CN103435102B - 氯化锰及其制备方法 - Google Patents
氯化锰及其制备方法 Download PDFInfo
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- CN103435102B CN103435102B CN201310384422.9A CN201310384422A CN103435102B CN 103435102 B CN103435102 B CN 103435102B CN 201310384422 A CN201310384422 A CN 201310384422A CN 103435102 B CN103435102 B CN 103435102B
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- CN
- China
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- chloride tetrahydrate
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- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 229910021380 Manganese Chloride Inorganic materials 0.000 title abstract 3
- GLFNIEUTAYBVOC-UHFFFAOYSA-L Manganese chloride Chemical compound Cl[Mn]Cl GLFNIEUTAYBVOC-UHFFFAOYSA-L 0.000 title abstract 3
- 229940099607 manganese chloride Drugs 0.000 title abstract 3
- 235000002867 manganese chloride Nutrition 0.000 title abstract 3
- 239000011565 manganese chloride Substances 0.000 title abstract 3
- 238000006243 chemical reaction Methods 0.000 claims abstract description 53
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims abstract description 40
- VASIZKWUTCETSD-UHFFFAOYSA-N manganese(II) oxide Inorganic materials [Mn]=O VASIZKWUTCETSD-UHFFFAOYSA-N 0.000 claims abstract description 31
- 235000019270 ammonium chloride Nutrition 0.000 claims abstract description 20
- 238000001704 evaporation Methods 0.000 claims abstract description 15
- 238000010438 heat treatment Methods 0.000 claims abstract description 15
- 239000012535 impurity Substances 0.000 claims abstract description 7
- 238000007670 refining Methods 0.000 claims abstract description 7
- CNFDGXZLMLFIJV-UHFFFAOYSA-L manganese(II) chloride tetrahydrate Chemical compound O.O.O.O.[Cl-].[Cl-].[Mn+2] CNFDGXZLMLFIJV-UHFFFAOYSA-L 0.000 claims description 31
- 238000002425 crystallisation Methods 0.000 claims description 30
- 239000000706 filtrate Substances 0.000 claims description 24
- 230000008025 crystallization Effects 0.000 claims description 22
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 21
- 238000000926 separation method Methods 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 18
- 239000000047 product Substances 0.000 claims description 17
- 230000008020 evaporation Effects 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 13
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 12
- 238000005649 metathesis reaction Methods 0.000 claims description 12
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 11
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 11
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 11
- 239000011572 manganese Substances 0.000 claims description 9
- CJDPJFRMHVXWPT-UHFFFAOYSA-N barium sulfide Chemical compound [S-2].[Ba+2] CJDPJFRMHVXWPT-UHFFFAOYSA-N 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 8
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 229910001422 barium ion Inorganic materials 0.000 claims description 3
- 239000012452 mother liquor Substances 0.000 claims description 3
- 230000020477 pH reduction Effects 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- 229910052788 barium Inorganic materials 0.000 claims description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- -1 iron ion Chemical class 0.000 claims description 2
- 238000003786 synthesis reaction Methods 0.000 claims description 2
- 239000010405 anode material Substances 0.000 abstract description 2
- 238000000354 decomposition reaction Methods 0.000 abstract 2
- PPNAOCWZXJOHFK-UHFFFAOYSA-N manganese(2+);oxygen(2-) Chemical compound [O-2].[Mn+2] PPNAOCWZXJOHFK-UHFFFAOYSA-N 0.000 abstract 2
- 238000001914 filtration Methods 0.000 description 8
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 229910052700 potassium Inorganic materials 0.000 description 5
- 229910017840 NH 3 Inorganic materials 0.000 description 4
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 4
- 229910052793 cadmium Inorganic materials 0.000 description 4
- 229910052804 chromium Inorganic materials 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 229910052745 lead Inorganic materials 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- BIGPRXCJEDHCLP-UHFFFAOYSA-N ammonium bisulfate Chemical compound [NH4+].OS([O-])(=O)=O BIGPRXCJEDHCLP-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 2
- 239000010406 cathode material Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 238000009616 inductively coupled plasma Methods 0.000 description 2
- 229910001416 lithium ion Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 206010065042 Immune reconstitution inflammatory syndrome Diseases 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- WCMHZFHLWGFVCQ-UHFFFAOYSA-N [Ba].[Mn] Chemical compound [Ba].[Mn] WCMHZFHLWGFVCQ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000001636 atomic emission spectroscopy Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000007516 brønsted-lowry acids Chemical class 0.000 description 1
- 150000007528 brønsted-lowry bases Chemical class 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 1
- XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 description 1
- QCAWEPFNJXQPAN-UHFFFAOYSA-N methoxyfenozide Chemical compound COC1=CC=CC(C(=O)NN(C(=O)C=2C=C(C)C=C(C)C=2)C(C)(C)C)=C1C QCAWEPFNJXQPAN-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Polyesters Or Polycarbonates (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Description
1# | 2# | 3# | |
MnCl2·4H2Owt% | 99.87 | 99.81 | 99.75 |
K ppm | ≤10.0 | ≤10.0 | ≤10.0 |
Na ppm | ≤10.0 | ≤10.0 | ≤10.0 |
Ca ppm | 23.2 | 20.0 | 21.7 |
Mg ppm | ≤20.0 | ≤20.0 | ≤20.0 |
Fe ppm | 4.7 | 4.9 | 4.7 |
SO4 2-ppm | ≤500.0 | ≤500.0 | ≤500.0 |
Cu ppm | ND | ND | ND |
Zn ppm | ND | ND | ND |
Cd ppm | ND | ND | ND |
Pb ppm | ND | ND | ND |
Cr ppm | ND | ND | ND |
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201310384422.9A CN103435102B (zh) | 2013-08-29 | 2013-08-29 | 氯化锰及其制备方法 |
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CN201310384422.9A CN103435102B (zh) | 2013-08-29 | 2013-08-29 | 氯化锰及其制备方法 |
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CN103435102A CN103435102A (zh) | 2013-12-11 |
CN103435102B true CN103435102B (zh) | 2015-07-22 |
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CN201310384422.9A Expired - Fee Related CN103435102B (zh) | 2013-08-29 | 2013-08-29 | 氯化锰及其制备方法 |
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Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN112939088B (zh) * | 2021-03-31 | 2022-11-04 | 合肥市未来药物开发有限公司 | 一种四水合氯化锰原料药的制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101798119A (zh) * | 2010-03-29 | 2010-08-11 | 贵州红星发展股份有限公司 | 一种制备一水合硫酸锰的方法 |
CN102115136A (zh) * | 2010-12-31 | 2011-07-06 | 谢善情 | 用氯化钡废渣制备硫酸钡联产氯化锰的方法 |
CN102674465A (zh) * | 2012-05-23 | 2012-09-19 | 贵州红星发展股份有限公司 | 含HCl的尾气回收氯气并制备氯化锰的方法及该氯化锰结晶 |
CN102923750A (zh) * | 2012-11-26 | 2013-02-13 | 贵州红星发展股份有限公司 | 一种复分解法高纯碳酸钡及其制备方法 |
-
2013
- 2013-08-29 CN CN201310384422.9A patent/CN103435102B/zh not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101798119A (zh) * | 2010-03-29 | 2010-08-11 | 贵州红星发展股份有限公司 | 一种制备一水合硫酸锰的方法 |
CN102115136A (zh) * | 2010-12-31 | 2011-07-06 | 谢善情 | 用氯化钡废渣制备硫酸钡联产氯化锰的方法 |
CN102674465A (zh) * | 2012-05-23 | 2012-09-19 | 贵州红星发展股份有限公司 | 含HCl的尾气回收氯气并制备氯化锰的方法及该氯化锰结晶 |
CN102923750A (zh) * | 2012-11-26 | 2013-02-13 | 贵州红星发展股份有限公司 | 一种复分解法高纯碳酸钡及其制备方法 |
Non-Patent Citations (2)
Title |
---|
冯务群主编.《药学类高职高专系列教材 分析化学》.《药学类高职高专系列教材 分析化学》.河南科学技术出版社,2007,(第1版),第291页. * |
朱洪法主编.《催化剂手册》.《催化剂手册》.金盾出版社,2008,(第1版),第331-332页. * |
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Effective date of registration: 20141215 Address after: 561206 Guizhou city of Anshun province Zhenning County small town Applicant after: Beijing Wankun Jiahong Science and Technology Development Co., Ltd. Address before: 561206 Guizhou city of Anshun province Zhenning County small town Applicant before: Beijing Wankun Jiahong Science and Technology Development Co., Ltd. Applicant before: Shenzhen Haoyitong Investment & Development Co., Ltd. |
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