CN103447041B - 使用快速干燥阶段制备催化剂的方法及其用于费托合成的用途 - Google Patents

使用快速干燥阶段制备催化剂的方法及其用于费托合成的用途 Download PDF

Info

Publication number
CN103447041B
CN103447041B CN201310209278.5A CN201310209278A CN103447041B CN 103447041 B CN103447041 B CN 103447041B CN 201310209278 A CN201310209278 A CN 201310209278A CN 103447041 B CN103447041 B CN 103447041B
Authority
CN
China
Prior art keywords
stage
oxide carrier
catalyst
drying
impregnated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201310209278.5A
Other languages
English (en)
Chinese (zh)
Other versions
CN103447041A (zh
Inventor
S.莫里
F.迪尔
A.贝利耶
J.洛佩
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Eni SpA
Original Assignee
IFP Energies Nouvelles IFPEN
Eni SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN, Eni SpA filed Critical IFP Energies Nouvelles IFPEN
Publication of CN103447041A publication Critical patent/CN103447041A/zh
Application granted granted Critical
Publication of CN103447041B publication Critical patent/CN103447041B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/005—Spinels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/392—Metal surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B01J35/77—Compounds characterised by their crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/333—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the platinum-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Crystallography & Structural Chemistry (AREA)
CN201310209278.5A 2012-05-30 2013-05-30 使用快速干燥阶段制备催化剂的方法及其用于费托合成的用途 Active CN103447041B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR12/01543 2012-05-30
FR1201543A FR2991199B1 (fr) 2012-05-30 2012-05-30 Procede de preparation d'un catalyseur mettant en oeuvre une etape de sechage rapide et son utilisation pour la synthese fischer-tropsch

Publications (2)

Publication Number Publication Date
CN103447041A CN103447041A (zh) 2013-12-18
CN103447041B true CN103447041B (zh) 2017-07-28

Family

ID=48092877

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310209278.5A Active CN103447041B (zh) 2012-05-30 2013-05-30 使用快速干燥阶段制备催化剂的方法及其用于费托合成的用途

Country Status (7)

Country Link
US (1) US9180435B2 (enExample)
EP (1) EP2669006B1 (enExample)
JP (1) JP6307225B2 (enExample)
CN (1) CN103447041B (enExample)
CA (1) CA2817684C (enExample)
DK (1) DK2669006T3 (enExample)
FR (1) FR2991199B1 (enExample)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9079172B2 (en) 2012-03-13 2015-07-14 Celanese International Corporation Promoters for cobalt-tin catalysts for reducing alkanoic acids
US9333496B2 (en) * 2012-02-29 2016-05-10 Celanese International Corporation Cobalt/tin catalyst for producing ethanol
FR3018702B1 (fr) * 2014-03-20 2017-10-20 Ifp Energies Now Catalyseur fischer-tropsch a base d'un metal du groupe viiib et d'un support d'oxydes comprenant de l'alumine, de la silice, une spinelle et du phosphore
WO2016097402A1 (en) 2014-12-19 2016-06-23 Bp P.L.C. Process for preparation of a supported cobalt-containing fischer-tropsch synthesis catalyst
JP6456204B2 (ja) * 2015-03-24 2019-01-23 千代田化工建設株式会社 芳香族炭化水素の水素化触媒及びそれを用いた水素化処理方法
CN106352683A (zh) * 2016-10-20 2017-01-25 北京石油化工工程有限公司 易受温度、氧气影响的催化剂前驱体工业干燥方法及系统
FR3064498B1 (fr) * 2017-03-30 2021-10-29 Ifp Energies Now Procede de preparation de catalyseurs a base de cobalt
RU2674161C1 (ru) * 2018-05-24 2018-12-05 федеральное государственное бюджетное образовательное учреждение высшего образования "Южно-Российский государственный политехнический университет (НПИ) имени М.И. Платова" Катализатор для получения синтетических углеводородов из СО и Н2 и способ его приготовления
FR3100990B1 (fr) * 2019-09-19 2022-01-07 Institut Nat Des Sciences Appliquees De Toulouse Ensemble catalytique comprenant un matériau ferromagnétique micrométrique et utilisation dudit ensemble pour des réactions de catalyse hétérogène

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102380386A (zh) * 2010-07-16 2012-03-21 恩尼有限公司 用于费托合成的在二氧化硅-氧化铝载体上的钴基催化剂

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4139493A (en) * 1977-08-03 1979-02-13 Union Oil Company Of California Silica-promoted hydrofining catalyst and process
US4160745A (en) * 1977-12-01 1979-07-10 Exxon Research & Engineering Co. Method of preparing highly active nickel catalysts and catalysts prepared by said method
US4497704A (en) * 1983-04-04 1985-02-05 Uop Inc. Hydrocarbon conversion process
US4447556A (en) * 1983-04-04 1984-05-08 Uop Inc. Hydrocarbon conversion catalyst and use thereof
US5036032A (en) * 1988-03-25 1991-07-30 Exxon Research And Engineering Company Selective catalysts and their preparation for catalytic hydrocarbon synthesis
US5258411A (en) * 1990-10-15 1993-11-02 Exxon Research And Engineering Co. Activation conditions to maximize the HCS activity of supported cobalt catalysts (OP-3706)
US5168091A (en) * 1990-10-15 1992-12-01 Exxon Research And Engineering Company Activation conditions to maximize the HSC activity of supported cobalt catalysts
EP1237652A1 (en) 1999-12-01 2002-09-11 Sasol Technology (Proprietary) Limited Cobalt catalysts
US7280738B2 (en) * 2001-04-09 2007-10-09 International Business Machines Corporation Method and system for specifying a selection of content segments stored in different formats
AR034912A1 (es) * 2001-07-27 2004-03-24 Sasol Tech Pty Ltd Produccion de cera obtenida mediante sintesis fischer-tropsch
US7341976B2 (en) * 2002-10-16 2008-03-11 Conocophillips Company Stabilized boehmite-derived catalyst supports, catalysts, methods of making and using
US7449486B2 (en) * 2004-10-19 2008-11-11 Array Biopharma Inc. Mitotic kinesin inhibitors and methods of use thereof
FR2879478B1 (fr) * 2004-12-17 2007-10-26 Inst Francais Du Petrole Catalyseur a base de cobalt pour la synthese fisher-tropsch
RU2279912C1 (ru) * 2005-03-04 2006-07-20 Общество с ограниченной ответственностью "Объединенный центр исследований и разработок " Катализатор синтеза углеводородов c5-c100 способ их получения и способ получения катализатора
WO2006119311A2 (en) * 2005-05-02 2006-11-09 Symyx Technologies, Inc. High surface area metal and metal oxide materials and methods of making same
WO2007071899A1 (en) 2005-12-21 2007-06-28 Johnson Matthey Plc Metal nitrate conversion method
JP2007307436A (ja) * 2006-05-16 2007-11-29 Ihi Corp フィッシャー・トロプシュ合成触媒とその製造方法
US8575410B2 (en) * 2009-03-31 2013-11-05 Uop Llc Process for oligomerizing dilute ethylene
US9242229B2 (en) * 2010-08-09 2016-01-26 Gtl.F1 Ag Fischer-tropsch catalysts

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102380386A (zh) * 2010-07-16 2012-03-21 恩尼有限公司 用于费托合成的在二氧化硅-氧化铝载体上的钴基催化剂

Also Published As

Publication number Publication date
CN103447041A (zh) 2013-12-18
EP2669006B1 (fr) 2018-06-13
EP2669006A1 (fr) 2013-12-04
FR2991199A1 (fr) 2013-12-06
US9180435B2 (en) 2015-11-10
US20130324623A1 (en) 2013-12-05
CA2817684A1 (fr) 2013-11-30
CA2817684C (fr) 2021-03-30
JP2013248610A (ja) 2013-12-12
FR2991199B1 (fr) 2015-05-15
DK2669006T3 (en) 2018-10-01
JP6307225B2 (ja) 2018-04-04

Similar Documents

Publication Publication Date Title
CN103447041B (zh) 使用快速干燥阶段制备催化剂的方法及其用于费托合成的用途
CN103447040B (zh) 使用至少一个快速干燥阶段和至少一个流化床干燥阶段制备催化剂的方法及其用于费托合成的用途
CN102380386B (zh) 用于费托合成的在二氧化硅-氧化铝载体上的钴基催化剂
AU2013336290B2 (en) Process for preparing a Fischer-Tropsch catalyst
WO2014023955A2 (en) Treating of catalyst support
Isaeva et al. Fischer–Tropsch synthesis over MOF-supported cobalt catalysts (Co@ MIL-53 (Al))
CN102202787A (zh) 钴催化剂前体
US11020728B2 (en) Catalyst comprising a boron-doped active phase
Naeem et al. Syngas production from dry reforming of methane over nano Ni polyol catalysts
CN102781574A (zh) 费托合成催化剂及其制造方法、以及烃的制造方法
CA3028590A1 (en) A cobalt-containing catalyst composition
CN106040257A (zh) 费托合成催化剂及其制备方法和催化剂以及费托合成方法
CA3215982A1 (en) Carbon dioxide methanation catalyst molded body and method for producing the same
Hossain et al. Thermo‐catalytic conversion of greenhouse gases (CO2 and CH4) to CO‐rich hydrogen by CeO2 modified calcium iron oxide supported nickel catalyst
JP2014518757A (ja) コバルト含有炭化水素合成触媒前駆体を調製する方法
WO2010055808A1 (ja) 不飽和炭化水素および含酸素化合物の製造方法、触媒およびその製造方法
Tan et al. Catalytic deoxygenation of stearic acid into olefins over Pt catalysts supported on MOF-derived metal oxides
JP6694108B2 (ja) メタンの二酸化炭素改質用カプセル化触媒、及びそれを用いた合成ガスの製造方法
KR20180014148A (ko) 고성능 철/알루미나 지지체 촉매의 제조 방법 및 이를 이용한 합성 액체연료 제조 방법
JP2022182945A (ja) 脱水素用触媒
JP2025060092A (ja) 炭化水素製造触媒、炭化水素製造触媒の製造方法、及び炭化水素の製造方法
CN106582708A (zh) 一种负载型催化剂和应用及费托合成反应的方法
AU2015264798A1 (en) Fischer-Tropsch catalysts and method of preparation thereof
KR20170123358A (ko) 고성능 철/알루미나 지지체 촉매의 제조 방법 및 이를 이용한 합성 액체연료 제조 방법
NZ618839A (en) Process for preparing a cobalt-containing fischer tropsch catalyst

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant