CN103387641A - 一种反式-1,4-结构的丁二烯-异戊二烯共聚橡胶及其制备方法 - Google Patents
一种反式-1,4-结构的丁二烯-异戊二烯共聚橡胶及其制备方法 Download PDFInfo
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- CN103387641A CN103387641A CN2012101386217A CN201210138621A CN103387641A CN 103387641 A CN103387641 A CN 103387641A CN 2012101386217 A CN2012101386217 A CN 2012101386217A CN 201210138621 A CN201210138621 A CN 201210138621A CN 103387641 A CN103387641 A CN 103387641A
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- butadiene
- isoprene
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- copolymer rubber
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- 229920001577 copolymer Polymers 0.000 title claims abstract description 57
- 229920001971 elastomer Polymers 0.000 title claims abstract description 37
- 239000005060 rubber Substances 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims abstract description 60
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims abstract description 51
- 239000010936 titanium Substances 0.000 claims abstract description 39
- 238000007334 copolymerization reaction Methods 0.000 claims abstract description 30
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 29
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 28
- 238000006243 chemical reaction Methods 0.000 claims abstract description 27
- 239000000463 material Substances 0.000 claims abstract description 19
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims abstract description 6
- 239000000178 monomer Substances 0.000 claims description 36
- 239000003054 catalyst Substances 0.000 claims description 26
- 239000003292 glue Substances 0.000 claims description 20
- 238000006116 polymerization reaction Methods 0.000 claims description 13
- 238000001035 drying Methods 0.000 claims description 12
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 10
- 239000011954 Ziegler–Natta catalyst Substances 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 10
- 150000003609 titanium compounds Chemical class 0.000 claims description 9
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 claims description 7
- 239000004411 aluminium Substances 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 claims description 4
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 claims description 3
- 229910000086 alane Inorganic materials 0.000 claims description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 claims description 2
- 235000011147 magnesium chloride Nutrition 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 150000002899 organoaluminium compounds Chemical group 0.000 claims description 2
- 230000032696 parturition Effects 0.000 claims description 2
- -1 Titanium compound Chemical class 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 8
- 230000015572 biosynthetic process Effects 0.000 abstract description 5
- 238000003786 synthesis reaction Methods 0.000 abstract description 5
- 230000003197 catalytic effect Effects 0.000 abstract description 3
- 238000005299 abrasion Methods 0.000 abstract description 2
- 150000001399 aluminium compounds Chemical class 0.000 abstract 1
- 229910001629 magnesium chloride Inorganic materials 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- 229910003074 TiCl4 Inorganic materials 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 3
- 229910052744 lithium Inorganic materials 0.000 description 3
- 150000003608 titanium Chemical class 0.000 description 3
- 229910052793 cadmium Inorganic materials 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000020169 heat generation Effects 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- 229920003051 synthetic elastomer Polymers 0.000 description 2
- 239000005061 synthetic rubber Substances 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
- TWDJIKFUVRYBJF-UHFFFAOYSA-N Cyanthoate Chemical compound CCOP(=O)(OCC)SCC(=O)NC(C)(C)C#N TWDJIKFUVRYBJF-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 101100010166 Mus musculus Dok3 gene Proteins 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 230000002929 anti-fatigue Effects 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- VLLYOYVKQDKAHN-UHFFFAOYSA-N buta-1,3-diene;2-methylbuta-1,3-diene Chemical compound C=CC=C.CC(=C)C=C VLLYOYVKQDKAHN-UHFFFAOYSA-N 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000012718 coordination polymerization Methods 0.000 description 1
- 229920001887 crystalline plastic Polymers 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000013536 elastomeric material Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 229920001206 natural gum Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000010058 rubber compounding Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
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- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
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Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104629114A (zh) * | 2015-02-02 | 2015-05-20 | 柳州市同进汽车零部件制造有限公司 | 减震橡胶组合物 |
CN105601814A (zh) * | 2016-03-24 | 2016-05-25 | 青岛科技大学 | 反式丁戊共聚橡胶的工业化生产方法及实施该方法的装置 |
CN105754023A (zh) * | 2016-03-24 | 2016-07-13 | 青岛科技大学 | 一种反式-1,4-聚二烯烃复合橡胶的制备方法 |
CN106750637A (zh) * | 2017-01-24 | 2017-05-31 | 山东华聚高分子材料有限公司 | 一种纳米碳材料填充的反式‑1,4‑丁二烯‑异戊二烯共聚复合橡胶及其制备方法 |
CN107033406A (zh) * | 2016-11-29 | 2017-08-11 | 株洲时代新材料科技股份有限公司 | 一种耐寒橡胶复合材料及其制备方法及由该耐寒橡胶复合材料制作的铁垫板下弹性垫板 |
CN107686536A (zh) * | 2017-09-30 | 2018-02-13 | 青岛科技大学 | 反式‑1,4‑丁二烯‑异戊二烯共聚橡胶的工业生产方法及实施该方法的装置 |
US10308792B2 (en) * | 2013-10-08 | 2019-06-04 | The Goodyear Tire & Rubber Company | Rubbery blend containing trans isoprene-butadiene copolymer |
CN110511300A (zh) * | 2019-09-18 | 2019-11-29 | 青岛科技大学 | 一种卤化的反式丁二烯-异戊二烯共聚橡胶及其制备方法和用途 |
CN111333762A (zh) * | 2019-12-20 | 2020-06-26 | 青岛竣翔科技有限公司 | 一种梳妆结构聚法尼烯橡胶及其制备方法 |
CN112210128A (zh) * | 2019-07-09 | 2021-01-12 | 中国石油化工股份有限公司 | 一种基于梯度嵌段锂系bir的轮胎胎侧胶料及制备方法 |
CN112210127A (zh) * | 2019-07-09 | 2021-01-12 | 中国石油化工股份有限公司 | 一种高性能子午线轮胎胎面基部用胶及其制备方法 |
CN112210040A (zh) * | 2019-07-09 | 2021-01-12 | 中国石油化工股份有限公司 | 一种宽分布聚丁二烯-异戊二烯橡胶及其制备方法 |
CN113087829A (zh) * | 2021-04-07 | 2021-07-09 | 青岛科技大学 | 一种端基官能化的合成橡胶及其制备方法与用途 |
CN113563685A (zh) * | 2020-04-29 | 2021-10-29 | 中国石油化工股份有限公司 | 一种全钢载重子午线轮胎配方胶料及其制备方法 |
CN114369294A (zh) * | 2022-01-12 | 2022-04-19 | 青岛科技大学 | 一种聚二烯烃釜内合金及其制备方法与用途 |
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Cited By (28)
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US10308792B2 (en) * | 2013-10-08 | 2019-06-04 | The Goodyear Tire & Rubber Company | Rubbery blend containing trans isoprene-butadiene copolymer |
CN104629114A (zh) * | 2015-02-02 | 2015-05-20 | 柳州市同进汽车零部件制造有限公司 | 减震橡胶组合物 |
RU2705220C1 (ru) * | 2016-03-24 | 2019-11-06 | Циндао Юниверсити Оф Сайенс Энд Текнолоджи | Способ промышленного получения транс-бутадиен-изопренового сополимерного каучука и установка для него |
CN105601814A (zh) * | 2016-03-24 | 2016-05-25 | 青岛科技大学 | 反式丁戊共聚橡胶的工业化生产方法及实施该方法的装置 |
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WO2017161898A1 (zh) * | 2016-03-24 | 2017-09-28 | 青岛科技大学 | 反式丁戊共聚橡胶的工业化生产方法及实施该方法的装置 |
CN105754023B (zh) * | 2016-03-24 | 2020-11-03 | 青岛科技大学 | 一种反式-1,4-聚二烯烃复合橡胶的制备方法 |
US10988561B2 (en) | 2016-03-24 | 2021-04-27 | Qingdao University Of Science And Technology | Method for industrial production of trans-butadiene-isoprene copolymer rubber and apparatus therefor |
CN107033406A (zh) * | 2016-11-29 | 2017-08-11 | 株洲时代新材料科技股份有限公司 | 一种耐寒橡胶复合材料及其制备方法及由该耐寒橡胶复合材料制作的铁垫板下弹性垫板 |
CN107033406B (zh) * | 2016-11-29 | 2019-03-15 | 株洲时代新材料科技股份有限公司 | 一种耐寒橡胶复合材料及其制备方法及由该耐寒橡胶复合材料制作的铁垫板下弹性垫板 |
CN106750637A (zh) * | 2017-01-24 | 2017-05-31 | 山东华聚高分子材料有限公司 | 一种纳米碳材料填充的反式‑1,4‑丁二烯‑异戊二烯共聚复合橡胶及其制备方法 |
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CN113087829A (zh) * | 2021-04-07 | 2021-07-09 | 青岛科技大学 | 一种端基官能化的合成橡胶及其制备方法与用途 |
CN113087829B (zh) * | 2021-04-07 | 2023-08-29 | 青岛科技大学 | 一种端基官能化的合成橡胶及其制备方法与用途 |
CN114369294A (zh) * | 2022-01-12 | 2022-04-19 | 青岛科技大学 | 一种聚二烯烃釜内合金及其制备方法与用途 |
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