CN103299463B - 气体扩散电极 - Google Patents

气体扩散电极 Download PDF

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Publication number
CN103299463B
CN103299463B CN201180059733.7A CN201180059733A CN103299463B CN 103299463 B CN103299463 B CN 103299463B CN 201180059733 A CN201180059733 A CN 201180059733A CN 103299463 B CN103299463 B CN 103299463B
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Prior art keywords
diffusion layer
layer
electrode
diffusion
gas
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Expired - Fee Related
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CN201180059733.7A
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Chinese (zh)
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CN103299463A (zh
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嶋宗孝之
约翰尼斯·奇洛斯
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Permascand AB
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Permascand AB
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
    • C25B11/095—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds at least one of the compounds being organic
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8605—Porous electrodes
    • H01M4/8621—Porous electrodes containing only metallic or ceramic material, e.g. made by sintering or sputtering
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C25B11/03—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
    • C25B11/031—Porous electrodes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C25B11/03—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
    • C25B11/031—Porous electrodes
    • C25B11/032—Gas diffusion electrodes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/055—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
    • C25B11/069—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material consisting of at least one single element and at least one compound; consisting of two or more compounds
    • C25B11/071—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material consisting of at least one single element and at least one compound; consisting of two or more compounds comprising metal or alloy powder and non-metallic binders
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/075—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound
    • C25B11/081—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound the element being a noble metal
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00—Hybrid cells; Manufacture thereof
    • H01M12/04—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
    • H01M12/06—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8605—Porous electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8647—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
    • H01M4/8657—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites layered
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8663—Selection of inactive substances as ingredients for catalytic active masses, e.g. binders, fillers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8803—Supports for the deposition of the catalytic active composition
    • H01M4/8807—Gas diffusion layers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
    • H01M4/8882—Heat treatment, e.g. drying, baking
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
    • H01M4/8882—Heat treatment, e.g. drying, baking
    • H01M4/8885—Sintering or firing
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8663—Selection of inactive substances as ingredients for catalytic active masses, e.g. binders, fillers
    • H01M4/8668—Binders
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Composite Materials (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
  • Inert Electrodes (AREA)
CN201180059733.7A 2010-12-29 2011-12-23 气体扩散电极 Expired - Fee Related CN103299463B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201061427868P 2010-12-29 2010-12-29
EP10197276 2010-12-29
US61/427,868 2010-12-29
EP10197276.8 2010-12-29
PCT/EP2011/073937 WO2012089658A1 (en) 2010-12-29 2011-12-23 Gas diffusion electrode

Publications (2)

Publication Number Publication Date
CN103299463A CN103299463A (zh) 2013-09-11
CN103299463B true CN103299463B (zh) 2016-09-28

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Country Status (5)

Country Link
US (1) US9023549B2 (enExample)
EP (1) EP2659536B1 (enExample)
JP (1) JP6049633B2 (enExample)
CN (1) CN103299463B (enExample)
WO (1) WO2012089658A1 (enExample)

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DE102011080936A1 (de) * 2011-08-15 2013-02-21 Robert Bosch Gmbh Elektrode und Energiespeicher umfassend eine Elektrode
JP6578611B2 (ja) * 2013-11-25 2019-09-25 独立行政法人国立高等専門学校機構 空気電池用正極及びこの正極を用いた空気電池
DE102014204372A1 (de) * 2014-03-11 2015-09-17 Bayer Materialscience Ag Verfahren zur Herstellung von katalytisch aktiven Pulvern aus metallischem Silber oder aus Mischungen aus von metallischem Silber mit Silberoxid zur Herstellung von Gasdiffusionselektroden
KR102231210B1 (ko) * 2014-04-08 2021-03-22 삼성에스디아이 주식회사 리튬 공기 전지용 양극, 이의 제조 방법 및 이를 포함하는 리튬 공기 전지
EP3227945B1 (en) 2014-12-03 2022-01-19 Coulombic, Inc. Electrodes and electrochemical devices and methods of making electrodes and electrochemical devices
DE102015215309A1 (de) 2015-08-11 2017-02-16 Siemens Aktiengesellschaft Präparationstechnik von kohlenwasserstoffselektiven Gasdiffusionselektroden basierend auf Cu-haltigen-Katalysatoren
CN105655601A (zh) * 2016-03-28 2016-06-08 北方民族大学 直接硼氢化物燃料电池阳极催化剂的制备方法及应用
CA3026321C (en) 2016-06-02 2023-10-03 Sigma-Aldrich Co. Llc Using programmable dna binding proteins to enhance targeted genome modification
CA3019358A1 (en) 2016-07-22 2018-01-25 Nantenergy, Inc. Mist elimination system for electrochemical cells
JP2019521497A (ja) 2016-07-22 2019-07-25 ナントエナジー，インク． 電気化学セル内の水分及び二酸化炭素管理システム
BR112019004880A2 (pt) 2016-09-15 2019-06-11 Nantenergy, Inc. sistema de bateria híbrida
WO2018075870A1 (en) 2016-10-21 2018-04-26 Fluidic Inc. Corrugated fuel electrode
DE102016224466A1 (de) 2016-12-08 2018-06-14 Siemens Aktiengesellschaft Elektrolysezelle oder Elektrodenplatte mit einer Gasdiffusionselektrode und Verfahren zu deren Betrieb
WO2018187561A1 (en) 2017-04-06 2018-10-11 Jaramillo Mateo Cristian Refuelable battery for the electric grid and method of using thereof
US11611115B2 (en) 2017-12-29 2023-03-21 Form Energy, Inc. Long life sealed alkaline secondary batteries
DE102018210457A1 (de) * 2018-06-27 2020-01-02 Siemens Aktiengesellschaft Gasdiffusionselektrode zur Kohlendioxid-Verwertung, Verfahren zu deren Herstellung sowie Elektrolysezelle mit Gasdiffusionselektrode
US12237548B2 (en) 2018-06-29 2025-02-25 Form Energy, Inc. Stack of electric batteries including series of fluidly connected unit cells
CN112805868A (zh) 2018-06-29 2021-05-14 福恩能源公司 金属空气电化学电池构架
US11973254B2 (en) 2018-06-29 2024-04-30 Form Energy, Inc. Aqueous polysulfide-based electrochemical cell
CN120049075A (zh) 2018-07-27 2025-05-27 福恩能源公司 用于电化学电池的负电极
US12308414B2 (en) 2019-06-28 2025-05-20 Form Energy, Inc. Device architectures for metal-air batteries
US12294086B2 (en) 2019-07-26 2025-05-06 Form Energy, Inc. Low cost metal electrodes
US11949129B2 (en) 2019-10-04 2024-04-02 Form Energy, Inc. Refuelable battery for the electric grid and method of using thereof
US12381244B2 (en) 2020-05-06 2025-08-05 Form Energy, Inc. Decoupled electrode electrochemical energy storage system
JP2023124753A (ja) * 2022-02-25 2023-09-06 株式会社豊田中央研究所 反応触媒及びそれを用いた電気化学リアクタ
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JP2003109606A (ja) * 2001-09-28 2003-04-11 Matsushita Electric Ind Co Ltd 高分子電解質型燃料電池とその製造方法
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EP2659536A1 (en) 2013-11-06
US20130280625A1 (en) 2013-10-24
US9023549B2 (en) 2015-05-05
EP2659536B1 (en) 2018-08-15
JP6049633B2 (ja) 2016-12-21
JP2014502673A (ja) 2014-02-03
CN103299463A (zh) 2013-09-11
WO2012089658A1 (en) 2012-07-05

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