CN103210017B - 可用作燃料电池中的膜的三嗪聚合物 - Google Patents

可用作燃料电池中的膜的三嗪聚合物 Download PDF

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Publication number
CN103210017B
CN103210017B CN201180038238.8A CN201180038238A CN103210017B CN 103210017 B CN103210017 B CN 103210017B CN 201180038238 A CN201180038238 A CN 201180038238A CN 103210017 B CN103210017 B CN 103210017B
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polymer
triazine
group
triazine polymer
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CN103210017A (zh
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M·费杜尔科
A·德尔菲诺
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Societe de Technologie Michelin SAS
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MICHELIN RECHERCHE ET TECHNIQUE SA
Compagnie Generale des Etablissements Michelin SCA
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
    • C08G65/38—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols
    • C08G65/40—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols from phenols (I) and other compounds (II), e.g. OH-Ar-OH + X-Ar-X, where X is halogen atom, i.e. leaving group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/0622—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms
    • C08G73/0638—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms with at least three nitrogen atoms in the ring
    • C08G73/0644—Poly(1,3,5)triazines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02—Polythioethers
    • C08G75/0204—Polyarylenethioethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02—Polythioethers
    • C08G75/0204—Polyarylenethioethers
    • C08G75/0209—Polyarylenethioethers derived from monomers containing one aromatic ring
    • C08G75/0213—Polyarylenethioethers derived from monomers containing one aromatic ring containing elements other than carbon, hydrogen or sulfur
    • C08G75/0222—Polyarylenethioethers derived from monomers containing one aromatic ring containing elements other than carbon, hydrogen or sulfur containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02—Polythioethers
    • C08G75/0204—Polyarylenethioethers
    • C08G75/0227—Polyarylenethioethers derived from monomers containing two or more aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02—Polythioethers
    • C08G75/0204—Polyarylenethioethers
    • C08G75/0236—Polyarylenethioethers containing atoms other than carbon or sulfur in a linkage between arylene groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02—Polythioethers
    • C08G75/0204—Polyarylenethioethers
    • C08G75/0286—Chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/12—Polythioether-ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/20—Polysulfones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/20—Polysulfones
    • C08G75/23—Polyethersulfones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2256—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions other than those involving carbon-to-carbon bonds, e.g. obtained by polycondensation
    • C08J5/2262—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions other than those involving carbon-to-carbon bonds, e.g. obtained by polycondensation containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/02—Polythioethers; Polythioether-ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/06—Polysulfones; Polyethersulfones
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/103—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having nitrogen, e.g. sulfonated polybenzimidazoles [S-PBI], polybenzimidazoles with phosphoric acid, sulfonated polyamides [S-PA] or sulfonated polyphosphazenes [S-PPh]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1058—Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties
    • H01M8/106—Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties characterised by the chemical composition of the porous support
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2381/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen, or carbon only; Polysulfones; Derivatives of such polymers
    • C08J2381/06—Polysulfones; Polyethersulfones
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0082—Organic polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Polyethers (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Conductive Materials (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Fuel Cell (AREA)
CN201180038238.8A 2010-08-04 2011-07-06 可用作燃料电池中的膜的三嗪聚合物 Active CN103210017B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1056437 2010-08-04
FR1056437A FR2963623B1 (fr) 2010-08-04 2010-08-04 Polymere triazine utilisable comme membrane dans une pile a combustible
PCT/EP2011/061423 WO2012016777A1 (fr) 2010-08-04 2011-07-06 Polymere triazine utilisable comme membrane dans une pile a combustible

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Publication Number Publication Date
CN103210017A CN103210017A (zh) 2013-07-17
CN103210017B true CN103210017B (zh) 2015-06-03

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US (1) US8889817B2 (cg-RX-API-DMAC7.html)
EP (1) EP2601243B1 (cg-RX-API-DMAC7.html)
JP (1) JP5963747B2 (cg-RX-API-DMAC7.html)
CN (1) CN103210017B (cg-RX-API-DMAC7.html)
BR (1) BR112013001608A2 (cg-RX-API-DMAC7.html)
CA (1) CA2805556A1 (cg-RX-API-DMAC7.html)
FR (1) FR2963623B1 (cg-RX-API-DMAC7.html)
WO (1) WO2012016777A1 (cg-RX-API-DMAC7.html)

Families Citing this family (10)

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FR2965808B1 (fr) * 2010-08-04 2013-10-18 Michelin Soc Tech Monomere triazine soufre utilisable pour la synthese d'une membrane polymere pour pile a combustible
FR3005054B1 (fr) 2013-04-26 2016-07-01 Michelin & Cie Polymere utilisable notamment comme primaire d'adhesion pour le collage de metal a du caoutchouc
FR3005050A1 (fr) 2013-04-26 2014-10-31 Michelin & Cie Compose polyol soufre utilisable comme monomere pour la synthese de polyurethane
JP5960763B2 (ja) * 2014-08-22 2016-08-02 タカハタプレシジョンジャパン株式会社 陰イオン交換樹脂、燃料電池用電解質膜、電極触媒層形成用バインダー、電池電極触媒層および燃料電池
KR102222055B1 (ko) 2014-09-30 2021-03-03 꽁빠니 제네날 드 에따블리세망 미쉘린 황 함유 방향족 폴리올 화합물
KR101771323B1 (ko) 2014-10-28 2017-08-24 주식회사 엘지화학 브랜처용 불소계 화합물, 이를 이용한 고분자 및 이를 이용한 고분자 전해질막
US20170279130A1 (en) 2016-03-24 2017-09-28 United Technologies Corporation Separator layer for flow battery
US11056698B2 (en) 2018-08-02 2021-07-06 Raytheon Technologies Corporation Redox flow battery with electrolyte balancing and compatibility enabling features
CN111416140B (zh) * 2020-01-11 2021-04-13 山东理工大学 2,4,6-三氧代-1,3,5-三嗪-三磷酸盐掺杂pbi质子交换膜的制备方法
US11271226B1 (en) 2020-12-11 2022-03-08 Raytheon Technologies Corporation Redox flow battery with improved efficiency

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CN1176265A (zh) * 1996-09-10 1998-03-18 赫彻斯特股份公司 含有硫醚基团的聚亚芳基化合物的氧化方法
US20050221135A1 (en) * 2004-03-30 2005-10-06 Cooray Nawalage F Sulfonic acid group-containing, proton-conducting polymer composition, a solid electrolyte membrane and a solid polymer fuel cell
CN101733005A (zh) * 2009-12-10 2010-06-16 山东东岳神舟新材料有限公司 一种改性的交联全氟离子交换膜

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US6495209B1 (en) 1998-02-20 2002-12-17 Lynntech, Inc. Process of making a composite membrane
JP2001081303A (ja) * 1999-09-16 2001-03-27 Hitachi Chem Co Ltd 高分子固体電解質、高分子固体電解質の製造法及び電気化学的デバイス
JP3617802B2 (ja) * 2000-03-30 2005-02-09 富士写真フイルム株式会社 光情報記録媒体及び情報記録方法
JP2002341520A (ja) * 2001-05-14 2002-11-27 Fuji Photo Film Co Ltd 紫外線吸収剤前駆体を含有する組成物、及び画像形成方法
US7135537B2 (en) 2003-05-01 2006-11-14 E.I. Du Pont De Nemours And Company Sulfonimide-containing poly(arylene ether)s and poly(arylene ether sulfone)s, methods for producing the same, and uses thereof
AU2003250029A1 (en) 2003-07-10 2005-01-28 Conception Et Developpement Michelin S.A. Method and device for the stacking of fuel cells
FR2873498B1 (fr) 2004-07-20 2007-08-10 Conception & Dev Michelin Sa Arret d'une pile a combustible alimentee en oxygene pur
US20080160363A1 (en) 2004-07-20 2008-07-03 Akinori Tsukada Control of the Polymer Humidifying Membrane of a Fuel Cell
FR2883666B1 (fr) 2005-03-25 2013-07-05 Conception & Dev Michelin Sa Pile a combustible a membrane polymere
JP4237156B2 (ja) * 2005-03-28 2009-03-11 富士通株式会社 電解質組成物、固体電解質膜、固体高分子型燃料電池および固体電解質膜の製造方法
EP1883671A2 (en) * 2005-05-27 2008-02-06 Polyfuel, Inc. End-capped ion-conductive polymers
JP2006338928A (ja) * 2005-05-31 2006-12-14 Hitachi Chem Co Ltd 補強高分子電解質、電極−高分子電解質膜接合体、燃料電池並びにそれらの製造方法
FR2914111B1 (fr) 2007-03-20 2009-05-15 Conception Dev Michelin S A Pile a combustible a electrolyte polymere
JP2010272363A (ja) 2008-05-21 2010-12-02 Sumitomo Chemical Co Ltd ポリマー、ポリアリーレン系ブロック共重合体、高分子電解質、高分子電解質膜及び燃料電池
FR2963622B1 (fr) * 2010-08-04 2012-08-17 Michelin Soc Tech Monomere perfluoroalcane aromatique soufre et sulfone
FR2963621B1 (fr) * 2010-08-04 2012-08-17 Soc Tech Michelin Monomere perfluoroalcane aromatique
FR2965808B1 (fr) * 2010-08-04 2013-10-18 Michelin Soc Tech Monomere triazine soufre utilisable pour la synthese d'une membrane polymere pour pile a combustible

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Publication number Priority date Publication date Assignee Title
CN1176265A (zh) * 1996-09-10 1998-03-18 赫彻斯特股份公司 含有硫醚基团的聚亚芳基化合物的氧化方法
US20050221135A1 (en) * 2004-03-30 2005-10-06 Cooray Nawalage F Sulfonic acid group-containing, proton-conducting polymer composition, a solid electrolyte membrane and a solid polymer fuel cell
CN101733005A (zh) * 2009-12-10 2010-06-16 山东东岳神舟新材料有限公司 一种改性的交联全氟离子交换膜

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Publication number Publication date
US8889817B2 (en) 2014-11-18
CN103210017A (zh) 2013-07-17
EP2601243B1 (fr) 2017-03-08
US20130217851A1 (en) 2013-08-22
JP5963747B2 (ja) 2016-08-03
WO2012016777A1 (fr) 2012-02-09
FR2963623A1 (fr) 2012-02-10
FR2963623B1 (fr) 2012-08-17
BR112013001608A2 (pt) 2016-05-17
EP2601243A1 (fr) 2013-06-12
JP2013533364A (ja) 2013-08-22
CA2805556A1 (fr) 2012-02-09

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