CN103098818A - Pesticide compound mixture containing clothianidin and monosultap and pesticide fertilizer and production method thereof - Google Patents
Pesticide compound mixture containing clothianidin and monosultap and pesticide fertilizer and production method thereof Download PDFInfo
- Publication number
- CN103098818A CN103098818A CN2013100007260A CN201310000726A CN103098818A CN 103098818 A CN103098818 A CN 103098818A CN 2013100007260 A CN2013100007260 A CN 2013100007260A CN 201310000726 A CN201310000726 A CN 201310000726A CN 103098818 A CN103098818 A CN 103098818A
- Authority
- CN
- China
- Prior art keywords
- fertilizer
- clothianidin
- sugarcane
- pesticide
- insecticide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003337 fertilizer Substances 0.000 title claims abstract description 112
- PGOOBECODWQEAB-UHFFFAOYSA-N (E)-clothianidin Chemical compound [O-][N+](=O)\N=C(/NC)NCC1=CN=C(Cl)S1 PGOOBECODWQEAB-UHFFFAOYSA-N 0.000 title claims abstract description 103
- 239000005888 Clothianidin Substances 0.000 title claims abstract description 102
- 239000000203 mixture Substances 0.000 title claims abstract description 57
- 239000000575 pesticide Substances 0.000 title claims abstract description 27
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 21
- 150000001875 compounds Chemical class 0.000 title abstract description 5
- MBNMHBAJUNHZRE-UHFFFAOYSA-M thiosultap monosodium Chemical compound [Na+].OS(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O MBNMHBAJUNHZRE-UHFFFAOYSA-M 0.000 title abstract description 5
- 239000002917 insecticide Substances 0.000 claims abstract description 53
- 241000134979 Ceratovacuna lanigera Species 0.000 claims abstract description 20
- 239000000853 adhesive Substances 0.000 claims abstract description 5
- 230000001070 adhesive effect Effects 0.000 claims abstract description 5
- 239000000945 filler Substances 0.000 claims abstract description 5
- 240000000111 Saccharum officinarum Species 0.000 claims description 80
- 235000007201 Saccharum officinarum Nutrition 0.000 claims description 78
- 239000002131 composite material Substances 0.000 claims description 37
- 239000003814 drug Substances 0.000 claims description 37
- 239000000126 substance Substances 0.000 claims description 23
- 238000013329 compounding Methods 0.000 claims description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 15
- 241000270708 Testudinidae Species 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 13
- 239000011734 sodium Substances 0.000 claims description 12
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 11
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 11
- 229910052708 sodium Inorganic materials 0.000 claims description 11
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 11
- 241001515929 Fulmekiola serrata Species 0.000 claims description 9
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 8
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 8
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 8
- 229920005551 calcium lignosulfonate Polymers 0.000 claims description 8
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 claims description 8
- 239000003607 modifier Substances 0.000 claims description 8
- -1 neopelex Chemical compound 0.000 claims description 8
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 8
- 239000005995 Aluminium silicate Substances 0.000 claims description 7
- 239000003905 agrochemical Substances 0.000 claims description 7
- 235000012211 aluminium silicate Nutrition 0.000 claims description 7
- UDHMTPILEWBIQI-UHFFFAOYSA-N butyl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(=O)OCCCC)=CC=CC2=C1 UDHMTPILEWBIQI-UHFFFAOYSA-N 0.000 claims description 7
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 7
- 229920000570 polyether Polymers 0.000 claims description 7
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- 229910000278 bentonite Inorganic materials 0.000 claims description 6
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 6
- QTPSOVJLZXSTEB-UHFFFAOYSA-L calcium;dodecyl sulfate Chemical compound [Ca+2].CCCCCCCCCCCCOS([O-])(=O)=O.CCCCCCCCCCCCOS([O-])(=O)=O QTPSOVJLZXSTEB-UHFFFAOYSA-L 0.000 claims description 6
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 6
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
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- 239000008107 starch Substances 0.000 claims description 5
- 235000019698 starch Nutrition 0.000 claims description 5
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 4
- 239000005864 Sulphur Substances 0.000 claims description 4
- 229910021536 Zeolite Inorganic materials 0.000 claims description 4
- 150000001413 amino acids Chemical class 0.000 claims description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 4
- 239000002270 dispersing agent Substances 0.000 claims description 4
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 4
- 239000004021 humic acid Substances 0.000 claims description 4
- LCRMGUFGEDUSOG-UHFFFAOYSA-N naphthalen-1-ylsulfonyloxymethyl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(OCOS(=O)(=O)C=3C4=CC=CC=C4C=CC=3)=O)=CC=CC2=C1 LCRMGUFGEDUSOG-UHFFFAOYSA-N 0.000 claims description 4
- 239000012188 paraffin wax Substances 0.000 claims description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 4
- 235000011152 sodium sulphate Nutrition 0.000 claims description 4
- 239000010457 zeolite Substances 0.000 claims description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 2
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- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 2
- 239000004115 Sodium Silicate Substances 0.000 claims description 2
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- 239000000618 nitrogen fertilizer Substances 0.000 claims description 2
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- 239000002686 phosphate fertilizer Substances 0.000 claims description 2
- 239000011295 pitch Substances 0.000 claims description 2
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- 229940072033 potash Drugs 0.000 claims description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 2
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- 241000607479 Yersinia pestis Species 0.000 abstract description 16
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- DUEPRVBVGDRKAG-UHFFFAOYSA-N carbofuran Chemical compound CNC(=O)OC1=CC=CC2=C1OC(C)(C)C2 DUEPRVBVGDRKAG-UHFFFAOYSA-N 0.000 description 6
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- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241001640040 Dorysthenes granulosus Species 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 241000917171 Eriosomatinae Species 0.000 description 1
- 241001515931 Fulmekiola Species 0.000 description 1
- 229930191978 Gibberellin Natural products 0.000 description 1
- 241000256602 Isoptera Species 0.000 description 1
- 241001179564 Melanaphis sacchari Species 0.000 description 1
- MTXSIJUGVMTTMU-UHFFFAOYSA-N Neonicotine Natural products N1CCCCC1C1=CC=CN=C1 MTXSIJUGVMTTMU-UHFFFAOYSA-N 0.000 description 1
- 239000005941 Thiamethoxam Substances 0.000 description 1
- WZLMXYBCAZZIRQ-UHFFFAOYSA-N [N].[P].[K] Chemical compound [N].[P].[K] WZLMXYBCAZZIRQ-UHFFFAOYSA-N 0.000 description 1
- OIPILFWXSMYKGL-UHFFFAOYSA-N acetylcholine Chemical compound CC(=O)OCC[N+](C)(C)C OIPILFWXSMYKGL-UHFFFAOYSA-N 0.000 description 1
- 229960004373 acetylcholine Drugs 0.000 description 1
- 102000015296 acetylcholine-gated cation-selective channel activity proteins Human genes 0.000 description 1
- 108040006409 acetylcholine-gated cation-selective channel activity proteins Proteins 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- JLQUFIHWVLZVTJ-UHFFFAOYSA-N carbosulfan Chemical compound CCCCN(CCCC)SN(C)C(=O)OC1=CC=CC2=C1OC(C)(C)C2 JLQUFIHWVLZVTJ-UHFFFAOYSA-N 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- YKBZOVFACRVRJN-UHFFFAOYSA-N dinotefuran Chemical compound [O-][N+](=O)\N=C(/NC)NCC1CCOC1 YKBZOVFACRVRJN-UHFFFAOYSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000004720 fertilization Effects 0.000 description 1
- IXORZMNAPKEEDV-UHFFFAOYSA-N gibberellic acid GA3 Natural products OC(=O)C1C2(C3)CC(=C)C3(O)CCC2C2(C=CC3O)C1C3(C)C(=O)O2 IXORZMNAPKEEDV-UHFFFAOYSA-N 0.000 description 1
- 239000003448 gibberellin Substances 0.000 description 1
- 239000003630 growth substance Substances 0.000 description 1
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 1
- 230000035987 intoxication Effects 0.000 description 1
- 231100000566 intoxication Toxicity 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229960003512 nicotinic acid Drugs 0.000 description 1
- 235000001968 nicotinic acid Nutrition 0.000 description 1
- 239000011664 nicotinic acid Substances 0.000 description 1
- 230000000050 nutritive effect Effects 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 210000004681 ovum Anatomy 0.000 description 1
- BULVZWIRKLYCBC-UHFFFAOYSA-N phorate Chemical compound CCOP(=S)(OCC)SCSCC BULVZWIRKLYCBC-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 210000004894 snout Anatomy 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Fertilizers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a pesticide compound mixture containing clothianidin and monosultap and a pesticide fertilizer and a production method thereof, wherein the pesticide fertilizer consists of pesticide active ingredients, fertilizers, inert fillers, adhesives and dispersion agents. The pesticide compound mixture containing clothianidin and monosultap and the pesticide fertilizer and the production method thereof provided by the invention have the advantages that the pesticide active ingredients, namely clothianidin and monosultap, are compounded to have an obvious synergism effect, the using amount and the using times of the pesticide are obviously reduced, the cost is lowered, also the drug resistance generation of pests can be delayed, and meanwhile the insecticidal spectrum is expanded. The pesticide fertilizer also is good, has the functions of insecticide and nutrition supply, relieves the labor intensity, reduces labor times of farmers, reduces the agriculture input for users, and meanwhile also plays a positive acceleration effect for agriculture production and income increasing. The pesticide compound mixture and the pesticide fertilizer can be applied to preventing and treating stem borers, ceratovacuna lanigera zehntner, thrips serrata kobus, alissonotum impressicolle arrow and cerambycidae.
Description
Technical field
The present invention relates to a kind of agriculture chemical compounding mixture, particularly take clothianidin and desinsection list as pesticide activity component, the medicine fertilizer and the production method thereof that integrate desinsection, nutritive effect, this agriculture chemical compounding mixture and insecticide fertilizer can be used for preventing and treating the Sugarcane Pests such as sugarcane borer, sugar cane cottony aphid, Sugarcane Thrips, sugarcane tortoise, sugarcane root prionid.
Background technology
Sugarcane is the important economic crops of China, and its vegetative period is long, and output is high, and it is many that absorb nutrient whole breeding time, is one of larger crop of fertilizer requirement.People have also taken away nitrogen phosphorus potassium a large amount of in soil in sugarcane in results, so the need of production artificially applying fertilizer of sugarcane.Except needing a large amount of fertilizer, also need Sugarcane Pests is prevented and treated in the sugarcane production process.Sugarcane borer, sugarcane tortoise, sugar cane cottony aphid, Sugarcane Thrips, sugarcane root prionid are the primary pest in sugarcane production, improperly will cause sugarcane to drop in production over a large area and reduce the sugarcane quality if prevent and treat.In the control of Sugarcane Pests, the sugarcane grower often uses high-toxic pesticide to prevent and treat, and the intoxication accident that causes every year is of common occurrence, so China has put into effect a series of high-toxic pesticide policies of using that limit.Face the situation of comprehensive forbidding for terbufos, carbofuran, the contour malicious agricultural chemicals of thimet, the novel pesticide of good, efficient, the low toxicity of absorption, environmental protection substitutes high-toxic pesticide and is seeming very urgent in sugarcane production at present in develop and spread.Wherein, neonicotine pesticide clothianidin and sandworm toxin insecticide desinsection list are two very important kinds in low-toxin farm chemicals.
The desinsection list, english common name: Molosultap, chemical name are 2-N, N dimethylamine base-1-sodium thiosulfate base-3-propane thiosulfate, CA registration number: 29547-00-0, molecular formula C
5H
14O
7S
4Na, molecular weight 333.4, be the analog of artificial synthetic nereistoxin, be acetylcholine inhibitor, have stronger tag, stomach toxicity and interior suction conduction, without residual hazard, free from environmental pollution, be the comparatively ideal medicament of present comprehensive regulation insect pest, particularly sugarcane borer etc. there is special efficacy, also can prevent and treat sugarcane aphid, thrips etc., be an extremely successful example of the synthetic exploitation of China's chemobionics.Clothianidin, english common name: Clothiandin, chemical name are (E)-1-(2-chloro-1,3-thiazoles-5-ylmethyl)-3-methyl-2-2-nitroguanidine, CA registration number: 210880-92-5, molecular formula C
6H
8ClN
5O
2S, molecular weight 249.7, it is the important kind in second generation anabasine insecticide, be nicotinic acid nAChR ligands inhibitor, have stronger tag, stomach toxicity and interior suction conduction, under low-down dosage, efficient to suckings pest such as the woolly aphid of harm sugarcane, thrips, mealybugs, simultaneously sugarcane tortoise, day bovine, termite, locust grasshopper class and snout moth's larva etc. also there are very high preventive effect, belong to public nuisance-free agricultural chemicals.Yet the price of clothianidin is relatively high, has limited it and has further applied, and therefore need improve on using method, as add other active component or synergistic component, to reduce the dosage on producing, reduces cost accounting.In agricultural production, it should be noted that the generation that prevents pest resistance to insecticide simultaneously, a kind of effective method is to carry out composite with two kinds of different insecticides.Adopt the different pesticide compositional of the mode of action also to demonstrate synergistic effect, namely mixture to the inhibitory action of the insect desired value higher than each component independent role in mixture, is the target of exploitation pesticide compositional preparation.
In agricultural production, people wish also that a pesticidal preparations once uses and can play simultaneously desinsection and nutrient supply function, and two, field operating procedure is united two into one, and save labour, time, the energy, reduce agriculture production cost.Therefore develop the fertile preparation of the medicine that possesses simultaneously desinsection and nutrient supply function very necessary.
By Indexing of Scien. and Tech. Literature, we find following Chinese patent about sugarcane insecticide fertilizer, for example: patent " a kind of sugarcane foliage medicinal fertilizer formulation " (application number: 200710066471), disclose a kind of sugarcane foliage medicinal fertilizer formulation and production method.The production method of this sugarcane foliage medicinal fertilizer is: first add by mass percentage following former powder: 95% Imidacloprid 10%, 95% desinsection list 75%, 98% cartap 15%, add again with the kaolin of former medicine equivalent as packing agent after fully mixing and be equivalent to the wetting agent of former medicine 2%, then the crushing, stirring mixing; Then adding by mass percentage zinc sulphate 40%, manganese sulphate 20%, borax 36%, ammonium molybdate 3.5% and 0.5% gibberellin in agitator is growth regulator; Agricultural chemicals and little fertilizer are mixed in the ratio of 1: 2, form medicine fertile.Be sprayed at after 200 times of this sugarcane foliage medicinal fertilizer dilute with waters on sugarcane plant blade face.After the spray medicine, 1 day sugar cane cottony aphid control efficiency reaches more than 96%, reaches 100% after 3 days, simultaneously sugarcane borer ovum and larva is had certain control action, reduces the withered heart seedling in field; After Foliage Absorption, it is green that Sugarcane Leaves turns, and output improves 15%, and field hammer degree improves 0.2%.the Fang Feng of the applicant Chemical Industry Inst., Guangxi Zhuang Autonomous Region, Lai Kaiping, Ye Yiqiang, Huang Kelin, MoBing Rong, Wang Jun also discloses " a kind of sugarcane insecticide fertilizer and production method thereof " (application number: 200910114621.1), described medicine fertilizer comprises insecticidal constituent and the npk fertilizer of carbosulfan and worm hydrazides, trace element and stabilizing agent, this sugarcane insecticide fertilizer is to the sugarcane borer, the control efficiency of sugarcane tortoise is all over 80%, the control treatment of also not executing insecticide is compared with not applying fertilizer, sugarcane yield all increases substantially, volume increase is all over 40%.At present, there is not yet report about sugarcane pesticide-fertilizer product and the correlative study that contains clothianidin and desinsection list.Patent CN102696586A and CN102696587A mention and use nicotinic insecticide (clothianidin-containing) and sandworm toxin insecticide (containing the desinsection list) to carry out composite, but the content that unexposed clothianidin and desinsection list are concrete, and the application technology after clothianidin and desinsection list composite and outstanding advantages thereof are also there are no report.
Summary of the invention
The purpose of this invention is to provide that a kind of interior absorption is good, efficient, low-residual, be difficult for producing the compounded preparation of pesticide of resistance, and complex preparation is combined with fertilizer science and a kind of insecticide fertilizer granule of developing, applied once not only can apply fertilizer but also can kill on sugarcane field and soil insect in agricultural production, overcome that user under the prior art condition wants twice or the way of use of insecticide and fertilizer repeatedly, saved time and artificial.
Agriculture chemical compounding mixture of the present invention comprises clothianidin, desinsection list, can also comprise auxiliary material.
Agriculture chemical compounding mixture of the present invention, take this mixture as benchmark, the weight percentage of clothianidin and desinsection list is 21～65%, and wherein the weight proportion of clothianidin and desinsection list is 1: 4 to 1: 24, and all the other are auxiliary material.
In insecticide fertilizer of the present invention, agriculture chemical compounding mixture weight percentage composition is 10%～95%, and the weight of fertilizer percentage composition is 5%～90%.
In insecticide fertilizer of the present invention, take the fertile gross weight of medicine as benchmark, the weight percentage of clothianidin is 0.01%～1%, and the weight percentage of desinsection list is for being 0.1%～5.0%.
Auxiliary material described in agriculture chemical compounding mixture of the present invention is two or more in inert filler, adhesive and dispersant.
Fertilizer of the present invention is one or more in nitrogenous fertilizer, phosphate fertilizer, potash fertilizer, composite fertilizer, moderate-element fertilizer, trace element fertilizer, alga fertilizer, humic acid fertilizer, amino acid fertilizer.
Inert filler of the present invention be silica sand, diatomite, bentonite, kaolin, attapulgite, clay, white carbon, precipitated calcium carbonate, talcum powder and zeolite one or more.
Adhesive of the present invention be in cellulose and modifier, starch and modifier thereof, rosin and modifier thereof, paraffin and modifier thereof, natural plant gum, animal glue, sulphur, pitch, polyvinyl alcohol, polyvinyl acetate, gypsum and sodium silicate one or more.
Dispersant of the present invention is one or more in lauryl sodium sulfate, lauryl alcohol sodium sulphate, dodecyl sulphate calcium, neopelex, sodium butylnaphthalenesulfonate, sodium lignin sulfonate, sodium methylene bis-naphthalene sulfonate, calcium lignosulfonate, polyethers ichthyodin, fatty alcohol-polyoxyethylene ether sodium sulfonate, alkanolamide sodium sulfonate of ethoxylated.
The production method of agriculture chemical compounding mixture of the present invention: after clothianidin, desinsection list and auxiliary material are weighed, mix and obtain product.
The production method of insecticide fertilizer of the present invention is weighed agriculture chemical compounding mixture and fertilizer, adopts one or more in extruder grain, rolling granulation, coating pelletizing technique, obtains pesticide-fertilizer product.
Agriculture chemical compounding mixture of the present invention and insecticide fertilizer can be prevented and treated the Sugarcane Pests such as sugarcane borer, sugar cane cottony aphid, Sugarcane Thrips, sugarcane tortoise, sugarcane root prionid.
Agriculture chemical compounding mixture and insecticide fertilizer of the present invention can use separately, also are used in conjunction with other agricultural chemicals or fertilizer according to actual needs.
The present invention has following remarkable result:
(1) clothianidin and desinsection list is composite, mutually have synergistic effect, not only kept the plurality of advantages of former agricultural chemicals single dose, but also made each component in mixture in the situation that activity is not lost the working concentration reduction, thereby the activity of mixture is increased.
(2) clothianidin and desinsection list is composite, make insect be difficult to eliminate simultaneously two kinds of mode of action different insecticides to its impact, delay that in insect colony, pesticide resistance is individual produces.
(3) clothianidin and desinsection list is composite, can enlarge insecticidal spectrum, make product can prevent and treat simultaneously multiple Sugarcane Pests.
(4) the present invention is a kind of fertile preparation of medicine of efficiently killing soil insect.Clothianidin and desinsection Dan Jun have good interior suction conductivity, be easy to be transmitted to by the Root Absorption of sugarcane plant each position, thereby the insect of cause harm sugarcane acrial part and under ground portion is all played killing action.
(5) the fertile preparation of a kind of medicine developed by the combination of sciences of insecticide and fertilizer of the present invention, alleviated peasant's labour intensity and work number of times, and the production that reduces the peasant drops into, and also positive facilitation is also played in the increasing both production and income of agricultural simultaneously.
Embodiment
Following examples only play the effect that is described further to the present invention, those skilled in the art the present invention is carried out other replace and revise all within protection scope of the present invention.In following embodiment, the each component proportioning all is weight percentage.
Embodiment 1 (3.6% clothianidin desinsection list fertilizer granules)
Clothianidin 0.15%, desinsection list 3.45%, fertilizer is trace element fertilizer, comprise trbasic zinc phosphate, copper sulphate, iron sulfate, manganese sulphate, boric acid, sodium tetraborate, ammonium molybdate, wherein zinc content 0.4%, copper content 0.4%, iron content 0.2%, manganese content 0.4%, boron content 0.5%, molybdenum content 0.1%, starch sulfate 10%, neopelex 5%, sodium lignin sulfonate 5%, surplus are diatomite.Clothianidin, desinsection list, neopelex, sodium lignin sulfonate and diatomite with the abundant efflorescence of cracker and mix, are formed certain density pesticide activity component premix.Trbasic zinc phosphate, copper sulphate, iron sulfate, manganese sulphate, boric acid, sodium tetraborate, ammonium molybdate and diatomite with the abundant efflorescence of cracker and mix, are formed certain density trace element fertilizer premix.Starch sulfate and water were mixed fully gelatinization under 80 ℃ by weight 1: 2.Add together with starch sulfate after gelatinization after pesticide activity component premix, trace element fertilizer premix are fully mixed and make the fertile particle of medicine in Squeezinggranulator, after drying, cooling, screening, check, carry out finished product packing.
Embodiment 2 (5.4% clothianidin desinsection list fertilizer granules)
Clothianidin 0.6%, desinsection list 4.8%, fertilizer is trace element fertilizer, comprise zinc sulphate, trbasic zinc phosphate, manganese sulphate, boric acid, sodium tetraborate, ammonium molybdate, wherein zinc content 0.2%, boron content 0.6%, manganese content 0.2%, molybdenum content 0.2%, dodecyl sulphate calcium 4%, calcium lignosulfonate 5%, surplus is attapulgite.Clothianidin, desinsection list, zinc sulphate, trbasic zinc phosphate, manganese sulphate, boric acid, sodium tetraborate, ammonium molybdate, dodecyl sulphate calcium, calcium lignosulfonate and attapulgite with the abundant efflorescence of cracker and mix, are formed the fertile premix of medicine.The fertile premix of medicine is added together with appropriate water make the fertile particle of medicine in granulating disc, after drying, cooling, screening, check, carry out finished product packing.
Embodiment 3 (6% clothianidin desinsection list fertilizer granules)
Clothianidin 1.0%, desinsection list 5.0%, talcum powder 4%, gum Arabic 10%, lauryl alcohol sodium sulphate 3%, sodium butylnaphthalenesulfonate 6%, surplus is potassium fulvate.Clothianidin, desinsection list, potassium fulvate, lauryl alcohol sodium sulphate, sodium butylnaphthalenesulfonate and talcum powder with the abundant efflorescence of cracker and mix, are formed the fertile premix of medicine.Gum Arabic and water were mixed fully dissolving under 80 ℃ by weight 1: 2.The fertile premix of medicine is added together with gum Arabic after dissolving make the fertile particle of medicine in Squeezinggranulator, after drying, cooling, screening, check, carry out finished product packing.
Embodiment 4 (0.36% clothianidin desinsection list fertilizer granules)
Clothianidin 0.02%, desinsection 10.34 %, kaolin 2.64%, ammonium sulfate 18%, urea 28%, potassium sulphate 18%, superphosphate 18%, paraffin 8%, dodecyl sulphate calcium 2%, calcium lignosulfonate 5%.Clothianidin, desinsection list, kaolin, ammonium sulfate, urea, potassium sulphate, superphosphate, dodecyl sulphate calcium and calcium lignosulfonate are pulverized and mixed, drop into and make the fertile particle of medicine in roller pelletizer, with the paraffin dressing of melting.To be cooled, the screening, the check after carry out finished product packing.
Embodiment 5 (0.45% clothianidin desinsection list fertilizer granules)
Clothianidin 0.05%, desinsection list 0.4%, zeolite 2.48%, sulphur 7%, alkanolamide sodium sulfonate of ethoxylated 2%, surplus is urea.First clothianidin, the alone zeolite adsorption of desinsection, then add urea and alkanolamide sodium sulfonate of ethoxylated to pulverize and mix, drop into and make the fertile particle of medicine in roller pelletizer, with the sulphur dressing of melting.To be cooled, the screening, the check after carry out finished product packing.
Embodiment 6 (0.52% clothianidin desinsection list fertilizer granules)
Clothianidin 0.04%, desinsection list 0.48%, white carbon 5.48%, urea 20%, rosin 8%, sodium butylnaphthalenesulfonate 2%, fatty alcohol-polyoxyethylene ether sodium sulfonate 4%, surplus is alga fertilizer.First clothianidin, the alone white carbon of desinsection are adsorbed, then add urea, lauryl sodium sulfate, polyethers ichthyodin and alga fertilizer to pulverize and mix, drop into and make the fertile particle of medicine in granulating disc, with the rosin dressing of melting.To be cooled, the screening, the check after carry out finished product packing.
Embodiment 7 (0.69% clothianidin desinsection list fertilizer granules)
Clothianidin 0.03%, desinsection list 0.66%, perlite 7%, fused calcium magnesium phosphate 10%, urea 30%, rosin 12%, lauryl sodium sulfate 3%, polyethers ichthyodin 3%, surplus is amino acid fertilizer.First clothianidin, the alone perlite of desinsection are adsorbed, then add successively fused calcium magnesium phosphate, amino acid fertilizer, urea, lauryl sodium sulfate, polyethers ichthyodin to pulverize and mix, drop into and make the fertile particle of medicine in granulating disc, with the rosin dressing of melting.To be cooled, the screening, the check after carry out finished product packing.
Embodiment 8 (0.84% clothianidin desinsection list fertilizer granules)
Clothianidin 0.04%, desinsection list 0.8%, bentonite 6.16%, fused calcium magnesium phosphate 20%, urea 20%, potassium sulphate 20%, humic acid 18%, rosin 10%, lauryl sodium sulfate 2%, fatty alcohol-polyoxyethylene ether sodium sulfonate 3%.First clothianidin, the alone bentonite absorption of desinsection; add successively again fused calcium magnesium phosphate, urea, potassium sulphate, humic acid, lauryl sodium sulfate and fatty alcohol-polyoxyethylene ether sodium sulfonate to pulverize and mix; drop into and make the fertile particle of medicine in granulating disc, with the rosin dressing of melting.To be cooled, the screening, the check after carry out finished product packing.
Embodiment 9 (21% clothianidin desinsection list wetting powder)
Clothianidin 4%, desinsection list 17%, sodium lignin sulfonate 7%, sodium methylene bis-naphthalene sulfonate 3%, surplus is talcum powder.Clothianidin, desinsection list, sodium lignin sulfonate, sodium methylene bis-naphthalene sulfonate and talcum powder are mixed, then the material after mixing adds and be crushed to fineness in airslide disintegrating mill and reach 325 orders, carry out after the assay was approved finished product packing.
Embodiment 10 (36% clothianidin desinsection list wetting powder)
Clothianidin 1.5%, desinsection list 34.5%, lauryl sodium sulfate 5%, polyethers ichthyodin 4%, surplus is kaolin.Clothianidin, desinsection list, lauryl sodium sulfate, polyethers ichthyodin and kaolin are mixed, then the material after mixing adds and be crushed to fineness in airslide disintegrating mill and reach 325 orders, carry out after the assay was approved finished product packing.
Embodiment 11 (51% clothianidin desinsection list wetting powder)
Clothianidin 3%, desinsection list 48%, alkanolamide sodium sulfonate of ethoxylated 7%, calcium lignosulfonate 3%, surplus is attapulgite.Clothianidin, desinsection list, alkanolamide sodium sulfonate of ethoxylated, calcium lignosulfonate and attapulgite are mixed, then the material after mixing adds and be crushed to fineness in airslide disintegrating mill and reach 325 orders, carry out after the assay was approved finished product packing.
Embodiment 12 (65% clothianidin desinsection list wetting powder)
Clothianidin 5%, desinsection list 60%, lauryl sodium sulfate 5%, sodium butylnaphthalenesulfonate 7%, surplus is bentonite.Clothianidin, desinsection list, lauryl sodium sulfate, sodium butylnaphthalenesulfonate and bentonite are mixed, then the material after mixing adds and be crushed to fineness in airslide disintegrating mill and reach 325 orders, carry out after the assay was approved finished product packing.
Embodiment 13 (the composite Toxicity Determination to sugar cane cottony aphid of desinsection list and anabasine insecticide)
with sugar cane cottony aphid Ceratovacuna lanigera 3 age nymph as target, pass through indoor biometrics, clear and definite desinsection list and clothianidin, Diacloden Thiamethoxam, thiacloprid Thiacloprid, Imidacloprid Imidacloprid, Acetamiprid Acetamiprid, Nitenpyram Nitenpyram, synergy situation after several anabasine insecticides such as MTI-446 Dinotefuran are composite, test method is with reference to farm-chemical indoor determination test rule NYT1154.4-2006 and NYT1154.7-2006, every processing repeats for 4 times, 15 examination worms of every repetition, be not treated to blank if do not contain medicament.Calculate co-toxicity coefficient according to the Sun-Johnson method, carry out synegism evaluation according to co-toxicity coefficient, if co-toxicity coefficient＞120 are synergistic effect, if 120 〉=co-toxicity coefficient＞80 are summation action, if co-toxicity coefficient≤80 are antagonism, the results are shown in Table 1.
The composite co-toxicity coefficient to sugar cane cottony aphid of table 1 desinsection list and anabasine insecticide
Desinsection list and several anabasine insecticide are composite as seen from the table, each proportioning of mixture to the co-toxicity coefficient of sugar cane cottony aphid all greater than more than 80, antagonism does not appear, illustrate desinsection list and anabasine insecticide composite be feasible.Compare with other combination, when desinsection list and clothianidin are composite, co-toxicity coefficient is higher, when the desinsection list: during clothianidin＞1: 4, synergistic effect, wherein desinsection list are arranged: all greater than 200, make up apparently higher than other by synergistic effect at 24: 1～16: 1 o'clock co-toxicity coefficients for clothianidin.
Embodiment 14 (the composite Toxicity Determination to sugar cane cottony aphid of clothianidin and sandworm toxin insecticide)
On the basis of embodiment 13, take clothianidin as main reagent agent, still with sugar cane cottony aphid 3 age nymph as target, by indoor biometrics, the synergy situation after several sandworm toxin insecticides such as clear and definite clothianidin and desinsection list, dimehypo Bisultap, cartap Cartap, thiocyclam Thiocyclam, bensultap Bensultap are composite.Test method and synegism evaluation the results are shown in Table 2 with embodiment 13.
Table 2 clothianidin and sandworm toxin insecticide composite to sugar cane cottony aphid its malicious coefficient
Clothianidin and sandworm toxin insecticide are composite as seen from the table, each proportioning of mixture to the co-toxicity coefficient of sugar cane cottony aphid all greater than more than 80, antagonism does not appear, illustrate clothianidin and neires toxin several pesticides composite be feasible.Other combination is compared, when clothianidin and desinsection list are composite, co-toxicity coefficient is higher, when clothianidin: during desinsection monoamine＜4: 1, synergistic effect, wherein clothianidin are arranged all: all greater than 200, make up apparently higher than other by synergistic effect at 1: 12～1: 24 o'clock co-toxicity coefficient for the desinsection monoamine.
Embodiment 15 (the composite Toxicity Determination to several Sugarcane Pests of clothianidin and desinsection list)
By indoor biometrics, the composite rear synergy situation to several sugarcane primary pests of clear and definite clothianidin and desinsection list.Effective object according to clothianidin and desinsection list, fall into the adult of 2 instar larvaes of line dark fund tortoise plastron Alissonotum impressicolle and sugarcane root prionid Dorysthenes granulosus and sugarcane abdomen tooth thrips Fulmekiola serratus as target with chilo infuscatellus Chilotraea influscatellus, sugarcane, test clothianidin and the desinsection list mixture virulence to the examination worm, test method and synegism evaluation the results are shown in Table 3 with embodiment 13.
The composite co-toxicity coefficient to chilo infuscatellus, prominent back of the body sugarcane tortoise, sugar cane cottony aphid and sugarcane root prionid of table 3 clothianidin and desinsection list
Composite each proportioning of clothianidin and desinsection list falls into the co-toxicity coefficient of line dark fund tortoise plastron, sugarcane abdomen tooth thrips and these several sugarcane primary pests of sugarcane root prionid all greater than 120 to chilo infuscatellus, sugarcane as seen from the table, synergistic effect is arranged, illustrate mixture to the inhibitory action of examination worm higher than clothianidin in mixture and the desinsection only desired value of effect only, so clothianidin and the desinsection list composite be feasible.
Embodiment 16 (field medicine effect test of the sugarcane insecticide fertilizer of clothianidin-containing and desinsection list and manure trial)
Embodiment 1～4 and the prepared product of embodiment 6 are carried out field medicine effect test and manure trial.Test method and effect assessment are with reference to pesticide field efficacy medicine test criterion GB/T 17980.61-2004, GB/T 17980.62-2004 and GB/T 17980.63-2004.Wherein preventing and kill off the field experiment of sugarcane borer (sociales are chilo infuscatellus), sugarcane woolly aphid, Sugarcane Thrips (sociales are sugarcane abdomen tooth thrips) carries out at Wuming County doube bridge town, Guangxi sugarcane field; Preventing and kill off the field experiment of sugarcane tortoise (sociales are that sugarcane falls into line dark fund tortoise plastron) carries out at the little Pingyang of Laibin city of Guangxi town sugarcane field; Preventing and kill off the field experiment of sugarcane root prionid carries out at Wa Tang town, Guigang, Guangxi sugarcane field.After off-test, the sugarcane yield of each test region of statistics, average and survey product.Test minute following processing the: 1. with the prepared product of embodiment 1 (i.e. 3.6% clothianidin desinsection list fertilizer granules) and 50kg composite fertilizer (N content 18%, P
2O
5Content 10%, K
2O content is 12%, Hereinafter the same) mixes to apply as base manure afterwards; 2. mix with the prepared product of embodiment 2 (i.e. 5.4% clothianidin desinsection list fertilizer granules) and 50kg composite fertilizer and apply as base manure afterwards; 3. mix with the prepared product of embodiment 3 (i.e. 6% clothianidin desinsection list fertilizer granules) and 50kg composite fertilizer and apply as base manure afterwards; 4. directly apply as base manure with the prepared product of embodiment 4 (i.e. 0.36% clothianidin desinsection list fertilizer granules), use 50kg for every mu.5. directly apply as base manure with the prepared product of embodiment 6 (i.e. 0.52% clothianidin desinsection list fertilizer granules), use 35kg for every mu.6. mix with the prepared product of embodiment 9 (i.e. 21% clothianidin desinsection list wetting powder) and 50kg composite fertilizer and apply as base manure afterwards; 7. mix with the prepared product of embodiment 10 (i.e. 36% clothianidin desinsection list wetting powder) and 50kg composite fertilizer and apply as base manure afterwards; 8. mix with the prepared product of embodiment 11 (i.e. 51% clothianidin desinsection list wetting powder) and 50kg composite fertilizer and apply as base manure afterwards; 9. mix with the prepared product of embodiment 12 (i.e. 65% clothianidin desinsection list wetting powder) and 50kg composite fertilizer and apply as base manure afterwards; The contrast insecticide is 3.6% clothianidin granule, 3.6% granular insecticide and 5% carbofuran granule, will contrast respectively insecticide and 50kg composite fertilizer during use and mix and apply as base manure afterwards.Above each processed and established equal 3 repetitions, and every repetitive administration area is 1 mu, and every mu of pesticide activity component is 0.18kg (pure).Remaining farming operation is carried out routinely.Result of the test such as table 4.
Land for growing field crops drug effect and the fertilizer efficiency (2011 year) of table 4 test medicine to several Sugarcane Pests
Field application test result in different sugarcanes districts shows, as base manure apply product of the present invention to the control efficiency of sugarcane borer, sugarcane tortoise, sugar cane cottony aphid, Sugarcane Thrips and sugarcane root prionid all over 81%, under same concentrations, its drug effect is all good than using separately clothianidin, desinsection list and carbofuran granule.After the fertile processing of medicine of the present invention, sugarcane yield also is better than respectively contrasting insecticide+composite fertilizer's processing.Compare with the blank processing of also not executing insecticide of not applying fertilizer, sugarcane yield all increases substantially, and volume increase is all over 42%.
Embodiment 17 (field medicine effect test of the sugarcane insecticide fertilizer of clothianidin-containing and desinsection list and manure trial)
Embodiment 5, embodiment 7 and the prepared product of embodiment 8 are carried out field medicine effect test and manure trial.Test method and effect assessment are with reference to pesticide field efficacy medicine test criterion GB/T 17980.61-2004 and GB/T17980.62-2004.Test is carried out at Wuming County Xian Hu town, Guangxi sugarcane field, and primary pest is sugarcane borer (sociales are chilo infuscatellus), sugarcane woolly aphid, Sugarcane Thrips (sociales are sugarcane abdomen tooth thrips).After off-test, the sugarcane yield of each test region of statistics, average and survey product.Test minute following processing the: 1. apply as topdressing when the large ridging of sugarcane with the prepared product of embodiment 5 (i.e. 0.45% clothianidin desinsection list fertilizer granules); 2. apply as topdressing when the large ridging of sugarcane with the prepared product of embodiment 7 (i.e. 0.69% clothianidin-desinsection list fertilizer granules); 3. apply as topdressing when the large ridging of sugarcane with the prepared product of embodiment 8 (i.e. 0.84% clothianidin desinsection list fertilizer granules).The contrast insecticide is 3.6% clothianidin granule, 3.6% granular insecticide and 5% carbofuran granule, will contrast respectively during use insecticide and 50kg composite fertilizer mix rear equally when the large ridging of sugarcane the conduct fertilizer that topdresses apply.Above each processed and established equal 3 repetitions, and every repetitive administration area is 1 mu, and every mu of pesticide activity component is 0.18kg (pure).Remaining farming operation is carried out routinely.Result of the test such as table 5.
Land for growing field crops drug effect and the fertilizer efficiency (2011 year) of table 5 test medicine to several Sugarcane Pests
Field application test result shows, sugarcane large when ridging apply as topdressing embodiment 5, embodiment 7 and the prepared pesticide-fertilizer product of embodiment 8 to the control efficiency of sugarcane borer, sugar cane cottony aphid and Sugarcane Thrips all over 83%, under same concentrations, its drug effect is all good than using separately clothianidin, desinsection list and carbofuran granule.After the fertile processing of medicine of the present invention, sugarcane yield also is better than respectively contrasting insecticide+composite fertilizer's processing.Compare with the blank processing of also not executing insecticide of not applying fertilizer, sugarcane yield increases substantially equally, and volume increase is all over 44%.
Sugarcane special medicated fertilizer granule of the present invention is the fertile preparation of compound medicine that the insecticide of employing clothianidin and two kinds of different mechanisms of action of desinsection list processes, said preparation toxicity is low, drug effect is desirable, be one of ideal substitute kind of terbufos, the contour malicious granular pesticide of carbofuran, satisfy simultaneously the field fertilization needs.
Claims (13)
1. an agriculture chemical compounding mixture, comprise clothianidin and desinsection list.
2. agriculture chemical compounding mixture as claimed in claim 1, it is characterized in that: take this mixture as benchmark, the weight percentage of clothianidin and desinsection list is 21～65%, and wherein the weight proportion of clothianidin and desinsection list is 1: 4 to 1: 24, and all the other are auxiliary material.
3. insecticide fertilizer that comprises the described agriculture chemical compounding mixture of claim 1 or 2 is characterized in that: the composite mixture weight percentage composition of the fertile Pesticides of described medicine is 10%～95%, and the weight of fertilizer percentage composition is 5%～90%.
4. insecticide fertilizer as claimed in claim 3 is characterized in that: take the fertile gross weight of medicine as benchmark, the weight percentage of clothianidin is 0.01%～1%, and the weight percentage of desinsection list is for being 0.1%～5.0%.
5. insecticide fertilizer as described in claim 3 or 4, it is characterized in that: contain auxiliary material in described agriculture chemical compounding mixture, auxiliary material is two or more in inert filler, adhesive and dispersant.
6. insecticide fertilizer as described in claim 3 or 4, it is characterized in that: described fertilizer is one or more in nitrogenous fertilizer, phosphate fertilizer, potash fertilizer, composite fertilizer, moderate-element fertilizer, trace element fertilizer, alga fertilizer, humic acid fertilizer, amino acid fertilizer.
7. insecticide fertilizer as claimed in claim 5 is characterized in that: described inert filler be in silica sand, diatomite, bentonite, kaolin, attapulgite, clay, white carbon, precipitated calcium carbonate, talcum powder and zeolite one or more.
8. insecticide fertilizer as claimed in claim 5 is characterized in that: described adhesive be in cellulose and modifier, starch and modifier thereof, rosin and modifier thereof, paraffin and modifier thereof, natural plant gum, animal glue, sulphur, pitch, polyvinyl alcohol, polyvinyl acetate, gypsum and sodium silicate one or more.
9. insecticide fertilizer as claimed in claim 5, it is characterized in that: described dispersant is one or more in lauryl sodium sulfate, lauryl alcohol sodium sulphate, dodecyl sulphate calcium, neopelex, sodium butylnaphthalenesulfonate, sodium lignin sulfonate, sodium methylene bis-naphthalene sulfonate, calcium lignosulfonate, polyethers ichthyodin, fatty alcohol-polyoxyethylene ether sodium sulfonate, alkanolamide sodium sulfonate of ethoxylated.
10. the production method of agriculture chemical compounding mixture as claimed in claim 1 or 2, is characterized in that, after clothianidin, desinsection list and auxiliary material are weighed, mixes and obtain product.
11. the purposes of agriculture chemical compounding mixture as claimed in claim 1 or 2 aspect the agricultural chemicals that is used for control sugarcane borer, sugar cane cottony aphid, Sugarcane Thrips, sugarcane tortoise and sugarcane root prionid.
12. the production method as the described insecticide fertilizer of claim 2-9, it is characterized in that, agriculture chemical compounding mixture and fertilizer are weighed, comprise in case of necessity other auxiliary material, adopt one or more in extruder grain, rolling granulation, coating pelletizing technique, obtain the granule product.
13. insecticide fertilizer as described in claim 3-9 is in the purposes aspect the agricultural chemicals of control sugarcane borer, sugar cane cottony aphid, Sugarcane Thrips, sugarcane tortoise and sugarcane root prionid.
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| CN103708978A (en) * | 2013-12-25 | 2014-04-09 | 广西农战士高工效农业技术有限公司 | Mixed slow controlled-release fertilizer of organic and inorganic pesticides |
| CN103708978B (en) * | 2013-12-25 | 2016-07-13 | 广西农战士高工效农业技术有限公司 | A kind of organic-inorganic pestsides synthesis sustained-controll-release fertiliser |
| CN104041509A (en) * | 2014-04-30 | 2014-09-17 | 北海市农业科学研究所 | Fertilizer mixing medicament for control of corn pests and application thereof |
| CN104151088A (en) * | 2014-09-02 | 2014-11-19 | 联保作物科技有限公司 | Pesticide fertilizer slow release preparation, as well as preparation method and application method thereof |
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| CN104151088B (en) * | 2014-09-02 | 2016-12-07 | 联保作物科技有限公司 | A kind of medicine fertilizer slow-release preparation, its preparation method and application process |
| CN105384502A (en) * | 2015-11-10 | 2016-03-09 | 无锡市路华肥料科技有限公司 | Fertilizer for preventing cotton aphids |
| CN105777406A (en) * | 2016-05-25 | 2016-07-20 | 广西金穗农药有限公司 | Pesticide and fertilizer mixture containing clothianidin |
| CN107827624A (en) * | 2017-12-20 | 2018-03-23 | 青岛住商中农肥料有限公司 | A kind of Synergistic slow release urea and its preparation technology |
| CN110577432A (en) * | 2018-06-09 | 2019-12-17 | 王忠厚 | Formula of water-soluble silicon fertilizer taking Chinese herbal medicines as additives |
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| CN112521211A (en) * | 2020-12-04 | 2021-03-19 | 中诚国联（河南）生物科技有限公司 | High-tower pesticide-fertilizer containing dinotefuran and monosultap and application thereof |
| CN112661574A (en) * | 2021-02-04 | 2021-04-16 | 赤天化科技集团有限公司 | High-tower pesticide-fertilizer containing clothianidin and dinotefuran and preparation method thereof |
| CN112956480A (en) * | 2021-02-04 | 2021-06-15 | 四川眉山凯尔化工有限公司 | Pesticide raw material formula |
| CN112707765A (en) * | 2021-02-06 | 2021-04-27 | 广西植保农药厂有限公司 | Lodging-resistant sugarcane pesticide fertilizer |
| CN114304176A (en) * | 2021-12-10 | 2022-04-12 | 赤天化科技集团有限公司 | Insecticidal composition containing monosultap and application thereof |
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