CN104322560A - Thiamethoxam and humic acid-containing pesticide synergistic composition - Google Patents
Thiamethoxam and humic acid-containing pesticide synergistic composition Download PDFInfo
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- CN104322560A CN104322560A CN201410488646.9A CN201410488646A CN104322560A CN 104322560 A CN104322560 A CN 104322560A CN 201410488646 A CN201410488646 A CN 201410488646A CN 104322560 A CN104322560 A CN 104322560A
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- humic acid
- diacloden
- ethiprole
- peanut
- thiamethoxam
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- 239000000203 mixture Substances 0.000 title claims abstract description 46
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 title claims abstract description 34
- 239000004021 humic acid Substances 0.000 title claims abstract description 34
- 239000000575 pesticide Substances 0.000 title claims abstract description 21
- 230000002195 synergetic effect Effects 0.000 title claims abstract description 18
- 239000005941 Thiamethoxam Substances 0.000 title abstract 4
- NWWZPOKUUAIXIW-FLIBITNWSA-N thiamethoxam Chemical compound [O-][N+](=O)\N=C/1N(C)COCN\1CC1=CN=C(Cl)S1 NWWZPOKUUAIXIW-FLIBITNWSA-N 0.000 title abstract 4
- 239000008187 granular material Substances 0.000 claims abstract description 9
- NWWZPOKUUAIXIW-DHZHZOJOSA-N (E)-thiamethoxam Chemical compound [O-][N+](=O)/N=C/1N(C)COCN\1CC1=CN=C(Cl)S1 NWWZPOKUUAIXIW-DHZHZOJOSA-N 0.000 claims description 33
- FNELVJVBIYMIMC-UHFFFAOYSA-N Ethiprole Chemical compound N1=C(C#N)C(S(=O)CC)=C(N)N1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl FNELVJVBIYMIMC-UHFFFAOYSA-N 0.000 claims description 30
- 239000004480 active ingredient Substances 0.000 claims description 6
- 239000003864 humus Substances 0.000 claims description 5
- 235000017060 Arachis glabrata Nutrition 0.000 abstract description 31
- 241001553178 Arachis glabrata Species 0.000 abstract description 31
- 235000010777 Arachis hypogaea Nutrition 0.000 abstract description 31
- 235000018262 Arachis monticola Nutrition 0.000 abstract description 31
- 235000020232 peanut Nutrition 0.000 abstract description 31
- 239000003814 drug Substances 0.000 abstract description 13
- 239000003795 chemical substances by application Substances 0.000 abstract description 8
- ZOCSXAVNDGMNBV-UHFFFAOYSA-N 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile Chemical compound NC1=C(S(=O)C(F)(F)F)C(C#N)=NN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl ZOCSXAVNDGMNBV-UHFFFAOYSA-N 0.000 abstract 2
- 239000005899 Fipronil Substances 0.000 abstract 2
- 229940079593 drug Drugs 0.000 abstract 2
- 229940013764 fipronil Drugs 0.000 abstract 2
- 235000013399 edible fruits Nutrition 0.000 description 16
- 241000238631 Hexapoda Species 0.000 description 13
- 241000607479 Yersinia pestis Species 0.000 description 10
- 239000002689 soil Substances 0.000 description 10
- 238000000034 method Methods 0.000 description 9
- 231100000419 toxicity Toxicity 0.000 description 8
- 230000001988 toxicity Effects 0.000 description 8
- 230000000857 drug effect Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000003905 agrochemical Substances 0.000 description 5
- 238000011835 investigation Methods 0.000 description 5
- 239000005906 Imidacloprid Substances 0.000 description 4
- 230000006378 damage Effects 0.000 description 4
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 4
- 229940056881 imidacloprid Drugs 0.000 description 4
- 239000002917 insecticide Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- XLNZEKHULJKQBA-UHFFFAOYSA-N terbufos Chemical compound CCOP(=S)(OCC)SCSC(C)(C)C XLNZEKHULJKQBA-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- MTXSIJUGVMTTMU-JTQLQIEISA-N (S)-anabasine Chemical compound N1CCCC[C@H]1C1=CC=CN=C1 MTXSIJUGVMTTMU-JTQLQIEISA-N 0.000 description 2
- 241001414720 Cicadellidae Species 0.000 description 2
- 241001498622 Cixius wagneri Species 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 229930014345 anabasine Natural products 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000003337 fertilizer Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- BTCSSZJGUNDROE-UHFFFAOYSA-N gamma-aminobutyric acid Chemical compound NCCCC(O)=O BTCSSZJGUNDROE-UHFFFAOYSA-N 0.000 description 2
- 238000003306 harvesting Methods 0.000 description 2
- 230000010534 mechanism of action Effects 0.000 description 2
- 238000010899 nucleation Methods 0.000 description 2
- BULVZWIRKLYCBC-UHFFFAOYSA-N phorate Chemical compound CCOP(=S)(OCC)SCSCC BULVZWIRKLYCBC-UHFFFAOYSA-N 0.000 description 2
- 238000009331 sowing Methods 0.000 description 2
- 210000002784 stomach Anatomy 0.000 description 2
- 238000013268 sustained release Methods 0.000 description 2
- 239000012730 sustained-release form Substances 0.000 description 2
- 230000009885 systemic effect Effects 0.000 description 2
- 230000001018 virulence Effects 0.000 description 2
- OGNSCSPNOLGXSM-UHFFFAOYSA-N (+/-)-DABA Natural products NCCC(N)C(O)=O OGNSCSPNOLGXSM-UHFFFAOYSA-N 0.000 description 1
- OEDUIFSDODUDRK-UHFFFAOYSA-N 5-phenyl-1h-pyrazole Chemical group N1N=CC=C1C1=CC=CC=C1 OEDUIFSDODUDRK-UHFFFAOYSA-N 0.000 description 1
- 241001136249 Agriotes lineatus Species 0.000 description 1
- 241000272525 Anas platyrhynchos Species 0.000 description 1
- 241001600407 Aphis <genus> Species 0.000 description 1
- 208000031872 Body Remains Diseases 0.000 description 1
- DKZLNHQOAWHHDR-UHFFFAOYSA-N ClC=1SC(=CN1)CC1(CC(C(=O)O)=CC(=C1)C)C(=O)O Chemical compound ClC=1SC(=CN1)CC1(CC(C(=O)O)=CC(=C1)C)C(=O)O DKZLNHQOAWHHDR-UHFFFAOYSA-N 0.000 description 1
- 241000254173 Coleoptera Species 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- 241000382353 Pupa Species 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- DUEPRVBVGDRKAG-UHFFFAOYSA-N carbofuran Chemical compound CNC(=O)OC1=CC=CC2=C1OC(C)(C)C2 DUEPRVBVGDRKAG-UHFFFAOYSA-N 0.000 description 1
- 235000019994 cava Nutrition 0.000 description 1
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- 239000003245 coal Substances 0.000 description 1
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- 239000000470 constituent Substances 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 229960003692 gamma aminobutyric acid Drugs 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 231100000225 lethality Toxicity 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
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- 230000004060 metabolic process Effects 0.000 description 1
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- 238000009335 monocropping Methods 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 208000011580 syndromic disease Diseases 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
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- 230000007704 transition Effects 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a thiamethoxam and humic acid-containing pesticide synergistic composition, effective components comprises 0.5% ~ 2% by weight of thiamethoxam, 0.5 ~ 3% by weight of fipronil and 1% ~ 5% by weight of humic acid. The pesticide granule prepared by mixing the thiamethoxam, the fipronil and the humic acid can be used for control of peanut grub, can greatly improve the drug efficacy, reduces pesticide dosage per mu, reduces the use cost, prolongs duration time of drug efficacy, and can overcome the shortcoming that resistance is easy to produce due to a single agent.
Description
Technical field
The present invention relates to a kind of pesticide synergistic composition, specifically the pesticide synergistic composition of Diacloden, ethiprole and humic acid.
Background technology
Grub is the main soil insect of peanut of causing harm, and seedling stage, harm usually caused the disconnected ridge that is short of seedling, and was blooming between pod bearing period, gnaw fruit pin, the pod of peanut under ground portion, severe one causes ghost, generally can cause the peanut underproduction 20% ~ 40%, can 70% ~ 80% be reached time serious, even have no harvest.For the control of peanut grub, the contour malicious pesticide preparation pesticide-clay mixture of past custom Furadan, thimet, terbufos granule spreads fertilizer over the fields, unreasonable the using of high-toxic pesticide usually causes person poultry poisoning, and residue of pesticide are larger simultaneously, pollute environment and pod.Therefore, the Ministry of Agriculture announces No. 1586 bulletin, take to limit further by control measures to high-toxic pesticide, regulation stopped the application for registration and the production permit application that accept thimet from 15 days June in 2011, from 31 days October in 2013, stop the medicament selling and use containing terbufos composition.Therefore filter out low toxicity, the medicament that efficient, mu uses the low control peanut grub of cost is particularly important.
Diacloden, chemical name is: 3-(2-chloro-1,3-thiazole-5-ylmethyl)-5-methyl isophthalic acid, 3,5-oxadiazines-4-base fork (nitro) amine, be second generation anabasine insecticide, the mechanism of action is similar to first generation anabasine insecticides such as Imidacloprids, but has higher activity.To insect, there is stomach toxicity, tag, systemic action, the features such as speed of action is fast, the lasting period is long.Be mainly used at present anti-eliminating aphis, plant hopper, leafhopper, the sucking mouth parts such as aleyrodid insect.In controlling underground pest, its product mainly makes seed treatment seed dressing, " Diacloden seed dressing control peanut soil pest test of pesticide effectiveness " delivered as syndrome in Ganyu County Kingsoft town agricultural technology service center confirms, 70% Diacloden seed treatment dispersibles pulvis and mixes peanut kind and have peanut grub and control worm the effect of protective yield preferably.
Ethiprole, it is Phenylpyrazole insecticides, have stomach toxicity, tag and certain systemic action, main its mechanism of action of insect that hinders is the fluoride metabolism hindering insect γ-aminobutyric acid to control, and has very high insecticidal activity to plant hopper, leafhopper, Lepidoptera, coleoptera larvae.The control of main application sanitary insect pest at present, relevant report is had in the control of soil insect, as the Chen Chunli of Shandong Agricultural Administrators College, " 54% Imidacloprid ethiprole FS and 60% Imidacloprid FS is to the control of peanut soil pest " that Wang Shaomin delivers, indicate and show: use 54% Imidacloprid ethiprole FS to peanut safety in the peanut seeding phase, to wireworm, the peanut soil pests such as grub have obvious preventive and therapeutic effect, use 54% Imidacloprid ethiprole FS and there is significant fruit retention effect, can obviously reduce wormed fruit rate, improve peanut pod output.
The type organic matter that humus is vegeto-animal remains to be formed through microbial decomposition and conversion and a series of natural transition process, is extensively present in occurring in nature, and there is its existence on soil, waters, coal, shale and earth's surface.The effect that humic acid can play sustained-release synergistic to agricultural chemicals, slows down decomposition, reduce toxicity, extend drug effect, reduce consumption, much tested and put into practice confirm.Illustrate in " humic acid and agricultural chemicals attenuation synergistic " that Feng Yuanqi as China Humic Acid TIA delivers that humic acid is combined with agricultural chemicals, drug effect can be improved, extend the drug effect phase (5 ~ 7d), (insecticide reduces consumption about 30% to reduce dosage, bactericide consumption reduces about 50%), and can toxic hazard be reduced.
At present, also not using Diacloden, ethiprole and the humus relevant report as the mixture preparation control peanut grub of active ingredient, the present invention is undertaken composite by Diacloden, ethiprole and humic acid, medicament synergy is obvious, substantially increase control efficiency, decrease the amount of application of agricultural chemicals, have good control efficiency to peanut grub.
Summary of the invention
Technical problem to be solved by this invention is, provides a kind of pesticide synergistic composition, and for the control of peanut grub, have control efficiency remarkable, mu is originally lower, the advantage that amount of application is less.
The present invention solves the problems of the technologies described above taked technical scheme: containing Diacloden and humic acid pesticide synergistic composition, active ingredient is made up of Diacloden, ethiprole and humic acid, Diacloden percentage by weight is in the composition 0.5% ~ 2.0%, ethiprole percentage by weight is in the composition 0.5 ~ 3.0%, and humus percentage by weight is in the composition 1.0% ~ 5.0%.
The formulations of pesticide prepared by pesticide synergistic composition of the present invention are granule.
Pesticide synergistic composition of the present invention, required adjuvant comprise binding agent, wetting agent, sustained release agent, disintegrant, coloring agent, carrier or other be of value to the active ingredient material that plays of stable and drug effect in the formulation, all various compositions that are conventional in pesticidal preparations or permission use, be not particularly limited, concrete composition and consumption are determined by test according to recipe requirements.
The present invention has following advantage and useful technique effect, peanut grub control is used for by the granular pesticide of Diacloden, ethiprole, humic acid mixture, significantly can improve drug effect, reduce agricultural chemicals mu consumption, reduce use cost, extend the duration of drug effect, the shortcoming that single dose easily produces resistance can be overcome simultaneously.
Embodiment
Below in conjunction with embodiment to technical scheme of the present invention and technique effect further instruction, percentage of the present invention is all weight percentage.
The embodiment of the present invention is the method adopting Toxicity Determination and field control effectiveness test to combine.First by indoor toxicity test, the synergistic effect of pharmacy mix is evaluated according to the co-toxicity coefficient method (CTC) of SunJohnson (1960), calculate co-toxicity coefficient (CTC), the co-toxicity coefficient (CTC) >=120 of built agent shows as synergistic effect; CTC≤80 show as antagonism; 80<CTC<120 shows as summation action.On this basis, then carry out field control effectiveness test.
One, indoor joint toxicity measuring test
1, for examination insect: the pupa of grub and mature larva pick up from peanut ground, Nanning suburb, sprout wings into adult in solarium, and mate and oviposit contains in the soil of fertilizer in insectary, for subsequent use after growing to 3 instar larvaes.
2, experimental scheme: test is with reference to People's Republic of China (PRC) agricultural industry criteria NY/T1154.7-2006, test is with Diacloden, ethiprole, humic acid three kinds of single doses medicament in contrast, using the mixture preparation mixture 1# ~ mixture 6# containing Diacloden, ethiprole, humic acid 3 active ingredients as mensuration medicament, contrast medicament, mensuration medicament are designed six gradient concentration process by active constituent content, respectively not contain the space management of medicament in contrast.
The percentage by weight of the Diacloden of mixture 1# ~ mixture 6#, ethiprole, humic acid is as follows:
Mixture 1#: Diacloden 0.5%, ethiprole 0.5%, humic acid 2%
Mixture 2#: Diacloden 1.0%, ethiprole 1.5%, humic acid 1.5%
Mixture 3#: Diacloden 1.5%, ethiprole 0.5%, humic acid 3.0%
Mixture 4#: Diacloden 2.0%, ethiprole 0.5%, humic acid 5.0%
Mixture 5#: Diacloden 0.5%, ethiprole 3.0%, humic acid 2.5%
Mixture 6#: Diacloden 0.5%, ethiprole 2.0%, humic acid 1.0%
3, test method: single dose Diacloden, ethiprole, humic acid are prepared into respectively and the mother liquor of each mixed agent are diluted to 6 series concentration, be placed in beaker respectively for subsequent use, adopt 10s dip method, draw the unnecessary liquid of examination worm with filter paper, afterwards examination worm is put into insect box and raise, each process 3 repetition, each to repeat examination borer population used be 40, and arrange blank, after medicine, 72h checks dead borer population simultaneously, calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC
50value.
4, analysis of statistical results:
The indoor joint toxicity measuring result of the test statistics of table 1 Diacloden, ethiprole and humic acid
| Medicament | Virulence regression equation | Correlation coefficient | LC 50(ppm) | Co-toxicity coefficient |
| Diacloden | y＝1.5494x+3.3846 | 0.9925 | 11.03 | / |
| Ethiprole | y＝1.3434x+2.8116 | 0.9901 | 42.56 | / |
| Humic acid | y＝1.1850x+2.1822 | 0.9923 | 238.68 | / |
| Mixture 1# | y＝1.9163x+2.3367 | 0.9980 | 24.54 | 186.8 |
| Mixture 2# | y＝1.7559x+3.0488 | 0.9889 | 12.92 | 234.2 |
| Mixture 3# | y＝1.8457x+2.6792 | 0.9950 | 18.09 | 172.4 |
| Mixture 4# | y＝1.5773x+3.1785 | 0.9855 | 14.28 | 245.3 |
| Mixture 5# | y＝1.8290x+2.5661 | 0.9918 | 21.42 | 221.8 |
| Mixture 6# | y＝1.6821x+2.8679 | 0.9924 | 18.51 | 195.9 |
Indoor joint toxicity measuring result of the test is as shown in table 1, as known from Table 1, the co-toxicity coefficient (CTC) >=120 of built agent, has obvious synergistic effect, determining built agent in Toxicity Determination has on the basis of synergistic effect, has carried out field control effectiveness test.
Two field control effectiveness tests
1 test arrangement and enforcement
1.1 experimental field overview medicaments: test is located at Peanut continuous cropping ground, Xixiangtang District, Nanning City, and ground, experimental field is smooth, and soil fertility uniformity, preceding crop is peanut, and this ground grub is laid particular stress on throughout the year.
1.2 experimental scheme: the 3.5% Diacloden ethiprole humic acid granule that the ratio ratio corresponding to mixture 2# be prepared into corresponding to 4% Diacloden ethiprole humic acid granule and mixture 5# is prepared into is set to experimental group 1 and experimental group 2, and amount of application is 2.5 kgs/acre.Respectively using 2% Diacloden granule, 3% ethiprole granule and 5% humic acid granule as product control group 1, control group 2 and control group 3, amount of application is 5.0 kgs/acre, arranges blank group CK simultaneously.
1.3 test periods: on April 20th, 2013 is sowed, and Furrow sowing during sowing, planting density is 150000 caves/hm2.Plot area is 20m.Repeat 3 times, random district group arranges, and each community uses the dosage corresponding to experimental scheme respectively in seed furrow.Climate at seeding time is good, and each community is emerged neatly, and soil moisture content foot, peanut grows fine.
1.4 index is investigated: in the harvesting peanut phase, every community gets middle 2 row respectively, the killed situation of investigation peanut pod, collects peanut pod and carries out indoor species test, and carry out classification to the killed situation of peanut pod.O level: pod is complete without killed shape; I level: pod epidermis has killed vestige; II grade: pod has killed duck eye but kernel is complete; III level: pod has killed large hole kernel killed 50%; IV level: pod benevolence all killed more than 50%.Wherein III and IV grade of killed pod is without any edible and commodity value, is loss fruit, is not counted in output.
The killed fruit number/investigation peanut of killed fruit rate=peanut total fruit number
Insect pest situation index=Σ (fruit that is injured × this fruit progression of being injured)/(investigation total fruit number × the highest level of being injured) × 100%
Control efficiency=(check plot insect pest situation index one treatment region insect pest situation index)/check plot insect pest situation index × 100%
Damage fruit loss rate=(3 grades of killed fruit numbers of killed fruit number+4 grades)/investigation total fruit number × 100%
2 interpretations of result
As can be seen from following table 2 investigation statistics table, experimental group 1, experimental group 2 pairs of peanut grubs have good control efficiency, average control efficiency is 81.28% and 83.63%, the anti-Be very effective of the control group 1 be used alone than Diacloden, ethiprole, humic acid, control group 2, control group 3, to demonstrate with Diacloden, ethiprole, humic acid be further active ingredient, and mixed agent has good control efficiency to peanut grub.
Table 2 Diacloden, ethiprole, humus and mixed agent are to the control efficiency of peanut soil pest grub
| Test process | Average killed fruit rate (%) | Average damage fruit rate (%) | Average control efficiency (%) |
| Product experimental group 1 | 18.58 | 9.33 | 81.28 |
| Product experimental group 2 | 16.50 | 8.17 | 83.63 |
| Product control group 1 | 21.83 | 14.08 | 76.24 |
| Product control group 2 | 32.25 | 21.83 | 71.34 |
| Product control group 3 | 47.67 | 27.08 | 52.54 |
| Blank (CK) | 65.75 | 36.33 | / |
Claims (2)
1. containing Diacloden and humic acid pesticide synergistic composition, it is characterized in that, active ingredient is made up of Diacloden, ethiprole and humic acid, Diacloden percentage by weight is in the composition 0.5% ~ 2.0%, ethiprole percentage by weight is in the composition 0.5 ~ 3.0%, and humus percentage by weight is in the composition 1.0% ~ 5.0%.
2. according to claim 1 containing Diacloden and humic acid pesticide synergistic composition, it is characterized in that, described pesticide synergistic composition is prepared into granule.
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| CN108707038A (en) * | 2018-08-17 | 2018-10-26 | 湖州常华苗木有限公司 | A kind of stock growing special fertilizer and preparation method thereof |
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| 廖伟萍等: "锐劲特+阿克泰防治早稻"两迁"害虫效果试验", 《广西植保》, no. 20, 15 December 2007 (2007-12-15), pages 56 - 57 * |
| 陆欣: "对应用腐植酸类物质防治作物病虫害的一些看法", 《江西腐植酸》, no. 1, 2 April 1981 (1981-04-02) * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108707038A (en) * | 2018-08-17 | 2018-10-26 | 湖州常华苗木有限公司 | A kind of stock growing special fertilizer and preparation method thereof |
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