CN103101927B - 一种im-5分子筛纤维及其合成方法 - Google Patents

一种im-5分子筛纤维及其合成方法 Download PDF

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Publication number
CN103101927B
CN103101927B CN201110353591.7A CN201110353591A CN103101927B CN 103101927 B CN103101927 B CN 103101927B CN 201110353591 A CN201110353591 A CN 201110353591A CN 103101927 B CN103101927 B CN 103101927B
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China
Prior art keywords
molecular sieve
bromide
sio
length
scope
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CN201110353591.7A
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English (en)
Chinese (zh)
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CN103101927A (zh
Inventor
凌凤香
杨卫亚
王少军
沈智奇
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China Petroleum and Chemical Corp
Sinopec Fushun Research Institute of Petroleum and Petrochemicals
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China Petroleum and Chemical Corp
Sinopec Fushun Research Institute of Petroleum and Petrochemicals
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Priority to CN201110353591.7A priority Critical patent/CN103101927B/zh
Application filed by China Petroleum and Chemical Corp, Sinopec Fushun Research Institute of Petroleum and Petrochemicals filed Critical China Petroleum and Chemical Corp
Priority to PCT/CN2012/001473 priority patent/WO2013067764A1/zh
Priority to IN4216CHN2014 priority patent/IN2014CN04216A/en
Priority to EP12848379.9A priority patent/EP2778135B1/en
Priority to CA2855178A priority patent/CA2855178C/en
Priority to US14/356,725 priority patent/US9327277B2/en
Priority to KR1020147015493A priority patent/KR101914615B1/ko
Publication of CN103101927A publication Critical patent/CN103101927A/zh
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C01B39/40—Type ZSM-5 using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/10—Particle morphology extending in one dimension, e.g. needle-like
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/54—Particles characterised by their aspect ratio, i.e. the ratio of sizes in the longest to the shortest dimension
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Geology (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN201110353591.7A 2011-11-10 2011-11-10 一种im-5分子筛纤维及其合成方法 Active CN103101927B (zh)

Priority Applications (7)

Application Number Priority Date Filing Date Title
CN201110353591.7A CN103101927B (zh) 2011-11-10 2011-11-10 一种im-5分子筛纤维及其合成方法
IN4216CHN2014 IN2014CN04216A (enExample) 2011-11-10 2012-10-30
EP12848379.9A EP2778135B1 (en) 2011-11-10 2012-10-30 Fibrous im-5 molecular sieve and preparation process thereof
CA2855178A CA2855178C (en) 2011-11-10 2012-10-30 A fibrous im-5 molecular sieve and the preparation process thereof
PCT/CN2012/001473 WO2013067764A1 (zh) 2011-11-10 2012-10-30 一种纤维状im-5分子筛及其制备方法
US14/356,725 US9327277B2 (en) 2011-11-10 2012-10-30 Fibrous IM-5 molecular sieve and preparation process thereof
KR1020147015493A KR101914615B1 (ko) 2011-11-10 2012-10-30 섬유형 im-5 분자체 및 그 제조 방법

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201110353591.7A CN103101927B (zh) 2011-11-10 2011-11-10 一种im-5分子筛纤维及其合成方法

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CN103101927A CN103101927A (zh) 2013-05-15
CN103101927B true CN103101927B (zh) 2014-12-31

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US (1) US9327277B2 (enExample)
EP (1) EP2778135B1 (enExample)
KR (1) KR101914615B1 (enExample)
CN (1) CN103101927B (enExample)
CA (1) CA2855178C (enExample)
IN (1) IN2014CN04216A (enExample)
WO (1) WO2013067764A1 (enExample)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5862807B2 (ja) * 2012-02-21 2016-02-16 エクソンモービル ケミカル パテンツ インコーポレイテッド 分子篩材料、その合成および使用
CN107324356A (zh) * 2017-06-28 2017-11-07 中国石油天然气集团公司 一种介孔择型分子筛及其制备方法
CN109485066A (zh) * 2018-11-28 2019-03-19 东莞理工学院 一种棒状zsm-5分子筛的制备方法
CN111977668B (zh) * 2019-05-22 2022-08-30 中国石油天然气股份有限公司 一种im-5分子筛及其制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1234012A (zh) * 1996-10-21 1999-11-03 法国石油公司 Im－5沸石,其制备方法及其作为催化剂的应用
CN1249270A (zh) * 1998-09-25 2000-04-05 北京燕山石油化工公司研究院 一种β沸石的合成方法
CN101862669A (zh) * 2010-06-23 2010-10-20 东南大学 异丁烷脱氢制异丁烯催化剂及其制备方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7276224B2 (en) * 2002-06-11 2007-10-02 Regents Of The University Of Minnesota Synthesis of nanoporous particles
US7799128B2 (en) * 2008-10-10 2010-09-21 Roman Cement, Llc High early strength pozzolan cement blends
CN103101926B (zh) * 2011-11-10 2014-10-15 中国石油化工股份有限公司 一种空心球形im-5分子筛及其制备方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1234012A (zh) * 1996-10-21 1999-11-03 法国石油公司 Im－5沸石,其制备方法及其作为催化剂的应用
CN1249270A (zh) * 1998-09-25 2000-04-05 北京燕山石油化工公司研究院 一种β沸石的合成方法
CN101862669A (zh) * 2010-06-23 2010-10-20 东南大学 异丁烷脱氢制异丁烯催化剂及其制备方法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
IM-5:A Highly Thermal and Hydrothermal Shape-Selective Cracking Zeolite;Avelino Corma 等;《Journal of Catalysis》;20020114;第206卷;第125-133页 *
Synthesis, characterization, and catalytic properties of zeolites IM-5 and NU-88;Song-Ho Lee 等;《Journal of Catalysis》;20030401;第215卷;第151–170页 *

Also Published As

Publication number Publication date
CA2855178C (en) 2019-10-29
EP2778135A1 (en) 2014-09-17
US9327277B2 (en) 2016-05-03
CA2855178A1 (en) 2013-05-16
US20140323288A1 (en) 2014-10-30
CN103101927A (zh) 2013-05-15
KR101914615B1 (ko) 2018-11-05
EP2778135B1 (en) 2017-05-10
IN2014CN04216A (enExample) 2015-07-17
KR20140118993A (ko) 2014-10-08
WO2013067764A1 (zh) 2013-05-16
EP2778135A4 (en) 2015-08-19

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