FR3100990B1 - Ensemble catalytique comprenant un matériau ferromagnétique micrométrique et utilisation dudit ensemble pour des réactions de catalyse hétérogène - Google Patents

Ensemble catalytique comprenant un matériau ferromagnétique micrométrique et utilisation dudit ensemble pour des réactions de catalyse hétérogène Download PDF

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FR3100990B1
FR3100990B1 FR1910344A FR1910344A FR3100990B1 FR 3100990 B1 FR3100990 B1 FR 3100990B1 FR 1910344 A FR1910344 A FR 1910344A FR 1910344 A FR1910344 A FR 1910344A FR 3100990 B1 FR3100990 B1 FR 3100990B1
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assembly
ferromagnetic material
heterogeneous catalysis
catalytic
micrometric
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FR3100990A1 (fr
Inventor
Julien Marbaix
Sumeet Kale
Stéphane Faure
Aikaterini Soulantika
Bruno Chaudret
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Centre National de la Recherche Scientifique CNRS
Institut National des Sciences Appliquees de Toulouse
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Centre National de la Recherche Scientifique CNRS
Institut National des Sciences Appliquees de Toulouse
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Application filed by Centre National de la Recherche Scientifique CNRS, Institut National des Sciences Appliquees de Toulouse filed Critical Centre National de la Recherche Scientifique CNRS
Priority to CA3147684A priority patent/CA3147684A1/fr
Priority to US17/761,181 priority patent/US20230241588A1/en
Priority to PCT/FR2020/051626 priority patent/WO2021053307A1/fr
Priority to CN202080075562.6A priority patent/CN114667187B/zh
Priority to JP2022517500A priority patent/JP2022549603A/ja
Priority to AU2020350156A priority patent/AU2020350156A1/en
Priority to EP20820266.3A priority patent/EP4031280A1/fr
Publication of FR3100990A1 publication Critical patent/FR3100990A1/fr
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12Silica and alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/745Iron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/755Nickel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/33Electric or magnetic properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/50Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/50Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/58Fabrics or filaments
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04Mixing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/34Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/341Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation
    • B01J37/342Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation of electric, magnetic or electromagnetic fields, e.g. for magnetic separation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/12Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon dioxide with hydrogen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/50Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon dioxide with hydrogen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12Silica and alumina
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/10Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74Iron group metals
    • C07C2523/755Nickel

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Plasma & Fusion (AREA)
  • Optics & Photonics (AREA)
  • Electromagnetism (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Ensemble catalytique pour la réalisation d’une réaction de catalyse hétérogène dans une plage de températures T donnée caractérisé en ce qu’il comprend l’association d’au moins un composé catalytique apte à catalyser ladite réaction dans la plage de températures T et d’un matériau ferromagnétique sous forme de particules micrométriques et/ou de fils, ledit matériau ferromagnétique étant apte à être chauffé par induction magnétique au moyen d’un inducteur de champ. Utilisation dudit ensemble catalytique pour la mise en œuvre d’une réaction de catalyse hétérogène telle qu’une réaction de méthanation. Figure pour l’abrégé : Fig. 2
FR1910344A 2019-09-19 2019-09-19 Ensemble catalytique comprenant un matériau ferromagnétique micrométrique et utilisation dudit ensemble pour des réactions de catalyse hétérogène Active FR3100990B1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
FR1910344A FR3100990B1 (fr) 2019-09-19 2019-09-19 Ensemble catalytique comprenant un matériau ferromagnétique micrométrique et utilisation dudit ensemble pour des réactions de catalyse hétérogène
US17/761,181 US20230241588A1 (en) 2019-09-19 2020-09-18 Catalytic assembly comprising a micrometric ferromagnetic material and use of said assembly for heterogeneous catalysis reactions
PCT/FR2020/051626 WO2021053307A1 (fr) 2019-09-19 2020-09-18 Ensemble catalytique comprenant un matériau ferromagnétique micrométrique et utilisation dudit ensemble pour des réactions de catalyse hétérogène
CN202080075562.6A CN114667187B (zh) 2019-09-19 2020-09-18 包含微米铁磁材料的催化组件以及所述组件用于多相催化反应的用途
CA3147684A CA3147684A1 (fr) 2019-09-19 2020-09-18 Ensemble catalytique comprenant un materiau ferromagnetique micrometrique et utilisation dudit ensemble pour des reactions de catalyse heterogene
JP2022517500A JP2022549603A (ja) 2019-09-19 2020-09-18 マイクロメトリック強磁性体を含む触媒アセンブリ及び不均一系触媒反応のための前記アセンブリの使用
AU2020350156A AU2020350156A1 (en) 2019-09-19 2020-09-18 Catalytic assembly comprising a micrometric ferromagnetic material and use of said assembly for heterogeneous catalysis reactions
EP20820266.3A EP4031280A1 (fr) 2019-09-19 2020-09-18 Ensemble catalytique comprenant un matériau ferromagnétique micrométrique et utilisation dudit ensemble pour des réactions de catalyse hétérogène

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1910344 2019-09-19
FR1910344A FR3100990B1 (fr) 2019-09-19 2019-09-19 Ensemble catalytique comprenant un matériau ferromagnétique micrométrique et utilisation dudit ensemble pour des réactions de catalyse hétérogène

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FR3100990A1 FR3100990A1 (fr) 2021-03-26
FR3100990B1 true FR3100990B1 (fr) 2022-01-07

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FR1910344A Active FR3100990B1 (fr) 2019-09-19 2019-09-19 Ensemble catalytique comprenant un matériau ferromagnétique micrométrique et utilisation dudit ensemble pour des réactions de catalyse hétérogène

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US (1) US20230241588A1 (fr)
EP (1) EP4031280A1 (fr)
JP (1) JP2022549603A (fr)
CN (1) CN114667187B (fr)
AU (1) AU2020350156A1 (fr)
CA (1) CA3147684A1 (fr)
FR (1) FR3100990B1 (fr)
WO (1) WO2021053307A1 (fr)

Family Cites Families (14)

* Cited by examiner, † Cited by third party
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US4359379A (en) * 1979-12-21 1982-11-16 Nippon Oil Company, Ltd. Process for fluid catalytic cracking of distillation residual oils
US4541924A (en) * 1982-09-22 1985-09-17 Exxon Research And Engineering Co. Composition and hydrotreating process for the operation of a magnetically stabilized fluidized bed
CA2410927A1 (fr) * 2002-11-05 2004-05-05 Michel Petitclerc Reacteur a chauffage electrique pour le reformage en phase gazeuse
JP5369126B2 (ja) * 2010-04-28 2013-12-18 日本精線株式会社 水素化反応/脱水素化反応用のワイヤー触媒成形品
US8568665B2 (en) * 2010-12-28 2013-10-29 Nippon Seisen Co., Ltd. Catalyst structure and hydrogenation/dehydrogenation reaction module using the same catalyst structure
US9488085B2 (en) * 2013-09-18 2016-11-08 Advanced Technology Emission Solutions Inc. Catalytic converter structures with induction heating
CA2885546C (fr) * 2012-10-05 2018-06-05 Cornell University Enzymes formant des ensembles mesoporeux integres dans des echafaudages macroporeux
FR3003774B1 (fr) 2013-04-02 2018-03-02 Institut National Des Sciences Appliquees De Toulouse Procede chimique catalyse par des nanoparticules ferromagnetiques
PL407582A1 (pl) * 2014-03-19 2015-09-28 Instytut Elektrotechniki Sposób prowadzenia reakcji chemicznej z udziałem katalizatora proszkowego
JP2018507007A (ja) * 2014-12-24 2018-03-15 コーニンクレッカ フィリップス エヌ ヴェKoninklijke Philips N.V. 空気浄化のための新しいタイプの熱触媒酸化材料およびその装置
RU2729274C2 (ru) * 2015-10-28 2020-08-05 Хальдор Топсеэ А/С Дегидрирование этилбензола с получением стирола
FR3045412B1 (fr) * 2015-12-18 2018-01-12 Institut National Des Sciences Appliquees De Toulouse Nanoparticules de carbure de fer, procede pour leur preparation et leur utilisation pour la production de chaleur
WO2017186615A1 (fr) * 2016-04-26 2017-11-02 Haldor Topsøe A/S Procédé de synthèse de nitriles
US10486967B2 (en) * 2017-05-04 2019-11-26 Honeywell International Inc. Inductively heated methane pyrolysis reactor for advanced oxygen recovery in environmental control and life support systems

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Publication number Publication date
AU2020350156A1 (en) 2022-03-31
WO2021053307A1 (fr) 2021-03-25
JP2022549603A (ja) 2022-11-28
CA3147684A1 (fr) 2021-03-25
EP4031280A1 (fr) 2022-07-27
FR3100990A1 (fr) 2021-03-26
CN114667187A (zh) 2022-06-24
CN114667187B (zh) 2024-05-24
US20230241588A1 (en) 2023-08-03

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