CN103030473A - Sugarcane pesticide fertilizer granule with chlorantraniliprole and preparation method thereof - Google Patents
Sugarcane pesticide fertilizer granule with chlorantraniliprole and preparation method thereof Download PDFInfo
- Publication number
- CN103030473A CN103030473A CN2013100143458A CN201310014345A CN103030473A CN 103030473 A CN103030473 A CN 103030473A CN 2013100143458 A CN2013100143458 A CN 2013100143458A CN 201310014345 A CN201310014345 A CN 201310014345A CN 103030473 A CN103030473 A CN 103030473A
- Authority
- CN
- China
- Prior art keywords
- fertilizer
- sugarcane
- granules
- clothianidin
- pesticide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Fertilizers (AREA)
Abstract
The invention relates to a sugarcane pesticide fertilizer granule with chlorantraniliprole. The sugarcane pesticide fertilizer granule is prepared from an organic fertilizer, an inorganic fertilizer, a pesticide active ingredient, an addition agent and an excipient, wherein the organic fertilizer is prepared from fulvic acid and chitin, and the pesticide active ingredient is prepared from the chlorantraniliprole and clothianidin. The weight percentage of the ingredients of the pesticide fertilizer granule is as follows: 3-12 percent of fulvic acid, 1-3 percent of chitin, 26.91-43.55 percent of inorganic fertilizer, 0.01-0.2 percent of chlorantraniliprole, 0.02-0.5 percent of clothianidin and 0.5-1 percent of addition agent, and the excipient is complemented until the total weight of the pesticide fertilizer granule is 100 percent. The insecticidal particles and the compound fertilizer particles are respectively pelleted, so that the quality stability of products can be ensured, the sugarcane is prevented from being prejudiced by pests or is less affected by the pests, the yield and the quality of the sugarcane are increased, the use cost is reduced, and the income of farmers is increased.
Description
Technical field
The present invention relates to agricultural chemicals and fertilizer mixed technology field, specifically sugarcane insecticide fertilizer granular formulation of a kind of containing chlorantraniliprole and preparation method thereof.
Background technology
Sugarcane is the main raw material of sugaring, simultaneously, or the important source material of light industry, chemical industry and the energy, as using bagasse papermaking, molasses preparing alcohol etc.At present, China's sugarcane acreage surpasses 2,500 ten thousand mu, mainly is distributed in the provinces and regions such as southern Guangxi, Yunnan, Guangdong, Guizhou, Fujian, Hainan, wherein, the cultivated area in Guangxi and output surpass 60% of the whole nation, and sucrose had become the mainstay industry in Guangxi already.
Sugarcane must absorb various nutritive ingredients from environment in process of growth, could satisfy the needs of growth.Outside de-carbon (C), hydrogen (H), oxygen (O) element, also need macroelement nitrogen (N), phosphorus (P
2O
5), potassium (K
2And trace element manganese (Mn), boron (B), copper (Cu), iron (Fe), zinc (Zn), molybdenum (Mo), chlorine (Cl), silicon (Si) etc. O), and moderate-element calcium (Ca), sulphur (S), magnesium (Mg).Usually these elements can absorb from air, water and soil and obtain, but because the long-term planting of sugarcane, nutritive ingredient in the soil runs off in a large number, the needs of farm crop normal growth have been difficult to satisfy, follow and what arrive is that disease and pest is day by day serious, output descends day by day, and having a strong impact on to grow cane is main peasant's income.When cane planting by fertilising to replenish the deficiency of Nutrient Elements in Soil, be to improve the effective means of output.
According to the sugarcane production characteristic, the fertilizer that is specially adapted for sugarcane production is called sugarcane special-purpose fertilizer, is generally composite fertilizer.At present, domestic more existing research institutions and enterprise are at the research and production sugarcane special-purpose fertilizer.Chinese patent 200710066326.4 discloses a kind of special compound fertilizer for sugar-cane, and is different to the demand of fertilizer according to the different times of sugarcane production, is divided into the base manure Chemical Mixed Fertilizer and two kinds of the Chemical Mixed Fertilizers of topdressing, and the base manure prescription is N-P in mass ratio
2O
5-K
2O-ZNO:10-10-8-0.5, base manure Chemical Mixed Fertilizer comprise several compositions of urea, fused(calcium magnesium)phosphate, vitriolate of tartar, zinc sulfate and stopping composition; The prescription that topdresses is N-P in mass ratio
2O
5-K
2O:18-6-4, the Chemical Mixed Fertilizer that topdresses comprise urea, general calcium, vitriolate of tartar and several compositions of stopping composition.Chinese patent 201110413115.X discloses a kind of special-purpose sugarcane composite fertilizer and production method thereof, and its raw material comprises inorganic fertilizer, fertilizer, aminoacids complex, moderate-element and trace element; The weight percent that its each component accounts for sugarcane composite fertilizer gross weight is: inorganic fertilizer 16%～29%, fertilizer 15～30%, aminoacids complex 5%～15%, moderate-element 0.1%～0.5%, trace element 0.03%～0.1%.Chinese patent 200910095151.9 discloses a kind of special compound fertilizer for sugar cane, in the composite fertilizer the ratio of nitrogenous, phosphorus, potassium, silicon oxide be 8～12: 8～12: 8～12: 0.15～0.3.
Sugarcane is in planting process, and disease and pest is very large on the impact of its growth, yield and quality, and is serious even cause total crop failure.The insect of harm sugarcane is divided into subterranean pest-insect and ground insect two large classes, subterranean pest-insect comprises chafer, weevil, termite, wireworm, mole cricket, longicorn, cricket etc., the root of main harm sugarcane and sugarcane bud, wherein serious with chafer and weevil harm, the loss that causes is maximum; Insect comprises the snout moth's larva and the woolly aphid that endangers leaf, thrips, leafhopper, plant hopper, mythimna separata, locust etc. of harm sugarcane stem on the ground, causes sugarcane production bad, quality variation.For prevent underground and on the ground various insects to the infringement of sugarcane, usually can spread fertilizer over the fields corresponding agricultural chemicals at sugarcane field, selected agricultural chemicals mostly is greatly the granule that contains high malicious composition, exists larger potential safety hazard.On the other hand, fertilizer and agricultural chemicals are bought respectively and are used, and not only increase sugarcane grower's cost, also increased workload, and in recent years, the price of labour power rise constantly, has also strengthened undoubtedly planting cost.
At present, domestic existing research institution and enterprise conduct a research to develop both can provide the sugarcane production desired nutritional, can prevent and treat again the agricultural chemicals of Sugarcane Pests and the pesticide-fertilizer product of fertilizer unification.Chinese patent 201110372231.1 discloses a kind of sugarcane fertilizer and production method of preventing and treating subterranean pest-insect, and its raw material comprises inorganic fertilizer, fertilizer, medicament, plant-growth regulator and binding agent; The weight percent that its each component accounts for the sugarcane fertilizer gross weight is: inorganic fertilizer 45%～92%, fertilizer 7～50%, medicament 0.25%～3.5%, plant modifying agent 0.04%～0.05%, binding agent 0.075%～3.0%; Described medicament is the combination of Volaton, Chlorpyrifos 94 and Provado or MTI-446, the weight proportion between component: Volaton: Chlorpyrifos 94: Provado or MTI-446 are 1～2:1:0.1～4.5; Described plant-growth regulator is sodium nitrophenolate.This invention is added farm chemical ingredients Volaton, Chlorpyrifos 94 and MTI-446 in the middle of the fertilizer to, plays medicine, fertile double effects, and saving of work and time can alleviate sugarcane grower's labour intensity to a certain extent.But because the development of pest resistance, Volaton and Chlorpyrifos 94 descend gradually to the preventive effect of underground insect and the Provado preventive effect to the ground insect, and the former medicine cost of MTI-446 is higher, in the certain difficulty of the universal existence in sugarcane district.Therefore, need to seek a kind of more efficient, more favourable to the sugarcane grower alternative medicine fertilizer.At present, the sugarcane insecticide fertilizer granular formulation of containing chlorantraniliprole and clothianidin also has no report.
Summary of the invention
Technical problem to be solved by this invention is for the fertile deficiency that exists of above-mentioned existing sugarcane medicine, sugarcane insecticide fertilizer granular formulation of a kind of containing chlorantraniliprole and preparation method thereof is provided, ensure that sugarcane is not subjected to or is subjected to less insect to encroach on, improve the yield and quality of sugarcane, reduce use cost, increase the income of peasant household.
The present invention solves the problems of the technologies described above the technical scheme of taking: a kind of sugarcane insecticide fertilizer granular formulation of containing chlorantraniliprole, formed by fertilizer, inorganic fertilizer, pesticide active ingredient, auxiliary agent and vehicle, described fertilizer is comprised of xanthohumic acid and chitin, described pesticide active ingredient is comprised of Rynaxypyr and clothianidin, and the weight percent content of described each component of fertilizer granules is:
Xanthohumic acid 3～12%;
Chitin 1～3%;
Inorganic fertilizer 26.91～43.55%;
Rynaxypyr 0.01～0.2%;
Clothianidin 0.02～0.5%;
Auxiliary agent 0.5～1%;
Vehicle complements to 100% of fertilizer granules gross weight.
Described inorganic fertilizer is comprised of the nutritive element of following weight percent content:
Nitrogen 12～16%;
Phosphorus 5～8%;
Potassium 8～11%;
Sulphur 1～4%;
Calcium 0.5～2.5%;
Magnesium 0.2～1%;
Zinc 0.1～0.5%;
Boron 0.1～0.5%;
Molybdenum 0.01～0.05%.
Described auxiliary agent is sodium lauryl sulphate, calcium lignin sulphonate, sodium lignosulfonate, naphthalenesulfonate formaldehyde condensation compound, sulfonated alkyl naphathalene formaldehyde condensation products or pulls open at least a in the powder.
Described vehicle is at least a in starch, polyvinyl alcohol, carboxymethyl cellulose, clay, diatomite, carclazyte, kaolin, wilkinite or the calcium carbonate.
The preparation method of the sugarcane insecticide fertilizer granular formulation of described containing chlorantraniliprole may further comprise the steps:
(1) preparation pesticide granules: according to weight part, get 2.8～14.97 parts of 0.01～0.2 part of Rynaxypyr, 0.02～0.5 part of clothianidin, 0.5～1 part of auxiliary agent and vehicle, pulverize, mix, it is even to add the moistening rear remix of water, use the Squeezinggranulator granulation, obtain containing the pesticide granules of Rynaxypyr and clothianidin after the drying, for subsequent use;
(2) preparation compound fertilizer granules: according to weight part, get 3～12 parts of xanthohumic acids, 1～3 part of chitin, 12～16 parts in nitrogen, 5～8 parts in phosphorus, 8～11 parts in potassium, 1～4 part of sulphur, 0.5～2.5 part of calcium, 0.2～1 part in magnesium, 0.1～0.5 part on zinc, 0.1～0.5 part of boron, 0.01～0.05 part of molybdenum and vehicle, the addition of vehicle makes the total weight parts of pesticide granules and compound fertilizer granules reach 100 parts; Raw material pulverizing with getting mixes, and it is even to add the moistening rear remix of water, uses the Squeezinggranulator granulation, obtains compound fertilizer granules after the drying, for subsequent use;
(3) in mixing equipment, the pesticide granules of step (1) gained and the compound fertilizer granules of step (2) gained are fully mixed, detect qualified rear packing, namely get the sugarcane insecticide fertilizer granular formulation of containing chlorantraniliprole.
In described step (1) and the step (2), pulverizing used equipment is micronizer mill, Universalpulverizer or Raymond machine, smashing fineness 〉=100 orders; Described Squeezinggranulator is screw extruder pelletizer; Described to add water moistening, and amount of water is for pulverizing 2～5% of raw material weight; Described drying is fluidised bed drying or rotary drying;
Described mixing equipment is Agravicmixer or duplex cone-type mixer, and mixing time is 10～30 minutes; The fineness of product is 2mm～5mm, moisture≤3%, expulsion rate≤5%.
The sugarcane insecticide fertilizer granular formulation of containing chlorantraniliprole of the present invention is applied to prevent and treat subterranean pest-insect and the ground insect of harm sugarcane, comprise grub, mole cricket, cutworm, sugarcane tortoise, termite, snout moth's larva, aphid, thrips or trialeurodes vaporariorum, compared with prior art, have following beneficial effect:
(1) the present invention selects chlorine worm the machine acid amides and clothianidin as the farm chemical ingredients in the fertilizer granules, play synergy, reduce the total consumption of medicament and delay the effect that pest resistance occurs, ensure that sugarcane is not subjected to or is subjected to less pest damage, improve output, increase the income at plantation family.
(2) among the present invention according to the growth characteristic of sugarcane, the inorganic fertilizer of combination can provide for the normal growth of sugarcane essential N, P, K, Ca, S, Mg, Zn, B and Mo nutritive element, reaches the effect of stable yields and volume increase.
(3) the fertilizer xanthohumic acid among the present invention and chitin can be regulated the physiological function of sugarcane, promote the growth of sugarcane, improve the resistance of sugarcane, thereby make sugarcane production-increasing.
(4) the present invention has desinsection and dedicated fertilizer dual-use function to sugarcane, the plantation family is once purchased and is used, can reach the double effects of insect protected and fertilizer, reduced the purchase cost of medicament and fertilizer, reduced the labor capacity of dispenser and fertilising, thereby can significantly reduce cost, be peasant household's additional income.
(5) respectively granulation of the desinsection particle in the product of the present invention and compound fertilizer granules, be equivalent to farm chemical ingredients and fertilizer and be in respectively relatively independent environment, mixing rear granulation process with conventional dose and fertilizer compares, activeconstituents Rynaxypyr and clothianidin in the medicament have more stable physicochemical property, guarantee the quality stability of product, thereby prolonged the shelf lives of medicament.
(6) the present invention adopts extruder grain explained hereafter fertilizer granules, add binding agent, make product of the present invention have stronger hardness, be difficult for being washed away by the water leaching in the soil, reduce the loss of medicament and fertilizer, improved the utilization ratio of medicament and fertilizer, and prolong the lasting period of medicament and fertilizer, thereby reduce consumption and the spraying times of agricultural chemicals, alleviate environmental stress, also reduced the cost at plantation family.
Embodiment
The below is take the sugarcane insecticide fertilizer granular formulation for preparing 100 kilograms of containing chlorantraniliproles of the present invention as embodiment, and the present invention is further described, but do not limit the scope of the invention.Those skilled in the art can prepare corresponding sugarcane insecticide fertilizer granular formulation according to this specification sheets.Need to prove, in the minor modifications of in the art the present invention being done, change the color of product as in formula for a product of the present invention, increasing the toning material, content ratio to active insecticidal components in the prescription is carried out small adjustment, each component of fertilizer, auxiliary agent, binding agent kind and content are carried out less adjustment, and preparation technology's of the present invention parameter, equipment suitably adjusted etc., all do not change essence of the present invention.Except Special Statement was arranged, degree of the present invention was weight percent content.
Embodiment 1
0.03% chlorine worm clothianidin sugarcane insecticide fertilizer granular formulation prescription and preparation method
Prescription:
Pesticide granules: Rynaxypyr 0.01kg, clothianidin 0.02kg, sodium lignosulfonate 0.4kg, sodium lauryl sulphate 0.1kg, polyvinyl alcohol 0.5kg, kaolin 13.97kg;
Compound fertilizer granules: urea 26kg, vitriolate of tartar 3.75kg, Repone K 3.56kg, dipotassium hydrogen phosphate 9.7kg, double superhosphate 4.29kg, magnesium sulfate heptahydrate 2.03kg, Zinc Sulphate Heptahydrate 0.44kg, borax 0.9kg, ammonium molybdate 0.0204kg, xanthohumic acid 3kg, chitin 1kg, starch 5kg, clay 25.3096kg; Wherein, the inorganic fertilizer nutrition composition constitutes: nitrogen (N) 12kg, phosphorus (P
2O
5) 5kg, potassium (K
2O) 8kg, sulphur 1kg, calcium 0.6kg, magnesium 0.2kg, zinc 0.1kg, boron 0.1kg, molybdenum 0.01kg.
The preparation method:
(1) the pesticide granules prescription is pulverized with micronizer mill, mixed, it is moistening to add water, amount of water is 2% of the pulverizing raw material weight, and then mixes, and uses the screw extruder pelletizer granulation, behind fluidised bed drying, obtain containing the pesticide granules of Rynaxypyr and clothianidin, for subsequent use;
(2) the compound fertilizer granules prescription is pulverized with micronizer mill, mixed, it is moistening to add water, amount of water is 2% of the pulverizing raw material weight, and then mixes, and uses the screw extruder pelletizer granulation, behind fluidised bed drying, obtain compound fertilizer granules, for subsequent use;
(3) in Agravicmixer, the pesticide granules of step (1) gained and the compound fertilizer granules of step (2) gained were fully mixed 10 minutes, the fineness that detects the control product is 2mm～5mm, moisture≤3%, expulsion rate≤5%, detect qualified rear packing, namely get 0.03% chlorine worm clothianidin sugarcane insecticide fertilizer granular formulation.
Embodiment 2
0.05% chlorine worm clothianidin sugarcane insecticide fertilizer granular formulation prescription and preparation method thereof
Prescription:
Pesticide granules: Rynaxypyr 0.02kg, clothianidin 0.03kg, calcium lignin sulphonate 0.2kg pulls open powder 0.3kg, polyvinyl alcohol 0.5kg, kaolin 3.95kg;
Compound fertilizer granules: urea 26kg, vitriolate of tartar 3.75kg, Repone K 3.56kg, dipotassium hydrogen phosphate 9.7kg, double superhosphate 4.29kg, magnesium sulfate heptahydrate 2.03kg, Zinc Sulphate Heptahydrate 0.44kg, borax 0.9kg, ammonium molybdate 0.0204kg, xanthohumic acid 12kg, chitin 3kg, starch 5kg, calcium carbonate 10kg, clay 14.3096kg; Wherein, the inorganic fertilizer nutrition composition constitutes: nitrogen (N) 12kg, phosphorus (P
2O
5) 5kg, potassium (K
2O) 8kg, sulphur 1kg, calcium 0.6kg, magnesium 0.2kg, zinc 0.1kg, boron 0.1kg, molybdenum 0.01kg.
The preparation method:
(1) the pesticide granules prescription is pulverized with Universalpulverizer, mixed, it is moistening to add water, amount of water is 3% of the pulverizing raw material weight, and then mixes, and uses the screw extruder pelletizer granulation, behind rotary drying, obtain containing the pesticide granules of Rynaxypyr and clothianidin, for subsequent use;
(2) the compound fertilizer granules prescription is pulverized with Universalpulverizer, mixed, it is moistening to add water, and amount of water is 3% of the pulverizing raw material weight, and then mixes, and uses the screw extruder pelletizer granulation, obtains compound fertilizer granules behind rotary drying, and is for subsequent use;
(3) in the duplex cone-type mixer, the pesticide granules of step (1) gained and the compound fertilizer granules of step (2) gained were fully mixed 15 minutes, the fineness that detects the control product is 2mm～5mm, moisture≤3%, expulsion rate≤5%, detect qualified rear packing, namely get 0.05% chlorine worm clothianidin sugarcane insecticide fertilizer granular formulation.
Embodiment 3
0.1% chlorine worm clothianidin sugarcane insecticide fertilizer granular formulation prescription and preparation method thereof
Prescription:
Pesticide granules: Rynaxypyr 0.03kg, clothianidin 0.07kg, calcium lignin sulphonate 0.2kg pulls open powder 0.3kg, polyvinyl alcohol 0.5kg, kaolin 3.9kg;
Compound fertilizer granules: urea 34.78kg, vitriolate of tartar 7.3kg, Repone K 2.95kg, dipotassium hydrogen phosphate 13.33kg, double superhosphate 8kg, terra alba 5.95kg, magnesium sulfate heptahydrate 10.14kg, Zinc Sulphate Heptahydrate 2.2kg, borax 4.5kg, ammonium molybdate 0.1022kg, xanthohumic acid 3kg, chitin 1kg, carboxymethyl cellulose 1.7478kg; Wherein, the inorganic fertilizer nutrition composition constitutes: nitrogen (N) 16kg, phosphorus (P
2O
5) 8kg, potassium (K
2O) 11kg, sulphur 4kg, calcium 2.5kg, magnesium 1kg, zinc 0.5kg, boron 0.5kg, molybdenum 0.05kg.
The preparation method:
(1) the pesticide granules prescription is pulverized with Raymond machine, mixed, it is moistening to add water, amount of water is 5% of the pulverizing raw material weight, and then mixes, and uses the screw extruder pelletizer granulation, behind fluidised bed drying, obtain containing the pesticide granules of Rynaxypyr and clothianidin, for subsequent use;
(2) the compound fertilizer granules prescription is pulverized with Raymond machine, mixed, it is moistening to add water, and amount of water is 5% of the pulverizing raw material weight, and then mixes, and uses the screw extruder pelletizer granulation, obtains compound fertilizer granules behind fluidised bed drying, and is for subsequent use;
(3) in the duplex cone-type mixer, the pesticide granules of step (1) gained and the compound fertilizer granules of step (2) gained were fully mixed 30 minutes, the fineness that detects the control product is 2mm～5mm, moisture≤3%, expulsion rate≤5%, detect qualified rear packing, namely get 0.1% chlorine worm clothianidin sugarcane insecticide fertilizer granular formulation.
Continue Preparation Example 4-embodiment 11 according to embodiment 3 described preparation methods.
Embodiment 4
0.7% chlorine worm clothianidin sugarcane insecticide fertilizer granular formulation prescription
Pesticide granules: Rynaxypyr 0.2kg, clothianidin 0.5kg, naphthalenesulfonate formaldehyde condensation compound 0.6kg pulls open powder 0.4kg, starch 1kg, wilkinite 2.3kg;
Compound fertilizer granules: urea 34.78kg, vitriolate of tartar 7.3kg, Repone K 2.95kg, dipotassium hydrogen phosphate 13.33kg, double superhosphate 8kg, terra alba 5.95kg, magnesium sulfate heptahydrate 10.14kg, Zinc Sulphate Heptahydrate 2.2kg, borax 4.5kg, ammonium molybdate 0.1022kg, xanthohumic acid 3kg, chitin 1kg, diatomite 1.7478kg; Wherein, the inorganic fertilizer nutrition composition constitutes: nitrogen (N) 16kg, phosphorus (P
2O
5) 8kg, potassium (K
2O) 11kg, sulphur 4kg, calcium 2.5kg, magnesium 1kg, zinc 0.5kg, boron 0.5kg, molybdenum 0.05kg.
Embodiment 5
0.7% chlorine worm clothianidin sugarcane insecticide fertilizer granular formulation prescription
Pesticide granules: Rynaxypyr 0.2kg, clothianidin 0.5kg, naphthalenesulfonate formaldehyde condensation compound 0.6kg pulls open powder 0.4kg, starch 1kg, wilkinite 2.3kg;
Compound fertilizer granules: urea 26kg, vitriolate of tartar 3.75kg, Repone K 3.56kg, dipotassium hydrogen phosphate 9.7kg, double superhosphate 4.29kg, magnesium sulfate heptahydrate 2.03kg, Zinc Sulphate Heptahydrate 0.44kg, borax 0.9kg, ammonium molybdate 0.0204kg, xanthohumic acid 12kg, chitin 3kg, starch 5kg, clay 24.3096kg; Wherein, the inorganic fertilizer nutrition composition constitutes: nitrogen (N) 12kg, phosphorus (P
2O
5) 5kg, potassium (K
2O) 8kg, sulphur 1kg, calcium 0.6kg, magnesium 0.2kg, zinc 0.1kg, boron 0.1kg, molybdenum 0.01kg.
Embodiment 6
0.15% chlorine worm clothianidin sugarcane insecticide fertilizer granular formulation prescription
Pesticide granules: Rynaxypyr 0.05kg, clothianidin 0.1kg, naphthalenesulfonate formaldehyde condensation compound 0.4kg, calcium lignin sulphonate 0.5kg, starch 0.8kg, wilkinite 5.85kg;
Compound fertilizer granules: urea 30.43kg, vitriolate of tartar 14.8kg, dipotassium hydrogen phosphate 3.8kg, double superhosphate 10.71kg, magnesium sulfate heptahydrate 6.09kg, Zinc Sulphate Heptahydrate 1.76kg, borax 2.65kg, ammonium molybdate 0.0613kg, xanthohumic acid 7kg, chitin 2kg, starch 4kg, carclazyte 8.9987kg; Wherein, the inorganic fertilizer nutrition composition constitutes: nitrogen (N) 14kg, phosphorus (P
2O
5) 6.5kg, potassium (K
2O) 9.5kg, sulphur 3.7kg, calcium 1.5kg, magnesium 0.6kg, zinc 0.4kg, boron 0.3kg, molybdenum 0.03kg.
Embodiment 7
0.2% chlorine worm clothianidin sugarcane insecticide fertilizer granular formulation prescription
Pesticide granules: Rynaxypyr 0.1kg, clothianidin 0.1kg, naphthalenesulfonate formaldehyde condensation compound 0.5kg, calcium lignin sulphonate 0.3kg, polyvinyl alcohol 0.7kg, clay 5.8kg;
Compound fertilizer granules: urea 30.43kg, vitriolate of tartar 14.8kg, dipotassium hydrogen phosphate 3.8kg, double superhosphate 10.71kg, magnesium sulfate heptahydrate 6.09kg, Zinc Sulphate Heptahydrate 1.76kg, borax 2.65kg, ammonium molybdate 0.0613kg, xanthohumic acid 7kg, chitin 2kg, starch 4kg, clay 9.1987kg; Wherein, the inorganic fertilizer nutrition composition constitutes: nitrogen (N) 14kg, phosphorus (P
2O
5) 6.5kg, potassium (K
2O) 9.5kg, sulphur 3.7kg, calcium 1.5kg, magnesium 0.6kg, zinc 0.4kg, boron 0.3kg, molybdenum 0.03kg.
Embodiment 8
0.3% chlorine worm clothianidin sugarcane insecticide fertilizer granular formulation prescription
Pesticide granules: Rynaxypyr 0.2kg, clothianidin 0.1kg, sulfonated alkyl naphathalene formaldehyde condensation products 0.5kg, calcium lignin sulphonate 0.3kg, carboxymethyl cellulose 0.6kg, wilkinite 6kg;
Compound fertilizer granules: urea 30.43kg, vitriolate of tartar 14.8kg, dipotassium hydrogen phosphate 3.8kg, double superhosphate 10.71kg, magnesium sulfate heptahydrate 6.09kg, Zinc Sulphate Heptahydrate 1.76kg, borax 2.65kg, ammonium molybdate 0.0613kg, xanthohumic acid 9kg, chitin 2kg, starch 2.5kg, clay 8.4987kg; Wherein, the inorganic fertilizer nutrition composition constitutes: nitrogen (N) 14kg, phosphorus (P
2O
5) 6.5kg, potassium (K
2O) 9.5kg, sulphur 3.7kg, calcium 1.5kg, magnesium 0.6kg, zinc 0.4kg, boron 0.3kg, molybdenum 0.03kg.
Embodiment 9
0.4% chlorine worm clothianidin sugarcane insecticide fertilizer granular formulation prescription
Pesticide granules: Rynaxypyr 0.15kg, clothianidin 0.3kg, sulfonated alkyl naphathalene formaldehyde condensation products 0.3kg pulls open powder 0.6kg, carboxymethyl cellulose 0.9kg, clay 4kg;
Compound fertilizer granules: urea 30.43kg, vitriolate of tartar 14.8kg, dipotassium hydrogen phosphate 3.8kg, double superhosphate 10.71kg, magnesium sulfate heptahydrate 6.09kg, Zinc Sulphate Heptahydrate 1.76kg, borax 2.65kg, ammonium molybdate 0.0613kg, xanthohumic acid 5kg, chitin 3kg, carboxymethyl cellulose 2.5kg, clay 12.9487kg; Wherein, the inorganic fertilizer nutrition composition constitutes: nitrogen (N) 14kg, phosphorus (P
2O
5) 6.5kg, potassium (K
2O) 9.5kg, sulphur 3.7kg, calcium 1.5kg, magnesium 0.6kg, zinc 0.4kg, boron 0.3kg, molybdenum 0.03kg.
Embodiment 10
0.5% chlorine worm clothianidin sugarcane insecticide fertilizer granular formulation prescription
Pesticide granules: Rynaxypyr 0.2kg, clothianidin 0.3kg, naphthalenesulfonate formaldehyde condensation compound 0.5kg, calcium lignin sulphonate 0.4kg, carboxymethyl cellulose 1kg, kaolin 5.5kg;
Compound fertilizer granules: urea 32.6kg, vitriolate of tartar 10.07kg, dipotassium hydrogen phosphate 11.43kg, double superhosphate 7.14kg, magnesium sulfate heptahydrate 4.06kg, Zinc Sulphate Heptahydrate 1.32kg, borax 3.54kg, ammonium molybdate 0.0409kg, xanthohumic acid 10.5kg, chitin 1.6kg, carboxymethyl cellulose 3kg, clay 6.7991kg; Wherein, the inorganic fertilizer nutrition composition constitutes: nitrogen (N) 15kg, phosphorus (P
2O
5) 7kg, potassium (K
2O) 10kg, sulphur 2.5kg, calcium 1kg, magnesium 0.4kg, zinc 0.3kg, boron 0.4kg, molybdenum 0.02kg.
Application example
In March, 2011, carry out Sugarcane Pests control and volume increase field test on Laibin, Guangxi Province suburban area cane planting ground.Test arranges following processing according to unified cost budgeting:
Process 1-and process 10: the fertilizer granules that is respectively above-described embodiment 1-embodiment 10 gained;
Process 11:0.4% Rynaxypyr granule;
Process 12:0.5% clothianidin granule;
Processing 13:0.35% chlorine worm clothianidin granule (Rynaxypyr: clothianidin=0.1:0.25);
Process 14: the fertilizer that xanthohumic acid and chitin are mixed (xanthohumic acid: chitin=7:2);
Process 15: by urea 30.43%, vitriolate of tartar 14.8%, dipotassium hydrogen phosphate 3.8%, double superhosphate 10.71%, magnesium sulfate heptahydrate 6.09%, Zinc Sulphate Heptahydrate 1.76%, borax 2.65%, it is fertile that ammonium molybdate 0.0613%, starch 5%, clay complement to the composite inorganic that 100% component forms;
Except above-mentioned processing, this test also is provided with space management.Process 15 according to unified cost budgeting consumption with processing 1-, spread fertilizer over the fields when sugarcane is sowed, 3 repetitions are established in each processing, each experimental plot 67m
2, the residential quarter random alignment.After dispenser, investigated respectively the Harm of sugarcane sugarcane tortoise, snout moth's larva and thrips in 60 days, 120 days, investigation sugarcane production-increasing situation when results.Test-results sees Table 1.
Table 1: Sugarcane Pests control and volume increase field test results cartogram
As known from Table 1: utilize the present invention to be applied to sugarcane field, compare with alone granular pesticide, good to the prevention effect of Sugarcane Pests, the lasting period is longer, and compositely has a synergistic function; Compare with alone granular pesticide, alone inorganic fertilizer or alone fertilizer, the present invention is more obvious to the production-increasing function of sugarcane.
Claims (6)
1. the sugarcane insecticide fertilizer granular formulation of a containing chlorantraniliprole, formed by fertilizer, inorganic fertilizer, pesticide active ingredient, auxiliary agent and vehicle, it is characterized in that, described fertilizer is comprised of xanthohumic acid and chitin, described pesticide active ingredient is comprised of Rynaxypyr and clothianidin, and the weight percent content of described each component of fertilizer granules is:
Xanthohumic acid 3～12%;
Chitin 1～3%;
Inorganic fertilizer 26.91～43.55%;
Rynaxypyr 0.01～0.2%;
Clothianidin 0.02～0.5%;
Auxiliary agent 0.5～1%;
Vehicle complements to 100% of fertilizer granules gross weight.
2. the sugarcane insecticide fertilizer granular formulation of containing chlorantraniliprole according to claim 1 is characterized in that, described inorganic fertilizer is comprised of the nutritive element of following weight percent content:
Nitrogen 12～16%;
Phosphorus 5～8%;
Potassium 8～11%;
Sulphur 1～4%;
Calcium 0.5～2.5%;
Magnesium 0.2～1%;
Zinc 0.1～0.5%;
Boron 0.1～0.5%;
Molybdenum 0.01～0.05%.
3. the sugarcane insecticide fertilizer granular formulation of containing chlorantraniliprole according to claim 1 and 2, it is characterized in that described auxiliary agent is sodium lauryl sulphate, calcium lignin sulphonate, sodium lignosulfonate, naphthalenesulfonate formaldehyde condensation compound, sulfonated alkyl naphathalene formaldehyde condensation products or pulls open at least a in the powder.
4. the sugarcane insecticide fertilizer granular formulation of containing chlorantraniliprole according to claim 1 and 2, it is characterized in that described vehicle is at least a in starch, polyvinyl alcohol, carboxymethyl cellulose, clay, diatomite, carclazyte, kaolin, wilkinite or the calcium carbonate.
5. a preparation method who is applicable to the sugarcane insecticide fertilizer granular formulation of claim 1 or 2 described containing chlorantraniliproles is characterized in that, may further comprise the steps:
(1) preparation pesticide granules: according to weight part, get 2.8～14.97 parts of 0.01～0.2 part of Rynaxypyr, 0.02～0.5 part of clothianidin, 0.5～1 part of auxiliary agent and vehicle, pulverize, mix, it is even to add the moistening rear remix of water, use the Squeezinggranulator granulation, obtain containing the pesticide granules of Rynaxypyr and clothianidin after the drying, for subsequent use;
(2) preparation compound fertilizer granules: according to weight part, get 3～12 parts of xanthohumic acids, 1～3 part of chitin, 12～16 parts in nitrogen, 5～8 parts in phosphorus, 8～11 parts in potassium, 1～4 part of sulphur, 0.5～2.5 part of calcium, 0.2～1 part in magnesium, 0.1～0.5 part on zinc, 0.1～0.5 part of boron, 0.01～0.05 part of molybdenum and vehicle, the addition of vehicle makes the total weight parts of pesticide granules and compound fertilizer granules reach 100 parts; Raw material pulverizing with getting mixes, and it is even to add the moistening rear remix of water, uses the Squeezinggranulator granulation, obtains compound fertilizer granules after the drying, for subsequent use;
(3) in mixing equipment, the pesticide granules of step (1) gained and the compound fertilizer granules of step (2) gained are fully mixed, and the fineness of testing product is 2mm～5mm, moisture≤3%, the rear packing of expulsion rate≤5% namely gets the sugarcane insecticide fertilizer granular formulation of containing chlorantraniliprole.
6. the preparation method of the sugarcane insecticide fertilizer granular formulation of containing chlorantraniliprole according to claim 5 is characterized in that, step (1) and the described pulverizing of step (2) are with micronizer mill, Universalpulverizer or Raymond machine raw material to be pulverized; Described Squeezinggranulator is screw extruder pelletizer; Described to add water moistening, and amount of water is for pulverizing 2～5% of raw material weight; Described drying is fluidised bed drying or rotary drying; Described mixing refers to Agravicmixer or duplex cone-type mixer raw material be mixed, and mixing time is 10～30 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013100143458A CN103030473A (en) | 2013-01-15 | 2013-01-15 | Sugarcane pesticide fertilizer granule with chlorantraniliprole and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013100143458A CN103030473A (en) | 2013-01-15 | 2013-01-15 | Sugarcane pesticide fertilizer granule with chlorantraniliprole and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103030473A true CN103030473A (en) | 2013-04-10 |
Family
ID=48017927
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013100143458A Pending CN103030473A (en) | 2013-01-15 | 2013-01-15 | Sugarcane pesticide fertilizer granule with chlorantraniliprole and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103030473A (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103843571A (en) * | 2014-03-20 | 2014-06-11 | 张文礼 | Hard pod sweet pea culturing method |
| CN104262028A (en) * | 2014-10-21 | 2015-01-07 | 叶长东 | Pesticide-fertilizer composition containing dinotefuran and/or phoxim |
| CN104262039A (en) * | 2014-09-15 | 2015-01-07 | 武汉中农国际贸易有限公司 | Insect-controllable controlled-release fertilizer special for sugarcanes and preparation method thereof |
| CN104609989A (en) * | 2014-12-18 | 2015-05-13 | 广西大学 | A sugarcane special-purpose pesticide fertilizer and a preparing method thereof |
| CN105237255A (en) * | 2015-09-17 | 2016-01-13 | 广西天峨五福种业有限公司 | Insecticide fertilizer |
| CN105746567A (en) * | 2016-03-31 | 2016-07-13 | 杭州宇龙化工有限公司 | Agricultural insecticidal composition and application thereof |
| CN105936609A (en) * | 2016-06-20 | 2016-09-14 | 河南中天恒信生物化学科技有限公司 | Insecticide-fertilizer particle for paddy field and preparation method thereof |
| CN112273379A (en) * | 2020-10-30 | 2021-01-29 | 中诚国联（河南）生物科技有限公司 | Preparation method of slow-release fertilizer granules containing chlorantraniliprole and clothianidin |
| CN112500225A (en) * | 2020-12-14 | 2021-03-16 | 广西首控生物科技股份有限公司 | Pesticide fertilizer granules containing chlorantraniliprole and dinotefuran |
| CN112537978A (en) * | 2020-12-04 | 2021-03-23 | 中诚国联（河南）生物科技有限公司 | Preparation method and application of high-tower pesticide fertilizer for preventing and treating piercing-sucking pests and underground pests |
| CN113480358A (en) * | 2021-07-20 | 2021-10-08 | 河北禾润生物科技有限公司 | Pesticide-fertilizer composition and application thereof |
| CN113582776A (en) * | 2021-08-06 | 2021-11-02 | 安徽省司尔特肥业股份有限公司 | Garlic sulfur coating compound fertilizer and preparation method thereof |
| CN115462381A (en) * | 2022-06-30 | 2022-12-13 | 上海沪联生物药业（夏邑）股份有限公司 | Efficient insecticidal composition and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101709016A (en) * | 2009-12-11 | 2010-05-19 | 广西壮族自治区化工研究院 | Sugarcane insecticide fertilizer and production method thereof |
| CN102273440A (en) * | 2011-09-13 | 2011-12-14 | 广西田园生化股份有限公司 | Ultralow volume liquid containing clothianidin |
| CN102503706A (en) * | 2011-11-22 | 2012-06-20 | 广西力源宝农林科技发展有限责任公司 | Sugarcane fertilizer for preventing and treating soil insects and production method thereof |
-
2013
- 2013-01-15 CN CN2013100143458A patent/CN103030473A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101709016A (en) * | 2009-12-11 | 2010-05-19 | 广西壮族自治区化工研究院 | Sugarcane insecticide fertilizer and production method thereof |
| CN102273440A (en) * | 2011-09-13 | 2011-12-14 | 广西田园生化股份有限公司 | Ultralow volume liquid containing clothianidin |
| CN102503706A (en) * | 2011-11-22 | 2012-06-20 | 广西力源宝农林科技发展有限责任公司 | Sugarcane fertilizer for preventing and treating soil insects and production method thereof |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103843571A (en) * | 2014-03-20 | 2014-06-11 | 张文礼 | Hard pod sweet pea culturing method |
| CN103843571B (en) * | 2014-03-20 | 2016-03-30 | 张文礼 | A kind of cultivation method of hard pod Lathyrus odoratus |
| CN104262039A (en) * | 2014-09-15 | 2015-01-07 | 武汉中农国际贸易有限公司 | Insect-controllable controlled-release fertilizer special for sugarcanes and preparation method thereof |
| CN104262039B (en) * | 2014-09-15 | 2016-08-24 | 武汉中农国际贸易有限公司 | Control worm controlled release sugarcane special-purpose fertilizer and preparation method thereof |
| CN104262028B (en) * | 2014-10-21 | 2016-08-03 | 叶长东 | A kind of medicine fertilizer composition comprising MTI-446 and/or phoxim |
| CN104262028A (en) * | 2014-10-21 | 2015-01-07 | 叶长东 | Pesticide-fertilizer composition containing dinotefuran and/or phoxim |
| CN104609989A (en) * | 2014-12-18 | 2015-05-13 | 广西大学 | A sugarcane special-purpose pesticide fertilizer and a preparing method thereof |
| CN105237255A (en) * | 2015-09-17 | 2016-01-13 | 广西天峨五福种业有限公司 | Insecticide fertilizer |
| CN105746567A (en) * | 2016-03-31 | 2016-07-13 | 杭州宇龙化工有限公司 | Agricultural insecticidal composition and application thereof |
| CN105746567B (en) * | 2016-03-31 | 2018-03-02 | 杭州宇龙化工有限公司 | A kind of agricultural pesticide composition and application thereof |
| CN105936609A (en) * | 2016-06-20 | 2016-09-14 | 河南中天恒信生物化学科技有限公司 | Insecticide-fertilizer particle for paddy field and preparation method thereof |
| CN112273379A (en) * | 2020-10-30 | 2021-01-29 | 中诚国联（河南）生物科技有限公司 | Preparation method of slow-release fertilizer granules containing chlorantraniliprole and clothianidin |
| CN112537978A (en) * | 2020-12-04 | 2021-03-23 | 中诚国联（河南）生物科技有限公司 | Preparation method and application of high-tower pesticide fertilizer for preventing and treating piercing-sucking pests and underground pests |
| CN112500225A (en) * | 2020-12-14 | 2021-03-16 | 广西首控生物科技股份有限公司 | Pesticide fertilizer granules containing chlorantraniliprole and dinotefuran |
| CN112500225B (en) * | 2020-12-14 | 2022-06-24 | 广西首控生物科技股份有限公司 | Pesticide fertilizer granules containing chlorantraniliprole and dinotefuran |
| CN113480358A (en) * | 2021-07-20 | 2021-10-08 | 河北禾润生物科技有限公司 | Pesticide-fertilizer composition and application thereof |
| CN113582776A (en) * | 2021-08-06 | 2021-11-02 | 安徽省司尔特肥业股份有限公司 | Garlic sulfur coating compound fertilizer and preparation method thereof |
| CN115462381A (en) * | 2022-06-30 | 2022-12-13 | 上海沪联生物药业（夏邑）股份有限公司 | Efficient insecticidal composition and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103030474B (en) | Sugar cane pesticide fertilizer granule and preparation method thereof | |
| CN103030473A (en) | Sugarcane pesticide fertilizer granule with chlorantraniliprole and preparation method thereof | |
| CN103030475B (en) | Sugarcane pesticide fertilizer granule containing thiamethoxam and preparation method thereof | |
| CN101323547B (en) | Medicine fertilizer granular formulation for killing molluscous harmful to rice and manufacturing method thereof | |
| CN103739395B (en) | A kind of tobacco special organic inorganic compound pesticide fertilizer | |
| CN106977277A (en) | Potassium polyphosphate corn slow-release fertilizer and its production method | |
| CN103360162A (en) | Sugarcane sustained-release granular medicinal fertilizer | |
| CN101717316A (en) | Pesticide and fertilizer mixing particle agent for controlling soil insects and production method thereof | |
| CN103664276B (en) | A kind of Multi-element active silicon fertilizer based on oil shale | |
| CN102603426A (en) | Rice seedling-strengthening pesticide-containing fertilizer for preventing virus diseases of rice | |
| CN103098818A (en) | Pesticide compound mixture containing clothianidin and monosultap and pesticide fertilizer and production method thereof | |
| CN102060612B (en) | Special insecticide fertilizer for radish and preparation method thereof | |
| CN102351599A (en) | Quick-acting long-acting granular zinc fertilizer and preparation method thereof | |
| CN103588591A (en) | Insecticidal nutritional pesticide-fertilizer granules special for bananas | |
| CN105218233A (en) | Improve composite fertilizer and the production method thereof of cane sugar | |
| CN104211535A (en) | Biological organic fertilizer containing compound bacteria and preparation method of biological organic fertilizer | |
| CN104058810A (en) | Special fertilizer for tea-oil tree and preparation method thereof | |
| CN104151016A (en) | Efficient growth-promoting green organic-inorganic compound fertilizer | |
| CN102771503B (en) | Granule containing chitin | |
| CN104649820A (en) | Preparation method of special fertilizer for jackfruit | |
| CN102432379A (en) | Ultrafine vegetable seed coating agent | |
| CN108484306A (en) | It is a kind of efficiently to increase production wheat fertilizer and preparation method thereof | |
| CN105541506A (en) | Paddy-field pesticide-fertilizer sustained release granules and preparing method and application method thereof | |
| CN104817407A (en) | Paddy field pesticide-fertilizer granule containing silicon and zinc elements and chitosan and preparation method of same | |
| CN105175092A (en) | Liquid leaf fertilizer containing various plant extracts including alginic acid, preparation method for liquid leaf fertilizer and application method of liquid leaf fertilizer |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20130410 |