CN103405377A - Natural skin whitening and protecting composition and application thereof in cosmetics - Google Patents
Natural skin whitening and protecting composition and application thereof in cosmetics Download PDFInfo
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- CN103405377A CN103405377A CN2013103640626A CN201310364062A CN103405377A CN 103405377 A CN103405377 A CN 103405377A CN 2013103640626 A CN2013103640626 A CN 2013103640626A CN 201310364062 A CN201310364062 A CN 201310364062A CN 103405377 A CN103405377 A CN 103405377A
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Abstract
The invention relates to a natural skin whitening and protecting composition and an application thereof in cosmetics. The composition comprises the following components in percentage by weight: 1-9% of pomegranate pericarp extracts, 1-8% of extracts from pueraria, 1-9% of paeonol, 1-10% of radix angelicae extracts, 1-7% of white willow extracts, 1-9% of meadowfoam seed oil, 1-7% of cajeput oil, 0.5-6% of resveratrol, 0.5-7% of extracts of Lilium candidum, 0.5-8% of anthemis nobilis flower extract, 1-6% of white birch oil, 1-9% of Bletilla root extracts, 0.5-6% of flower extracts from white plumeria rubra, 1-6% of gardenia oil, 1-8% of extracts from Rhizoma Atractylodis Macrocephalae root, 1-9% of common perilla extracts, 1-7% of nymphaea alba extracts, and 1-10% of pearl extracts. The additive amount of the composition in cosmetics is 5-8wt%. The composition provided by the invention has a remarkable whitening effect, can be used as an additive and is stably added into various cosmetics, and is natural, green and safe.
Description
Technical field
The present invention relates to the natural skin care compositions, relate in particular to a kind of have the natural whiting compositions of white-skinned face function and the application in cosmetics thereof, belong to the daily cosmetics field.
Background technology
As the saying goes " a white screening three is ugly ".Since ancient times, the kermes pigment are almost the skin-lightening cosmetics of each adult female's indispensability, to modern, the various whitenings powdering such as skin whitener, concealer, foundation cream, loose powder, finishing powder, muffin product occurred especially.But whitening, if cured the disease, takes stopgap measures and need effect a permanent cure, only have inherent skin quality conditionedly, thoroughly radical cure affect arch-criminal---the melanin of whitening, and skin just can represent really natural beauty white light coloured silk from inside to outside.
Mainly there is following defect in current commercially available skin-lightening cosmetic: 1. in most of cosmetics whitening compositions, added human body and the harmful chemical composition of skin, as materials such as heavy metals, life-time service can damage the skin homergy, causes serious consequence; 2. in whitening composition, each component synergy is poor, does not reach the expection whitening effect.Therefore, a obvious pure natural skin care compositions of whitening effect that can be used as the cosmetics additive of research extremely is necessary.
Summary of the invention
For the above-mentioned defect that prior art whitening and skin-protecting product exists, the applicant is through Improvement, and purpose is to provide a kind of whitening effect significant natural whiting skin care compositions, and said composition is comprised of the component of following weight proportion (wt%):
Pomegranate Peel Extract 1 ~ 9%
Radix Puerariae extract 1 ~ 8%
Paeonol 1 ~ 9%
Radix Angelicae Dahuricae extract 1 ~ 10%
Salix alba leaf extract 1 ~ 7%
White Limnanthes Alba Seed Oil 1 ~ 9%
Cortex Melaleucae leucadendrae oil 1 ~ 7%
Resveratrol 0.5 ~ 6%
Bermuda lily flower extract 0.5 ~ 7%
Anthemis nobilis caul-fat 0.5 ~ 8%
Betula platyphylla Suk. oil 1 ~ 6%
Pseudobulbus Bletillae (Rhizoma Bletillae) root extract 1 ~ 9%
White Flos Plumeriae Acutifoliae flower extract 0.5 ~ 6%
Flos micheliae Albae oil 1 ~ 6%
Rhizoma Atractylodis Macrocephalae root extract 1 ~ 8%
Extracts from Perilla frutescens 1 ~ 9%
White pond lily flower extract 1 ~ 7%
Margarita extract 1 ~ 10%
Preferably, said composition is comprised of the component of following weight proportion (wt%):
Pomegranate Peel Extract 4 ~ 7%
Radix Puerariae extract 2 ~ 8%
Paeonol 2 ~ 9%
Radix Angelicae Dahuricae extract 5 ~ 10%
Salix alba leaf extract 2 ~ 7%
White Limnanthes Alba Seed Oil 4 ~ 9%
Cortex Melaleucae leucadendrae oil 4 ~ 7%
Resveratrol 1 ~ 6%
Bermuda lily flower extract 2 ~ 7%
Anthemis nobilis caul-fat 2 ~ 8%
Betula platyphylla Suk. oil 2 ~ 6%
Pseudobulbus Bletillae (Rhizoma Bletillae) root extract 3 ~ 9%
White Flos Plumeriae Acutifoliae flower extract 2 ~ 6%
Flos micheliae Albae oil 2 ~ 6%
Rhizoma Atractylodis Macrocephalae root extract 2 ~ 8%
Extracts from Perilla frutescens 5 ~ 9%
White pond lily flower extract 2 ~ 7%
Margarita extract 5 ~ 10%.
The preparation method of above-mentioned whitening and skin-protecting compositions be by each component by the proportion speed weighing, fully mix and stir, get final product.
Pomegranate Peel Extract as above has antioxidation, whitening function, can increase immune function of human body, has simultaneously bacteriostasis.
Its active component of Radix Puerariae extract is isoflavone (puerarin, daidzin, daidzein, genistein) as mentioned above, has whitening function, can effectively improve chloasma, make skin finer and smoother moist, glossy, skin elasticity increases, corse sweat pore improves, and wrinkle obviously reduces.
Paeonol is a kind of Chinese crude drug from extracting the root of Chinese national flower Flos Moutan as mentioned above, and chemical composition is 2 hydroxyls-4-methoxyacetophenone, and paeonol can suppress O in cell
2-Free-radical generating, can make skin whitening, and by fossil pigments Reduction fading in skin, the silt dissipating rashes that disappears, have the effects such as antiinflammatory, reducing swelling and alleviating pain, antiallergic, antiviral simultaneously.
Its chemical composition of Radix Angelicae Dahuricae extract contains isoimperatorin, imperatorin, bergapton, phellopterin, oxypeucedanin etc. as mentioned above, has the blood circulation of improvement, regulation of skin metabolism, radioprotective, antiinflammatory, improves the effects such as skin pruritus.
Salix alba leaf extract as above can promote resistance to compression albumen to form; General Promotion skin protective potential; effectively resist free radical, antioxidation, protection skin collagen protein, repair moisturizing, prevent that DNA is impaired, the injury effectively negative factors such as uvioresistant, pollution, emotion and pressure caused skin.
White Limnanthes Alba Seed Oil as above contains 18% two dodecadienoic acids, very approaching with the DHA structure; Contain the efficient natural antioxidant, can extend the retention cycle of the formula that contains easy oxidation vegetable oil and unstable material, effect is equal to Vitamin E acetate.
Cortex Melaleucae leucadendrae oil scalable sebum secretion amount as above, not only have very strong natural antibacterial inflammation-diminishing function, and little to skin irritation.
Resveratrol as above is a kind of natural polyphenol class material, mainly by removing or suppressing free radical, generates, and the inhibition lipid peroxidation, regulate the mechanism performance antioxidations such as antioxidation related enzyme activity.
Bermuda lily flower extract as above has very strong moisturizing and the effect of regulating skin moisture.
Anthemis nobilis caul-fat as above has the skin Caring effects such as anti-inflammatory, antibiotic, antiallergic, SOD sample activity, aging resistance, the generation of promotion elastic fiber.
Its main component of Betula platyphylla Suk. oil as above is salicylic acid, methyl salicylate, betulene and betulenol, has the effects such as pain relieving, sterilization, convergence, purification, sterilization.
In Pseudobulbus Bletillae (Rhizoma Bletillae) root extract as above, contain water-soluble glucosan, have the effect that promotes the epithelial cell reparation, smoothes away wrinkles, improves skin appearance.
The effects such as white Flos Plumeriae Acutifoliae flower extract as above has calm antiinflammatory, the skin of releiving.
Flos micheliae Albae oil as above is a kind of important quintessence oil fragrance of a flower spice of perfume industry, main component myrcene, limonene, cineole, linalool oxide etc.
Rhizoma Atractylodis Macrocephalae root extract as above has antioxidation, can effectively suppress lipid peroxidation, reduces the content of organizing lipid peroxide, avoids the destruction of harmful substance to the histiocyte 26S Proteasome Structure and Function.
The effects such as white pond lily extract as above has calm antiinflammatory, the skin of releiving, help dredging pore.
Margarita extract as above contains aminoacid and trace element various needed by human body and that easily absorb, have calm the nerves, detoxify, preserve youthful looks, the effect such as correcting and skin moisturizing and rejuvenating.
Another purpose of the present invention is to provide the application of above-mentioned skin care compositions in cosmetics.Said composition can
As the cosmetics additive, be applied in various cosmetics, be prepared into whitening emulsion with white-skinned face function, skin whitener, sunscreen cream, cleawhite pack etc., its addition is 2 ~ 10wt%, is preferably 5 ~ 8wt%.
Useful technique effect of the present invention is as follows:
The present invention is on the basis of a variety of causes that considers melanin formation, selected nearly 20 kinds of natural plants and Chinese herbal medicine extract form through effectively ratio is composite, comprising: (1) whitening agent such as Pomegranate Peel Extract, Radix Puerariae extract etc., can effectively improve skin gloss, help whitening; (2) sunscreen such as Betula platyphylla Suk. oil, Margarita extract etc., the stimulation that can effectively stop ultraviolet to form melanin; (3) antioxidant such as Salix alba leaf extract, white Limnanthes Alba Seed Oil, resveratrol etc., can suppress the facilitation that radical pair melanin forms; (4) antiinflammatory such as Anthemis nobilis caul-fat, white Flos Plumeriae Acutifoliae flower extract etc., can eliminate the facilitation that various inflammatory factors form melanin; (5) tyrosinase inhibitor such as paeonol etc., tryrosinase is the biosynthetic key enzyme of dermal melanin, have the effect of single phenolase and two phenolase concurrently, it can generate adjacent diphenol by single phenolic hydroxyl group oxidation, can make again adjacent diphenol oxidation generate o-quinone, and then changing into the pigments such as excellent melanocyte, pheomelanin, tyrosinase inhibitor energy restraint of tyrosinase activity, reduce pigmentation.The collaborative onset that cooperatively interacts of above-mentioned each component, the restraint of tyrosinase activity, reduce melanin and form fully and effectively, increase facial lightness, can also effectively resist ultraviolet, prevent skin tanning, have significant whitening effect, can be used as that additive is stable to be added in various cosmetics; Do not contain any artificial chemical composition, pure natural, green, safe and non-stimulating.
The accompanying drawing explanation
Fig. 1 is in tyrosinase inhibition test of the present invention, the schematic diagram of the whitening and skin-protecting compositions of variable concentrations on the impact of single phenolase, polyphenol enzyme inhibition rate.
The specific embodiment
The invention will be further elaborated by the following examples.
Related each raw material of following examples is the commercially available universal product, and related experimental technique is this area conventional method.
Natural whiting skin care compositions Preparation Example
Embodiment 1 ~ embodiment 3 each components of whitening and skin-protecting compositions and weight proportion are as shown in table 1.
Table 1 embodiment 1 ~ embodiment 3 each component of whitening and skin-protecting compositions and weight proportions
Preparation method: each component raw material, by the accurate weighing of above-mentioned weight proportion, is fully mixed and stirred, get final product.
Tyrosinase inhibition test
Tryrosinase is the melanocyte activating enzymes, is the key enzyme of controlling the melanocyte activity, has determined melanic synthesis rate.The single phenolase of tryrosinase is lived in measuring and be take 0.5 mmol/L TYR and be substrate, and the diphenol enzyme activity determination be take 0.5 mmol/L L-3,4 dihydroxyphenylalanine and is substrate.Press respectively table 1,1,2,3,4 group of mensuration liquid of table 2 preparation, at 37 ℃ of water-bath 20 min, be transferred to rapidly in cuvette after fully mixing, and surveys absorbance A in 475 nm places, calculates the suppression ratio of natural whiting to tryrosinase by following formula:
Suppression ratio (%)=[1-(A3-A4)/(A1-A2)] * 100%
In formula, A1, A2, A3, A4 represented respectively substrate, tryrosinase arranged, without the whitening and skin-protecting compositions; Without substrate, tryrosinase is arranged, without the whitening and skin-protecting compositions; Substrate is arranged, tryrosinase is arranged, the whitening and skin-protecting compositions is arranged; Without substrate, tryrosinase is arranged, the absorbance of the phosphoric acid buffer liquid system of these four kinds of combinations of whitening and skin-protecting compositions is arranged.
The suppression ratio test of whitening combination to tryrosinase:
Take TYR during as substrate, and reaction system is as follows: pH 6.8, TYR solution 0.5mL, tryrosinase solution 0.90mL, response time 20min, measure liquid and form referring to table 2.Mensuration embodiment 1 whitening and skin-protecting compositions is to the inhibitory action of tryrosinase under variable concentrations (0.2mg/mL, 0.4 mg/mL, 0.6 mg/mL, 0.8 mg/mL, the water of take is solvent), and result is referring to Fig. 1.
Take L-3,4 dihydroxyphenylalanine during as substrate, and reaction system is as follows: pH 6.8, L-3,4 dihydroxyphenylalanine solution 0.7mL, tryrosinase solution 0.50mL, response time are 5min, measure liquid and form referring to table 3.Mensuration embodiment 1 whitening and skin-protecting compositions is to the inhibitory action of tryrosinase under variable concentrations, and result is referring to Fig. 1.
Table 2 is measured liquid and is formed (TYR of take is substrate)
Table 3 is measured liquid and is formed (L-3,4 dihydroxyphenylalanine of take is substrate)
By Fig. 1, analyzed as can be knownly, the whitening and skin-protecting compositions increases with concentration the inhibitory action of tyrosine list phenolase, and while to concentration, being 0.8mg/mL, its suppression ratio maximum to tyrosine list phenolase, be 96.84%, and when concentration continued to increase, suppression ratio no longer increased; Equally, embodiment 1 whitening and skin-protecting compositions also increases with concentration the inhibitory action of tyrosine two phenolase, and while to concentration, being 1.0mg/mL, suppression ratio reaches 68.75%.As can be seen here, this whitening and skin-protecting compositions is the activity of restraint of tyrosinase effectively, reduces pigmentation, and then reaches the purpose of whitening.
Natural whiting skin care compositions Application Example
Application Example 1 cleawhite pack
The present embodiment cleawhite pack is comprised of the component of following weight proportion (wt%):
Butanediol 3%
Glycerol 2%
Embodiment 1 whitening and skin-protecting compositions 6%
Acrylamide dimethyl tauryl ammonium/VP copolymer 2%
PEG-40 castor oil hydrogenated 1%
Hyaluronate sodium (1wt%) 20%
Methyl isothiazoline 0.05%
Surplus is water
Preparation method: first acrylamide dimethyl tauryl ammonium/VP copolymer is all dissolved in water, then add successively other materials, stir, discharging, obtain.
Application Example 2 cleawhite over-night essences
The tender essence of the present embodiment whitening is comprised of the component of following weight proportion (wt%):
Water 86.3%
Glycerol 4%
Olive oil 1%
Embodiment 1 whitening and skin-protecting compositions 5%
Acrylamide dimethyl tauryl ammonium/VP copolymer 2%
PEG-40 castor oil hydrogenated 1%
Xanthan gum 0.3%
Diazolidinyl urea 0.2%
Essence 0.2%
Preparation method: first acrylamide dimethyl tauryl ammonium/VP copolymer is all dissolved in water, then add the xanthan gum dispersing and dissolving, add successively other materials, stir, discharging, obtain.
Application Example 3 whitening sun protection emulsions
The present embodiment whitening sun protection emulsion is comprised of the component of following weight proportion (wt%):
The A phase component:
The two stearates 2% of polyglycereol (3)
White oil 8%
Iso-octyl palmitate 1%
Isomery hexadecane 7%
The B phase component
Embodiment 2 whitening and skin-protecting compositionss 8%
Titanium dioxide 1%
Glycerol 5%
Magnesium sulfate heptahydrate 1%
The C phase component
Essence 0.1%
Methylisothiazolinone 0.5%
Surplus is water
Preparation method: the two stearates of polyglycereol (3), white oil, iso-octyl palmitate, isomery hexadecane form the A phase component; Divided titanium dioxide is dispersed in described water, adds embodiment 2 whitening and skin-protecting compositionss, glycerol, Magnesium sulfate heptahydrate, obtain the B phase component; A phase component and B phase component are heated to respectively to 85 ℃, then the A phase component are delayed and adds in the B phase component slowly, rapid stirring, used homogenizer to carry out the homogenizing processing after all adding simultaneously, 3 minutes time, is cooled to afterwards 40 ℃; Finally add the C phase component, continue to be stirred to fully cooling, discharging, obtain.
Application Example 4 whitening cream frosts
The present embodiment whitening cream frost is comprised of the component of following weight proportion (wt%):
The A phase component:
Polyoxyethylene (7) castor oil hydrogenated 2%
White oil 5%
Octadecanol 3%
Monoglyceride 1%
Squalane 6%
Isomery hexadecane 3%
The B phase component:
Embodiment 3 whitening and skin-protecting compositionss 5%
1,2-PD 8%
Magnesium sulfate heptahydrate 0.2%
The C phase component:
Essence 0.1%
2-phenyl phenol 0.5%
Surplus is water
Preparation method: polyoxyethylene (7) castor oil hydrogenated, octadecanol, white oil, monoglyceride, squalane, isomery hexadecane form the A phase component; Embodiment 3 whitening and skin-protecting compositionss, 1,2-PD, tween 80, Magnesium sulfate heptahydrate are mixed with described water, obtain the B phase component; A phase component and B phase component are heated to respectively to 85 ℃, then the A phase component are slowly added in the B phase component, rapid stirring, used homogenizer to carry out the homogenizing processing after all adding simultaneously, 3 minutes time, is cooled to afterwards 45 ℃; Finally add the C phase component, continue to be stirred to fully cooling, discharging, obtain.
Clinical usefulness experiment and whitening effect assessment
Select 30 trial volunteers, the women, between 30 ~ 40 years old age; The test position is two cheekbone sections of face, and right forearm inboard be untreated contrast part, every day sooner or later after clean, gets above-mentioned cleawhite over-night essences, whitening sun protection emulsion or whitening cream frost and evenly is applied in and tests position, and cleawhite pack three days is deposited once; Experiment starts from early summer, and experiment is measured each position respective value with color difference meter before starting, and after this measures once per month.
Test result: after three months, observe and experimenter's reaction according to service condition, fine and smooth moistening before experimenter's skin of face is all used, without dry sensation, glossy and elasticity, without anaphylaxis; By the color difference meter measurement result, show, L-value (lightness) has obviously and increases before using, and the inboard arm at position its L-value in whole process has obvious decline in contrast, proves that above-mentioned skin-lightening cosmetic can not only increase facial lightness, and can effectively resist ultraviolet, prevent skin tanning.
Above-described is only the preferred embodiment of the present invention; the present invention is not limited to above embodiment; other improvement and variation that those skilled in the art directly derive without departing from the spirit and concept in the present invention or associate, all should think and be included in protection scope of the present invention.
Claims (4)
1. natural whiting skin care compositions is characterized in that being comprised of the component of following weight proportion (wt%):
Pomegranate Peel Extract 1 ~ 9%
Radix Puerariae extract 1 ~ 8%
Paeonol 1 ~ 9%
Radix Angelicae Dahuricae extract 1 ~ 10%
Salix alba leaf extract 1 ~ 7%
White Limnanthes Alba Seed Oil 1 ~ 9%
Cortex Melaleucae leucadendrae oil 1 ~ 7%
Resveratrol 0.5 ~ 6%
Bermuda lily flower extract 0.5 ~ 7%
Anthemis nobilis caul-fat 0.5 ~ 8%
Betula platyphylla Suk. oil 1 ~ 6%
Pseudobulbus Bletillae (Rhizoma Bletillae) root extract 1 ~ 9%
White Flos Plumeriae Acutifoliae flower extract 0.5 ~ 6%
Flos micheliae Albae oil 1 ~ 6%
Rhizoma Atractylodis Macrocephalae root extract 1 ~ 8%
Extracts from Perilla frutescens 1 ~ 9%
White pond lily flower extract 1 ~ 7%
Margarita extract 1 ~ 10%.
2. natural whiting skin care compositions according to claim 1, is characterized in that being comprised of the component of following weight proportion (wt%): Pomegranate Peel Extract 4 ~ 7%
Radix Puerariae extract 2 ~ 8%
Paeonol 2 ~ 9%
Radix Angelicae Dahuricae extract 5 ~ 10%
Salix alba leaf extract 2 ~ 7%
White Limnanthes Alba Seed Oil 4 ~ 9%
Cortex Melaleucae leucadendrae oil 4 ~ 7%
Resveratrol 1 ~ 6%
Bermuda lily flower extract 2 ~ 7%
Anthemis nobilis caul-fat 2 ~ 8%
Betula platyphylla Suk. oil 2 ~ 6%
Pseudobulbus Bletillae (Rhizoma Bletillae) root extract 3 ~ 9%
White Flos Plumeriae Acutifoliae flower extract 2 ~ 6%
Flos micheliae Albae oil 2 ~ 6%
Rhizoma Atractylodis Macrocephalae root extract 2 ~ 8%
Extracts from Perilla frutescens 5 ~ 9%
White pond lily flower extract 2 ~ 7%
Margarita extract 5 ~ 10%.
3. according to the application of the described natural whiting skin care compositions of claim 1 ~ 2 any one in cosmetics, it is characterized in that: the addition of described skin care compositions in described cosmetics is 2 ~ 10wt%.
4. the application of natural whiting skin care compositions in cosmetics according to claim 3 is characterized in that: the addition of described skin care compositions in described cosmetics is 5 ~ 8wt%.
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