CN109321362A - A kind of balm that mosquito repellent removes formaldehyde essential oil and prepared with it - Google Patents

A kind of balm that mosquito repellent removes formaldehyde essential oil and prepared with it Download PDF

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Publication number
CN109321362A
CN109321362A CN201811331449.0A CN201811331449A CN109321362A CN 109321362 A CN109321362 A CN 109321362A CN 201811331449 A CN201811331449 A CN 201811331449A CN 109321362 A CN109321362 A CN 109321362A
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essential oil
formaldehyde
balm
mosquito repellent
oil
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Chinese (zh)
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葛永辉
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Guiyang University
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Guiyang University
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00—Essential oils; Perfumes
    • C11B9/0003—Compounds of unspecified constitution defined by the chemical reaction for their preparation
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08—Magnoliopsida [dicotyledons]
    • A01N65/22—Lamiaceae or Labiatae [Mint family], e.g. thyme, rosemary, skullcap, selfheal, lavender, perilla, pennyroyal, peppermint or spearmint
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08—Magnoliopsida [dicotyledons]
    • A01N65/28—Myrtaceae [Myrtle family], e.g. teatree or clove
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08—Magnoliopsida [dicotyledons]
    • A01N65/34—Rosaceae [Rose family], e.g. strawberry, hawthorn, plum, cherry, peach, apricot or almond
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08—Magnoliopsida [dicotyledons]
    • A01N65/36—Rutaceae [Rue family], e.g. lime, orange, lemon, corktree or pricklyash
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/40—Liliopsida [monocotyledons]
    • A01N65/48—Zingiberaceae [Ginger family], e.g. ginger or galangal
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Natural Medicines & Medicinal Plants (AREA)
  • Wood Science & Technology (AREA)
  • Dentistry (AREA)
  • Microbiology (AREA)
  • Mycology (AREA)
  • Plant Pathology (AREA)
  • Biotechnology (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Botany (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Cosmetics (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Fats And Perfumes (AREA)

Abstract

The invention discloses a kind of mosquito repellents to remove formaldehyde essential oil, including component have Lavender, ginger essential oil, almond essential oil, flores aurantii essential oil, Geranium Essential and eucalyptus oil.The invention also discloses a kind of mosquito repellents to remove formaldehyde balm.Essential oil and balm of the present invention have effects that mosquito repellent removes formaldehyde simultaneously, when being used as mosquito repellent balm its can solve the problems, such as current mosquito-repellent water and mosquito-repellent incense use the being irritating to the skin property of household pesticides ingredient such as Metadelphene, dimethyl phthalate with it is hypersensitive；As when formaldehyde balm being gone to use its have and go effect of formaldehyde good, the long advantage of timeliness.

Description

A kind of balm that mosquito repellent removes formaldehyde essential oil and prepared with it
Technical field
The balm for removing formaldehyde essential oil the present invention relates to a kind of mosquito repellent and being prepared with it, belongs to chemical technical field of daily necessities.
Background technique
Summer bite by mosquitos can not only make skin generate red and swollen itch etc., additionally it is possible to cause some serious infectious diseases, Affect people's health and life, the especially tender infant of skin.For mosquito repellent, people often spray mosquito-repellent water, burning point Mosquito-repellent incense uses anophelifuge medicament, but existing mosquito-repellent water and the main anophelifuge activity ingredient of mosquito-repellent incense are mostly Metadelphene, dimethyl phthalate, drive The household pesticides ingredient such as mosquito rouge or dihydropyrone belongs to micro- malicious product, and anaphylaxis irritant to the skin of contact.
Formaldehyde is also known as formaldehyde, is colourless gas, there is special penetrating odor, main to the irritating effect such as human eye, nose Harm shows the stimulation to skin and mucosa, and when formaldehyde reaches a certain concentration indoors, people just has sense of discomfort, is greater than 0.08mg/m3Concentration of formaldehyde can cause to be envious, eye is itched, throat discomfort or pain, hoarseness, sneeze, uncomfortable in chest, asthma, skin Inflammation etc..When concentration of formaldehyde is in 0.12~1.2mg/m3When, immune function of human body can be made abnormal, when concentration of formaldehyde 0.06~ 0.07mg/m3When, it can make children that asthma occur.As it can be seen that formaldehyde harm to the human body is very big.Through inquiring, in the prior art Not having to remove the product of formaldehyde by mosquito repellent simultaneously.
Summary of the invention
The technical problem to be solved by the present invention is providing a kind of balm that mosquito repellent removes formaldehyde essential oil and prepared with it, essential oil Have effects that mosquito repellent removes formaldehyde simultaneously with balm, it can solve current mosquito-repellent water when using as mosquito repellent balm and mosquito-repellent incense uses The being irritating to the skin property of household pesticides ingredient such as Metadelphene, dimethyl phthalate and hypersensitive problem；As going formaldehyde balm to use When it has and goes effect of formaldehyde good, the long advantage of timeliness.
The technical scheme is that a kind of mosquito repellent removes formaldehyde essential oil, including component have Lavender, ginger extract Oil, almond essential oil, flores aurantii essential oil, Geranium Essential and eucalyptus oil.
The volume parts of the component are as follows: 10~15 parts of Lavender, 1~5 part of ginger essential oil, almond essential oil 10~15 Part, 15~20 parts of flores aurantii essential oil, 10~15 parts of Geranium Essential, 2~10 parts of eucalyptus oil.
The present invention also provides a kind of mosquito repellents to remove formaldehyde balm, and it includes that the mosquito repellent removes formaldehyde that the mosquito repellent, which removes formaldehyde balm, Essential oil, four oleate of anhydrous sorbitol and agar amidin, preparation method are as follows:
Mosquito repellent is gone formaldehyde essential oil and four oleate of anhydrous sorbitol to mix uniformly by step 1 by weight 1:1, is obtained mixed Object is closed, it is spare；
Step 2 stirs agar amidin oil bath heating to boiling, naturally cools to 60 DEG C, continues to stir solidifying Glue；
The mixture is added in 60 DEG C of the gel by step 3 by weight 4:100, is stirred 3~5 minutes and is mixed It is even, obtain mixed gel；
Step 4, by mixed gel encapsulating into container, packaging, obtain mosquito repellent remove formaldehyde balm.
The agar amidin, which is suspended in pure water by agar powder according to the ratio of weight percent 2%, to be obtained.
Through testing and analyzing, balm of the present invention, essential oil have complicated chemical active ingredient, generally can mainly be summarized as with Lower three kinds of chemical functional group's types: 1) terpenoid-monoterpene/sequiterpene and its corresponding oxide, which constitute volatile oil Main component, generally there is stronger bioactivity and aromatic odor, such as the menthol (menthol) that contains in peppermint oil and The main component camphor (camphor) contained in camphorated oil is all terpenoid；2) aromatic compound-is phenylpropyl alcohol mostly Plain class derivative (propenyl benzene/propenyl benzene phenol etc.) is as shown in Figure 1, such compound has fragrant phenyl ring, while generally having active It is organic to be easy to noxious volatile in same air for the propylene structure of property, such double bond functional group chemical reactivity with higher Compound (formaldehyde, methanol etc.) and the oxide and peroxide for having injury to human body, are translated into corresponding innocuous substance. 3) aliphatic category compound-is mainly alkane, alkene, esters and its acid compounds of small molecule amount.Such compound It is different from oil long-chain fat acids compound, there is smaller molecular weight and is easy to volatilize and noresidue, while such Fat-soluble splendid small molecule can form certain gas soluble mixture with harmful small molecule in air, accelerate as formaldehyde is small The quick removing of molecule.It removes outside above-mentioned three classes compound, there are also the substance such as mustard oil (mustard of some volatilization oil samples Oil), volatile almond oil (volatile bitter almond oil), garlic oil (garlic oil) etc., but such compound Often appear in the plant extracts of specific type.
Active chemical components in essential oil are its basic material base for playing its in vivo bioactivity function, activity chemistry The particularity chemical functional group having in ingredient is primarily present the important chemistry of two classes from the perspective of organic chemical reactions Reaction type: the 1) radical reaction and its oxidation reaction of photoinduction；2) activity double key reacted with the olefine aldehyde condensation of formaldehyde (also known as The organic name reaction of Prins reaction-).Volatile oil generally all has preferable optical activity, and specific rotatory power is generally distributed In within the scope of+97o~177o, and there is strong index of refraction, index of refraction is between 1.43~1.61.Since it is with good light Physical property is learned, different types of important activity functional group can induce the freedom of some particularity under the irradiation of sunlight Base, the free radical can capture the organic micromolecule compound such as aldehydes and alcohol compound of potential high activity in air, thus Realize the removing to some harmful substances.As shown in Fig. 2, australene acts on the hydroxyl radical reaction in air in illumination Under the oxidation of oxygen through the air efficiently can convert aldehyde acid compounds for harmful substance hydroxyl radical free radical. Australene be in essential oil in common main active, be widely present in different phytovolatilization oil extracts.
In addition, aldoketones organic micromolecule compound is main volatile harmful substance existing for air, such compound Aldehyde carbonyl groups or ketone carbonyl with high activity are the functional groups for having primary chemical to injure to body.Early in 1919, Holland Chemical HendrikJacobusPrins is reported using styrene, firpene, amphene, eugenol, isosafrole and anethole as raw material Prins reaction.And this kind of small organic molecule containing double bonds is exactly the main component in many volatile oil.Generally much wave Hair oil can because there are also some activity functional groups and have certain acidity, simultaneously because in humid air per se with one Fixed slant acidity medium such as carbon dioxide etc. provides preferable potential condition for such chemical reaction.It is as shown in Figure 3 The chemical reaction of one simple formaldehyde and terminal double bond.In short, volatile oil chemical component has the complexity of height, tool The multifarious chemical functional group having has established its multifarious application may.
In conclusion essential oil except formaldehyde mechanism it is as follows, the small molecules such as formaldehyde harmful substance by in essential oil contain double bond Functional group generate polymerization reaction, gradually form harmless long-chain molecule, while molecular weight increases, after specific gravity is higher than air, no It floats in air again, as shown in Figure 4.
The beneficial effects of the present invention are: this product have many advantages, such as it is natural, nontoxic, non-stimulated, safe and efficient；Repelling effect Than more significant, and strong antibacterial, to air have thorough detergent power, especially go effect of formaldehyde preferable.This product Fragrance can incorporate well in various living environments naturally, simple and elegant, and because being pure natural essential oil as smell source, without times The addition of what artificial flavors, to pregnant woman and infant without any stimulation, is also subjected to odor-sensitive crowd, and volatilize at Dividing can react with formaldehyde, float on formaldehyde no longer in air, achieve the purpose that remove formaldehyde.In addition, 100 grams of this product are in 15- In 20 square metres of non-closed rooms, under room temperature, can uniformly it spread 20-30 days, the duration is longer, and use cost is lower.
Detailed description of the invention
The chemical structural formula of Fig. 1 aromatic compound；
The key reaction mechanism of Fig. 2 australene and hydroxyl radical free radical；
The Prins of Fig. 3 formaldehyde reacts；
Fig. 4 essential oil removes the reaction mechanism of formaldehyde.
Specific embodiment
Invention is described further below with reference to specific embodiment:
Embodiment 1: mosquito repellent removes formaldehyde essential oil, including component have Lavender, ginger essential oil, almond essential oil, flores aurantii Essential oil, Geranium Essential and eucalyptus oil.
Embodiment 2: mosquito repellent removes formaldehyde balm, and component includes that mosquito repellent removes formaldehyde essential oil, four oleate of anhydrous sorbitol and fine jade Cosmetics aqueous solution, wherein mosquito repellent goes formaldehyde essential oil by Lavender 10kg, ginger essential oil 1kg, almond essential oil 15kg, flores aurantii essence Oily 15kg, Geranium Essential 10kg, eucalyptus oil 2kg are mixed to get, balm the preparation method is as follows:
Mosquito repellent is gone formaldehyde essential oil and four oleate of anhydrous sorbitol to mix uniformly by step 1 by weight 1:1, is obtained mixed Object is closed, it is spare；
Step 2 stirs agar amidin oil bath heating to boiling, naturally cools to 60 DEG C, continues to stir solidifying Glue, wherein agar amidin is suspended in pure water according to the ratio of weight percent 2% by agar powder and is obtained；
The mixture is added in 60 DEG C of the gel by step 3 by weight 4:100, is stirred 3~5 minutes and is mixed It is even, obtain mixed gel；
Step 4, by mixed gel encapsulating into container, packaging, obtain mosquito repellent remove formaldehyde balm.
Embodiment 3: being Lavender 15kg, ginger essential oil 5kg, almond essential oil except mosquito repellent removes the formula of formaldehyde essential oil Outside 10kg, flores aurantii essential oil 20kg, Geranium Essential 15kg, eucalyptus oil 10kg, remaining is same as Example 2.
Embodiment 4: being Lavender 12kg, ginger essential oil 3kg, almond essential oil except mosquito repellent removes the formula of formaldehyde essential oil Outside 12kg, flores aurantii essential oil 16kg, Geranium Essential 13kg, eucalyptus oil 6kg, remaining is same as Example 2.
Embodiment 5: being Lavender 11kg, ginger essential oil 2kg, almond essential oil except mosquito repellent removes the formula of formaldehyde essential oil Outside 11kg, flores aurantii essential oil 17kg, Geranium Essential 12kg, eucalyptus oil 5kg, remaining is same as Example 2.
Formaldehyde Test: according to GB/T17657-2013 examination criteria, taking the essential oil or balm in the embodiment 1-5 of equivalent, Being acted on volume is 1.5m3, concentration of formaldehyde 0.143mg/m3Sealed compartment in 168h, detect first respectively in 72h and 168h Aldehyde concentration the results are shown in Table 1.
As seen from the above table, essential oil and balm PARA FORMALDEHYDE PRILLS(91,95) of the present invention has preferable removal effect, wherein the duration of essential oil It is shorter, and the duration of balm is longer, up to 168h or more, and formaldehyde removal is more thorough.
Mosquito repellent experiment: taking the essential oil or balm in the embodiment 1-5 of equivalent, tested in the case where simulating summer night environment, real The essential oil or balm applied in a 1-5 reach 2-3 days in the repelling effect close to nonirritant reaction after human respiratory, embodiment 1, And the repelling effect of embodiment 2-5 was up to 20 days or so.
Lavender, ginger essential oil, almond essential oil, flores aurantii essential oil, Geranium Essential and eucalyptus oil can in the present invention Using steam distillation, co_2 supercritical fluid extraction method, solvent method, squeezing method or other medicines well known in the art Agent extracting method is obtained by extracting in medicinal material.Alternatively, directly by being commercially available in the market.Four oleate of anhydrous sorbitol is one A nonionic surface active agent for being widely used in food, cosmetics and medicine field, reaches a certain concentration in aqueous solution When can form organized assembles-micella that lipophilic group is inside, hydrophilic radical is outside；After forming micella, it is insoluble in the essence of water Oil component can enter the kernel of micella and solubility in aqueous solution dramatically increases, and can be improved the stabilization of essential oil Property.
The above content is a further detailed description of the present invention in conjunction with specific preferred embodiments, and it cannot be said that Specific implementation of the invention is only limited to these instructions.For those of ordinary skill in the art to which the present invention belongs, exist Under the premise of not departing from present inventive concept, a number of simple deductions or replacements can also be made, all shall be regarded as belonging to of the invention Protection scope.

Claims (4)

1. a kind of mosquito repellent removes formaldehyde essential oil, it is characterised in that: including component have Lavender, ginger essential oil, almond essential oil, Flores aurantii essential oil, Geranium Essential and eucalyptus oil.
2. mosquito repellent according to claim 1 removes formaldehyde essential oil, it is characterised in that: the volume parts of the component are as follows: smoke clothing 10~15 parts of careless essential oil, 1~5 part of ginger essential oil, 10~15 parts of almond essential oil, 15~20 parts of flores aurantii essential oil, Geranium Essential 10 ~15 parts, 2~10 parts of eucalyptus oil.
3. a kind of mosquito repellent removes formaldehyde balm, it is characterised in that: it includes described in claims 1 or 2 that the mosquito repellent, which removes formaldehyde balm, Mosquito repellent go formaldehyde essential oil, four oleate of anhydrous sorbitol and agar amidin, preparation method as follows:
Mosquito repellent is gone formaldehyde essential oil and four oleate of anhydrous sorbitol to mix uniformly by step 1 by weight 1:1, obtains mixture, It is spare；
Step 2 stirs agar amidin oil bath heating to boiling, naturally cools to 60 DEG C, continues to stir to obtain gel；
The mixture is added in 60 DEG C of the gel by step 3 by weight 4:100, is stirred 3~5 minutes and is mixed, obtains To mixed gel；
Step 4, by mixed gel encapsulating into container, packaging, obtain mosquito repellent remove formaldehyde balm.
4. mosquito repellent according to claim 3 removes formaldehyde balm, it is characterised in that: the agar amidin is pressed by agar powder It is suspended in pure water and obtains according to the ratio of weight percent 2%.
CN201811331449.0A 2018-11-09 2018-11-09 A kind of balm that mosquito repellent removes formaldehyde essential oil and prepared with it Pending CN109321362A (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003138290A (en) * 2001-11-01 2003-05-14 Takasago Internatl Corp Perfume composition having mosquito repellent effect
CN103060092A (en) * 2012-12-25 2013-04-24 林翔云 Essence composition capable of eliminating formaldehyde hazards and preparation method thereof
CN103462834A (en) * 2013-08-16 2013-12-25 许春晖 Room-temperature volatile natural plant essential oil mosquito repelling gel
CN105961466A (en) * 2016-05-23 2016-09-28 贵州依珀逸品生物科技有限公司 Purely natural essential oil mosquito-repellent balm and preparation method thereof
CN107096367A (en) * 2017-05-04 2017-08-29 吴金龙 Plants essential oil scavenging solution and preparation method thereof
CN107815349A (en) * 2017-10-30 2018-03-20 贵州德莱易生物科技有限公司 One kind removes formaldehyde essential oil
CN107866145A (en) * 2017-10-30 2018-04-03 贵州德莱易生物科技有限公司 One kind de-tastes spray except formaldehyde

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003138290A (en) * 2001-11-01 2003-05-14 Takasago Internatl Corp Perfume composition having mosquito repellent effect
US20030138470A1 (en) * 2001-11-01 2003-07-24 Takasago International Corporation Fragrant composition having mosquito-repelling effect
CN103060092A (en) * 2012-12-25 2013-04-24 林翔云 Essence composition capable of eliminating formaldehyde hazards and preparation method thereof
CN103462834A (en) * 2013-08-16 2013-12-25 许春晖 Room-temperature volatile natural plant essential oil mosquito repelling gel
CN105961466A (en) * 2016-05-23 2016-09-28 贵州依珀逸品生物科技有限公司 Purely natural essential oil mosquito-repellent balm and preparation method thereof
CN107096367A (en) * 2017-05-04 2017-08-29 吴金龙 Plants essential oil scavenging solution and preparation method thereof
CN107815349A (en) * 2017-10-30 2018-03-20 贵州德莱易生物科技有限公司 One kind removes formaldehyde essential oil
CN107866145A (en) * 2017-10-30 2018-04-03 贵州德莱易生物科技有限公司 One kind de-tastes spray except formaldehyde

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