CN103462834B - Room temperature volatile-type natural plant essential oils mosquito repellent gel - Google Patents

Room temperature volatile-type natural plant essential oils mosquito repellent gel Download PDF

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CN103462834B
CN103462834B CN201310358719.8A CN201310358719A CN103462834B CN 103462834 B CN103462834 B CN 103462834B CN 201310358719 A CN201310358719 A CN 201310358719A CN 103462834 B CN103462834 B CN 103462834B
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essential oils
parts
natural plant
oil
plant essential
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CN103462834A (en
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苏毅生
欧祥平
许春晖
张利春
黄丽凤
张会琴
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

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Abstract

The present invention relates to culicifuge technical field, provide a kind of environmental protection, harmless, do not need heating at room temperature volatilizable, can distribute joyful smell, repelling effect good, to skin nonirritant, containing the room temperature volatile-type natural plant essential oils mosquito repellent gel of any pesticide raw material, safety, comprise each component of following weight portion: 5~30 parts of natural plant essential oils, 5~30 parts of solubilizer, 0.5~10 part of adjuvant, 20~80 parts of purified water; Described natural plant essential oils comprises: in four kinds of lavender oils, eucalyptus oil, citronella oil, Blumea oil at least two kinds, the parts by weight of described four kinds of essential oils are: 0.1~15 part of lavender oil, 0.1~15 part of eucalyptus oil, 0.1~15 part of citronella oil, Blumea oil 0.1~15.

Description

Room temperature volatile-type natural plant essential oils mosquito repellent gel
Technical field
The present invention relates to culicifuge technical field, relate in particular to room temperature volatile-type natural plant essential oils mosquito repellent gel.
Background technology
Mosquito stings thorn people, inhales human blood, also propagates various diseases, has a strong impact on the mankind's life and health. Mosquito repellent and to keep away mosquito product very ripe through development for many years, product on the market mainly contains insect aerosol, electric heating or needs igniting mosquito-repellent incense product, floral water etc. Insect aerosol, electric heating or to need igniting mosquito-repellent incense product be mainly that waving of chemical composition (being generally agricultural chemicals) by having certain toxicity is loose, may cause discomfort or certain healthy hidden danger to part population (as infant), in addition electric heating and the potential safety hazard of lighting the product existence consumption energy or initiation fire; The mosquito product of keeping away that directly acts on skin also likely causes the uncomfortable of human body and the safe excitant problem to skin.
Chinese Patent Application No. 201210195806.1 discloses a kind of mosquito repellent gel and preparation method, formed by mosquito repellent active ingredient and gel carrier, gel agent composition is made up of the component of following mass percent: mosquito-repellent (R2) 5%~20%, matrix 0.5%~1.5%, neutralization bases 0.8%~2%, NMF 5%~16%, anticorrisive agent 0.2%~0.4%, appropriate essence, all the other are deionized water, amount to 100%, described mosquito-repellent is laurine 1, 2-propylene glycol acetal, this mosquito repellent gel is slow setting formulation, mosquito component can slowly discharge, thereby extended the mosquito repellent time, but contain laurine 1 in this mosquito repellent gel, 2-propylene glycol acetal, there is certain toxicity, dangerous, environmental protection not.
Therefore that exploitation is a kind of is harmless to human-body safety while using, environmental protection, to the non-irritating mosquito repellent product of human body skin, there is huge society and economic implications.
Summary of the invention
Therefore, for above content, the invention provides a kind of environmental protection, harmless, do not need heating at room temperature volatilizable, can distribute joyful smell, repelling effect good, to skin nonirritant, containing the room temperature volatile-type natural plant essential oils mosquito repellent gel of any pesticide raw material, safety.
For achieving the above object, the present invention is achieved by the following technical solutions: room temperature volatile-type natural plant essential oils mosquito repellent gel, is characterized in that, comprise each component of following weight portion: 5~30 parts of natural plant essential oils, 5~30 parts of solubilizer, 0.5~10 part of adjuvant, 20~80 parts of purified water; Described natural plant essential oils comprises: in four kinds of lavender oils, eucalyptus oil, citronella oil, Blumea oil at least two kinds, the parts by weight of described four kinds of essential oils are: 0.1~15 part of lavender oil, 0.1~15 part of eucalyptus oil, 0.1~15 part of citronella oil, Blumea oil 0.1~15.
Further improve and be: described solubilizer be in nonyl phenol polyethers-10, Cremophor RH40, oleth-20, laureth-9 any one or two or more with arbitrarily than the mixture mixing.
Further improve and be: described adjuvant comprises gel, acid-base modifier, anticorrisive agent and spices.
Further improve and be: described gel is any one in carbomer, xanthans, dehydrogenation xanthans, hydroxypropyl methylcellulose, hydroxyethylcellulose, agar, carragheen, and described acid-base modifier is triethanolamine or citric acid; Described spices is Isolongifolenone.
Further improve and be: the weight portion of described each material is: 0.1~1 part of carbomer, 0.1~2 part of xanthans, 0.1~2 part of dehydrogenation xanthans, 0.1~2 part of hydroxypropyl methylcellulose, 0.1~2 part of hydroxyethylcellulose, 0.1~5 part, agar, 0.1~5 part of carragheen; Acid-base modifier: 0~1 part of triethanolamine, 0~4 part of citric acid; Anticorrisive agent: 0.1~0.5 part of DMDMH, 0.05~0.1 part of methylchloroisothiazandnone; Spices: 0.1~4 part of Isolongifolenone.
Further improve and be: described purified water is distilled water or deionized water.
By adopting aforementioned techniques scheme, the invention has the beneficial effects as follows:
1, mosquito repellent gel mosquito repellent function primary raw material essential oil of the present invention derives from plant, nontoxic, human body is had no adverse effects, and environmental protection, repelling effect is stable.
2, use described plants essential oil and solubilizer to optimize proportioning, preparation mosquito repellent gel, makes the present invention both have obvious repelling effect, has again the effect in pure and fresh delicate fragrance room.
3, mosquito repellent gel repelling effect of the present invention is outstanding, and described natural plant essential oils all has obvious mosquito-repelling function, and result of the test of the present invention shows, two kinds and above essential oil compound have obvious repellent action to Anopheles sinensis, Culex quinquefasciatus, aedes albopictus.
4, in the present invention, natural plant essential oils is used for to mosquito repellent gel, 120 grams of dress effective mosquito repellent times of product were higher than 720 hours.
5, in the present invention, mosquito repellent gel is transparent or opaque colloid, fragrant odour, and sealing is placed and is had good stability half a year. In-5 DEG C~-1 DEG C refrigerator, place 24h, take out while recovering room temperature and wad a quilt with cotton with solidifying without layering, smell is constant; In the insulating box of (40 ± 1) DEG C, place 24h, take out and observe not stratifiedly, smell is constant.
6, mosquito repellent gel of the present invention, through rabbit irritation test, is observed 48 hours, and result is smeared position without any bad reaction, illustrates that product of the present invention is to skin nonirritant and anaphylaxis; Reality use in simulation room is randomly drawed Healthy People and is entered and evaluate and test, and fragrant odour with fresh air in sensory effects room, makes people joyful.
Detailed description of the invention
Describe embodiments of the present invention in detail below with reference to specific embodiment, to the present invention, how application technology means solve technical problem whereby, and the implementation procedure of reaching technique effect can fully understand and implement according to this.
If do not specialize, the conventional means that the technological means adopting in embodiment is well known to those skilled in the art, the reagent adopting and product are also and can business obtain. Source, the trade name of agents useful for same and be necessary to list its constituent person all indicated in the time occurring first.
Embodiment mono-
Room temperature volatile-type natural plant essential oils mosquito repellent gel, comprise each component of following weight portion: 7 parts of lavender oils, 1 part, 20 parts oleth-20 of eucalyptus oil, 0.5 part of carbomer, 0.5 part of triethanolamine, 0.3 part of DMDMH, 3.7 parts of Isolongifolenones, 67 parts of distilled water.
Embodiment bis-
Room temperature volatile-type natural plant essential oils mosquito repellent gel, comprises each component of following weight portion: 6 parts of lavender oils, 2 parts of eucalyptus oils, 2 parts, 25 parts nonyl phenol polyethers-10 of Blumea oil, 1 part of hydroxypropyl methylcellulose, 0.3 part of DMDMH, 0.7 part of Isolongifolenone, 63 parts of deionized waters.
Embodiment tri-
Room temperature volatile-type natural plant essential oils mosquito repellent gel, comprises each component of following weight portion: laureth-9 of 6 parts of lavender oils, 2 parts of eucalyptus oils, 2 parts of Blumea oils, 2 parts, 8 parts of citronella oils, nonyl phenol polyethers-10 of 7 parts, 0.4 part of 0.1 part of 0.5 part of 1 part of Cremophor RH40, hydroxyethylcellulose, xanthans, methylchloroisothiazandnone, Isolongifolenone, 64 parts of the distilled water of 7 parts.
Embodiment tetra-
Room temperature volatile-type natural plant essential oils mosquito repellent gel, comprises each component of following weight portion: 5 parts of eucalyptus oils, 5 parts of Blumea oils, 3 parts, 8 parts laureth-9 of citronella oil, 8 parts of nonyl phenol polyethers-10,8 parts of Cremophor RH40s, 1 part of dehydrogenation xanthans, 0.1 part of methylchloroisothiazandnone, 0.9 part of Isolongifolenone, 61 parts of deionized waters.
Embodiment five
Room temperature volatile-type natural plant essential oils mosquito repellent gel, comprises each component of following weight portion: 4 parts of eucalyptus oils, 5 parts of Blumea oils, 6 parts of citronella oils, 25 parts of Cremophor RH40s, 1 part of carragheen, 0.1 part of methylchloroisothiazandnone, 0.9 part of Isolongifolenone, 58 parts of distilled water.
Embodiment six
Room temperature volatile-type natural plant essential oils mosquito repellent gel, comprises each component of following weight portion: 3 parts of lavender oils, 3 parts of eucalyptus oils, 2 parts of Blumea oils, 2 parts of citronella oils, 20 parts of Cremophor RH40s, 1 part, agar, 0.1 part of methylchloroisothiazandnone, 0.9 part of Isolongifolenone, 68 parts of deionized waters.
Embodiment seven:
Room temperature volatile-type natural plant essential oils mosquito repellent gel, comprises each component of following weight portion: 12 parts of lavender oils, 1 part of eucalyptus oil, 1 part of Blumea oil, 6 parts of citronella oils, 28 parts of Cremophor RH40s, 1.5 parts, agar, 0.1 part of methylchloroisothiazandnone, 0.4 part of Isolongifolenone, 50 parts of distilled water.
The mosquito repellent rate test result of the each embodiment of table 1
Embodiment/mosquito repellent rate Anopheles sinensis Culex quinquefasciatus Aedes albopictus
Embodiment 1 96.8 89.3 91.6
Embodiment 2 97.5 89.3 93.1
Embodiment 3 96.3 90.4 93.2
Embodiment 4 98.1 90.1 92.3
Embodiment 5 99.2 89.8 95.4
Embodiment 6 96.3 93.1 94.6
Embodiment 7 98.6 92.7 95.2
From table one, mosquito repellent gel repelling effect of the present invention is outstanding, and the room temperature volatile-type natural plant essential oils mosquito repellent gel of described embodiment mono-to seven configuration all has obvious mosquito-repelling function. Result of the test of the present invention shows, two kinds and above essential oil compound have obvious repellent action to Anopheles sinensis, Culex quinquefasciatus, aedes albopictus, mosquito repellent gel mosquito repellent function primary raw material essential oil of the present invention derives from plant, nontoxic, human body is had no adverse effects, environmental protection, repelling effect is stable. Use described plants essential oil and solubilizer to optimize proportioning, preparation mosquito repellent gel, makes the present invention both have obvious repelling effect, has again the effect in pure and fresh delicate fragrance room. In the present invention, natural plant essential oils is used for to mosquito repellent gel, 120 grams of dress effective mosquito repellent times of product were higher than 720 hours. In the present invention, mosquito repellent gel is transparent or opaque colloid, fragrant odour, and sealing is placed and is had good stability half a year. In-5 DEG C~-1 DEG C refrigerator, place 24h, take out while recovering room temperature and wad a quilt with cotton with solidifying without layering, smell is constant; In the insulating box of (40 ± 1) DEG C, place 24h, take out and observe not stratifiedly, smell is constant. Mosquito repellent gel of the present invention, through rabbit irritation test, is observed 48 hours, and result is smeared position without any bad reaction, illustrates that product of the present invention is to skin nonirritant and anaphylaxis; Reality use in simulation room is randomly drawed Healthy People and is entered and evaluate and test, and fragrant odour with fresh air in sensory effects room, makes people joyful.
Wherein, described lavender oil, eucalyptus oil, citronella oil, Blumea oil are natural plant essential oils, and lavender oil is at 0.1~15 part, eucalyptus oil is at 0.1~15 part, citronella oil is at 0.1~15 part, Blumea oil is 0.1~15, and natural plant essential oils is two or more composite the forming of said components, and its overall control is at 5~30 parts; Described nonyl phenol polyethers-10, Cremophor RH40, oleth-20, laureth-9 are solubilizer, solubilizer can be above-described any one or two or more with arbitrarily than mix mixture, its overall control is at 5~30 parts, gel, acid-base modifier, anticorrisive agent and spices are adjuvant, in described carbomer, xanthans, dehydrogenation xanthans, hydroxypropyl methylcellulose, hydroxyethylcellulose, agar, carragheen, be gel, triethanolamine or citric acid are acid-base modifier; Described Isolongifolenone is spices, the weight portion of described each material: 0.1~1 part of carbomer, 0.1~2 part of xanthans, 0.1~2 part of dehydrogenation xanthans, 0.1~2 part of hydroxypropyl methylcellulose, 0.1~2 part of hydroxyethylcellulose, 0.1~5 part, agar, 0.1~5 part of carragheen; Acid-base modifier: 0~1 part of triethanolamine, 0~4 part of citric acid; Anticorrisive agent: 0.1~0.5 part of DMDMH, 0.05~0.1 part of methylchloroisothiazandnone; Spices: 0.1~4 part of Isolongifolenone, the overall control of described adjuvant is at 0.5~10 part; Described is that distilled water or deionized water are purified water, and its consumption is at 20~80 parts. In above parameter area, all can realize object of the present invention.
Above record, only, for utilizing the embodiment of this origination techniques content, modification, variation that any those skilled in the art use this creation to do, all belong to the scope of the claims that this creation is advocated, and be not limited to those disclosed embodiments.

Claims (5)

1. room temperature volatile-type natural plant essential oils mosquito repellent gel, is characterized in that, comprises each component of following weight portion: 5~30 parts of natural plant essential oils, 5~30 parts of solubilizer, 0.5~10 part of adjuvant, 20~80 parts of purified water; Described natural plant essential oils is: in four kinds of lavender oils, eucalyptus oil, citronella oil, Blumea oil at least two kinds, the parts by weight of described four kinds of essential oils are: 0.1~15 part of lavender oil, 0.1~15 part of eucalyptus oil, 0.1~15 part of citronella oil, 0.1~15 part of Blumea oil, described adjuvant is gel, acid-base modifier, anticorrisive agent and spices, and described spices is Isolongifolenone.
2. room temperature volatile-type natural plant essential oils mosquito repellent gel according to claim 1, is characterized in that: described solubilizer be in nonyl phenol polyethers-10, Cremophor RH40, oleth-20, laureth-9 any one or two or more with arbitrarily than mix mixture.
3. room temperature volatile-type natural plant essential oils mosquito repellent gel according to claim 1, it is characterized in that: described gel is any one in carbomer, xanthans, dehydrogenation xanthans, hydroxypropyl methylcellulose, hydroxyethylcellulose, agar, carragheen, and described acid-base modifier is triethanolamine.
4. room temperature volatile-type natural plant essential oils mosquito repellent gel according to claim 3, is characterized in that: the weight of the each component of described adjuvant is: 0.1~5 part of 0.1~5 part, 0.1~2 part of 0.1~2 part of 0.1~2 part of 0.1~2 part of 0.1~1 part of carbomer or xanthans or dehydrogenation xanthans or hydroxypropyl methylcellulose or hydroxyethylcellulose or agar or carragheen; Acid-base modifier: 0.5~1 part of triethanolamine; Anticorrisive agent: 0.1~0.5 part of DMDMH, 0.05~0.1 part of methylchloroisothiazandnone; Spices: 0.1~4 part of Isolongifolenone.
5. according to the room temperature volatile-type natural plant essential oils mosquito repellent gel described in claim 1 or 2 or 3 or 4, it is characterized in that: described purified water is distilled water or deionized water.
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