CN103243411A - 一种基于4,4’-二氨基二苯醚高性能有机纤维的制备方法 - Google Patents
一种基于4,4’-二氨基二苯醚高性能有机纤维的制备方法 Download PDFInfo
- Publication number
- CN103243411A CN103243411A CN2013101985097A CN201310198509A CN103243411A CN 103243411 A CN103243411 A CN 103243411A CN 2013101985097 A CN2013101985097 A CN 2013101985097A CN 201310198509 A CN201310198509 A CN 201310198509A CN 103243411 A CN103243411 A CN 103243411A
- Authority
- CN
- China
- Prior art keywords
- diaminodiphenyl ether
- preparation
- performance organic
- organic fibre
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 83
- HLBLWEWZXPIGSM-UHFFFAOYSA-N 4-Aminophenyl ether Chemical compound C1=CC(N)=CC=C1OC1=CC=C(N)C=C1 HLBLWEWZXPIGSM-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims abstract description 29
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 claims abstract description 40
- 229920000137 polyphosphoric acid Polymers 0.000 claims abstract description 25
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000007872 degassing Methods 0.000 claims abstract description 12
- 238000000034 method Methods 0.000 claims abstract description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000003513 alkali Substances 0.000 claims abstract description 9
- 238000005406 washing Methods 0.000 claims abstract description 9
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 7
- 238000001914 filtration Methods 0.000 claims abstract description 6
- 238000001035 drying Methods 0.000 claims abstract description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 39
- 238000006243 chemical reaction Methods 0.000 claims description 39
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 19
- 229960001755 resorcinol Drugs 0.000 claims description 19
- 229920000642 polymer Polymers 0.000 claims description 16
- 238000009987 spinning Methods 0.000 claims description 13
- 238000010792 warming Methods 0.000 claims description 12
- 239000012043 crude product Substances 0.000 claims description 9
- 238000004140 cleaning Methods 0.000 claims description 8
- 238000002166 wet spinning Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 239000000178 monomer Substances 0.000 claims description 4
- 239000012535 impurity Substances 0.000 claims description 2
- 239000011347 resin Substances 0.000 abstract description 9
- 229920005989 resin Polymers 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 6
- 238000010438 heat treatment Methods 0.000 abstract description 6
- -1 poly(p-phenylene-2,6-benzobisoxazole) Polymers 0.000 abstract description 5
- 238000006116 polymerization reaction Methods 0.000 abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- OYFRNYNHAZOYNF-UHFFFAOYSA-N 2,5-dihydroxyterephthalic acid Chemical compound OC(=O)C1=CC(O)=C(C(O)=O)C=C1O OYFRNYNHAZOYNF-UHFFFAOYSA-N 0.000 abstract 2
- GAKFXHZPQGSWHQ-UHFFFAOYSA-N 4,6-diaminobenzene-1,3-diol;hydrochloride Chemical compound Cl.NC1=CC(N)=C(O)C=C1O GAKFXHZPQGSWHQ-UHFFFAOYSA-N 0.000 abstract 1
- 229920001921 poly-methyl-phenyl-siloxane Polymers 0.000 abstract 1
- 230000001681 protective effect Effects 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 238000005516 engineering process Methods 0.000 description 9
- 239000002131 composite material Substances 0.000 description 6
- 235000019441 ethanol Nutrition 0.000 description 5
- 238000005470 impregnation Methods 0.000 description 5
- 238000009533 lab test Methods 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229940085805 fiberall Drugs 0.000 description 2
- 238000013021 overheating Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 238000005554 pickling Methods 0.000 description 2
- 238000006068 polycondensation reaction Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- RDMFEHLCCOQUMH-UHFFFAOYSA-N 2,4'-Diphenyldiamine Chemical group C1=CC(N)=CC=C1C1=CC=CC=C1N RDMFEHLCCOQUMH-UHFFFAOYSA-N 0.000 description 1
- ZBMISJGHVWNWTE-UHFFFAOYSA-N 3-(4-aminophenoxy)aniline Chemical compound C1=CC(N)=CC=C1OC1=CC=CC(N)=C1 ZBMISJGHVWNWTE-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 150000003961 organosilicon compounds Chemical class 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Artificial Filaments (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310198509.7A CN103243411B (zh) | 2013-05-24 | 2013-05-24 | 一种基于4,4’-二氨基二苯醚高性能有机纤维的制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310198509.7A CN103243411B (zh) | 2013-05-24 | 2013-05-24 | 一种基于4,4’-二氨基二苯醚高性能有机纤维的制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103243411A true CN103243411A (zh) | 2013-08-14 |
CN103243411B CN103243411B (zh) | 2015-02-18 |
Family
ID=48923279
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201310198509.7A Active CN103243411B (zh) | 2013-05-24 | 2013-05-24 | 一种基于4,4’-二氨基二苯醚高性能有机纤维的制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103243411B (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110205698A (zh) * | 2019-06-10 | 2019-09-06 | 中科金绮新材料科技有限公司 | 聚对苯撑苯并二噁唑高模纤维的制备工艺 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH038814A (ja) * | 1989-06-01 | 1991-01-16 | Toray Ind Inc | 濃染色された高強度、高弾性率ポリエステル系繊維 |
CN101358385A (zh) * | 2008-04-09 | 2009-02-04 | 北京服装学院 | 一种改性聚苯并双噁唑纤维及其制备方法 |
CN102277647A (zh) * | 2011-06-20 | 2011-12-14 | 东华大学 | 一种聚酰亚胺异形纤维的制备方法 |
CN102691207A (zh) * | 2012-05-31 | 2012-09-26 | 华东理工大学 | 一种兼具耐紫外光和耐湿热老化的pbo纤维的制备方法 |
-
2013
- 2013-05-24 CN CN201310198509.7A patent/CN103243411B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH038814A (ja) * | 1989-06-01 | 1991-01-16 | Toray Ind Inc | 濃染色された高強度、高弾性率ポリエステル系繊維 |
CN101358385A (zh) * | 2008-04-09 | 2009-02-04 | 北京服装学院 | 一种改性聚苯并双噁唑纤维及其制备方法 |
CN102277647A (zh) * | 2011-06-20 | 2011-12-14 | 东华大学 | 一种聚酰亚胺异形纤维的制备方法 |
CN102691207A (zh) * | 2012-05-31 | 2012-09-26 | 华东理工大学 | 一种兼具耐紫外光和耐湿热老化的pbo纤维的制备方法 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110205698A (zh) * | 2019-06-10 | 2019-09-06 | 中科金绮新材料科技有限公司 | 聚对苯撑苯并二噁唑高模纤维的制备工艺 |
CN110205698B (zh) * | 2019-06-10 | 2022-01-04 | 中科金绮新材料科技有限公司 | 聚对苯撑苯并二噁唑高模纤维的制备工艺 |
Also Published As
Publication number | Publication date |
---|---|
CN103243411B (zh) | 2015-02-18 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR101891367B1 (ko) | 리그닌-함유 전구체 섬유 및 또한 탄소 섬유 제조를 위한 방법 | |
CN101358385B (zh) | 一种改性聚苯并双噁唑纤维及其制备方法 | |
CN110344131B (zh) | 一种丝胶蛋白改性再生纤维素纤维及其制备方法 | |
CN103243410B (zh) | 一种基于2,3,5,6-四氨基吡啶盐酸盐高性能有机纤维的制备方法 | |
CN101161880A (zh) | 一种聚丙烯腈基碳纤维原丝的制备方法 | |
CN102260932A (zh) | 聚对苯撑苯并二噁唑纤维的制备方法 | |
CN103469343A (zh) | 一种改善芳纶纤维中微纤之间相互作用力的方法 | |
CN101487143B (zh) | 一种聚酰亚胺纤维的制备方法 | |
CN102296376B (zh) | 聚对苯撑苯并二噁唑纤维的生产方法 | |
CN101215732B (zh) | 耐紫外的pbo纤维及其制备方法 | |
CN103243411B (zh) | 一种基于4,4’-二氨基二苯醚高性能有机纤维的制备方法 | |
CN1285778C (zh) | 一种制备聚对苯撑苯并二噁唑纤维的新方法 | |
CN103243412B (zh) | 一种基于3,3’,4,4’-四氨基联苯盐酸盐高性能有机纤维的制备方法 | |
CN1286882C (zh) | 聚苯并噁唑的制备方法 | |
CN103014902B (zh) | 一种聚酰亚胺纤维及其制备方法 | |
CN109082010A (zh) | 一种无卤膨胀阻燃碳纤维增强聚丙烯树脂复合材料及其制备方法 | |
CN101397696A (zh) | 抗紫外老化聚对苯撑苯并二噁唑(pbo)纤维的制备方法 | |
KR102043621B1 (ko) | 방사성이 향상된 리그닌을 이용한 탄소섬유 및 이의 제조방법 | |
CN103160950B (zh) | 一种防紫外pbo纤维的制备方法 | |
JP2014025166A (ja) | ポリフェニレンスルフィド繊維の製造方法 | |
CN112135859A (zh) | 一类自身具备抗氧化稳定性的多混复合盐单体与多元聚苯并二唑液晶聚合物及其制备与应用 | |
CN110724262B (zh) | 一类含咪噁唑结构的三元耐光液晶共聚物及其制备与应用 | |
CN111809396B (zh) | 一种高性能纤维预浸工艺 | |
CN108285518B (zh) | 一种芳纶基聚氨酯硬质泡沫及其制备方法 | |
CN111058103A (zh) | 一种交联大分子氢键复合物纤维的制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C53 | Correction of patent of invention or patent application | ||
CB03 | Change of inventor or designer information |
Inventor after: Wang Yang Inventor after: Wang Dan Inventor after: Tian Yaxin Inventor before: Wang Yang Inventor before: Zhang Yu Inventor before: Tian Yaxin |
|
COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: WANG YANG ZHANG YU TIAN YAXIN TO: WANG YANG WANG DAN TIAN YAXIN |
|
CB03 | Change of inventor or designer information |
Inventor after: Gao Po Inventor after: Wang Dan Inventor after: Tian Yaxin Inventor before: Wang Yang Inventor before: Wang Dan Inventor before: Tian Yaxin |
|
COR | Change of bibliographic data | ||
TR01 | Transfer of patent right |
Effective date of registration: 20211208 Address after: 315000 room 3-206, building 2, Chuangye building, No. 66 academician Road, high tech Zone, Ningbo, Zhejiang Patentee after: Ningbo xunzetong Information Technology Co.,Ltd. Address before: 150080 No. 74, Xuefu Road, Nangang District, Heilongjiang, Harbin Patentee before: Heilongjiang University |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20211228 Address after: 315000 No. 98 Dinghai Road, Zhaobaoshan street, Zhenhai District, Ningbo City, Zhejiang Province Patentee after: Zhejiang Yongchuan Jujia New Material Technology Co.,Ltd. Address before: 315000 room 3-206, building 2, Chuangye building, No. 66 academician Road, high tech Zone, Ningbo, Zhejiang Patentee before: Ningbo xunzetong Information Technology Co.,Ltd. |
|
TR01 | Transfer of patent right |