CN103270057B - 含氟聚合物组合物及其纯化方法 - Google Patents

含氟聚合物组合物及其纯化方法 Download PDF

Info

Publication number
CN103270057B
CN103270057B CN201180062357.7A CN201180062357A CN103270057B CN 103270057 B CN103270057 B CN 103270057B CN 201180062357 A CN201180062357 A CN 201180062357A CN 103270057 B CN103270057 B CN 103270057B
Authority
CN
China
Prior art keywords
fluorinated
molecular weight
low molecular
ppm
emulsifier
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201180062357.7A
Other languages
English (en)
Chinese (zh)
Other versions
CN103270057A (zh
Inventor
克劳斯·辛策
迈克尔·于尔根斯
京特·J·肯普夫
哈拉尔德·卡斯帕
凯·赫尔穆特·洛哈斯
安德烈·施特赖特尔
奥列格·夏伊绍科夫
蒂尔曼·C·兹普利斯
赫伯特·柯尼希曼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of CN103270057A publication Critical patent/CN103270057A/zh
Application granted granted Critical
Publication of CN103270057B publication Critical patent/CN103270057B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F6/00—Post-polymerisation treatments
    • C08F6/001—Removal of residual monomers by physical means
    • C08F6/003—Removal of residual monomers by physical means from polymer solutions, suspensions, dispersions or emulsions without recovery of the polymer therefrom
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/26—Treatment of water, waste water, or sewage by extraction
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/02—Monomers containing chlorine
    • C08F14/04—Monomers containing two carbon atoms
    • C08F14/08—Vinylidene chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18—Monomers containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/10—Aqueous solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/20—Aqueous medium with the aid of macromolecular dispersing agents
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104—Devices therefor; Their operating or servicing
    • C02F1/46109—Electrodes
    • C02F2001/46133—Electrodes characterised by the material
    • C02F2001/46138—Electrodes comprising a substrate and a coating
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104—Devices therefor; Their operating or servicing
    • C02F1/46109—Electrodes
    • C02F2001/46133—Electrodes characterised by the material
    • C02F2001/46138—Electrodes comprising a substrate and a coating
    • C02F2001/46147—Diamond coating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/10—Copolymer characterised by the proportions of the comonomers expressed as molar percentages
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Hydrology & Water Resources (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)
  • Fertilizers (AREA)
CN201180062357.7A 2010-12-23 2011-12-21 含氟聚合物组合物及其纯化方法 Expired - Fee Related CN103270057B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB1021790.9 2010-12-23
GBGB1021790.9A GB201021790D0 (en) 2010-12-23 2010-12-23 Fluoropolymer compostions and purification methods thereof
PCT/US2011/066456 WO2012088258A1 (en) 2010-12-23 2011-12-21 Fluoropolymer compositions and purification methods thereof

Publications (2)

Publication Number Publication Date
CN103270057A CN103270057A (zh) 2013-08-28
CN103270057B true CN103270057B (zh) 2016-08-17

Family

ID=43598849

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201180062357.7A Expired - Fee Related CN103270057B (zh) 2010-12-23 2011-12-21 含氟聚合物组合物及其纯化方法

Country Status (6)

Country Link
US (2) US9453086B2 (enExample)
EP (1) EP2655440B1 (enExample)
JP (1) JP6054878B2 (enExample)
CN (1) CN103270057B (enExample)
GB (1) GB201021790D0 (enExample)
WO (1) WO2012088258A1 (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014088804A1 (en) * 2012-12-04 2014-06-12 3M Innovative Properties Company Partially fluorinated polymers
WO2014088820A1 (en) * 2012-12-04 2014-06-12 3M Innovative Properties Company Highly fluorinated polymers
WO2018072367A1 (zh) * 2016-10-21 2018-04-26 中南大学 一种硼掺杂金刚石电极及其制备方法与应用
WO2020041712A1 (en) * 2018-08-23 2020-02-27 Evoqua Water Technologies Llc System and method for electrochemical oxidation of polyfluoroalkyl substances in water
TW202033573A (zh) * 2018-12-17 2020-09-16 美商3M新設資產公司 包括可固化氟聚合物及固化劑之組成物及製造及使用其之方法
JP7389366B2 (ja) * 2019-04-26 2023-11-30 ダイキン工業株式会社 フルオロポリマー水性分散液の製造方法、排水の処理方法、及び、フルオロポリマー水性分散液
EP3945074A1 (en) 2020-07-30 2022-02-02 3M Innovative Properties Company Process to reduce the concentration of fluoroorganic acidic compound in aqueous dispersions
EP3945099A1 (en) * 2020-07-30 2022-02-02 3M Innovative Properties Company Process for removal of fluoroorganic compounds from aqueous media
EP4219412A1 (en) 2022-01-27 2023-08-02 3M Innovative Properties Company Closed-loop technologies for purifying fluorine containing water streams
US20240102960A1 (en) * 2022-09-23 2024-03-28 Hach Company Dynamic end-point total organic fluoride measurement
WO2025135028A1 (ja) * 2023-12-19 2025-06-26 Ａｇｃ株式会社 含フッ素重合体の製造方法、固体組成物

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5364508A (en) * 1992-11-12 1994-11-15 Oleh Weres Electrochemical method and device for generating hydroxyl free radicals and oxidizing chemical substances dissolved in water
US6315886B1 (en) * 1998-12-07 2001-11-13 The Electrosynthesis Company, Inc. Electrolytic apparatus and methods for purification of aqueous solutions
WO2002088207A1 (en) * 2001-05-02 2002-11-07 3M Innovative Properties Company Emulsifier free aqueous emulsion polymerization process for making fluoropolymers
CN1753941A (zh) * 2003-02-28 2006-03-29 3M创新有限公司 不含或含少量低分子量氟化表面活性剂的含氟聚合物分散体
WO2007011633A1 (en) * 2005-07-15 2007-01-25 3M Innovative Properties Company Aqueous emulsion polymerization of fluorinated monomers using a fluorinated surfactant

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2908001C2 (de) 1979-03-01 1981-02-19 Hoechst Ag, 6000 Frankfurt Verfahren zur Herstellung konzentrierter Dispersionen von Fluorpolymeren
JPS5715885A (en) * 1980-06-30 1982-01-27 Nippon Rensui Kk Method for recovery of high-purity waste water of washing
JP3006049B2 (ja) * 1990-07-26 2000-02-07 ダイキン工業株式会社 溶融加工可能なテトラフルオロエチレン共重合体の低分子量体除去方法
US5453477A (en) 1992-05-01 1995-09-26 Alliedsignal Inc. Process of polymerizing chloroetrifluoroethylene with alkyl hydroperoxide and metal metabisulfite
JP3441193B2 (ja) * 1994-09-30 2003-08-25 日本ゼオン株式会社 高純度の重合体の製造方法
US5955556A (en) 1995-11-06 1999-09-21 Alliedsignal Inc. Method of manufacturing fluoropolymers
US7071271B2 (en) * 2003-10-30 2006-07-04 3M Innovative Properties Company Aqueous emulsion polymerization of functionalized fluoromonomers
US7659335B2 (en) * 2004-10-13 2010-02-09 Dupont-Mitsui Fluorochemicals Co Ltd Fluoropolymer dispersion and electrode composition containing same
US7666927B2 (en) 2004-12-22 2010-02-23 E.I. Du Pont De Nemours And Company Removing fluorosurfactant from aqueous fluoropolymer dispersions using anion exchange polymer with functional groups resistant to degradation to trialkylamines
US7671112B2 (en) 2005-07-15 2010-03-02 3M Innovative Properties Company Method of making fluoropolymer dispersion
GB2430437A (en) 2005-09-27 2007-03-28 3M Innovative Properties Co Method of making a fluoropolymer
JP5141255B2 (ja) 2005-10-17 2013-02-13 旭硝子株式会社 ポリテトラフルオロエチレン水性乳化液、それから得られるポリテトラフルオロエチレンファインパウダーおよび多孔体
JP5343355B2 (ja) 2005-10-26 2013-11-13 旭硝子株式会社 含フッ素乳化剤の残留量が少ないフッ素樹脂およびその製造方法
EP1849809A1 (en) * 2006-04-26 2007-10-31 Solvay Solexis S.p.A. Tetrafluoroethylene polymer particles
US7754795B2 (en) 2006-05-25 2010-07-13 3M Innovative Properties Company Coating composition
EP2058291B1 (en) 2006-08-31 2012-11-28 Asahi Glass Company, Limited Perfluorocarboxylic acid salt and method for producing the same
GB0625071D0 (en) 2006-12-15 2007-01-24 3M Innovative Properties Co Process for removing fluorinated emulsifier from fluoropolmer dispersions using an ion-exchange resin and dispersions obtained therefrom
WO2008101137A1 (en) 2007-02-16 2008-08-21 3M Innovative Properties Company System and process for the removal of fluorochemicals from water
GB0712191D0 (en) * 2007-06-25 2007-08-01 3M Innovative Properties Co Process for removing fluorinated compounds for an aqueous phase originating from the preparation of fluoropolymers
US8399703B2 (en) * 2007-07-24 2013-03-19 Daikin Industries, Ltd. Compound, method for producing the same and method for producing fluoropolymer
CN101821301B (zh) 2007-10-12 2012-06-27 3M创新有限公司 制备纯净含氟聚合物的方法
WO2010035448A1 (ja) * 2008-09-24 2010-04-01 栗田工業株式会社 ダイヤモンド電極及びダイヤモンド電極の製造方法
US8153738B2 (en) 2008-12-23 2012-04-10 E I Du Pont De Nemours And Company Fluoropolymer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer
US9103838B2 (en) 2009-02-04 2015-08-11 Lyzer Diagnostics, Inc. Apparatus and methods for separating and analyzing components in fluids
DE102009013380A1 (de) * 2009-03-09 2010-09-16 Hansgrohe Ag Verfahren zum Abbau von teilfluorierten und perfluorierten Tensiden
DE102009038125A1 (de) 2009-08-14 2011-02-17 Hansgrohe Ag Verfahren zur Aufarbeitung von tensidhaltigen Abfällen oder Abwässern

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5364508A (en) * 1992-11-12 1994-11-15 Oleh Weres Electrochemical method and device for generating hydroxyl free radicals and oxidizing chemical substances dissolved in water
US6315886B1 (en) * 1998-12-07 2001-11-13 The Electrosynthesis Company, Inc. Electrolytic apparatus and methods for purification of aqueous solutions
WO2002088207A1 (en) * 2001-05-02 2002-11-07 3M Innovative Properties Company Emulsifier free aqueous emulsion polymerization process for making fluoropolymers
CN1753941A (zh) * 2003-02-28 2006-03-29 3M创新有限公司 不含或含少量低分子量氟化表面活性剂的含氟聚合物分散体
WO2007011633A1 (en) * 2005-07-15 2007-01-25 3M Innovative Properties Company Aqueous emulsion polymerization of fluorinated monomers using a fluorinated surfactant

Also Published As

Publication number Publication date
EP2655440B1 (en) 2016-08-17
JP6054878B2 (ja) 2016-12-27
US20130281607A1 (en) 2013-10-24
GB201021790D0 (en) 2011-02-02
WO2012088258A1 (en) 2012-06-28
CN103270057A (zh) 2013-08-28
US20160362508A1 (en) 2016-12-15
EP2655440A1 (en) 2013-10-30
US9809658B2 (en) 2017-11-07
JP2014501305A (ja) 2014-01-20
US9453086B2 (en) 2016-09-27

Similar Documents

Publication Publication Date Title
CN103270057B (zh) 含氟聚合物组合物及其纯化方法
US4683040A (en) Process for electrolysis of sodium chloride
US4178218A (en) Cation exchange membrane and use thereof in the electrolysis of sodium chloride
JP5482652B2 (ja) 含フッ素重合体の製造方法および含フッ素イオン交換膜
JP5129128B2 (ja) 乳化剤としての部分フッ素化されたオリゴマーの存在下におけるフッ素化モノマーの水性エマルション重合
CA1119350A (en) Ion-exchange structures of copolymer blends
JP5021642B2 (ja) ペルフルオロポリエーテル界面活性剤を用いるフッ素化モノマー類の水性乳化重合
JP2018528316A (ja) スルホニルペンダント基を有するテトラフルオロエチレンのコポリマーを作製する方法
EP0030104B1 (en) Process for preparing organic dispersion of acid-type fluorinated polymer
TW201805316A (zh) 具有磺醯側基之氟化共聚物及製造離子聚合物之方法
EP0753534B1 (en) Cation exchange membrane for electrolysis and process for producing potassium hydroxide of high purity
EP1928922A1 (en) Method of making a fluoropolymer
EP2989131A1 (en) Cross-linkable polymers comprising sulfonic acid functional groups
JPS6356257B2 (enExample)
US9340632B2 (en) Process for producing fluorinated copolymer
CN110785443B (zh) 含氟聚合物、含官能团的含氟聚合物及电解质膜的制造方法
JPH0978280A (ja) 電解用陽イオン交換膜及び高純度水酸化カリウムの製造方法
JPH07118332A (ja) フッ素化モノマーの回収方法
JPH1135624A (ja) フッ素化モノマーの回収方法
JPS5865727A (ja) 改良された含フツ素陽イオン交換樹脂膜
JPS6253341A (ja) 改良された含フツ素陽イオン交換膜
JP2000344825A (ja) フルオロカーボンポリマー粒子の製造方法
JP2020100816A (ja) 陽イオン交換膜、含フッ素系重合体、含フッ素系重合体の製造方法、及び電解槽
JPS5829802B2 (ja) カイリヨウサレタ イオンコウカンキガンユウフルオロポリマ−ノ セイゾウホウホウ
JPS6410543B2 (enExample)

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160817

Termination date: 20201221

CF01 Termination of patent right due to non-payment of annual fee