CN103068494B - 在基底上具有改善的耐磨性和硬度的不粘涂层 - Google Patents
在基底上具有改善的耐磨性和硬度的不粘涂层 Download PDFInfo
- Publication number
- CN103068494B CN103068494B CN201180038613.9A CN201180038613A CN103068494B CN 103068494 B CN103068494 B CN 103068494B CN 201180038613 A CN201180038613 A CN 201180038613A CN 103068494 B CN103068494 B CN 103068494B
- Authority
- CN
- China
- Prior art keywords
- particles
- inorganic filler
- microns
- coated substrate
- particle size
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J201/00—Adhesives based on unspecified macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/08—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
- B05D5/083—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface involving the use of fluoropolymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/08—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/56—Three layers or more
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J127/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers
- C09J127/02—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J127/12—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2202/00—Metallic substrate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2202/00—Metallic substrate
- B05D2202/10—Metallic substrate based on Fe
- B05D2202/15—Stainless steel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2601/00—Inorganic fillers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2601/00—Inorganic fillers
- B05D2601/02—Inorganic fillers used for pigmentation effect, e.g. metallic effect
- B05D2601/08—Aluminium flakes or platelets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2601/00—Inorganic fillers
- B05D2601/20—Inorganic fillers used for non-pigmentation effect
- B05D2601/24—Titanium dioxide, e.g. rutile
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2601/00—Inorganic fillers
- B05D2601/20—Inorganic fillers used for non-pigmentation effect
- B05D2601/26—Abrasives
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/252—Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
- Y10T428/31544—Addition polymer is perhalogenated
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US37140610P | 2010-08-06 | 2010-08-06 | |
| US61/371,406 | 2010-08-06 | ||
| US61/371406 | 2010-08-06 | ||
| PCT/US2011/046722 WO2012019088A1 (en) | 2010-08-06 | 2011-08-05 | Non-stick coating having improved abrasion resistance and hardness on a substrate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103068494A CN103068494A (zh) | 2013-04-24 |
| CN103068494B true CN103068494B (zh) | 2015-01-28 |
Family
ID=44511557
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201180038613.9A Expired - Fee Related CN103068494B (zh) | 2010-08-06 | 2011-08-05 | 在基底上具有改善的耐磨性和硬度的不粘涂层 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US8642171B2 (enExample) |
| JP (1) | JP5779647B2 (enExample) |
| KR (1) | KR101962482B1 (enExample) |
| CN (1) | CN103068494B (enExample) |
| WO (1) | WO2012019088A1 (enExample) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9580609B2 (en) * | 2012-01-09 | 2017-02-28 | The Chemours Company Fc, Llc | Aqueous binder solutions |
| JP6066581B2 (ja) * | 2012-04-27 | 2017-01-25 | 三井・デュポンフロロケミカル株式会社 | ポリマー粒子、それを含有する水性分散液、及びそれを用いたフッ素樹脂塗料組成物 |
| WO2014012161A1 (en) * | 2012-07-17 | 2014-01-23 | Her Majesty The Queen In Right Of Canada As Represented By The Minister Of Natural Resources | Method and composite for preparing heat exchangers for corrosive environments |
| EP2882894A1 (en) * | 2012-08-09 | 2015-06-17 | E. I. du Pont de Nemours and Company | Improved barrier fabrics |
| US9057001B2 (en) * | 2012-11-02 | 2015-06-16 | Rockwell Automation Technologies, Inc. | Transparent non-stick coating composition, method and apparatus |
| FR2997616A1 (fr) * | 2012-11-06 | 2014-05-09 | Seb Sa | Dispositif de cuisson presentant une surface de cuisson comportant un revetement antiadhesif en ceramique non oxyde ou au moins partiellement non oxyde, et article culinaire ou appareil electromenager de cuisson comportant un tel dispositif de cuisson |
| CN102952465A (zh) * | 2012-11-14 | 2013-03-06 | 无锡卡秀堡辉涂料有限公司 | 一种水性不粘锅内涂炊具用辊涂施工涂料 |
| US20140272430A1 (en) * | 2013-03-15 | 2014-09-18 | Sabic Innovative Plastics Ip B.V. | Process of making dispersed polyetherimide micronized particles and process of coating and further forming of these particles products made therefrom |
| US11072144B2 (en) | 2013-11-26 | 2021-07-27 | Daikin Industries, Ltd. | Laminate |
| JP6883429B2 (ja) * | 2014-05-20 | 2021-06-09 | ピーピージー・インダストリーズ・オハイオ・インコーポレイテッドPPG Industries Ohio,Inc. | 改善された硬度及び耐衝撃性を有するゾル‐ゲル組成物、被膜を形成する方法及び被覆された物品 |
| FR3022553A1 (fr) * | 2014-06-20 | 2015-12-25 | Seb Sa | Composition de primaire en phase aqueuse via des polymeres heterocycliques sous forme de poudres obtenues par broyage |
| DE102015201168A1 (de) * | 2015-01-23 | 2016-07-28 | Aktiebolaget Skf | Sensor |
| WO2016161264A2 (en) * | 2015-04-01 | 2016-10-06 | 3M Innovative Properties Company | Multilayer articles comprising a release surface and methods thereof |
| US20180250708A1 (en) * | 2015-04-01 | 2018-09-06 | 3M Innovative Properties Company | Multilayer articles comprising a release surface and methods thereof |
| WO2016161271A2 (en) | 2015-04-01 | 2016-10-06 | 3M Innovative Properties Company | Multilayer articles comprising a release surface and methods thereof |
| JP2018524440A (ja) * | 2015-07-10 | 2018-08-30 | ウィットフォード コーポレーション | 高離型性及び低摩擦性を有する機能性コーティング形成用組成物 |
| WO2017140514A1 (en) * | 2016-02-15 | 2017-08-24 | Nv Bekaert Sa | Wire for hook and eye brassiere closures |
| CN105925043A (zh) * | 2016-06-07 | 2016-09-07 | 平顶山市美伊金属制品有限公司 | 一种含有可吸收锌元素的不粘锅喷涂料 |
| CN106065212A (zh) * | 2016-06-07 | 2016-11-02 | 平顶山市美伊金属制品有限公司 | 一种含有可吸收钙元素的不粘锅喷涂料 |
| CN105925029A (zh) * | 2016-06-07 | 2016-09-07 | 平顶山市美伊金属制品有限公司 | 一种含有可吸收铁元素的不粘锅喷涂料 |
| JP6461050B2 (ja) * | 2016-06-28 | 2019-01-30 | エスシージー ケミカルズ カンパニー,リミテッド | 高放射率コーティング組成物およびその製造プロセス |
| JP7213800B2 (ja) * | 2016-10-12 | 2023-01-27 | ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー | 低温焼成フッ素重合体コーティング |
| JP7105787B2 (ja) * | 2017-02-07 | 2022-07-25 | ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー | 摩耗及び擦傷に耐性のある焦げ付き防止コーティングでコーティングされた基材 |
| US10598419B2 (en) * | 2017-05-19 | 2020-03-24 | Zhejiang Ocean University | Seawater fluidized ice manufacturing equipment and method |
| CN107760183A (zh) * | 2017-11-10 | 2018-03-06 | 宁波市恩迪卫浴有限公司 | 一种耐磨耐热的复合涂料及其制备方法 |
| JP7182636B2 (ja) * | 2018-02-06 | 2022-12-02 | サーモロン コリア カンパニー リミテッド | ダイヤモンド及び着色マイカを含む非付着性セラミックコーティング |
| US12150586B2 (en) | 2018-08-20 | 2024-11-26 | Advanced Flexible Composites, Inc. | Nonstick cookware materials, and methods for manufacture and use |
| FR3091532B1 (fr) | 2019-01-07 | 2022-07-29 | Seb Sa | Revetement antiadhesif |
| PL3955785T3 (pl) * | 2019-04-15 | 2025-12-01 | Advanced Flexible Composites, Inc. | Nieprzywierające materiały kompozytowe i formowane nieprzywierające naczynia kuchenne |
| JP6819717B2 (ja) * | 2019-04-19 | 2021-01-27 | ダイキン工業株式会社 | 被覆組成物及び被覆物品 |
| CN110305579B (zh) * | 2019-06-05 | 2021-07-06 | 浙江鹏孚隆科技股份有限公司 | 耐磨耐刮及使用寿命长的不粘涂层及其涂覆方法 |
| PL3964300T3 (pl) * | 2020-09-04 | 2023-07-17 | Industrielack Ag | Bezfluorowa powłoka antyadhezyjna oraz sposób jej wytwarzania |
| CN115044853B (zh) * | 2022-06-29 | 2023-09-15 | 武汉苏泊尔炊具有限公司 | 用于炊具的非晶不粘材料和非晶不粘涂层 |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4177320A (en) * | 1976-12-10 | 1979-12-04 | Daikin Kogyo Co., Ltd. | Article coated with fluorocarbon polymer |
| EP1016466A2 (en) * | 1999-02-19 | 2000-07-05 | E.I. Du Pont De Nemours & Co. (Inc.) | Abrasion resistant coatings |
| US20020150778A1 (en) * | 2000-08-17 | 2002-10-17 | Leech Lawrence D. | Multiple coat non-stick coating system and articles coated with same |
| WO2006066027A1 (en) * | 2004-12-16 | 2006-06-22 | E. I. Du Pont De Nemours And Company | Fluoropolymer release coating having improved heat transfer properties and abrasion resistance |
| US20080050509A1 (en) * | 2002-12-12 | 2008-02-28 | Orion Industries, Ltd. | Anti-microbial electrosurgical electrode and method of manufacturing same |
| CN101242912A (zh) * | 2005-08-12 | 2008-08-13 | 纳幕尔杜邦公司 | 改善不粘涂层在基材上的耐腐蚀性的方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4380618A (en) | 1981-08-21 | 1983-04-19 | E. I. Du Pont De Nemours And Company | Batch polymerization process |
| US5079073A (en) | 1989-08-21 | 1992-01-07 | E. I. Du Pont De Nemours And Company | Non-stick coating system with thin undercoat of polyamide imide |
| US6403213B1 (en) | 1999-05-14 | 2002-06-11 | E. I. Du Pont De Nemours And Company | Highly filled undercoat for non-stick finish |
| JP3608037B2 (ja) * | 2000-02-10 | 2005-01-05 | 大阪瓦斯株式会社 | 調理器具用部材及び調理器具 |
| US6761964B2 (en) | 2001-04-02 | 2004-07-13 | E. I. Du Pont De Nemours And Company | Fluoropolymer non-stick coatings |
| US6863974B2 (en) | 2002-09-13 | 2005-03-08 | Akzo Nobel Coatings International B.V. | Multilayer non-stick coating |
| JP2004283699A (ja) * | 2003-03-20 | 2004-10-14 | Osaka Gas Co Ltd | 高耐久性コーティングを施したガス使用設備用部材 |
| US7858188B2 (en) * | 2005-12-14 | 2010-12-28 | Dupont-Mitsui Fluorochemicals Co Ltd | Non-stick coating composition comprising diamond particles and substrate |
| US8012542B2 (en) * | 2005-12-30 | 2011-09-06 | E.I. Du Pont De Nemours And Company | Fluoropolymer coating compositions containing adhesive polymers and substrate coating process |
| US8158251B2 (en) * | 2008-02-07 | 2012-04-17 | E. I. Du Pont De Nemours And Company | Article with non-stick finish and improved scratch resistance |
-
2011
- 2011-08-04 US US13/197,965 patent/US8642171B2/en not_active Expired - Fee Related
- 2011-08-05 WO PCT/US2011/046722 patent/WO2012019088A1/en not_active Ceased
- 2011-08-05 JP JP2013524127A patent/JP5779647B2/ja active Active
- 2011-08-05 CN CN201180038613.9A patent/CN103068494B/zh not_active Expired - Fee Related
- 2011-08-05 KR KR1020137005635A patent/KR101962482B1/ko not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4177320A (en) * | 1976-12-10 | 1979-12-04 | Daikin Kogyo Co., Ltd. | Article coated with fluorocarbon polymer |
| EP1016466A2 (en) * | 1999-02-19 | 2000-07-05 | E.I. Du Pont De Nemours & Co. (Inc.) | Abrasion resistant coatings |
| US20020150778A1 (en) * | 2000-08-17 | 2002-10-17 | Leech Lawrence D. | Multiple coat non-stick coating system and articles coated with same |
| US20080050509A1 (en) * | 2002-12-12 | 2008-02-28 | Orion Industries, Ltd. | Anti-microbial electrosurgical electrode and method of manufacturing same |
| WO2006066027A1 (en) * | 2004-12-16 | 2006-06-22 | E. I. Du Pont De Nemours And Company | Fluoropolymer release coating having improved heat transfer properties and abrasion resistance |
| CN101242912A (zh) * | 2005-08-12 | 2008-08-13 | 纳幕尔杜邦公司 | 改善不粘涂层在基材上的耐腐蚀性的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2013538706A (ja) | 2013-10-17 |
| US8642171B2 (en) | 2014-02-04 |
| US20120034448A1 (en) | 2012-02-09 |
| CN103068494A (zh) | 2013-04-24 |
| KR20130096721A (ko) | 2013-08-30 |
| JP5779647B2 (ja) | 2015-09-16 |
| KR101962482B1 (ko) | 2019-03-26 |
| WO2012019088A1 (en) | 2012-02-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20171226 Address after: Delaware, USA Patentee after: THE CHEMOURS COMPANY FC, LLC Address before: Wilmington, Delaware, USA Patentee before: E. I. du Pont de Nemours and Co. |
|
| TR01 | Transfer of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150128 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |