CN103341325B - 一种两用型膜清洗剂、制备方法及其应用 - Google Patents
一种两用型膜清洗剂、制备方法及其应用 Download PDFInfo
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- CN103341325B CN103341325B CN201310240786.XA CN201310240786A CN103341325B CN 103341325 B CN103341325 B CN 103341325B CN 201310240786 A CN201310240786 A CN 201310240786A CN 103341325 B CN103341325 B CN 103341325B
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- 239000002253 acid Substances 0.000 claims description 27
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 24
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 11
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
- 230000009471 action Effects 0.000 claims description 9
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 6
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 4
- 229910017604 nitric acid Inorganic materials 0.000 claims description 4
- 238000010298 pulverizing process Methods 0.000 claims description 4
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- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 3
- 229910000403 monosodium phosphate Inorganic materials 0.000 claims description 2
- 235000019799 monosodium phosphate Nutrition 0.000 claims description 2
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims description 2
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims description 2
- 239000001488 sodium phosphate Substances 0.000 claims description 2
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 2
- 235000011008 sodium phosphates Nutrition 0.000 claims description 2
- 229940048086 sodium pyrophosphate Drugs 0.000 claims description 2
- 235000019818 tetrasodium diphosphate Nutrition 0.000 claims description 2
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 2
- 239000013638 trimer Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 12
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract description 7
- 229910052938 sodium sulfate Inorganic materials 0.000 abstract description 5
- 235000011152 sodium sulphate Nutrition 0.000 abstract description 5
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 abstract description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 abstract description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 abstract 2
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 abstract 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 abstract 1
- 239000001768 carboxy methyl cellulose Substances 0.000 abstract 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 abstract 1
- 229940073507 cocamidopropyl betaine Drugs 0.000 abstract 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 abstract 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 abstract 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- 239000001509 sodium citrate Substances 0.000 abstract 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 abstract 1
- 239000000176 sodium gluconate Substances 0.000 abstract 1
- 229940005574 sodium gluconate Drugs 0.000 abstract 1
- 235000012207 sodium gluconate Nutrition 0.000 abstract 1
- 235000010344 sodium nitrate Nutrition 0.000 abstract 1
- 239000004317 sodium nitrate Substances 0.000 abstract 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 abstract 1
- 230000002195 synergetic effect Effects 0.000 abstract 1
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 230000008569 process Effects 0.000 description 6
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 238000005063 solubilization Methods 0.000 description 3
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- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
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- 238000002474 experimental method Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
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- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- -1 sodium alkyl benzene Chemical class 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 description 1
- UGTHTQWIQKEDEH-BQBZGAKWSA-N L-alanyl-L-prolylglycine zwitterion Chemical compound C[C@H](N)C(=O)N1CCC[C@H]1C(=O)NCC(O)=O UGTHTQWIQKEDEH-BQBZGAKWSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
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- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 235000019830 sodium polyphosphate Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
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- 238000000108 ultra-filtration Methods 0.000 description 1
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- 229910052726 zirconium Inorganic materials 0.000 description 1
Landscapes
- Separation Using Semi-Permeable Membranes (AREA)
- Detergent Compositions (AREA)
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Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105080347A (zh) * | 2014-05-20 | 2015-11-25 | 天津市鑫磊净化设备有限公司 | 一种中空纤维超滤膜清洗剂及其制备、应用方法 |
CN104069740B (zh) * | 2014-07-26 | 2016-06-22 | 威海翔宇环保科技股份有限公司 | 反渗透膜专用碱性清洗剂及应用方法 |
CN105056765A (zh) * | 2015-08-20 | 2015-11-18 | 太仓市金鹿电镀有限公司 | 一种超滤膜表面有机污染物的清洗方法及其清洗液的制备方法 |
CN105413475A (zh) * | 2015-11-17 | 2016-03-23 | 新疆水处理工程技术研究中心有限公司 | 一种适用于清洗中空纤维纳滤膜的清洗剂及其制备方法 |
CN107149877A (zh) * | 2016-03-02 | 2017-09-12 | 上海丰信环保科技有限公司 | 中水回用膜碱性清洗剂 |
CN106334455A (zh) * | 2016-11-04 | 2017-01-18 | 中海油天津化工研究设计院有限公司 | 一种适用于含环烷酸溶解油炼油废水处理的膜清洗剂 |
CN106943880A (zh) * | 2017-01-17 | 2017-07-14 | 南京中材水务股份有限公司 | 一种膜清洗剂、其制备方法及其应用 |
JP6468305B2 (ja) * | 2017-03-07 | 2019-02-13 | 栗田工業株式会社 | 水処理薬品及びその調製方法、並びにポリアミド系逆浸透膜の洗浄方法 |
CN107824054A (zh) * | 2017-11-22 | 2018-03-23 | 广东桑海环保有限公司 | 一种反渗透膜清洗剂及其制备方法 |
CN110180392B (zh) * | 2019-06-20 | 2020-04-14 | 海南中橡科技有限公司 | 一种从制胶废水中提取白坚木皮醇用滤膜的清洗方法 |
CN111992047A (zh) * | 2020-08-04 | 2020-11-27 | 烟台金正环保科技有限公司 | 一种焦化废水行业膜清洗剂、制备及清洗方法 |
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CN102002722A (zh) * | 2009-08-28 | 2011-04-06 | 比亚迪股份有限公司 | 一种不锈钢清洗剂及一种不锈钢清洗方法 |
CN102658034A (zh) * | 2012-04-30 | 2012-09-12 | 景德镇陶瓷学院 | 一种纳米涂层修饰改性陶瓷微滤膜清洗剂及其制备方法和应用 |
CN102921305A (zh) * | 2012-10-25 | 2013-02-13 | 贵阳时代沃顿科技有限公司 | 一种反渗透膜中残留芳香胺类物质的清洗剂及清洗方法 |
CN103127836A (zh) * | 2011-11-30 | 2013-06-05 | 上海梅山钢铁股份有限公司 | 陶瓷膜清洗剂 |
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Patent Citations (4)
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CN102002722A (zh) * | 2009-08-28 | 2011-04-06 | 比亚迪股份有限公司 | 一种不锈钢清洗剂及一种不锈钢清洗方法 |
CN103127836A (zh) * | 2011-11-30 | 2013-06-05 | 上海梅山钢铁股份有限公司 | 陶瓷膜清洗剂 |
CN102658034A (zh) * | 2012-04-30 | 2012-09-12 | 景德镇陶瓷学院 | 一种纳米涂层修饰改性陶瓷微滤膜清洗剂及其制备方法和应用 |
CN102921305A (zh) * | 2012-10-25 | 2013-02-13 | 贵阳时代沃顿科技有限公司 | 一种反渗透膜中残留芳香胺类物质的清洗剂及清洗方法 |
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Address after: Jimei District of Xiamen City, Fujian province 361000 sun ban Nan Lu Yongxiang garden 37 Building 1003 Applicant after: Wu Zhangfeng Address before: Two, building 1, No. 8, Xinguang Road, Xinyang street, Haicang District, Fujian, Xiamen 361000, China Applicant before: Wu Zhangfeng |
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Application publication date: 20131009 Assignee: Xiamen Zhengcheng Membrane Cleaning Technology Co.,Ltd. Assignor: Wu Zhangfeng Contract record no.: 2015350000022 Denomination of invention: Dual-purpose film cleaning agent and its preparation method and use Granted publication date: 20150107 License type: Exclusive License Record date: 20150408 |
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Effective date of registration: 20171205 Address after: 361000 unit 598, No. 598, Jimei District, Jimei District, Nan Lu, unit 403 Patentee after: Xiamen Zhengcheng Membrane Cleaning Technology Co.,Ltd. Address before: Jimei District of Xiamen City, Fujian province 361000 sun ban Nan Lu Yongxiang garden 37 Building 1003 Patentee before: Wu Zhangfeng |