CN103030475B - Sugarcane pesticide fertilizer granule containing thiamethoxam and preparation method thereof - Google Patents
Sugarcane pesticide fertilizer granule containing thiamethoxam and preparation method thereof Download PDFInfo
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Abstract
The invention relates to a sugarcane pesticide fertilizer granule containing thiamethoxam. The sugarcane pesticide fertilizer granule is prepared from an organic fertilizer, an inorganic fertilizer, a pesticide active ingredient, an addition agent and an excipient, wherein the organic fertilizer is prepared from fulvic acid and chitin, and the pesticide active ingredient is prepared from clothianidin and fipronil. The weight percentage of the ingredients of the pesticide fertilizer granule is as follows: 3-12 percent of fulvic acid, 1-3 percent of chitin, 26.91-43.55 percent of inorganic fertilizer, 0.02-0.5 percent of clothianidin, 0.02-0.5 percent of fipronil and 0.5-1 percent of addition agent, and the excipient is complemented until the total weight of the pesticide fertilizer granule is 100 percent. The insecticidal particles and the compound fertilizer particles are respectively pelleted, so that the quality stability of products can be ensured, the sugarcane is prevented from being prejudiced by pests or is less affected by the pests, the yield and the quality of the sugarcane are increased, the use cost is reduced, and the income of farmers is increased.
Description
Technical field
The present invention relates to agricultural chemicals and fertilizer mixed technology field, specifically a kind of sugarcane insecticide fertilizer granular formulation containing Diacloden.
Background technology
Sugarcane is the main raw material of sugaring, meanwhile, or the important source material of light industry, chemical industry and the energy, as used bagasse papermaking, molasses preparing alcohol etc.At present, China's sugarcane acreage exceedes 2,500 ten thousand mu, is mainly distributed in the provinces and regions such as southern Guangxi, Yunnan, Guangdong, Guizhou, Fujian, Hainan, wherein, the cultivated area in Guangxi and output exceed 60% of the whole nation, and sucrose had become the mainstay industry in Guangxi already.
Sugarcane, in process of growth, must absorb various nutritive ingredients from environment, could meet the needs of growth.Outside de-carbon (C), hydrogen (H), oxygen (O) element, also need macroelement nitrogen (N), phosphorus (P
2o
5), potassium (K
2, and moderate-element calcium (Ca), sulphur (S), magnesium (Mg), and trace element manganese (Mn), boron (B), copper (Cu), iron (Fe), zinc (Zn), molybdenum (Mo), chlorine (Cl), silicon (Si) etc. O).Conventionally these elements can absorb and obtain from air, water and soil, but due to the long-term planting of sugarcane, nutritive ingredient in soil runs off in a large number, the needs of farm crop normal growth are difficult to meet, follow and what arrive is that disease and pest is day by day serious, output declines day by day, and having a strong impact on to grow cane is main peasant's income.In the time of cane planting by fertilising to supplement the deficiency of Nutrient Elements in Soil, be to improve the effective means of output.
According to sugarcane production characteristic, the fertilizer that is specially adapted for sugarcane production is called sugarcane special-purpose fertilizer, is generally composite fertilizer.At present, domestic more existing research institutions and enterprise are at research and production sugarcane special-purpose fertilizer.Chinese patent 200710066326.4 discloses a kind of special compound fertilizer for sugar-cane, and the demand difference according to the different times of sugarcane production to fertilizer is divided into base manure Chemical Mixed Fertilizer and two kinds of the Chemical Mixed Fertilizers of topdressing, and base manure formula is N-P in mass ratio
2o
5-K
2o-ZNO:10-10-8-0.5, base manure Chemical Mixed Fertilizer comprises several compositions of urea, fused(calcium magnesium)phosphate, potassium sulfate, zinc sulfate and stopping composition; The formula that topdresses is N-P in mass ratio
2o
5-K
2o:18-6-4, the Chemical Mixed Fertilizer that topdresses comprises urea, general calcium, potassium sulfate and several compositions of stopping composition.Chinese patent 201110413115.X discloses a kind of special sugarcane composite fertilizer and production method thereof, and its raw material comprises inorganic fertilizer, fertilizer, aminoacids complex, moderate-element and trace element; The weight percent that its each component accounts for sugarcane composite fertilizer gross weight is: inorganic fertilizer 16%～29%, fertilizer 15～30%, aminoacids complex 5%～15%, moderate-element 0.1%～0.5%, trace element 0.03%～0.1%.Chinese patent 200910095151.9 discloses a kind of special compound fertilizer for sugar cane, in composite fertilizer the ratio of nitrogenous, phosphorus, potassium, silicon oxide be 8～12: 8～12: 8～12: 0.15～0.3.
Sugarcane is in planting process, and disease and pest is very large on its growth, yield and quality impact, serious even causes total crop failure.The insect of harm sugarcane is divided into subterranean pest-insect and the large class of ground insect two, subterranean pest-insect comprises chafer, weevil, termite, wireworm, mole cricket, longicorn, cricket etc., the root of main harm sugarcane and sugarcane bud, wherein serious with chafer and weevil harm, the loss maximum causing; Insect comprises the snout moth's larva and the woolly aphid of harm leaf, thrips, leafhopper, plant hopper, mythimna separata, locust etc. that endanger sugarcane stem on the ground, causes sugarcane production bad, quality variation.For the infringement to sugarcane of the various insects that prevent underground and aboveground, conventionally can spread fertilizer over the fields corresponding agricultural chemicals at sugarcane field, selected agricultural chemicals is mostly the granule containing high malicious composition, exists larger potential safety hazard.On the other hand, fertilizer and agricultural chemicals are bought respectively and are used, and not only increase sugarcane grower's cost, also increased workload, and in recent years, the price of labour power constantly rise, and has also strengthened undoubtedly planting cost.
At present, domestic existing research institution and enterprise conduct a research to develop both can provide sugarcane production desired nutritional, can prevent and treat again the agricultural chemicals of Sugarcane Pests and the pesticide-fertilizer product of fertilizer unification.Chinese patent 201110372231.1 discloses a kind of sugarcane fertilizer and production method of preventing and treating subterranean pest-insect, and its raw material comprises inorganic fertilizer, fertilizer, medicament, plant-growth regulator and binding agent; The weight percent that its each component accounts for sugarcane fertilizer gross weight is: inorganic fertilizer 45%～92%, fertilizer 7～50%, medicament 0.25%～3.5%, plant modifying agent 0.04%～0.05%, binding agent 0.075%～3.0%; Described medicament is the combination of Volaton, Chlorpyrifos 94 and Provado or MTI-446, the weight proportion between component: Volaton: Chlorpyrifos 94: Provado or MTI-446 are 1～2:1:0.1～4.5; Described plant-growth regulator is sodium nitrophenolate.This invention is added farm chemical ingredients Volaton, Chlorpyrifos 94 and MTI-446 in the middle of fertilizer to, plays medicine, fertile double effects, and saving of work and time can alleviate sugarcane grower's labour intensity to a certain extent.But due to the development of pest resistance, Volaton and Chlorpyrifos 94 preventive effect and the Provado to subterranean pest-insect declines gradually to the preventive effect of ground insect, and the former medicine cost of MTI-446 is higher, the certain difficulty of universal existence in Zhe district.Therefore, one need to be found more efficient, the alternative medicine fertilizer more favourable to sugarcane grower.At present, have no report containing the sugarcane insecticide fertilizer granular formulation of Diacloden and ethiprole.
Summary of the invention
Technical problem to be solved by this invention is for the fertile deficiency existing of above-mentioned existing sugarcane medicine, a kind of sugarcane insecticide fertilizer granular formulation and preparation method containing Diacloden is provided, ensure that sugarcane is not subject to or is subject to less insect to encroach on, improve the yield and quality of sugarcane, reduce use cost, increase the income of peasant household.
The present invention solves the problems of the technologies described above taked technical scheme: a kind of sugarcane insecticide fertilizer granular formulation containing Diacloden, formed by fertilizer, inorganic fertilizer, pesticide active ingredient, auxiliary agent and vehicle, described fertilizer is made up of xanthohumic acid and chitin, described pesticide active ingredient is made up of Diacloden and ethiprole, and the weight percent content of the described each component of fertilizer granules is:
Xanthohumic acid 3～12%;
Chitin 1～3%;
Inorganic fertilizer 26.91～43.55%;
Diacloden 0.02～0.5%;
Ethiprole 0.02～0.5%;
Auxiliary agent 0.5～1%;
Vehicle complements to 100% of fertilizer granules gross weight.
Described inorganic fertilizer is made up of the nutritive element of following weight percent content:
Nitrogen 12～16%;
Phosphorus 5～8%;
Potassium 8～11%;
Sulphur 1～4%;
Calcium 0.5～2.5%;
Magnesium 0.2～1%;
Zinc 0.1～0.5%;
Boron 0.1～0.5%;
Molybdenum 0.01～0.05%.
Described auxiliary agent is sodium lauryl sulphate, calcium lignin sulphonate, sodium lignosulfonate, naphthalenesulfonate formaldehyde condensation compound, sulfonated alkyl naphathalene formaldehyde condensation products or pulls open at least one in powder.
Described vehicle is at least one in starch, polyvinyl alcohol, carboxymethyl cellulose, clay, diatomite, carclazyte, kaolin, wilkinite or calcium carbonate.
The preparation method of the described sugarcane insecticide fertilizer granular formulation containing Diacloden comprises the following steps:
(1) prepare pesticide granules: according to weight part, get 2.5～14.96 parts of 0.02～0.5 part of Diacloden, 0.02～0.5 part of ethiprole, 0.5～1 part of auxiliary agent and vehicle, pulverize, mix, the moistening rear remix that adds water is even, use Squeezinggranulator granulation, obtain the pesticide granules that contains Diacloden and ethiprole after dry, for subsequent use;
(2) prepare compound fertilizer granules: according to weight part, get 3～12 parts of xanthohumic acids, 1～3 part of chitin, 12～16 parts, nitrogen, 5～8 parts, phosphorus, 8～11 parts, potassium, 1～4 part of sulphur, 0.5～2.5 part of calcium, 0.2～1 part, magnesium, 0.1～0.5 part, zinc, 0.1～0.5 part of boron, 0.01～0.05 part of molybdenum and vehicle, the addition of vehicle makes the total weight parts of pesticide granules and compound fertilizer granules reach 100 parts; By got raw material pulverizing, mix, the moistening rear remix that adds water is even, uses Squeezinggranulator granulation, after being dried, obtains compound fertilizer granules, for subsequent use;
(3) in mixing equipment, the compound fertilizer granules of the pesticide granules of step (1) gained and step (2) gained is fully mixed, detect qualified rear packaging, obtain the sugarcane insecticide fertilizer granular formulation containing Diacloden.
In described step (1) and step (2), pulverizing equipment used is micronizer mill, Universalpulverizer or Raymond machine, smashing fineness >=100 order; Described Squeezinggranulator is screw extruder pelletizer; Described adding water is moistening, and amount of water is to pulverize 2～5% of raw material weight; Described is dried as fluidised bed drying or rotary drying;
Described mixing equipment is Agravicmixer or duplex cone-type mixer, and mixing time is 10～30 minutes; The fineness of product is 2mm～5mm, moisture≤3%, expulsion rate≤5%.
Sugarcane insecticide fertilizer granular formulation containing Diacloden of the present invention is applied to subterranean pest-insect and the ground insect of control harm sugarcane, comprise grub, mole cricket, cutworm, sugarcane tortoise, termite, longicorn, snout moth's larva, aphid, thrips, mythimna separata, trialeurodes vaporariorum or locust, compared with prior art, there is following beneficial effect:
(1) the present invention selects Diacloden and ethiprole as the farm chemical ingredients in fertilizer granules, Diacloden is a kind of s-generation nicotinoids high-efficient low toxicity insecticide with brand new, its mechanism of action is in conjunction with the nicotinic acid nAChR ligands that is positioned at insect neural system postsynaptic membrane, disturb pest movements neural system to stimulate normally conduction, insect is had to stomach toxicity, tag and systemic activity, after dispenser, can in plant, be inhaled rapidly and be transmitted to the each position of plant, have efficient, wide spectrum, consumption is few, toxicity is low, the drug effect lasting period is long, to crop without poisoning, use safety and with the advantage of conventional pesticide without cross resistance.Ethiprole is a kind of phenylpyrazole insecticides, for GABA-chloride channel inhibitor, its mechanism of action is to hinder the muriate metabolism of insect γ-aminobutyric acid control, to insect taking stomach poison function as main, have concurrently and tag and systemic action, have advantages of that insecticidal spectrum is wide, insecticidal activity is high, the lasting period is long, method of application is flexible and to crop without poisoning.The present invention, by Diacloden and Firponil compounded, plays synergy, reduces the total consumption of medicament and delays the effect that pest resistance occurs, ensures that sugarcane is not affected or less affected by pest damage, improves output, increases the income at plantation family.
(2) in the present invention according to the growth characteristic of sugarcane, the inorganic fertilizer of combination can provide essential N, P, K, Ca, S, Mg, Zn, B and Mo nutritive element for the normal growth of sugarcane, reaches the effect of stable yields and volume increase.
(3) the fertilizer xanthohumic acid in the present invention and chitin can regulate the physiological function of sugarcane, promote the growth of sugarcane, improve the resistance of sugarcane, thereby make sugarcane production-increasing.
(4) the present invention has desinsection and dedicated fertilizer dual-use function to sugarcane, plantation family is once purchased and uses, can reach the double effects of insect protected and fertilizer, reduce the purchase cost of medicament and fertilizer, reduce the labor capacity of dispenser and fertilising, thereby can significantly reduce costs, be peasant household's additional income.
(5) the desinsection particle in product of the present invention and compound fertilizer granules granulation respectively, be equivalent to farm chemical ingredients and fertilizer respectively in relatively independent environment, compared with granulation process after conventional dose and fertilizer mixing, activeconstituents Diacloden and ethiprole in medicament have more stable physicochemical property, ensure the quality stability of product, thereby extended the shelf lives of medicament.
(6) the present invention adopts extruder grain explained hereafter fertilizer granules, add binding agent, make product of the present invention there is stronger hardness, be difficult for being washed away by the water leaching in soil, reduce the loss of medicament and fertilizer, improved the utilization ratio of medicament and fertilizer, and extend the lasting period of medicament and fertilizer, thereby the consumption and the spraying times that reduce agricultural chemicals, alleviate environmental stress, also reduce the cost at plantation family.
Embodiment
Below taking prepare 100 kilograms of the present invention containing the sugarcane insecticide fertilizer granular formulation of Diacloden as embodiment, the present invention is further described, but do not limit the scope of the invention.Those skilled in the art can prepare corresponding sugarcane insecticide fertilizer granular formulation according to this specification sheets.It should be noted that, the minor modifications of in the art the present invention being done, change the color of product as increased toning material in formula for a product of the present invention, content ratio to active insecticidal components in formula is carried out small adjustment, the each component of fertilizer, auxiliary agent, binding agent kind and content are carried out to less adjustment, and parameter, equipment to preparation technology of the present invention carries out suitably adjusting etc., all do not change essence of the present invention.Outside Special Statement, degree of the present invention is weight percent content.
Embodiment 1
0.04% fluorine Diacloden sugarcane insecticide fertilizer granular formulation formula and preparation method thereof
Formula:
Pesticide granules: Diacloden 0.02kg, ethiprole 0.02kg, calcium lignin sulphonate 0.3kg, sodium lauryl sulphate 0.2kg, polyvinyl alcohol 0.5kg, kaolin 13.96kg;
Compound fertilizer granules: urea 26kg, potassium sulfate 3.75kg, Repone K 3.56kg, dipotassium hydrogen phosphate 9.7kg, double superhosphate 4.29kg, magnesium sulfate heptahydrate 2.03kg, Zinc Sulphate Heptahydrate 0.44kg, borax 0.9kg, ammonium molybdate 0.0204kg, xanthohumic acid 3kg, chitin 1kg, starch 5kg, clay 25.3096kg; Wherein, inorganic fertilizer nutrition composition is configured to: nitrogen (N) 12kg, phosphorus (P
2o
5) 5kg, potassium (K
2o) 8kg, sulphur 1kg, calcium 0.6kg, magnesium 0.2kg, zinc 0.1kg, boron 0.1kg, molybdenum 0.01kg.
Preparation method:
(1) pesticide granules formula is pulverized with micronizer mill, mixed, add water moistening, amount of water is to pulverize 2% of raw material weight, and then mixes, and uses screw extruder pelletizer granulation, after fluidised bed drying, obtain the pesticide granules that contains Diacloden and ethiprole, for subsequent use;
(2) compound fertilizer granules formula is pulverized with micronizer mill, mixed, add water moistening, amount of water is to pulverize 2% of raw material weight, and then mixes, and uses screw extruder pelletizer granulation, after fluidised bed drying, obtain compound fertilizer granules, for subsequent use;
(3) in Agravicmixer, the compound fertilizer granules of the pesticide granules of step (1) gained and step (2) gained is fully mixed 10 minutes, the fineness that detects control product is 2mm～5mm, moisture≤3%, expulsion rate≤5%, detect qualified rear packaging, obtain 0.04% fluorine Diacloden sugarcane insecticide fertilizer granular formulation.
Embodiment 2
0.05% fluorine Diacloden sugarcane insecticide fertilizer granular formulation formula and preparation method thereof
Formula:
Pesticide granules: Diacloden 0.03kg, ethiprole 0.02kg, sodium lignosulfonate 0.3kg, pulls open powder 0.3kg, polyvinyl alcohol 0.5kg, kaolin 3.85kg;
Compound fertilizer granules: urea 26kg, potassium sulfate 3.75kg, Repone K 3.56kg, dipotassium hydrogen phosphate 9.7kg, double superhosphate 4.29kg, magnesium sulfate heptahydrate 2.03kg, Zinc Sulphate Heptahydrate 0.44kg, borax 0.9kg, ammonium molybdate 0.0204kg, xanthohumic acid 12kg, chitin 3kg, starch 5kg, calcium carbonate 10kg, clay 14.3096kg; Wherein, inorganic fertilizer nutrition composition is configured to: nitrogen (N) 12kg, phosphorus (P
2o
5) 5kg, potassium (K
2o) 8kg, sulphur 1kg, calcium 0.6kg, magnesium 0.2kg, zinc 0.1kg, boron 0.1kg, molybdenum 0.01kg.
Preparation method:
(1) pesticide granules formula is pulverized with Universalpulverizer, mixed, add water moistening, amount of water is to pulverize 3% of raw material weight, and then mixes, and uses screw extruder pelletizer granulation, after rotary drying, obtain the pesticide granules that contains Diacloden and ethiprole, for subsequent use;
(2) compound fertilizer granules formula is pulverized with Universalpulverizer, mixed, add water moistening, amount of water is to pulverize 3% of raw material weight, and then mixes, and uses screw extruder pelletizer granulation, obtains compound fertilizer granules after rotary drying, for subsequent use;
(3) in duplex cone-type mixer, the compound fertilizer granules of the pesticide granules of step (1) gained and step (2) gained is fully mixed 15 minutes, the fineness that detects control product is 2mm～5mm, moisture≤3%, expulsion rate≤5%, detect qualified rear packaging, obtain 0.05% fluorine Diacloden sugarcane insecticide fertilizer granular formulation.
Embodiment 3
0.1% fluorine Diacloden sugarcane insecticide fertilizer granular formulation formula and preparation method thereof
Formula:
Pesticide granules: Diacloden 0.04kg, ethiprole 0.06kg, sulfonated alkyl naphathalene formaldehyde condensation products 0.2kg, pulls open powder 0.3kg, polyvinyl alcohol 0.5kg, kaolin 3.9kg;
Compound fertilizer granules: urea 34.78kg, potassium sulfate 7.3kg, Repone K 2.95kg, dipotassium hydrogen phosphate 13.33kg, double superhosphate 8kg, terra alba 5.95kg, magnesium sulfate heptahydrate 10.14kg, Zinc Sulphate Heptahydrate 2.2kg, borax 4.5kg, ammonium molybdate 0.1022kg, xanthohumic acid 3kg, chitin 1kg, carboxymethyl cellulose 1.7478kg; Wherein, inorganic fertilizer nutrition composition is configured to: nitrogen (N) 16kg, phosphorus (P
2o
5) 8kg, potassium (K
2o) 11kg, sulphur 4kg, calcium 2.5kg, magnesium 1kg, zinc 0.5kg, boron 0.5kg, molybdenum 0.05kg.
Preparation method:
(1) pesticide granules formula is pulverized with Raymond machine, mixed, add water moistening, amount of water is to pulverize 5% of raw material weight, and then mixes, and uses screw extruder pelletizer granulation, after fluidised bed drying, obtain the pesticide granules that contains Diacloden and ethiprole, for subsequent use;
(2) compound fertilizer granules formula is pulverized with Raymond machine, mixed, add water moistening, amount of water is to pulverize 5% of raw material weight, and then mixes, and uses screw extruder pelletizer granulation, obtains compound fertilizer granules after fluidised bed drying, for subsequent use;
(3) in duplex cone-type mixer, the compound fertilizer granules of the pesticide granules of step (1) gained and step (2) gained is fully mixed 30 minutes, the fineness that detects control product is 2mm～5mm, moisture≤3%, expulsion rate≤5%, detect qualified rear packaging, obtain 0.1% fluorine Diacloden sugarcane insecticide fertilizer granular formulation.
Continue Preparation Example 4-embodiment 11 according to the preparation method described in embodiment 3.
Embodiment 4
1% fluorine Diacloden sugarcane insecticide fertilizer granular formulation formula
Pesticide granules: Diacloden 0.5kg, ethiprole 0.5kg, naphthalenesulfonate formaldehyde condensation compound 0.6kg, pulls open powder 0.4kg, starch 1kg, kaolin 2kg;
Compound fertilizer granules: urea 34.78kg, potassium sulfate 7.3kg, Repone K 2.95kg, dipotassium hydrogen phosphate 13.33kg, double superhosphate 8kg, terra alba 5.95kg, magnesium sulfate heptahydrate 10.14kg, Zinc Sulphate Heptahydrate 2.2kg, borax 4.5kg, ammonium molybdate 0.1022kg, xanthohumic acid 3kg, chitin 1kg, diatomite 1.7478kg; Wherein, inorganic fertilizer nutrition composition is configured to: nitrogen (N) 16kg, phosphorus (P
2o
5) 8kg, potassium (K
2o) 11kg, sulphur 4kg, calcium 2.5kg, magnesium 1kg, zinc 0.5kg, boron 0.5kg, molybdenum 0.05kg.
Embodiment 5
1% fluorine Diacloden sugarcane insecticide fertilizer granular formulation formula
Pesticide granules: Diacloden 0.5kg, ethiprole 0.5kg, naphthalenesulfonate formaldehyde condensation compound 0.6kg, pulls open powder 0.4kg, starch 1kg, kaolin 2kg;
Compound fertilizer granules: urea 26kg, potassium sulfate 3.75kg, Repone K 3.56kg, dipotassium hydrogen phosphate 9.7kg, double superhosphate 4.29kg, magnesium sulfate heptahydrate 2.03kg, Zinc Sulphate Heptahydrate 0.44kg, borax 0.9kg, ammonium molybdate 0.0204kg, xanthohumic acid 12kg, chitin 3kg, starch 5kg, clay 24.3096kg; Wherein, inorganic fertilizer nutrition composition is configured to: nitrogen (N) 12kg, phosphorus (P
2o
5) 5kg, potassium (K
2o) 8kg, sulphur 1kg, calcium 0.6kg, magnesium 0.2kg, zinc 0.1kg, boron 0.1kg, molybdenum 0.01kg.
Embodiment 6
0.2% fluorine Diacloden sugarcane insecticide fertilizer granular formulation formula
Pesticide granules: Diacloden 0.15kg, ethiprole 0.05kg, naphthalenesulfonate formaldehyde condensation compound 0.4kg, calcium lignin sulphonate 0.5kg, starch 0.8kg, wilkinite 5kg;
Compound fertilizer granules: urea 30.43kg, potassium sulfate 14.8kg, dipotassium hydrogen phosphate 3.8kg, double superhosphate 10.71kg, magnesium sulfate heptahydrate 6.09kg, Zinc Sulphate Heptahydrate 1.76kg, borax 2.65kg, ammonium molybdate 0.0613kg, xanthohumic acid 7kg, chitin 2kg, starch 5kg, carclazyte 8.7987kg; Wherein, inorganic fertilizer nutrition composition is configured to: nitrogen (N) 14kg, phosphorus (P
2o
5) 6.5kg, potassium (K
2o) 9.5kg, sulphur 3.7kg, calcium 1.5kg, magnesium 0.6kg, zinc 0.4kg, boron 0.3kg, molybdenum 0.03kg.
Embodiment 7
0.3% fluorine Diacloden sugarcane insecticide fertilizer granular formulation formula
Pesticide granules: Diacloden 0.2kg, ethiprole 0.1kg, naphthalenesulfonate formaldehyde condensation compound 0.5kg, calcium lignin sulphonate 0.3kg, polyvinyl alcohol 0.7kg, clay 5kg;
Compound fertilizer granules: urea 30.43kg, potassium sulfate 14.8kg, dipotassium hydrogen phosphate 3.8kg, double superhosphate 10.71kg, magnesium sulfate heptahydrate 6.09kg, Zinc Sulphate Heptahydrate 1.76kg, borax 2.65kg, ammonium molybdate 0.0613kg, xanthohumic acid 7kg, chitin 2kg, starch 5kg, clay 8.8987kg; Wherein, inorganic fertilizer nutrition composition is configured to: nitrogen (N) 14kg, phosphorus (P
2o
5) 6.5kg, potassium (K
2o) 9.5kg, sulphur 3.7kg, calcium 1.5kg, magnesium 0.6kg, zinc 0.4kg, boron 0.3kg, molybdenum 0.03kg.
Embodiment 8
0.4% fluorine Diacloden sugarcane insecticide fertilizer granular formulation formula
Pesticide granules: Diacloden 0.25kg, ethiprole 0.15kg, naphthalenesulfonate formaldehyde condensation compound 0.4kg, pulls open powder 0.4kg, polyvinyl alcohol 0.7kg, wilkinite 5kg;
Compound fertilizer granules: urea 30.43kg, potassium sulfate 14.8kg, dipotassium hydrogen phosphate 3.8kg, double superhosphate 10.71kg, magnesium sulfate heptahydrate 6.09kg, Zinc Sulphate Heptahydrate 1.76kg, borax 2.65kg, ammonium molybdate 0.0613kg, xanthohumic acid 7kg, chitin 2kg, starch 5kg, clay 8.7987kg; Wherein, inorganic fertilizer nutrition composition is configured to: nitrogen (N) 14kg, phosphorus (P
2o
5) 6.5kg, potassium (K
2o) 9.5kg, sulphur 3.7kg, calcium 1.5kg, magnesium 0.6kg, zinc 0.4kg, boron 0.3kg, molybdenum 0.03kg.
Embodiment 9
0.5% fluorine Diacloden sugarcane insecticide fertilizer granular formulation formula
Pesticide granules: Diacloden 0.1kg, ethiprole 0.4kg, sulfonated alkyl naphathalene formaldehyde condensation products 0.5kg, calcium lignin sulphonate 0.3kg, carboxymethyl cellulose 0.6kg, wilkinite 6kg;
Compound fertilizer granules: urea 30.43kg, potassium sulfate 14.8kg, dipotassium hydrogen phosphate 3.8kg, double superhosphate 10.71kg, magnesium sulfate heptahydrate 6.09kg, Zinc Sulphate Heptahydrate 1.76kg, borax 2.65kg, ammonium molybdate 0.0613kg, xanthohumic acid 9kg, chitin 2kg, carboxymethyl cellulose 3kg, clay 7.7987kg; Wherein, inorganic fertilizer nutrition composition is configured to: nitrogen (N) 14kg, phosphorus (P
2o
5) 6.5kg, potassium (K
2o) 9.5kg, sulphur 3.7kg, calcium 1.5kg, magnesium 0.6kg, zinc 0.4kg, boron 0.3kg, molybdenum 0.03kg.
Embodiment 10
0.6% fluorine Diacloden sugarcane insecticide fertilizer granular formulation formula
Pesticide granules: Diacloden 0.5kg, ethiprole 0.1kg, sulfonated alkyl naphathalene formaldehyde condensation products 0.3kg, pulls open powder 0.6kg, carboxymethyl cellulose 0.9kg, clay 4.2kg;
Compound fertilizer granules: urea 30.43kg, potassium sulfate 14.8kg, dipotassium hydrogen phosphate 3.8kg, double superhosphate 10.71kg, magnesium sulfate heptahydrate 6.09kg, Zinc Sulphate Heptahydrate 1.76kg, borax 2.65kg, ammonium molybdate 0.0613kg, xanthohumic acid 5kg, chitin 3kg, carboxymethyl cellulose 3kg, clay 12.0987kg; Wherein, inorganic fertilizer nutrition composition is configured to: nitrogen (N) 14kg, phosphorus (P
2o
5) 6.5kg, potassium (K
2o) 9.5kg, sulphur 3.7kg, calcium 1.5kg, magnesium 0.6kg, zinc 0.4kg, boron 0.3kg, molybdenum 0.03kg.
Embodiment 11
0.8% fluorine Diacloden sugarcane insecticide fertilizer granular formulation formula
Pesticide granules: Diacloden 0.5kg, ethiprole 0.3kg, sulfonated alkyl naphathalene formaldehyde condensation products 0.3kg, pulls open powder 0.6kg, carboxymethyl cellulose 0.9kg, clay 4kg;
Compound fertilizer granules: urea 30.43kg, potassium sulfate 14.8kg, dipotassium hydrogen phosphate 3.8kg, double superhosphate 10.71kg, magnesium sulfate heptahydrate 6.09kg, Zinc Sulphate Heptahydrate 1.76kg, borax 2.65kg, ammonium molybdate 0.0613kg, xanthohumic acid 5kg, chitin 3kg, carboxymethyl cellulose 3kg, clay 12.0987kg; Wherein, inorganic fertilizer nutrition composition is configured to: nitrogen (N) 14kg, phosphorus (P
2o
5) 6.5kg, potassium (K
2o) 9.5kg, sulphur 3.7kg, calcium 1.5kg, magnesium 0.6kg, zinc 0.4kg, boron 0.3kg, molybdenum 0.03kg.
Application example
In March, 2011, Heng County, Nanning cane planting carry out Sugarcane Pests control and volume increase field test.Test, according to unified cost budgeting, arranges following processing:
Process 1-and process 11: the fertilizer granules that is respectively above-described embodiment 1-embodiment 11 gained;
Process 12:0.5% ethiprole granule;
Process 13:0.5% Diacloden granule;
Process 14:0.5% fluorine Diacloden granule (ethiprole: Diacloden=0.25:0.25);
Process 15: the fertilizer (xanthohumic acid: chitin=7:2) of xanthohumic acid and chitin mixture;
Process 16: by urea 30.43%, potassium sulfate 14.8%, dipotassium hydrogen phosphate 3.8%, double superhosphate 10.71%, magnesium sulfate heptahydrate 6.09%, Zinc Sulphate Heptahydrate 1.76%, borax 2.65%, ammonium molybdate 0.0613%, starch 5%, clay complements to the composite inorganic fertilizer of 100% component composition;
Except above-mentioned processing, this test is also provided with space management.Process 16 according to unified cost budgeting consumption by processing 1-, in the time that sugarcane is sowed, spread fertilizer over the fields, 3 repetitions are established in each processing, each experimental plot 67m
2, community random alignment.After dispenser 60 days, within 120 days, investigate respectively the Harm of sugarcane sugarcane tortoise and sugarcane moth borer, in the time of results, investigate sugarcane production-increasing situation.Test-results is in table 1.
Table 1: Sugarcane Pests control and volume increase field test results cartogram
As known from Table 1: utilize the present invention to be applied to sugarcane field, compared with alone granular pesticide, good to the prevention effect of sugarcane moth borer and sugarcane tortoise, the lasting period is longer, and compositely there is synergistic function; Compared with alone granular pesticide, alone inorganic fertilizer or alone fertilizer, the present invention is more obvious to the production-increasing function of sugarcane.
Claims (3)
1. the sugarcane insecticide fertilizer granular formulation containing Diacloden, formed by fertilizer, inorganic fertilizer, pesticide active ingredient, auxiliary agent and vehicle, it is characterized in that, described fertilizer is made up of xanthohumic acid and chitin, described pesticide active ingredient is made up of Diacloden and ethiprole, and the weight percent content of the described each component of fertilizer granules is:
Described inorganic fertilizer is made up of the nutritive element of following weight percent content:
Described auxiliary agent is sodium lauryl sulphate, calcium lignin sulphonate, sodium lignosulfonate, naphthalenesulfonate formaldehyde condensation compound, sulfonated alkyl naphathalene formaldehyde condensation products or pulls open at least one in powder;
Described vehicle is at least one in starch, polyvinyl alcohol, carboxymethyl cellulose, clay, diatomite, carclazyte, kaolin, wilkinite or calcium carbonate.
2. a preparation method who is applicable to the sugarcane insecticide fertilizer granular formulation containing Diacloden claimed in claim 1, is characterized in that, comprises the following steps:
(1) prepare pesticide granules: according to weight part, get 2.5～14.96 parts of 0.02～0.5 part of Diacloden, 0.02～0.5 part of ethiprole, 0.5～1 part of auxiliary agent and vehicle, pulverize, mix, the moistening rear remix that adds water is even, use Squeezinggranulator granulation, obtain the pesticide granules that contains Diacloden and ethiprole after dry, for subsequent use;
(2) prepare compound fertilizer granules: according to weight part, get 3～12 parts of xanthohumic acids, 1～3 part of chitin, 12～16 parts, nitrogen, 5～8 parts, phosphorus, 8～11 parts, potassium, 1～4 part of sulphur, 0.5～2.5 part of calcium, 0.2～1 part, magnesium, 0.1～0.5 part, zinc, 0.1～0.5 part of boron, 0.01～0.05 part of molybdenum and vehicle, the addition of vehicle makes the total weight parts of pesticide granules and compound fertilizer granules reach 100 parts; By got raw material pulverizing, mix, the moistening rear remix that adds water is even, uses Squeezinggranulator granulation, after being dried, obtains compound fertilizer granules, for subsequent use;
(3) in mixing equipment, the compound fertilizer granules of the pesticide granules of step (1) gained and step (2) gained is fully mixed, the fineness of testing product is 2mm～5mm, moisture≤3%, the rear packaging of expulsion rate≤5%, obtains the sugarcane insecticide fertilizer granular formulation containing Diacloden.
3. the preparation method of the sugarcane insecticide fertilizer granular formulation containing Diacloden according to claim 2, it is characterized in that, the described pulverizing of step (1) and step (2) is with micronizer mill, Universalpulverizer or Raymond machine, raw material to be pulverized; Described Squeezinggranulator is screw extruder pelletizer; Described adding water is moistening, and amount of water is to pulverize 2～5% of raw material weight; Described is dried as fluidised bed drying or rotary drying; Described mixing refers to and raw material mixed with Agravicmixer or duplex cone-type mixer, and mixing time is 10～30 minutes.
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| CN103360162B (en) * | 2013-07-17 | 2015-08-19 | 广州甘蔗糖业研究所湛江甘蔗研究中心 | A kind of Sugarcane sustained-release granular medicinal fertilizer |
| CN105439758A (en) * | 2014-08-21 | 2016-03-30 | 天津市汇源化学品有限公司 | Novel slow-release granules containing thiamethoxam and preparation method thereof |
| CN104163726A (en) * | 2014-09-02 | 2014-11-26 | 联保作物科技有限公司 | Pesticide fertilizer slow-release preparation, and preparation method and application method thereof |
| CN104322560B (en) * | 2014-09-23 | 2016-10-05 | 林丹凤 | Pesticide synergistic compositions containing Diacloden Yu humic acids |
| CN104262028B (en) * | 2014-10-21 | 2016-08-03 | 叶长东 | A kind of medicine fertilizer composition comprising MTI-446 and/or phoxim |
| CN104609989A (en) * | 2014-12-18 | 2015-05-13 | 广西大学 | A sugarcane special-purpose pesticide fertilizer and a preparing method thereof |
| CN105732219A (en) * | 2016-02-18 | 2016-07-06 | 云南省德宏傣族景颇族自治州甘蔗科学研究所 | Medical fertilizer for preventing and controlling ceratovacuna lanigera zehntner and using method thereof |
| CN113929530A (en) * | 2021-11-24 | 2022-01-14 | 天津市汉邦植物保护剂有限责任公司 | Combination granule containing chlorfenapyr and lufenuron and preparation method and application thereof |
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