CN103194003A - 一种低酸性酚醛泡沫及其制备方法 - Google Patents
一种低酸性酚醛泡沫及其制备方法 Download PDFInfo
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- CN103194003A CN103194003A CN2013101121070A CN201310112107A CN103194003A CN 103194003 A CN103194003 A CN 103194003A CN 2013101121070 A CN2013101121070 A CN 2013101121070A CN 201310112107 A CN201310112107 A CN 201310112107A CN 103194003 A CN103194003 A CN 103194003A
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- Prior art keywords
- acid
- phenol
- agent
- formaldehyde foam
- curing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 title claims abstract description 60
- 238000002360 preparation method Methods 0.000 title claims abstract description 26
- 239000006260 foam Substances 0.000 title abstract description 25
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims abstract description 76
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 65
- 239000002253 acid Substances 0.000 claims abstract description 63
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 29
- 239000005011 phenolic resin Substances 0.000 claims abstract description 29
- 238000000034 method Methods 0.000 claims abstract description 17
- 238000005187 foaming Methods 0.000 claims abstract description 10
- 239000004094 surface-active agent Substances 0.000 claims abstract description 5
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 60
- 239000013543 active substance Substances 0.000 claims description 28
- 239000000203 mixture Substances 0.000 claims description 21
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims description 18
- 239000007787 solid Substances 0.000 claims description 18
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 15
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 11
- CMPQUABWPXYYSH-UHFFFAOYSA-N phenyl phosphate Chemical compound OP(O)(=O)OC1=CC=CC=C1 CMPQUABWPXYYSH-UHFFFAOYSA-N 0.000 claims description 7
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 claims description 4
- 239000003921 oil Substances 0.000 claims description 4
- 239000004359 castor oil Substances 0.000 claims description 3
- 235000019438 castor oil Nutrition 0.000 claims description 3
- -1 freonll-11 Chemical compound 0.000 claims description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- 229920000136 polysorbate Polymers 0.000 claims description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 claims description 2
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N sec-butylidene Natural products CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 2
- 239000008096 xylene Substances 0.000 claims description 2
- 239000004088 foaming agent Substances 0.000 abstract 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 16
- 229920000053 polysorbate 80 Polymers 0.000 description 16
- 239000001117 sulphuric acid Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 229920003987 resole Polymers 0.000 description 5
- 206010000269 abscess Diseases 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000006253 efflorescence Methods 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 206010037844 rash Diseases 0.000 description 3
- 239000002893 slag Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229920001213 Polysorbate 20 Polymers 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 238000003760 magnetic stirring Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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CN201310112107.0A CN103194003B (zh) | 2013-04-02 | 2013-04-02 | 一种低酸性酚醛泡沫及其制备方法 |
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CN103194003A true CN103194003A (zh) | 2013-07-10 |
CN103194003B CN103194003B (zh) | 2014-07-16 |
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103435969A (zh) * | 2013-09-03 | 2013-12-11 | 四川大学 | 一种高强度耐温开孔酚醛树脂泡沫及其制备方法 |
CN104559044A (zh) * | 2014-12-30 | 2015-04-29 | 陕西师范大学 | 一种无腐蚀低密度高强度酚醛泡沫 |
CN105085972A (zh) * | 2015-08-31 | 2015-11-25 | 沈阳化工大学 | 一种降低酸性酚醛真空发泡制备可发性酚醛树脂方法 |
CN105086353A (zh) * | 2015-08-31 | 2015-11-25 | 沈阳化工大学 | 一种挥发性酚醛泡沫的制备方法 |
CN105111674A (zh) * | 2015-08-31 | 2015-12-02 | 沈阳化工大学 | 一种离子液体改进的低酸高活性酚醛树脂固化剂 |
CN105175664A (zh) * | 2015-11-05 | 2015-12-23 | 北京莱恩斯高新技术有限公司 | 用于酚醛泡沫塑料的酚醛树脂型表面活性剂及其制备方法 |
CN105732923A (zh) * | 2014-12-11 | 2016-07-06 | 苏州美克思科技发展有限公司 | 一种低酸性酚醛泡沫保温材料的制备方法 |
CN106009491A (zh) * | 2016-07-27 | 2016-10-12 | 武汉理工大学 | 一种轻质高强酚醛泡沫及其制备方法 |
CN109161160A (zh) * | 2018-09-19 | 2019-01-08 | 青岛威奥时代新材料有限公司 | 一种轻型酚醛发泡材料及制备轻型酚醛发泡复合材料方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102643512A (zh) * | 2012-05-10 | 2012-08-22 | 四川大学 | 低酸性酚醛树脂泡沫及其制备方法 |
CN102675821A (zh) * | 2012-06-08 | 2012-09-19 | 北京化工大学 | 一种低酸性酚醛泡沫的制备方法 |
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2013
- 2013-04-02 CN CN201310112107.0A patent/CN103194003B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102643512A (zh) * | 2012-05-10 | 2012-08-22 | 四川大学 | 低酸性酚醛树脂泡沫及其制备方法 |
CN102675821A (zh) * | 2012-06-08 | 2012-09-19 | 北京化工大学 | 一种低酸性酚醛泡沫的制备方法 |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103435969A (zh) * | 2013-09-03 | 2013-12-11 | 四川大学 | 一种高强度耐温开孔酚醛树脂泡沫及其制备方法 |
CN105732923A (zh) * | 2014-12-11 | 2016-07-06 | 苏州美克思科技发展有限公司 | 一种低酸性酚醛泡沫保温材料的制备方法 |
CN105732923B (zh) * | 2014-12-11 | 2018-05-25 | 苏州美克思科技发展有限公司 | 一种低酸性酚醛泡沫保温材料的制备方法 |
CN104559044A (zh) * | 2014-12-30 | 2015-04-29 | 陕西师范大学 | 一种无腐蚀低密度高强度酚醛泡沫 |
CN105085972A (zh) * | 2015-08-31 | 2015-11-25 | 沈阳化工大学 | 一种降低酸性酚醛真空发泡制备可发性酚醛树脂方法 |
CN105086353A (zh) * | 2015-08-31 | 2015-11-25 | 沈阳化工大学 | 一种挥发性酚醛泡沫的制备方法 |
CN105111674A (zh) * | 2015-08-31 | 2015-12-02 | 沈阳化工大学 | 一种离子液体改进的低酸高活性酚醛树脂固化剂 |
CN105085972B (zh) * | 2015-08-31 | 2017-11-14 | 沈阳化工大学 | 一种降低酸性酚醛真空发泡制备可发性酚醛树脂方法 |
CN105175664A (zh) * | 2015-11-05 | 2015-12-23 | 北京莱恩斯高新技术有限公司 | 用于酚醛泡沫塑料的酚醛树脂型表面活性剂及其制备方法 |
CN106009491A (zh) * | 2016-07-27 | 2016-10-12 | 武汉理工大学 | 一种轻质高强酚醛泡沫及其制备方法 |
CN109161160A (zh) * | 2018-09-19 | 2019-01-08 | 青岛威奥时代新材料有限公司 | 一种轻型酚醛发泡材料及制备轻型酚醛发泡复合材料方法 |
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CN103194003B (zh) | 2014-07-16 |
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Effective date of registration: 20240314 Address after: No. 1, Zhongtian Road, Yantan Industrial Concentration Zone, Yantan District, Zigong City, Sichuan Province, 643030 Patentee after: ZIGONG ZHONGTIANSHENG NEW MATERIAL TECHNOLOGY CO.,LTD. Country or region after: China Address before: 100080 No. 2 North First Street, Haidian District, Beijing, Zhongguancun Patentee before: INSTITUTE OF CHEMISTRY, CHINESE ACADEMY OF SCIENCES Country or region before: China |
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