 | A kind of 50 degree of low temperature Nursing health method for permanent waving hair |
| CN108392452A (en) * | 2018-06-01 | 2018-08-14 | 韩兴旺 | A kind of shampoo of nourishing hair and anti-breaking anti-avulsion |
| CN109646352A (en) * | 2019-01-10 | 2019-04-19 | 澳宝化妆品（惠州）有限公司 | A kind of hair-washing composition with anti-dandruff performance containing pomegranate rind extract |
| CN109875951A (en) * | 2019-03-29 | 2019-06-14 | 杭州伊瑟奇生物科技有限公司 | A kind of hair cleaning and nursing liquid |
| CN110227048A (en) * | 2019-07-22 | 2019-09-13 | 广州好迪集团有限公司 | Efficient anti-dandruff and itching-relieving shampoo, hair lotion and hair film |
| CN110227048B (en) * | 2019-07-22 | 2022-03-25 | 广州好迪集团有限公司 | High-efficiency dandruff-removing and itching-relieving shampoo, hair-care liquid and hair mask |
| CN112791041A (en) * | 2021-03-01 | 2021-05-14 | 李岳勿 | Plant shampoo and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103550108B (en) | 2016-01-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103550108B (en) | Nourishing hair and injury repairing shampoo | |
| CN104095792A (en) | Hair conditioner capable of nourishing hair and repairing damage | |
| CN101129313B (en) | Liquid shampoo for nourishing hair and preventing break and phalacrosis | |
| CN107536749B (en) | Traditional Chinese medicine shampoo and preparation process thereof | |
| CN110227048B (en) | High-efficiency dandruff-removing and itching-relieving shampoo, hair-care liquid and hair mask | |
| CN107375131B (en) | Dandruff-removing and hair-nourishing plant shampoo containing aescin | |
| CN108992385A (en) | Hair essence is educated in a kind of hair follicle reparation | |
| CN105073090A (en) | Semi-permanent hair straightening composition and method | |
| CN108785198B (en) | Hair-strengthening composition, shampoo and preparation method thereof | |
| CN107496317B (en) | Repairing and nursing shampoo containing periplaneta americana active ingredient | |
| CN107362110A (en) | Submissive shampoo of a kind of white ginger and preparation method thereof | |
| CN105919888A (en) | Mature ginger juice shampoo and preparation method thereof | |
| CN113122602A (en) | Preparation method and application of quaternized hydrolyzed wheat protein in special anti-hair loss shampoo for women | |
| CN106924116A (en) | One plant tea bran shampoo and preparation method thereof | |
| CN105832590A (en) | Washing-caring two-in-one hair health-caring product | |
| CN102429835B (en) | Keratin hairspray for hair and modeling products for hair | |
| CN110025545A (en) | A kind of hair-care essence liquid of the tough anticreep applied to head | |
| CN108703929A (en) | It is a kind of that there is the shampoo and preparation method thereof for nourishing scalp efficacy | |
| CN105412530A (en) | Traditional Chinese medicine extract with bacteriostasis, scrap removing and itch relieving function and preparation method and application thereof | |
| CN108653062A (en) | A kind of plant polypeptide shampoo | |
| CN103040673A (en) | Daffodil-essence plant nanometer dyeing and hairdressing gel | |
| CN103432227B (en) | Anti-hair loss Chinese herb compound of antagonism expression of androgen receptor and preparation method thereof | |
| CN111494286A (en) | Alopecia-stopping and hair-growing shampoo | |
| CN109984953A (en) | A kind of protein peptides take a shower, clean skin gel and preparation method thereof | |
| CN104257585A (en) | Hair repair and care type shampoo |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |