CN104322560B - Pesticide synergistic compositions containing Diacloden Yu humic acids - Google Patents
Pesticide synergistic compositions containing Diacloden Yu humic acids Download PDFInfo
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- CN104322560B CN104322560B CN201410488646.9A CN201410488646A CN104322560B CN 104322560 B CN104322560 B CN 104322560B CN 201410488646 A CN201410488646 A CN 201410488646A CN 104322560 B CN104322560 B CN 104322560B
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- diacloden
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- 239000000203 mixture Substances 0.000 title claims abstract description 52
- 239000004021 humic acid Substances 0.000 title claims abstract description 39
- NWWZPOKUUAIXIW-DHZHZOJOSA-N (E)-thiamethoxam Chemical compound [O-][N+](=O)/N=C/1N(C)COCN\1CC1=CN=C(Cl)S1 NWWZPOKUUAIXIW-DHZHZOJOSA-N 0.000 title claims abstract description 38
- 239000000575 pesticide Substances 0.000 title claims abstract description 25
- 230000002195 synergetic effect Effects 0.000 title claims abstract description 13
- FNELVJVBIYMIMC-UHFFFAOYSA-N Ethiprole Chemical compound N1=C(C#N)C(S(=O)CC)=C(N)N1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl FNELVJVBIYMIMC-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000004615 ingredient Substances 0.000 claims abstract description 6
- 230000000694 effects Effects 0.000 claims description 17
- 239000008187 granular material Substances 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims 1
- 235000017060 Arachis glabrata Nutrition 0.000 abstract description 19
- 241001553178 Arachis glabrata Species 0.000 abstract description 19
- 235000010777 Arachis hypogaea Nutrition 0.000 abstract description 19
- 235000018262 Arachis monticola Nutrition 0.000 abstract description 19
- 235000020232 peanut Nutrition 0.000 abstract description 19
- 230000000857 drug effect Effects 0.000 abstract description 8
- 230000002085 persistent effect Effects 0.000 abstract 1
- 235000013399 edible fruits Nutrition 0.000 description 14
- 239000003814 drug Substances 0.000 description 12
- 210000000582 semen Anatomy 0.000 description 10
- 241000238631 Hexapoda Species 0.000 description 8
- 241000607479 Yersinia pestis Species 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 230000002265 prevention Effects 0.000 description 8
- 231100000419 toxicity Toxicity 0.000 description 8
- 230000001988 toxicity Effects 0.000 description 8
- 239000002917 insecticide Substances 0.000 description 7
- 239000002689 soil Substances 0.000 description 6
- 241001465967 Holotrichia diomphalia Species 0.000 description 5
- 238000011835 investigation Methods 0.000 description 5
- 239000005906 Imidacloprid Substances 0.000 description 4
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 4
- 229940056881 imidacloprid Drugs 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- XLNZEKHULJKQBA-UHFFFAOYSA-N terbufos Chemical compound CCOP(=S)(OCC)SCSC(C)(C)C XLNZEKHULJKQBA-UHFFFAOYSA-N 0.000 description 4
- 230000006378 damage Effects 0.000 description 3
- 238000013401 experimental design Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 230000001018 virulence Effects 0.000 description 3
- MTXSIJUGVMTTMU-JTQLQIEISA-N (S)-anabasine Chemical compound N1CCCC[C@H]1C1=CC=CN=C1 MTXSIJUGVMTTMU-JTQLQIEISA-N 0.000 description 2
- 241001414720 Cicadellidae Species 0.000 description 2
- 241001498622 Cixius wagneri Species 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 229930014345 anabasine Natural products 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003337 fertilizer Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- BTCSSZJGUNDROE-UHFFFAOYSA-N gamma-aminobutyric acid Chemical compound NCCCC(O)=O BTCSSZJGUNDROE-UHFFFAOYSA-N 0.000 description 2
- 238000003306 harvesting Methods 0.000 description 2
- 238000010899 nucleation Methods 0.000 description 2
- BULVZWIRKLYCBC-UHFFFAOYSA-N phorate Chemical compound CCOP(=S)(OCC)SCSCC BULVZWIRKLYCBC-UHFFFAOYSA-N 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 238000009331 sowing Methods 0.000 description 2
- 210000002784 stomach Anatomy 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000009885 systemic effect Effects 0.000 description 2
- OGNSCSPNOLGXSM-UHFFFAOYSA-N (+/-)-DABA Natural products NCCC(N)C(O)=O OGNSCSPNOLGXSM-UHFFFAOYSA-N 0.000 description 1
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 description 1
- OEDUIFSDODUDRK-UHFFFAOYSA-N 5-phenyl-1h-pyrazole Chemical compound N1N=CC=C1C1=CC=CC=C1 OEDUIFSDODUDRK-UHFFFAOYSA-N 0.000 description 1
- 241001136249 Agriotes lineatus Species 0.000 description 1
- 241000272525 Anas platyrhynchos Species 0.000 description 1
- 241001600407 Aphis <genus> Species 0.000 description 1
- 208000031872 Body Remains Diseases 0.000 description 1
- 241000254173 Coleoptera Species 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- 241000382353 Pupa Species 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- DUEPRVBVGDRKAG-UHFFFAOYSA-N carbofuran Chemical compound CNC(=O)OC1=CC=CC2=C1OC(C)(C)C2 DUEPRVBVGDRKAG-UHFFFAOYSA-N 0.000 description 1
- 235000019994 cava Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000027326 copulation Effects 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229960003692 gamma aminobutyric acid Drugs 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 238000009335 monocropping Methods 0.000 description 1
- 239000010413 mother solution Substances 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 210000004681 ovum Anatomy 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 239000000447 pesticide residue Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000013268 sustained release Methods 0.000 description 1
- 239000012730 sustained-release form Substances 0.000 description 1
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- 238000010998 test method Methods 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Abstract
The present invention relates to containing Diacloden and humic acids pesticide synergistic compositions, effective ingredient is made up of Diacloden, ethiprole and humic acids, Diacloden percentage by weight in the composition is 0.5%～2.0%, ethiprole percentage by weight in the composition is 0.5～3.0%, and humic acids percentage by weight in the composition is 1.0%～5.0%.The present invention is prevented and treated for peanut grub by Diacloden, ethiprole, the granular pesticide of humic acids mixture, drug effect can be greatly improved, reduce pesticide mu consumption, reduce use cost, extend the persistent period of drug effect, the shortcoming that single dose easily produces resistance can be overcome simultaneously.
Description
Technical field
The present invention relates to a kind of pesticide synergistic compositions, specifically the pesticide synergistic compositions of Diacloden, ethiprole and humic acids.
Background technology
Holotrichia diomphalia Bates is the main subterranean pest-insect of Semen arachidis hypogaeae of causing harm, and seedling stage, harm frequently resulted in the disconnected ridge that is short of seedling, and in period of bearing pods of blooming, gnaws flower
The fruit pin of Radix Rehmanniae lower part, pod, severe one causes ghost, typically can cause the Semen arachidis hypogaeae underproduction 20%～40%, time serious up to
To 70%～80%, even have no harvest.For the preventing and treating of peanut grub, past custom Furadan, thimet, terbufos
Granule contour poison pesticide preparation pesticide-clay mixture spreads fertilizer over the fields, and unreasonable the using of high-toxic pesticide often results in person poultry poisoning, simultaneously pesticide residues ratio
Relatively big, environment and pod are polluted.Therefore, the Ministry of Agriculture announces No. 1586 bulletin, takes high-toxic pesticide to prohibit further
Limit the use of control measures, it is stipulated that from 15 days June in 2011, stopped accepting registration application and the production permit application of thimet, from
On October 31st, 2013 rises, and stops selling and using the medicament containing terbufos composition.Therefore filter out low toxicity, efficiently,
The medicament of the low preventing and treating peanut grub that mu uses cost is particularly important.
Diacloden, chemical name is: 3-(2-chloro-1,3-thiazoles-5-ylmethyl)-5-methyl isophthalic acid, 3,5-oxadiazines-4-base fork (nitre
Base) amine, it is second filial generation anabasine insecticide, the mechanism of action is similar to first generation anabasine insecticides such as imidacloprids, but has
Higher activity.Insect is had stomach toxicity, tag, systemic action, the feature such as speed of action is fast, lasting period length.Currently mainly
For anti-eliminating aphis, plant hopper, leafhopper, the insect of the sucking mouth parts such as aleyrodid.In terms of controlling underground pest, its product is main
Make seed treatment seed dressing, " the Diacloden seed dressing preventing and treating Semen arachidis hypogaeae delivered such as syndrome in Ganyu County Kingsoft town agricultural technology service center
The subterranean pest-insect test of pesticide effectiveness " confirm, 70% Diacloden seed treatment dispersibles powder and mixes Semen arachidis hypogaeae kind and have peanut grub preferably
Control worm the effect of protective yield.
Ethiprole, is Phenylpyrazole insecticides, has stomach toxicity, tags and certain systemic action, main its work of obstruction insecticide
It is the fluoride metabolism hindering insecticide γ-aminobutyric acid to control by mechanism, plant hopper, leafhopper, Lepidoptera, coleoptera larvae are had
The highest insecticidal activity.Currently mainly applying the preventing and treating of sanitary insect pest, the existing relevant report of preventing and treating subterranean pest-insect, such as Shandong
Chen Chunli, Wang Shaomin of province agricultural management cadre academy deliver " 54% imidacloprid ethiprole FS and 60% imidacloprid FS is to flower
The preventing and treating of raw subterranean pest-insect ", indicate and show: use 54% imidacloprid ethiprole FS to Semen arachidis hypogaeae safety in the peanut seeding phase, right
The peanut soil pest such as wireworm, Holotrichia diomphalia Bates has obvious preventive and therapeutic effect, uses 54% imidacloprid ethiprole FS and has significantly guarantor
Fruit effect, can substantially reduce wormed fruit rate, improves peanut pod yield.
Humic acids, is a vegeto-animal remains classes through the transition process formation of microbial decomposition and conversion and a series of nature
Organic substance, is widely present in nature, and there is its existence on soil, waters, coal, shale and earth's surface.Humic acids
Pesticide can be played sustained-release synergistic, slow down decomposition, reduction toxicity, the drug effect that extends, the effect of minimizing consumption, much be tried
Test and put into practice and confirmed.Such as explanation in " humic acids and pesticide attenuation synergistic " that the Feng Yuanqi of China Humic Acid TIA delivers
Humic acids is combined with pesticide, can improve drug effect, extends the drug effect phase (5～7d), and (insecticide reduces consumption 30% to reduce dosage
Left and right, antibacterial consumption reduces about 50%), it is possible to reduce toxic hazard.
At present, the most Diacloden, ethiprole and humic acids are not prevented and treated the relevant of peanut grub as the mixture preparation of effective ingredient
Report, the present invention is compounded with humic acids by Diacloden, ethiprole, and medicament potentiation is obvious, substantially increases prevention effect,
Decrease the amount of application of pesticide, peanut grub is had preferable prevention effect.
Summary of the invention
The technical problem to be solved is, it is provided that a kind of pesticide synergistic compositions, for the preventing and treating of peanut grub, tool
Having prevention effect notable, mu is the lowest, the advantage that amount of application is less.
The present invention solves above-mentioned technical problem and is adopted the technical scheme that: containing Diacloden and humic acids pesticide synergistic compositions, have
Effect composition is made up of Diacloden, ethiprole and humic acids, and Diacloden percentage by weight in the composition is 0.5%～2.0%, fluorine
Worm nitrile percentage by weight in the composition is 0.5～3.0%, and humic acids percentage by weight in the composition is 1.0%～5.0%.
The formulations of pesticide prepared by pesticide synergistic compositions of the present invention are granule.
Pesticide synergistic compositions of the present invention, required adjuvant includes binding agent, wetting agent, slow releasing agent, disintegrating agent, dye
Toner, carrier or other be of value to the material that effective ingredient is stable in the formulation and drug effect plays, be all conventional in pesticidal preparations or
Allowing the various compositions used, be not particularly limited, concrete composition and consumption are determined by test according to recipe requirements.
The invention have the advantages that and useful technique effect, by Diacloden, ethiprole, the granular pesticide of humic acids mixture
Prevent and treat for peanut grub, drug effect can be greatly improved, reduce pesticide mu consumption, reduce use cost, extend continuing of drug effect
Time, the shortcoming that single dose easily produces resistance can be overcome simultaneously.
Detailed description of the invention
Below in conjunction with embodiment to technical scheme and technique effect further instruction, percentage ratio of the present invention is equal
It is weight percentage.
The embodiment of the present invention is the method using Toxicity Determination and field control effectiveness test to combine.The virulence first passing through indoor is surveyed
Fixed, evaluate the potentiation of pharmacy mix according to the co-toxicity coefficient method (CTC) of SunJohnson (1960), calculate common poison system
Number (CTC), the co-toxicity coefficient (CTC) >=120 of built agent shows as potentiation；CTC≤80 show as antagonism；
80 < CTC < 120 show as summation action.On this basis, then carry out field control effectiveness test.
One, indoor joint toxicity measuring test
1, for examination insecticide: the pupa of Holotrichia diomphalia Bates and mature larva pick up from Semen arachidis hypogaeae ground, Nanning suburb, sprout wings into adult in solarium, and copulation is produced
Ovum is in insectary contains the soil of fertilizer, standby after length to 3 instar larvaes.
2, EXPERIMENTAL DESIGN: test with reference to People's Republic of China (PRC) agricultural industry criteria NY/T1154.7-2006, test with Diacloden,
Ethiprole, three kinds of single doses of humic acids are as comparison medicament, containing Diacloden, ethiprole, the mixture of 3 effective ingredient of humic acids
Comparison medicament, mensuration medicament, as measuring medicament, are separately designed six ladders by active constituent content by preparation mixture 1#～mixture 6#
Degree concentration processes, using the space management without medicament as comparison.
Mixture 1#～the Diacloden of mixture 6#, ethiprole, humic acids percentage by weight as follows:
Mixture 1#: Diacloden 0.5%, ethiprole 0.5%, humic acids 2%
Mixture 2#: Diacloden 1.0%, ethiprole 1.5%, humic acids 1.5%
Mixture 3#: Diacloden 1.5%, ethiprole 0.5%, humic acids 3.0%
Mixture 4#: Diacloden 2.0%, ethiprole 0.5%, humic acids 5.0%
Mixture 5#: Diacloden 0.5%, ethiprole 3.0%, humic acids 2.5%
Mixture 6#: Diacloden 0.5%, ethiprole 2.0%, humic acids 1.0%
3, test method: single dose Diacloden, ethiprole, humic acids being prepared as respectively and the mother solution of each mixed agent are diluted to
6 series concentration, are respectively placed in beaker standby, use 10s dip method, draw the examination unnecessary medicinal liquid of worm with filter paper, afterwards examination
Worm is put in insect box and raises, each process 3 repetition, and the examination borer population used by each repetition is 40, arranges blank simultaneously,
After medicine, 72h checks dead borer population, calculates mortality rate and corrected mortality, tries to achieve virulence regression equation and calculate LC50Value.
4, analysis of statistical results:
Table 1 Diacloden, ethiprole and humic acids indoor joint toxicity measuring result of the test statistics
| Medicament | Virulence regression equation | Correlation coefficient | LC50(ppm) | Co-toxicity coefficient |
| Diacloden | Y=1.5494x+3.3846 | 0.9925 | 11.03 | / |
| Ethiprole | Y=1.3434x+2.8116 | 0.9901 | 42.56 | / |
| Humic acids | Y=1.1850x+2.1822 | 0.9923 | 238.68 | / |
| Mixture 1# | Y=1.9163x+2.3367 | 0.9980 | 24.54 | 186.8 |
| Mixture 2# | Y=1.7559x+3.0488 | 0.9889 | 12.92 | 234.2 |
| Mixture 3# | Y=1.8457x+2.6792 | 0.9950 | 18.09 | 172.4 |
| Mixture 4# | Y=1.5773x+3.1785 | 0.9855 | 14.28 | 245.3 |
| Mixture 5# | Y=1.8290x+2.5661 | 0.9918 | 21.42 | 221.8 |
| Mixture 6# | Y=1.6821x+2.8679 | 0.9924 | 18.51 | 195.9 |
Indoor joint toxicity measuring result of the test is as shown in table 1, as known from Table 1, and the co-toxicity coefficient (CTC) >=120 of built agent,
There is obvious potentiation, determine on the basis of built agent has potentiation in Toxicity Determination, carried out field medicine
Effect test.
Two field control effectiveness tests
1 test arrangement and enforcement
1.1 experimental field overview medicaments: test is located at Peanut continuous cropping ground, Xixiangtang District, Nanning City, and ground, experimental plot is smooth, and soil fertility is uniform
Unanimously, preceding crop is Semen arachidis hypogaeae, and this ground Holotrichia diomphalia Bates is laid particular stress on throughout the year.
1.2 EXPERIMENTAL DESIGN: the ratio corresponding to mixture 2# is prepared as 4% Diacloden ethiprole humic acids granule and mixture
The 3.5% Diacloden ethiprole humic acids granule that ratio corresponding to 5# is prepared as is set to experimental group 1 and experimental group 2,
Amount of application is 2.5 kgs/acre.Make with 2% Diacloden granule, 3% ethiprole granule and 5% humic acids granule respectively
For product matched group 1, matched group 2 and matched group 3, amount of application is 5.0 kgs/acre, arranges blank group CK simultaneously.
1.3 test periods: on April 20th, 2013 is sowed, and Furrow sowing during sowing, planting density is 150000 caves/hm2.Little
District's area is 20m2.Being repeated 3 times, random district group arranges, and each community is used corresponding to EXPERIMENTAL DESIGN respectively in seed furrow
Dosage.Climate at seeding time is good, and each community is emerged neatly, and soil moisture content foot, Semen arachidis hypogaeae grows fine.
1.4 index investigation: in the harvesting peanut phase, every community takes middle 2 row respectively, investigates the killed situation of peanut pod, collects
Peanut pod carries out indoor species test, and situation killed to peanut pod carries out classification.O level: pod is completely without killed shape；
I level: pod epidermis has killed vestige；II grade: pod has killed duck eye but kernel is complete；III level: pod has killed
Big hole kernel killed 50%；IV level: pod core the most killed more than 50%.Wherein III and IV grade of killed pod is without any
Eat and commodity value, for loss fruit, be not counted in yield.
Killed fruit rate=Semen arachidis hypogaeae killed fruit number/investigation Semen arachidis hypogaeae total fruit number
Insect pest situation index=Σ (fruit that is injured × this fruit progression of being injured)/(investigation total fruit number × the highest victim stage) × 100%
Prevention effect=(check plot insect pest situation index one treatment region insect pest situation index)/check plot insect pest situation index × 100%
Damage fruit loss rate=(+4 grades of killed fruit numbers of 3 grades of killed fruit numbers)/investigation total fruit number × 100%
2 interpretations of result
From table 2 below investigation statistics table it can be seen that experimental group 1, experimental group 2 have preferable prevention effect to peanut grub, averagely
Prevention effect is 81.28% and 83.63%, the matched group 1 that is used alone than Diacloden, ethiprole, humic acids, matched group 2,
The anti-effect of matched group 3 is notable, demonstrates the mixed agent pair with Diacloden, ethiprole, humic acids as effective ingredient further
Peanut grub has preferable prevention effect.
Table 2 Diacloden, ethiprole, humic acids and the mixed agent prevention effect to peanut soil pest Holotrichia diomphalia Bates
Claims (2)
1. containing Diacloden and humic acids pesticide synergistic compositions, it is characterised in that effective ingredient is planted by Diacloden, ethiprole and corruption
Acid composition, Diacloden percentage by weight in the composition is 0.5%～2.0%, and ethiprole percentage by weight in the composition is
0.5～3.0%, humic acids percentage by weight in the composition is 1.0%～5.0%.
The most according to claim 1 containing Diacloden and humic acids pesticide synergistic compositions, it is characterised in that described pesticide increases
Effect compositions is prepared as granule.
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